KR101979963B1 - 차단 기능을 갖는 리튬 배터리 분리막 - Google Patents
차단 기능을 갖는 리튬 배터리 분리막 Download PDFInfo
- Publication number
- KR101979963B1 KR101979963B1 KR1020137021632A KR20137021632A KR101979963B1 KR 101979963 B1 KR101979963 B1 KR 101979963B1 KR 1020137021632 A KR1020137021632 A KR 1020137021632A KR 20137021632 A KR20137021632 A KR 20137021632A KR 101979963 B1 KR101979963 B1 KR 101979963B1
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- particles
- separator
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/4235—Safety or regulating additives or arrangements in electrodes, separators or electrolyte
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/411—Organic material
- H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/411—Organic material
- H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
- H01M50/417—Polyolefins
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/44—Fibrous material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/446—Composite material consisting of a mixture of organic and inorganic materials
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/449—Separators, membranes or diaphragms characterised by the material having a layered structure
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/449—Separators, membranes or diaphragms characterised by the material having a layered structure
- H01M50/454—Separators, membranes or diaphragms characterised by the material having a layered structure comprising a non-fibrous layer and a fibrous layer superimposed on one another
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/449—Separators, membranes or diaphragms characterised by the material having a layered structure
- H01M50/457—Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
- H01M50/491—Porosity
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2041—Two or more non-extruded coatings or impregnations
- Y10T442/2123—At least one coating or impregnation contains particulate material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/659—Including an additional nonwoven fabric
- Y10T442/673—Including particulate material other than fiber
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Cell Separators (AREA)
- Secondary Cells (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161434029P | 2011-01-19 | 2011-01-19 | |
| US61/434,029 | 2011-01-19 | ||
| US201161568680P | 2011-12-09 | 2011-12-09 | |
| US61/568,680 | 2011-12-09 | ||
| PCT/US2012/021863 WO2012100049A1 (en) | 2011-01-19 | 2012-01-19 | Lithium battery separator with shutdown function |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20140018877A KR20140018877A (ko) | 2014-02-13 |
| KR101979963B1 true KR101979963B1 (ko) | 2019-05-17 |
Family
ID=45558823
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020137021632A Expired - Fee Related KR101979963B1 (ko) | 2011-01-19 | 2012-01-19 | 차단 기능을 갖는 리튬 배터리 분리막 |
| KR1020137021631A Withdrawn KR20140018876A (ko) | 2011-01-19 | 2012-01-19 | 폐쇄 기능을 가진 리튬 배터리 격리판 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020137021631A Withdrawn KR20140018876A (ko) | 2011-01-19 | 2012-01-19 | 폐쇄 기능을 가진 리튬 배터리 격리판 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US20130022858A1 (enExample) |
| EP (2) | EP2666199B1 (enExample) |
| JP (2) | JP2014505339A (enExample) |
| KR (2) | KR101979963B1 (enExample) |
| CN (2) | CN103329309A (enExample) |
| WO (2) | WO2012100049A1 (enExample) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2004252568B2 (en) * | 2003-06-27 | 2011-06-30 | Ethicon, Incorporated | Regeneration and repair of neural tissue using postpartum-derived cells |
