KR101093477B1 - 스티렌을 중합시키기 위한 퍼옥사이드 투여 공정을포함하는 현탁 방법 - Google Patents
스티렌을 중합시키기 위한 퍼옥사이드 투여 공정을포함하는 현탁 방법 Download PDFInfo
- Publication number
- KR101093477B1 KR101093477B1 KR1020057019422A KR20057019422A KR101093477B1 KR 101093477 B1 KR101093477 B1 KR 101093477B1 KR 1020057019422 A KR1020057019422 A KR 1020057019422A KR 20057019422 A KR20057019422 A KR 20057019422A KR 101093477 B1 KR101093477 B1 KR 101093477B1
- Authority
- KR
- South Korea
- Prior art keywords
- initiator
- polymerization
- initiators
- monomer
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/18—Suspension polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
- C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
- C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03076088.8 | 2003-04-14 | ||
| EP03076088 | 2003-04-14 | ||
| US47196303P | 2003-05-20 | 2003-05-20 | |
| US60/471,963 | 2003-05-20 | ||
| US53022203P | 2003-12-17 | 2003-12-17 | |
| US60/530,222 | 2003-12-17 | ||
| PCT/EP2004/003661 WO2004089999A2 (en) | 2003-04-14 | 2004-04-02 | Dosing of peroxide to a suspension process wherein styrene is polymerized |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20060012583A KR20060012583A (ko) | 2006-02-08 |
| KR101093477B1 true KR101093477B1 (ko) | 2011-12-13 |
Family
ID=33162639
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020057019422A Expired - Fee Related KR101093477B1 (ko) | 2003-04-14 | 2004-04-02 | 스티렌을 중합시키기 위한 퍼옥사이드 투여 공정을포함하는 현탁 방법 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US7132485B2 (https=) |
| EP (1) | EP1613672B1 (https=) |
| JP (1) | JP4524279B2 (https=) |
| KR (1) | KR101093477B1 (https=) |
| CN (1) | CN100439406C (https=) |
| AR (1) | AR043865A1 (https=) |
| BR (1) | BRPI0409446B1 (https=) |
| CL (1) | CL2004000789A1 (https=) |
| MX (1) | MXPA05011015A (https=) |
| PL (1) | PL1613672T3 (https=) |
| TW (1) | TWI343924B (https=) |
| WO (1) | WO2004089999A2 (https=) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2879207B1 (fr) * | 2004-12-10 | 2007-07-06 | Commissariat Energie Atomique | Procede et dispositif de fabrication de billes ou de ballons en mousse polymere |
| US20100240782A1 (en) * | 2007-11-20 | 2010-09-23 | Akzo Nobel N.V. | Process for preparing styrene-based (co)polymers |
| US8815971B2 (en) * | 2008-12-22 | 2014-08-26 | ATRP Solutions, Inc. | Control over controlled radical polymerization processes |
| US8822610B2 (en) * | 2008-12-22 | 2014-09-02 | ATRP Solutions, Inc. | Control over controlled radical polymerization processes |
| SA110310245B1 (ar) | 2009-04-03 | 2014-11-12 | اكزو نوبل كيميكا | معلق بيروكسيد ثنائي آسيل صلب مائي |
| FR2948375B1 (fr) * | 2009-07-27 | 2011-12-30 | Arkema France | Procede de preparation de polystyrene expansible par injection en continu d'un peroxyde organique liquide |
| AU2010329986B2 (en) * | 2009-12-10 | 2014-12-04 | Akzo Nobel Chemicals International B.V. | Process for the polymerization of styrene |
| CN102603929B (zh) * | 2012-02-29 | 2014-10-29 | 无锡知益微球科技有限公司 | 一种高分子颗粒的制备方法 |
| KR101336251B1 (ko) * | 2012-08-29 | 2013-12-03 | 포항공과대학교 산학협력단 | 스티렌 단량체를 이용한 전기 방사된 폴리스티렌 나노 섬유의 제조 방법 및 폴리스티렌-양자점 하이브리드 나노섬유의 제조 방법 |
| CN102875734B (zh) * | 2012-09-29 | 2014-08-06 | 东莞新长桥塑料有限公司 | 回收级可发性聚苯乙烯以及利用种子聚合法制备回收级可发性聚苯乙烯的方法 |
