KR101907698B1 - 아세틸화 폴리글리세린 지방산 에스테르 및 이를 이용하여 가소화된 ｐｖｃ 절연물 - Google Patents
아세틸화 폴리글리세린 지방산 에스테르 및 이를 이용하여 가소화된 ｐｖｃ 절연물 Download PDFInfo
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- KR101907698B1 KR101907698B1 KR1020127010839A KR20127010839A KR101907698B1 KR 101907698 B1 KR101907698 B1 KR 101907698B1 KR 1020127010839 A KR1020127010839 A KR 1020127010839A KR 20127010839 A KR20127010839 A KR 20127010839A KR 101907698 B1 KR101907698 B1 KR 101907698B1
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- Prior art keywords
- fatty acid
- plasticizer
- ape
- acetylated
- composition
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- 235000014113 dietary fatty acids Nutrition 0.000 title claims abstract description 120
- 239000000194 fatty acid Substances 0.000 title claims abstract description 120
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- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
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- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims description 6
- 125000005313 fatty acid group Chemical group 0.000 claims 1
- 230000009286 beneficial effect Effects 0.000 abstract description 2
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- JYKSTGLAIMQDRA-UHFFFAOYSA-N tetraglycerol Chemical compound OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO JYKSTGLAIMQDRA-UHFFFAOYSA-N 0.000 description 39
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- KRADHMIOFJQKEZ-UHFFFAOYSA-N Tri-2-ethylhexyl trimellitate Chemical compound CCCCC(CC)COC(=O)C1=CC=C(C(=O)OCC(CC)CCCC)C(C(=O)OCC(CC)CCCC)=C1 KRADHMIOFJQKEZ-UHFFFAOYSA-N 0.000 description 5
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- LVEOKSIILWWVEO-UHFFFAOYSA-N tetradecyl 3-(3-oxo-3-tetradecoxypropyl)sulfanylpropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCC LVEOKSIILWWVEO-UHFFFAOYSA-N 0.000 description 1
- 238000001757 thermogravimetry curve Methods 0.000 description 1
- 229920002397 thermoplastic olefin Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 description 1
- YPDXSCXISVYHOB-UHFFFAOYSA-N tris(7-methyloctyl) benzene-1,2,4-tricarboxylate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCC(C)C)C(C(=O)OCCCCCCC(C)C)=C1 YPDXSCXISVYHOB-UHFFFAOYSA-N 0.000 description 1
- FJFYFBRNDHRTHL-UHFFFAOYSA-N tris(8-methylnonyl) benzene-1,2,4-tricarboxylate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC(C)C)C(C(=O)OCCCCCCCC(C)C)=C1 FJFYFBRNDHRTHL-UHFFFAOYSA-N 0.000 description 1
- 239000012178 vegetable wax Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
- C07C69/675—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids of saturated hydroxy-carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
- C07C69/33—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with hydroxy compounds having more than three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0016—Plasticisers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1515—Three-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
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| US24732909P | 2009-09-30 | 2009-09-30 | |
| US61/247,329 | 2009-09-30 | ||
| PCT/US2010/050664 WO2011041372A1 (en) | 2009-09-30 | 2010-09-29 | Acetylated polyglycerine fatty acid ester and a pvc insulator plasticised therewith |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20120104527A KR20120104527A (ko) | 2012-09-21 |