| US9666848B2 (en) | 2011-05-20 | 2017-05-30 | Dreamweaver International, Inc. | Single-layer lithium ion battery separator |
| WO2014073750A1 (ko) * | 2012-11-09 | 2014-05-15 | (주) 파이브레인 | 이차전지용 복합부직포 분리막 및 제조방법 |
| KR101490883B1 (ko) | 2012-12-18 | 2015-02-09 | (주) 파이브레인 | 이차전지용 복합부직포 분리막 및 제조방법 |
| US10700326B2 (en) | 2012-11-14 | 2020-06-30 | Dreamweaver International, Inc. | Single-layer lithium ion battery separators exhibiting low shrinkage rates at high temperatures |
| KR101705304B1 (ko) * | 2012-11-30 | 2017-02-09 | 주식회사 엘지화학 | 세퍼레이터, 그 제조방법 및 이를 구비한 전기화학소자 |
| US10103373B2 (en) * | 2013-01-23 | 2018-10-16 | South China University Of Technology | Diaphragm paper, and preparation method and application thereof |
| US10607790B2 (en) | 2013-03-15 | 2020-03-31 | Dreamweaver International, Inc. | Direct electrolyte gelling via battery separator composition and structure |
| KR101577387B1 (ko) * | 2013-05-06 | 2015-12-16 | 주식회사 엘지화학 | 이차전지, 이를 포함하는 이차전지 모듈 및 이차전지 팩 |
| KR101703957B1 (ko) * | 2013-10-31 | 2017-02-08 | 주식회사 엘지화학 | 유기-무기 복합 다공성 막, 이를 포함하는 세퍼레이터 및 전극 구조체 |
| US9735410B2 (en) * | 2013-11-05 | 2017-08-15 | E I Du Pont De Nemours And Company | Composite separator for electrochemical cell capable of sustained shutdown |
| US9853267B2 (en) | 2014-02-03 | 2017-12-26 | Ursatech Ltd. | Intumescent battery housing |
| WO2015171727A1 (en) * | 2014-05-07 | 2015-11-12 | E. I. Du Pont De Nemours And Company | Polyimide web separator for use in an electrochemical cell |
| WO2015198534A1 (ja) * | 2014-06-27 | 2015-12-30 | 日本ゼオン株式会社 | 非水系二次電池機能層用組成物、非水系二次電池用機能層および非水系二次電池 |
| KR101895100B1 (ko) * | 2014-07-22 | 2018-09-04 | 주식회사 엘지화학 | 분리막 및 그의 제조방법 |
| DE102014219451A1 (de) | 2014-09-25 | 2016-03-31 | Robert Bosch Gmbh | Galvanisches Element |
| US20160164057A1 (en) * | 2014-12-05 | 2016-06-09 | E I Du Pont De Nemours And Company | Electrochemical cell with polyimide separator and high-voltage positive electrode |
| CN104600233A (zh) * | 2015-02-04 | 2015-05-06 | 厦门大学 | 一种热关断复合隔膜及其应用 |
| CN107923051B (zh) * | 2015-04-08 | 2020-07-31 | 耶莱娜·斯托亚迪诺维奇 | 织造或非织造织物 |
| US20170092912A1 (en) * | 2015-09-30 | 2017-03-30 | Sumitomo Chemical Company, Limited | Film production method, battery separator film, nonaqueous electrolyte secondary battery separator, and nonaqueous electrolyte secondary battery |
| JP6288216B2 (ja) | 2016-02-09 | 2018-03-07 | 宇部興産株式会社 | ポリオレフィン微多孔膜、蓄電デバイス用セパレータフィルム、及び蓄電デバイス |
| US20190097265A1 (en) * | 2017-09-26 | 2019-03-28 | University Of South Florida | Phase-change nanoparticles for li-ion battery safety |
| KR102501467B1 (ko) | 2017-11-16 | 2023-02-20 | 삼성전자주식회사 | 복합분리막, 그 제조방법 및 이를 포함하는 이차전지 |
| WO2019122423A1 (en) | 2017-12-21 | 2019-06-27 | Dsm Ip Assets B.V. | Article comprising a substrate and a porous layer comprising polyolefin particles |
| US11424510B2 (en) | 2018-01-17 | 2022-08-23 | Lg Energy Solution, Ltd. | Separator having through-holes sealed by thermoplastic polymer and electrochemical device including the same |
| WO2019204244A1 (en) * | 2018-04-16 | 2019-10-24 | Board Of Regents, The University Of Texas System | Electrochemical devices and methods of making and use thereof |
| JP7133352B2 (ja) * | 2018-05-16 | 2022-09-08 | ロベルト・ボッシュ・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング | 異常検知機能を有するイオン伝導膜 |
| US11493967B2 (en) | 2018-06-01 | 2022-11-08 | Interdigital Madison Patent Holdings, Sas | Thermal shutdown with hysteresis |
| KR20220011154A (ko) * | 2019-05-24 | 2022-01-27 | 셀가드 엘엘씨 | 개선된 코팅된 전지 분리기 및 전지 |