| CN102863569B (zh) * | 2012-09-29 | 2014-05-14 | 东莞新长桥塑料有限公司 | 低挥发性有机物含量的阻燃型可发性聚苯乙烯树脂及其制备方法 |
| KR102156109B1 (ko) * | 2017-09-29 | 2020-09-15 | 주식회사 엘지화학 | 탄소섬유 제조용 아크릴로니트릴계 중합체의 제조방법 |
| US20240150504A1 (en) * | 2022-01-17 | 2024-05-09 | Lg Chem, Ltd. | Method of preparing polymer |
| KR102942737B1 (ko) | 2022-01-17 | 2026-03-23 | 주식회사 엘지화학 | 중합체의 제조방법 |
| CN117043204A (zh) * | 2022-01-17 | 2023-11-10 | 株式会社Lg化学 | 制备聚合物的方法 |
| WO2025186291A1 (en) | 2024-03-08 | 2025-09-12 | Nouryon Chemicals International B.V. | Process for recycling polystyrene |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5189069A (en) | 1990-09-15 | 1993-02-23 | Huels Aktiengesellschaft | Process for controlling the particle size in the preparation of expandable styrene polymers by suspension polymerization |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3451985A (en) | 1964-03-26 | 1969-06-24 | Monsanto Co | Method of polymerizing vinyl monomers |
| US4173688A (en) | 1973-07-23 | 1979-11-06 | Sekisui Kagaku Kogyo Kabushiki Kaisha | Process for preparing styrenic polymer foams |
| FR2238718A1 (en) | 1973-07-27 | 1975-02-21 | Sekisui Chemical Co Ltd | Polystyrene particles of uniform size, esp. for foams - by polymerising in suspension of fine polystyrene particles, contg. catalyst and polymn retarder |
| ZA818026B (en) * | 1980-11-26 | 1982-10-27 | Cellofoam Ag | Method of making uniformly-sized expandable polymeric particles |
| US4363881A (en) * | 1980-11-26 | 1982-12-14 | Cellofoam A.G. | Method of making uniformly-sized expandable polymeric particles |
| JPS6047037A (ja) * | 1983-08-24 | 1985-03-14 | Hitachi Chem Co Ltd | 発泡性スチレン系樹脂粒子の製造法 |
| EP0234705A3 (en) * | 1986-01-23 | 1989-01-25 | Mitsubishi Yuka Badische Co., Ltd. | Process for producing expandable polystyrene beads |
| JP2684400B2 (ja) * | 1989-01-09 | 1997-12-03 | 出光石油化学株式会社 | スチレン系重合体及びその製造方法 |
| JPH02255708A (ja) | 1989-03-30 | 1990-10-16 | Idemitsu Petrochem Co Ltd | スチレン系重合体の製造方法 |
| GB9020579D0 (en) * | 1990-09-20 | 1990-10-31 | Shell Int Research | Process for manufacture of poly(vinyl substituted aromatic)compounds and epdm rubber containing polymer compositions |
| JP2933707B2 (ja) | 1990-11-21 | 1999-08-16 | 鐘淵化学工業株式会社 | 発泡性スチレン系重合体粒子の製造方法 |
| EP0492712A1 (en) | 1990-12-24 | 1992-07-01 | Akzo Nobel N.V. | Peroxide compositions with ethoxylated water-soluble polymers |
| JP3054014B2 (ja) * | 1993-12-27 | 2000-06-19 | 積水化成品工業株式会社 | 発泡性スチレン系重合体粒子の製造方法 |
| DE19530765A1 (de) | 1995-08-22 | 1997-02-27 | Basf Ag | Kontinuierliches Verfahren zur Herstellung von expandierbaren Styrolpolymerisaten |
| JPH1017698A (ja) * | 1996-07-04 | 1998-01-20 | Shell Japan Kk | 発泡性スチレン系樹脂粒子 |
| GB9721603D0 (en) | 1997-10-10 | 1997-12-10 | Dyno Ind Asa | Method |
| WO1999054391A1 (en) * | 1998-04-17 | 1999-10-28 | Nova Chemicals (International) S.A. | Process for the preparation of expandable polymer particles |
| ID29411A (id) | 1998-09-21 | 2001-08-30 | Akzo Nobel Nv | Pengukuran kontinyu dari pemulai yang sangat cepat selama reaksi polimerisasi |
| DE19911960A1 (de) | 1999-03-17 | 2000-09-21 | Basf Ag | Verfahren zur Herstellung von Stilben/Styrol-Copolymeren |
| US6984702B2 (en) | 2000-03-22 | 2006-01-10 | Dynal Biotech Asa | Process for the preparation of functionalized polymer particles |
