CN104918908B - 从甘油制备丙烯醛的方法 - Google Patents

从甘油制备丙烯醛的方法 Download PDF

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Publication number
CN104918908B
CN104918908B CN201380057073.8A CN201380057073A CN104918908B CN 104918908 B CN104918908 B CN 104918908B CN 201380057073 A CN201380057073 A CN 201380057073A CN 104918908 B CN104918908 B CN 104918908B
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CN
China
Prior art keywords
catalyst
glycerol
change
glycerine
acrolein
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201380057073.8A
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English (en)
Chinese (zh)
Other versions
CN104918908A (zh
Inventor
拉贾·兹奈吉
让-马克·米莱
斯特凡·洛里当
帕特里克·雷伊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NATIONAL CENTER FOR SCIENTIFIC RESEARCH
Adisseo France SAS
Universite Claude Bernard Lyon 1
Original Assignee
NATIONAL CENTER FOR SCIENTIFIC RESEARCH
Adisseo France SAS
Universite Claude Bernard Lyon 1
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Filing date
Publication date
Application filed by NATIONAL CENTER FOR SCIENTIFIC RESEARCH, Adisseo France SAS, Universite Claude Bernard Lyon 1 filed Critical NATIONAL CENTER FOR SCIENTIFIC RESEARCH
Publication of CN104918908A publication Critical patent/CN104918908A/zh
Application granted granted Critical
Publication of CN104918908B publication Critical patent/CN104918908B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/132—Halogens; Compounds thereof with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/135—Halogens; Compounds thereof with titanium, zirconium, hafnium, germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/182—Phosphorus; Compounds thereof with silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
    • C07C319/12—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols by reactions not involving the formation of mercapto groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C07C319/18—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by addition of thiols to unsaturated compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN201380057073.8A 2012-10-30 2013-10-29 从甘油制备丙烯醛的方法 Expired - Fee Related CN104918908B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR12/60358 2012-10-30
FR1260358A FR2997398B1 (fr) 2012-10-30 2012-10-30 Procede de preparation de l’acroleine a partir de glycerol
PCT/FR2013/052582 WO2014068241A1 (fr) 2012-10-30 2013-10-29 Procédé de préparation de l'acroléine à partir de glycérol

Publications (2)

Publication Number Publication Date
CN104918908A CN104918908A (zh) 2015-09-16
CN104918908B true CN104918908B (zh) 2017-09-01

Family

ID=47666283

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380057073.8A Expired - Fee Related CN104918908B (zh) 2012-10-30 2013-10-29 从甘油制备丙烯醛的方法

Country Status (13)

Country Link
US (1) US9187395B2 (https=)
EP (1) EP2914569B1 (https=)
JP (1) JP6189965B2 (https=)
KR (1) KR102118501B1 (https=)
CN (1) CN104918908B (https=)
AR (1) AR093255A1 (https=)
BR (1) BR112015009711B1 (https=)
ES (1) ES2644604T3 (https=)
FR (1) FR2997398B1 (https=)
IN (1) IN2015DN03774A (https=)
MY (1) MY169928A (https=)
RU (1) RU2644767C2 (https=)
WO (1) WO2014068241A1 (https=)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102210508B1 (ko) * 2015-12-23 2021-02-01 주식회사 엘지화학 글리세린 탈수 반응용 촉매의 제조 방법 및 아크롤레인의 제조 방법

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007137785A (ja) * 2005-11-15 2007-06-07 Nippon Shokubai Co Ltd 多価アルコールの脱水方法
FR2897058B1 (fr) * 2006-02-07 2008-04-18 Arkema Sa Procede de preparation d'acroleine
DE102007004350A1 (de) * 2007-01-29 2008-07-31 Evonik Degussa Gmbh Verfahren zur Regenerierung eines Katalysators
FR2920767B1 (fr) * 2007-09-06 2009-12-18 Arkema France Procede de vaporisation reactive de glycerol
WO2009127889A1 (en) * 2008-04-16 2009-10-22 Arkema France Process for manufacturing acrolein from glycerol
FR2939791B1 (fr) * 2008-12-16 2011-01-14 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine brute
WO2011033689A1 (en) * 2009-09-18 2011-03-24 Nippon Kayaku Kabushiki Kaisha Catalyst and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin
FR2961507B1 (fr) 2010-06-17 2016-03-04 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine
CN101879456A (zh) * 2010-06-29 2010-11-10 江苏大学 甘油选择性脱水制备丙烯醛的工艺及其催化剂的制备方法

Also Published As

Publication number Publication date
US20150239815A1 (en) 2015-08-27
FR2997398A1 (fr) 2014-05-02
JP6189965B2 (ja) 2017-08-30
ES2644604T3 (es) 2017-11-29
US9187395B2 (en) 2015-11-17
JP2016500695A (ja) 2016-01-14
EP2914569A1 (fr) 2015-09-09
BR112015009711B1 (pt) 2021-02-02
MY169928A (en) 2019-06-17
RU2644767C2 (ru) 2018-02-14
AR093255A1 (es) 2015-05-27
FR2997398B1 (fr) 2014-11-21
EP2914569B1 (fr) 2017-08-30
RU2015120089A (ru) 2016-12-20
IN2015DN03774A (https=) 2015-10-02
KR20150092128A (ko) 2015-08-12
WO2014068241A1 (fr) 2014-05-08
KR102118501B1 (ko) 2020-06-03
CN104918908A (zh) 2015-09-16

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Granted publication date: 20170901