| CN111063852B (zh) * | 2019-09-17 | 2024-10-15 | 宁德时代新能源科技股份有限公司 | 隔离膜、其制备方法、锂离子二次电池及装置 |
| JP7581364B2 (ja) * | 2020-03-27 | 2024-11-12 | 新能源科技有限公司 | 電気化学装置及び当該電気化学装置を含む電子装置 |
| JP2023518890A (ja) * | 2020-03-27 | 2023-05-08 | 新能源科技有限公司 | 電気化学装置 |
| KR102536847B1 (ko) | 2020-11-30 | 2023-05-26 | 컨템포러리 엠퍼렉스 테크놀로지 씨오., 리미티드 | 분리막, 이를 포함하는 이차 전지 및 장치 |
| CN119994388A (zh) * | 2020-11-30 | 2025-05-13 | 宁德时代新能源科技股份有限公司 | 二次电池、电池模块、电池包以及用电装置 |
| EP4109658A4 (en) | 2020-11-30 | 2023-05-31 | Contemporary Amperex Technology Co., Limited | SEPARATOR, METHOD FOR PREPARING IT, AND SECONDARY BATTERY THEREOF, AND BATTERY MODULE, BATTERY PACK, AND DEVICE |
| US20220190325A1 (en) * | 2020-12-16 | 2022-06-16 | Nano And Advanced Materials Institute Limited | Particles in electrospun polymer fibers with thermal response properties |
| CN114142167B (zh) * | 2021-11-30 | 2023-05-02 | 珠海冠宇电池股份有限公司 | 一种隔膜和含有该隔膜的锂离子电池 |
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| JP2007157723A (ja) * | 2005-12-08 | 2007-06-21 | Hitachi Maxell Ltd | 電気化学素子用セパレータおよび電気化学素子 |
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| DE102007042554B4 (de) * | 2007-09-07 | 2017-05-11 | Carl Freudenberg Kg | Vliesstoff mit Partikelfüllung |
| WO2010008003A1 (ja) * | 2008-07-16 | 2010-01-21 | 東レ株式会社 | 蓄電デバイス用セパレータ |
| JP2010036064A (ja) * | 2008-07-31 | 2010-02-18 | Shibaura Mechatronics Corp | 液滴塗布装置及び方法 |
| JP5189459B2 (ja) * | 2008-10-27 | 2013-04-24 | 株式会社クラレ | リチウム電池用セパレータ及びそれを用いたリチウム電池 |
| KR101091228B1 (ko) * | 2008-12-30 | 2011-12-07 | 주식회사 엘지화학 | 다공성 코팅층을 구비한 세퍼레이터 및 이를 구비한 전기화학소자 |
| CN101826606A (zh) * | 2009-03-05 | 2010-09-08 | 丽水学院 | 聚四氟乙烯锂离子电池隔膜及制备方法 |
| KR101055536B1 (ko) * | 2009-04-10 | 2011-08-08 | 주식회사 엘지화학 | 다공성 코팅층을 포함하는 세퍼레이터, 그 제조방법 및 이를 구비한 전기화학소자 |
| DE102009017542A1 (de) * | 2009-04-17 | 2010-10-28 | Carl Freudenberg Kg | Unsymmetrischer Separator |
-
2012
- 2012-01-19 EP EP12701971.9A patent/EP2666199B1/en not_active Not-in-force
- 2012-01-19 US US13/353,468 patent/US20130022858A1/en not_active Abandoned
- 2012-01-19 JP JP2013550581A patent/JP2014505339A/ja active Pending
- 2012-01-19 JP JP2013550578A patent/JP2014506716A/ja active Pending
- 2012-01-19 WO PCT/US2012/021863 patent/WO2012100049A1/en not_active Ceased
- 2012-01-19 KR KR1020137021632A patent/KR101979963B1/ko not_active Expired - Fee Related
- 2012-01-19 CN CN2012800057225A patent/CN103329309A/zh active Pending
- 2012-01-19 EP EP12701972.7A patent/EP2666200A1/en not_active Withdrawn
- 2012-01-19 US US13/353,453 patent/US20130017431A1/en not_active Abandoned
- 2012-01-19 CN CN201280005595.9A patent/CN103329308B/zh not_active Expired - Fee Related
- 2012-01-19 WO PCT/US2012/021883 patent/WO2012100064A1/en not_active Ceased
- 2012-01-19 KR KR1020137021631A patent/KR20140018876A/ko not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007157723A (ja) * | 2005-12-08 | 2007-06-21 | Hitachi Maxell Ltd | 電気化学素子用セパレータおよび電気化学素子 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2012100064A1 (en) | 2012-07-26 |
| US20130022858A1 (en) | 2013-01-24 |
| JP2014505339A (ja) | 2014-02-27 |
| CN103329308B (zh) | 2016-09-14 |
| EP2666199A1 (en) | 2013-11-27 |
| CN103329309A (zh) | 2013-09-25 |
| KR20140018876A (ko) | 2014-02-13 |
| EP2666200A1 (en) | 2013-11-27 |
| US20130017431A1 (en) | 2013-01-17 |
| CN103329308A (zh) | 2013-09-25 |
| EP2666199B1 (en) | 2017-06-21 |
| JP2014506716A (ja) | 2014-03-17 |
| KR20140018877A (ko) | 2014-02-13 |
| WO2012100049A1 (en) | 2012-07-26 |
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