| DE10039388A1 (de) | 2000-08-11 | 2002-02-21 | Basf Ag | Stärkehaltige Polymerdispersionen |
-
2004
- 2004-04-02 WO PCT/EP2004/003661 patent/WO2004089999A2/en not_active Ceased
- 2004-04-02 PL PL04725375T patent/PL1613672T3/pl unknown
- 2004-04-02 BR BRPI0409446A patent/BRPI0409446B1/pt not_active IP Right Cessation
- 2004-04-02 JP JP2006505020A patent/JP4524279B2/ja not_active Expired - Fee Related
- 2004-04-02 MX MXPA05011015A patent/MXPA05011015A/es active IP Right Grant
- 2004-04-02 EP EP04725375.2A patent/EP1613672B1/en not_active Expired - Lifetime
- 2004-04-02 KR KR1020057019422A patent/KR101093477B1/ko not_active Expired - Fee Related
- 2004-04-02 CN CNB2004800129074A patent/CN100439406C/zh not_active Expired - Fee Related
- 2004-04-02 US US10/552,437 patent/US7132485B2/en not_active Expired - Lifetime
- 2004-04-13 CL CL200400789A patent/CL2004000789A1/es unknown
- 2004-04-13 AR ARP040101243A patent/AR043865A1/es unknown
- 2004-04-14 TW TW093110312A patent/TWI343924B/zh not_active IP Right Cessation
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5189069A (en) | 1990-09-15 | 1993-02-23 | Huels Aktiengesellschaft | Process for controlling the particle size in the preparation of expandable styrene polymers by suspension polymerization |
Also Published As
| Publication number | Publication date |
|---|---|
| AR043865A1 (es) | 2005-08-17 |
| CN100439406C (zh) | 2008-12-03 |
| PL1613672T3 (pl) | 2019-12-31 |
| US20060111529A1 (en) | 2006-05-25 |
| WO2004089999A3 (en) | 2005-01-06 |
| CL2004000789A1 (es) | 2005-01-21 |
| MXPA05011015A (es) | 2005-12-12 |
| EP1613672B1 (en) | 2019-06-12 |
| TW200508258A (en) | 2005-03-01 |
| BRPI0409446A (pt) | 2006-04-18 |
| TWI343924B (en) | 2011-06-21 |
| JP2006522844A (ja) | 2006-10-05 |
| US7132485B2 (en) | 2006-11-07 |
| EP1613672A2 (en) | 2006-01-11 |
| KR20060012583A (ko) | 2006-02-08 |
| CN1788025A (zh) | 2006-06-14 |
| WO2004089999A2 (en) | 2004-10-21 |
| JP4524279B2 (ja) | 2010-08-11 |
| BRPI0409446B1 (pt) | 2016-06-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101093477B1 (ko) | 스티렌을 중합시키기 위한 퍼옥사이드 투여 공정을포함하는 현탁 방법 | |
| AU2010329986B2 (en) | Process for the polymerization of styrene | |
| KR100603684B1 (ko) | 중합 반응시 매우 빠른 개시제의 연속 주입 방법 | |
| KR0138974B1 (ko) | 비드형 팽윤성 스티렌 중합체의 제조방법 | |
| EP1408056B2 (en) | Preparation of expandable styrene polymers | |
| KR100965925B1 (ko) | 중합 반응 중에 유기 개시제와 보호 콜로이드를 동시정량하는 방법 | |
| AU2002361137B2 (en) | Addition of organic initiators during the pressure drop in vinyl chloride monomer polymerization reactions | |
| KR20100090287A (ko) | 스티렌계 (코)폴리머의 제조 방법 | |
| RU2360929C2 (ru) | Дозирование пероксида в суспензионном способе, по которому полимеризуют стирол | |
| EP1375529A1 (en) | Addition of organic initiators during a pressure drop in vinyl chloride monomer polymerization reactions | |
| JPS6342921B2 (https=) | ||
| JP2002114813A (ja) | スチレン系重合体の製造方法 | |
| JPH02240110A (ja) | ビニル単量体用重合開始剤 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0105 | International application |
St.27 status event code: A-0-1-A10-A15-nap-PA0105 |
|
| R17-X000 | Change to representative recorded |
St.27 status event code: A-3-3-R10-R17-oth-X000 |
