KR101644349B1 - 실리콘-아크릴 공중합체 - Google Patents
실리콘-아크릴 공중합체 Download PDFInfo
- Publication number
- KR101644349B1 KR101644349B1 KR1020147032339A KR20147032339A KR101644349B1 KR 101644349 B1 KR101644349 B1 KR 101644349B1 KR 1020147032339 A KR1020147032339 A KR 1020147032339A KR 20147032339 A KR20147032339 A KR 20147032339A KR 101644349 B1 KR101644349 B1 KR 101644349B1
- Authority
- KR
- South Korea
- Prior art keywords
- silicone
- acrylic
- polymer
- group
- acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
- C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
- C08F299/08—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/442—Block-or graft-polymers containing polysiloxane sequences containing vinyl polymer sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
- C09J183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K3/1006—Materials in mouldable or extrudable form for sealing or packing joints or covers characterised by the chemical nature of one of its constituents
- C09K3/1018—Macromolecular compounds having one or more carbon-to-silicon linkages
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Sealing Material Composition (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US32714110P | 2010-04-23 | 2010-04-23 | |
| US61/327,141 | 2010-04-23 | ||
| PCT/US2011/032609 WO2011133408A2 (en) | 2010-04-23 | 2011-04-15 | Silicone-acrylic copolymer |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020127029107A Division KR101535847B1 (ko) | 2010-04-23 | 2011-04-15 | 실리콘-아크릴 공중합체 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20140141724A KR20140141724A (ko) | 2014-12-10 |
| KR101644349B1 true KR101644349B1 (ko) | 2016-08-01 |
Family
ID=44834733
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020147032339A Active KR101644349B1 (ko) | 2010-04-23 | 2011-04-15 | 실리콘-아크릴 공중합체 |
| KR1020127029107A Active KR101535847B1 (ko) | 2010-04-23 | 2011-04-15 | 실리콘-아크릴 공중합체 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020127029107A Active KR101535847B1 (ko) | 2010-04-23 | 2011-04-15 | 실리콘-아크릴 공중합체 |
Country Status (8)
| Country | Link |
|---|---|
| US (3) | US8664329B2 (enExample) |
| EP (1) | EP2561008B1 (enExample) |
| JP (1) | JP5826826B2 (enExample) |
| KR (2) | KR101644349B1 (enExample) |
| CN (1) | CN102947370B (enExample) |
| BR (1) | BR112012027110B1 (enExample) |
| RU (1) | RU2570574C2 (enExample) |
| WO (1) | WO2011133408A2 (enExample) |
Families Citing this family (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5609923B2 (ja) * | 2012-06-12 | 2014-10-22 | コニカミノルタ株式会社 | 中間転写体及びそれを有する画像形成装置 |
| CN103045082B (zh) * | 2012-12-16 | 2016-06-29 | 青岛文创科技有限公司 | 一种复合有机硅树脂及其制备方法 |
| US10894904B2 (en) | 2013-04-15 | 2021-01-19 | Nitto Denko Corporation | Pressure-sensitive adhesive sheet and pressure sensitive adhesive composition |
| JP6223836B2 (ja) * | 2013-04-15 | 2017-11-01 | 日東電工株式会社 | 粘着剤組成物および粘着シート |
| EP3004190B1 (en) | 2013-05-30 | 2020-02-12 | Dow Global Technologies LLC | Wood coating composition |
| CN105273667B (zh) * | 2014-06-06 | 2019-02-12 | 上海晶华胶粘新材料股份有限公司 | 耐高温硅丙压敏胶粘剂及其制备方法 |
| CN104263314B (zh) * | 2014-09-23 | 2016-03-02 | 佛山市日丰企业有限公司 | 一种改性硅酮弹性密封胶及其制备方法 |
| US10155902B2 (en) | 2014-09-24 | 2018-12-18 | Halliburton Energy Services, Inc. | Silane additives for improved sand strength and conductivity in fracturing applications |