| KR101907698B1 true KR101907698B1 (ko) | 2018-10-12 |
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| MX (1) | MX2012003940A (enExample) |
| TW (1) | TW201134853A (enExample) |
| WO (1) | WO2011041372A1 (enExample) |
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| BRPI0705621B1 (pt) * | 2007-12-10 | 2019-04-09 | Nexoleum Bioderivados Ltda. | Composição plastificte de pvc |
| CA2715287C (en) | 2008-02-15 | 2016-01-05 | Union Carbide Chemicals & Plastics Technology Llc | A replacement plasticizer system for phthalate-plasticized formulations |
| CN102648237B (zh) | 2009-09-30 | 2015-04-22 | 陶氏环球技术有限责任公司 | 蓖麻油的乙酰基化的衍生物以及它们与环氧化的脂肪酸酯的共混物 |
| WO2011041396A1 (en) | 2009-09-30 | 2011-04-07 | Dow Global Technologies Llc | Heat stabilized polymeric composition with epoxidized fatty acid ester plasticizer |
| US9422418B2 (en) | 2009-09-30 | 2016-08-23 | Dow Global Technologies Llc | Acetylated monoglyceride of 12-hydroxystearic acid and blends with epoxidized fatty acid esters |
| US8552098B2 (en) | 2009-09-30 | 2013-10-08 | Dow Global Technologies Llc | Purified acetylated derivatives of castor oil and compositions including same |
| CA2798296C (en) | 2010-05-10 | 2016-12-13 | Dow Global Technologies Llc | Flexible pvc compositions made with plasticizers derived from renewable sources |
| TW201209168A (en) | 2010-07-28 | 2012-03-01 | Dow Global Technologies Llc | Plasticizers made from oil extracted from microorganisms and polar polymeric compositions comprising the same |
| EP2751182B1 (en) * | 2011-09-30 | 2015-08-26 | Dow Global Technologies LLC | Plasticizer for low temperature unwind with weight retention during heat aging |
| CA2850326C (en) * | 2011-09-30 | 2019-11-12 | Dow Global Technologies Llc | Process for mixing polyvinyl chloride with a bio-based plasticizer |
| CA2861332C (en) * | 2012-02-08 | 2020-05-05 | Manish Mundra | Plasticizer compositions and methods for making plasticizer compositions |
| JP6216374B2 (ja) | 2012-06-22 | 2017-10-18 | ダウ グローバル テクノロジーズ エルエルシー | アセチル化ヒドロキシステアリン酸ポリオール可塑剤および可塑化ポリマー組成物 |
| CN104583292B (zh) | 2012-06-26 | 2017-10-27 | 陶氏环球技术有限责任公司 | 增塑剂和增塑的聚合物组合物 |
| BR112015008187B1 (pt) | 2012-10-18 | 2020-10-06 | Dow Global Technologies Llc. | Processo para fazer um plastificante, composição polimérica e artigo de manufatura |
| KR102017370B1 (ko) | 2012-11-12 | 2019-09-02 | 다우 글로벌 테크놀로지스 엘엘씨 | 에폭시화 지방산 알킬 에스테르 가소제 및 에폭시화 지방산 알킬 에스테르 가소제의 제조 방법 |
| WO2014072986A1 (en) | 2012-11-12 | 2014-05-15 | Dow Global Technologies Llc | Methods for making epoxidized fatty acid alkyl esters |
| CN102964748B (zh) * | 2012-12-20 | 2014-09-10 | 中国林业科学研究院林产化学工业研究所 | 一剂多效的油脂基pvc热稳定剂及其制备方法 |
| CA2896349A1 (en) | 2012-12-29 | 2014-07-03 | Saint-Gobain Performance Plastics Corporation | Flexible tube |
| US9685255B2 (en) * | 2013-03-11 | 2017-06-20 | Dow Global Technologies Llc | Synergistic blends of calcium carbonate and calcined clay |
| CA2904869C (en) * | 2013-03-15 | 2021-02-16 | Dow Global Technologies Llc | Epoxidized-fatty-acid-alkyl-ester plasticizers from natural-oil soap stock and methods for making such epoxidized-fatty-acid-alkyl-ester plasticizers |