| US10020185B2 (en) | 2014-10-07 | 2018-07-10 | Samsung Sdi Co., Ltd. | Composition for forming silica layer, silica layer, and electronic device |
| EP3034573A1 (en) | 2014-12-16 | 2016-06-22 | ALLNEX AUSTRIA GmbH | Flow modifier for coating compositions |
| KR101837971B1 (ko) | 2014-12-19 | 2018-03-13 | 삼성에스디아이 주식회사 | 실리카계 막 형성용 조성물, 실리카계 막, 및 전자 디바이스 |
| KR101833800B1 (ko) | 2014-12-19 | 2018-03-02 | 삼성에스디아이 주식회사 | 실리카계 막 형성용 조성물, 실리카계 막의 제조방법 및 상기 실리카계 막을 포함하는 전자 소자 |
| CN104531048B (zh) * | 2014-12-30 | 2016-08-24 | 南京信息工程大学 | 一种有机导电胶合剂及其制备方法 |
| WO2016130408A1 (en) * | 2015-02-09 | 2016-08-18 | Dow Corning Corporation | Multi-phase silicone acrylic hybrid visco-elastic compositions and methods of making same |
| KR20170014946A (ko) | 2015-07-31 | 2017-02-08 | 삼성에스디아이 주식회사 | 실리카 막 형성용 조성물, 실리카 막의 제조방법 및 실리카 막 |
| KR20170050078A (ko) * | 2015-10-29 | 2017-05-11 | 주식회사 엘지화학 | 리튬-황 이차전지 양극용 아크릴 바인더 |
| EP3275918A1 (en) * | 2016-07-27 | 2018-01-31 | Clariant Plastics & Coatings Ltd | Compositions comprising polyacrylate-polysilane block copolymers |
| EP3275909A1 (en) * | 2016-07-27 | 2018-01-31 | Clariant Plastics & Coatings Ltd | Novel polyacrylate-polysilane block copolymers |
| WO2018061991A1 (ja) | 2016-09-27 | 2018-04-05 | 富士フイルム株式会社 | 音響波プローブ用樹脂材料、音響レンズ、音響波プローブ、音響波測定装置、超音波診断装置、光音響波測定装置および超音波内視鏡 |
| FR3058153B1 (fr) * | 2016-10-28 | 2018-11-16 | Bostik Sa | Composition auto-adhesive pour le collage de substrats de basse energie de surface |
| CN106977666A (zh) * | 2017-04-27 | 2017-07-25 | 重庆三峡油漆股份有限公司 | 涂料用硝基纤维素替代物及其制备方法 |
| TWI782066B (zh) | 2017-08-03 | 2022-11-01 | 德商漢高股份有限及兩合公司 | 可固化的聚矽氧光學透明黏著劑及其用途 |
| US10738213B2 (en) | 2017-10-17 | 2020-08-11 | Ppg Industries Ohio, Inc. | Modified silicone coating composition |
| KR20200100610A (ko) | 2017-12-27 | 2020-08-26 | 헨켈 아이피 앤드 홀딩 게엠베하 | 광학적으로 투명한 감압성 접착제 및 그의 용도 |
| TWI846695B (zh) * | 2018-05-16 | 2024-07-01 | 德商漢高股份有限及兩合公司 | 製造聚矽氧-丙烯酸混合型壓敏性黏著劑組合物之一鍋製程 |
| KR102290643B1 (ko) | 2018-07-27 | 2021-08-17 | 주식회사 엘지화학 | 점착제 조성물, 이를 포함하는 점착 필름, 점착 필름을 포함하는 백플레이트 필름 및 점착 필름을 포함하는 플라스틱 유기 발광 디스플레이 |
| KR102290640B1 (ko) | 2018-07-27 | 2021-08-17 | 주식회사 엘지화학 | 점착제 조성물, 이를 포함하는 점착 필름, 점착 필름을 포함하는 백플레이트 필름 및 점착 필름을 포함하는 플라스틱 유기 발광 디스플레이 |
| KR102290629B1 (ko) | 2018-07-27 | 2021-08-17 | 주식회사 엘지화학 | 점착제 조성물, 이를 포함하는 점착 필름, 점착 필름을 포함하는 백플레이트 필름 및 점착 필름을 포함하는 플라스틱 유기 발광 디스플레이 |
| KR102293550B1 (ko) | 2018-07-27 | 2021-08-24 | 주식회사 엘지화학 | 점착제 조성물, 이를 포함하는 점착 필름, 점착 필름을 포함하는 백플레이트 필름 및 점착 필름을 포함하는 플라스틱 유기 발광 디스플레이 |
| KR102293549B1 (ko) | 2018-07-27 | 2021-08-24 | 주식회사 엘지화학 | 점착제 조성물, 이를 포함하는 점착 필름, 점착 필름을 포함하는 백플레이트 필름 및 점착 필름을 포함하는 플라스틱 유기 발광 디스플레이 |
| KR102293551B1 (ko) | 2018-07-27 | 2021-08-24 | 주식회사 엘지화학 | 점착제 조성물, 이를 포함하는 점착 필름, 점착 필름을 포함하는 백플레이트 필름 및 점착 필름을 포함하는 플라스틱 유기 발광 디스플레이 |
| KR102290639B1 (ko) | 2018-07-27 | 2021-08-17 | 주식회사 엘지화학 | 점착제 조성물, 이를 포함하는 점착 필름, 점착 필름을 포함하는 백플레이트 필름 및 점착 필름을 포함하는 플라스틱 유기 발광 디스플레이 |
| KR102293935B1 (ko) | 2018-07-27 | 2021-08-24 | 주식회사 엘지화학 | 점착제 조성물, 이를 포함하는 점착 필름, 점착 필름을 포함하는 백플레이트 필름 및 점착 필름을 포함하는 플라스틱 유기 발광 디스플레이 |
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| KR102303792B1 (ko) * | 2018-11-28 | 2021-09-23 | 주식회사 엘지화학 | 아크릴계 점착 조성물 및 이를 이용한 페인트 보호용 필름 |
| CN113272362B (zh) | 2018-12-21 | 2022-06-17 | 美国陶氏有机硅公司 | 硅酮-聚酯共聚物、包括硅酮-聚酯共聚物的密封剂和相关方法 |
| CA3122280A1 (en) * | 2018-12-21 | 2020-06-25 | Dow Silicones Corporation | Silicone-polyacrylate copolymer, sealants comprising same, and related methods |
| US11760841B2 (en) | 2018-12-21 | 2023-09-19 | Dow Silicones Corporation | Silicone-polycarbonate copolymer, sealants comprising same, and related methods |
| WO2020131708A2 (en) * | 2018-12-21 | 2020-06-25 | Dow Silicones Corporation | Silicone-organic copolymer, sealants comprising same, and related methods |
| WO2020186127A1 (en) * | 2019-03-14 | 2020-09-17 | Dow Silicones Corporation | Polyorganosiloxane having poly(meth)acrylate groups and methods for the preparation and use thereof |
| US11517518B2 (en) * | 2019-07-25 | 2022-12-06 | L'oréal | Two-step long-wear cosmetic system |
| MX2022002388A (es) | 2019-09-09 | 2022-03-17 | Dow Global Technologies Llc | Dispersion acuosa de particulas polimericas. |
| TWI707009B (zh) * | 2019-11-11 | 2020-10-11 | 長興材料工業股份有限公司 | 水性有機無機複合樹脂、含彼之塗料組合物 |
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| WO2023141959A1 (en) * | 2022-01-28 | 2023-08-03 | Henkel Ag & Co. Kgaa | Two-component silicone-based coating composition, coating method using the same and article thereof |
| JP2024005577A (ja) * | 2022-06-30 | 2024-01-17 | Dic株式会社 | 樹脂組成物、塗料、及び物品 |
| CN115477900B (zh) * | 2022-10-18 | 2023-06-30 | 深圳市高仁电子新材料有限公司 | 一种三层结构的丙烯酸类光学胶及其制备方法 |
| CN117285879B (zh) * | 2023-11-24 | 2024-02-27 | 江苏凯伦建材股份有限公司 | 一种预铺防水卷材及其制备方法 |
| CN118725800B (zh) * | 2024-06-12 | 2025-03-25 | 广东弘擎电子材料科技有限公司 | 一种液晶显示屏保护膜及其制备方法和应用 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001115376A (ja) | 1999-10-04 | 2001-04-24 | Nisshin Chem Ind Co Ltd | ガラス繊維用集束剤 |
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2011
- 2011-04-15 JP JP2013506189A patent/JP5826826B2/ja active Active
- 2011-04-15 CN CN201180030690.XA patent/CN102947370B/zh active Active
- 2011-04-15 EP EP11772467.4A patent/EP2561008B1/en active Active
- 2011-04-15 WO PCT/US2011/032609 patent/WO2011133408A2/en not_active Ceased
- 2011-04-15 KR KR1020147032339A patent/KR101644349B1/ko active Active
- 2011-04-15 KR KR1020127029107A patent/KR101535847B1/ko active Active
- 2011-04-15 RU RU2012149840/04A patent/RU2570574C2/ru not_active IP Right Cessation
- 2011-04-15 BR BR112012027110-5A patent/BR112012027110B1/pt not_active IP Right Cessation
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| JP2001115376A (ja) | 1999-10-04 | 2001-04-24 | Nisshin Chem Ind Co Ltd | ガラス繊維用集束剤 |
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|---|---|
| WO2011133408A3 (en) | 2012-02-16 |
| JP2013525543A (ja) | 2013-06-20 |
| RU2012149840A (ru) | 2014-05-27 |
| US20140128539A1 (en) | 2014-05-08 |
| US20150119536A1 (en) | 2015-04-30 |
| KR101535847B1 (ko) | 2015-07-13 |
| JP5826826B2 (ja) | 2015-12-02 |
| RU2570574C2 (ru) | 2015-12-10 |
| KR20140141724A (ko) | 2014-12-10 |
| EP2561008A4 (en) | 2013-11-06 |
| CN102947370B (zh) | 2016-05-11 |
| CN102947370A (zh) | 2013-02-27 |
| KR20130064066A (ko) | 2013-06-17 |
| WO2011133408A2 (en) | 2011-10-27 |
| EP2561008B1 (en) | 2018-02-28 |
| US8664329B2 (en) | 2014-03-04 |
| BR112012027110B1 (pt) | 2020-05-12 |
| EP2561008A2 (en) | 2013-02-27 |
| BR112012027110A2 (pt) | 2016-07-26 |
| US20130012653A1 (en) | 2013-01-10 |
| WO2011133408A4 (en) | 2012-04-12 |
| US8962748B2 (en) | 2015-02-24 |
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