| FR3010409B1 (fr) * | 2013-09-11 | 2017-12-22 | Total Marketing Services | Plastifiant pour mastics, plastisols et adhesifs |
| WO2015060126A1 (ja) * | 2013-10-23 | 2015-04-30 | 三菱レイヨン株式会社 | 二次電池電極用樹脂組成物、二次電池電極用溶液または分散液、二次電池電極用スラリー、二次電池用電極および二次電池 |
| KR101586274B1 (ko) * | 2013-11-01 | 2016-01-18 | 주식회사 엘지생활건강 | 식품용 랩 필름 조성물 및 이로부터 제조되는 랩 필름 |
| CN104177649A (zh) * | 2014-08-06 | 2014-12-03 | 河南正通化工有限公司 | 一种聚甘油脂肪酸酯增塑剂及其制备方法 |
| JP6720875B2 (ja) * | 2014-12-17 | 2020-07-08 | 日本ゼオン株式会社 | 塩化ビニル樹脂組成物及びその製造方法、塩化ビニル樹脂成形体及びその製造方法、並びに、積層体 |
| US9856366B2 (en) * | 2015-04-10 | 2018-01-02 | Georgia-Pacific Chemicals Llc | Plastic compositions that include plasticizers containing an acylated phenolated fatty acid ester |
| US10851219B2 (en) | 2015-10-27 | 2020-12-01 | Lg Chem, Ltd. | Plasticizer composition, resin composition, and methods for preparing same |
| WO2020263595A1 (en) | 2019-06-26 | 2020-12-30 | Eastman Chemical Company | Cyclohexane dicarboxylate mixed ester compositions useful as plasticizers |
| CN114008119A (zh) | 2019-06-26 | 2022-02-01 | 伊士曼化工公司 | 二醇醚芳基酯增塑剂 |
| US12163007B2 (en) | 2019-06-26 | 2024-12-10 | Eastman Chemical Company | Non-phthalate plasticizer blends for poly(vinyl chloride) resin compositions |
| EP3990534B1 (en) | 2019-06-26 | 2025-12-10 | Eastman Chemical Company | Mixed ester terephthalate compositions useful as plasticizers |
| WO2021024274A1 (en) * | 2019-08-05 | 2021-02-11 | Fine Organic Industries Limited | A personal care composition |
| CN110885563B (zh) * | 2019-11-01 | 2021-10-22 | 连州市凯恩斯纳米材料有限公司 | 一种pvc环保增塑剂及其制备方法 |
| KR102506279B1 (ko) * | 2020-07-01 | 2023-03-03 | 한화솔루션 주식회사 | 가소제 조성물, 및 이를 포함하는 염화비닐 수지 조성물 |
| JP2022087831A (ja) | 2020-12-01 | 2022-06-13 | サン－ゴバン パフォーマンス プラスティックス コーポレイション | 化学物質移送用途のための多層チューブ |
| CN113637149A (zh) * | 2021-09-01 | 2021-11-12 | 河南正通食品科技有限公司 | 一种乙酰寡聚乳酸单双甘油脂肪酸酯增塑剂及其制备方法 |
| CN113755047B (zh) * | 2021-09-06 | 2022-04-01 | 百草边大生物科技(青岛)有限公司 | 一种应用于儿童读物的含植物成分的大生物水性光油 |
| FR3137835A1 (fr) | 2022-07-15 | 2024-01-19 | L'oreal | Composition pour la coloration des fibres kératineuses |
| CN119570472B (zh) * | 2025-02-07 | 2025-05-27 | 中国石油大学(华东) | 一种降低co2混相压力的酯类气溶性表面活性剂及其制备方法和应用 |
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- 2010-09-29 CN CN201080054103.6A patent/CN102666697B/zh active Active
- 2010-09-29 JP JP2012532259A patent/JP5808330B2/ja active Active
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| JP2002226689A (ja) * | 2001-01-31 | 2002-08-14 | Asahi Kasei Corp | グリコール酸系樹脂組成物 |
| JP2006335874A (ja) | 2005-06-02 | 2006-12-14 | Kao Corp | 生分解性樹脂用可塑剤 |
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| MX2012003940A (es) | 2012-08-03 |
| CN102666697B (zh) | 2015-01-07 |
| WO2011041372A1 (en) | 2011-04-07 |
| JP2013506735A (ja) | 2013-02-28 |
| CA2775574C (en) | 2017-12-12 |
| BR112012007261A2 (pt) | 2020-12-22 |
| CN102666697A (zh) | 2012-09-12 |
| TW201134853A (en) | 2011-10-16 |
| US9481633B2 (en) | 2016-11-01 |
| EP2470596B1 (en) | 2013-07-17 |
| CA2775574A1 (en) | 2011-04-07 |
| EP2470596A1 (en) | 2012-07-04 |
| KR20120104527A (ko) | 2012-09-21 |
| JP5808330B2 (ja) | 2015-11-10 |
| US20120181056A1 (en) | 2012-07-19 |
| BR112012007261B1 (pt) | 2021-08-17 |
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