|
| PG1501 | Laying open of application |
St.27 status event code: A-1-1-Q10-Q12-nap-PG1501 |
|
| P11-X000 | Amendment of application requested |
St.27 status event code: A-2-2-P10-P11-nap-X000 |
|
| P13-X000 | Application amended |
St.27 status event code: A-2-2-P10-P13-nap-X000 |
|
| R17-X000 | Change to representative recorded |
St.27 status event code: A-3-3-R10-R17-oth-X000 |
|
| R17-X000 | Change to representative recorded |
St.27 status event code: A-3-3-R10-R17-oth-X000 |
|
| A201 | Request for examination | ||
| P11-X000 | Amendment of application requested |
St.27 status event code: A-2-2-P10-P11-nap-X000 |
|
| P13-X000 | Application amended |
St.27 status event code: A-2-2-P10-P13-nap-X000 |
|
| PA0201 | Request for examination |
St.27 status event code: A-1-2-D10-D11-exm-PA0201 |
|
| R17-X000 | Change to representative recorded |
St.27 status event code: A-3-3-R10-R17-oth-X000 |
|
| E902 | Notification of reason for refusal | ||
| PE0902 | Notice of grounds for rejection |
St.27 status event code: A-1-2-D10-D21-exm-PE0902 |
|
| E13-X000 | Pre-grant limitation requested |
St.27 status event code: A-2-3-E10-E13-lim-X000 |
|
| P11-X000 | Amendment of application requested |
St.27 status event code: A-2-2-P10-P11-nap-X000 |
|
| P13-X000 | Application amended |
St.27 status event code: A-2-2-P10-P13-nap-X000 |
|
| E701 | Decision to grant or registration of patent right | ||
| PE0701 | Decision of registration |
St.27 status event code: A-1-2-D10-D22-exm-PE0701 |
|
| GRNT | Written decision to grant | ||
| PR0701 | Registration of establishment |
St.27 status event code: A-2-4-F10-F11-exm-PR0701 |
|
| PR1002 | Payment of registration fee |
St.27 status event code: A-2-2-U10-U12-oth-PR1002 Fee payment year number: 1 |
|
| PG1601 | Publication of registration |
St.27 status event code: A-4-4-Q10-Q13-nap-PG1601 |
|
| FPAY | Annual fee payment |
Payment date: 20141124 Year of fee payment: 4 |
|
| PR1001 | Payment of annual fee |
St.27 status event code: A-4-4-U10-U11-oth-PR1001 Fee payment year number: 4 |
|
| FPAY | Annual fee payment |
Payment date: 20151124 Year of fee payment: 5 |
|
| PR1001 | Payment of annual fee |
St.27 status event code: A-4-4-U10-U11-oth-PR1001 Fee payment year number: 5 |
|
| FPAY | Annual fee payment |
Payment date: 20161124 Year of fee payment: 6 |
|
| PR1001 | Payment of annual fee |
St.27 status event code: A-4-4-U10-U11-oth-PR1001 Fee payment year number: 6 |
|
| FPAY | Annual fee payment |
Payment date: 20171129 Year of fee payment: 7 |
|
| PR1001 | Payment of annual fee |
St.27 status event code: A-4-4-U10-U11-oth-PR1001 Fee payment year number: 7 |
|
| PN2301 | Change of applicant |
St.27 status event code: A-5-5-R10-R11-asn-PN2301 |
|
| PN2301 | Change of applicant |
St.27 status event code: A-5-5-R10-R14-asn-PN2301 |
|
| FPAY | Annual fee payment |
Payment date: 20181123 Year of fee payment: 8 |
|
| PR1001 | Payment of annual fee |
St.27 status event code: A-4-4-U10-U11-oth-PR1001 Fee payment year number: 8 |
|
| FPAY | Annual fee payment |
Payment date: 20191127 Year of fee payment: 9 |
|
| PR1001 | Payment of annual fee |
St.27 status event code: A-4-4-U10-U11-oth-PR1001 Fee payment year number: 9 |
|
| PN2301 | Change of applicant |
St.27 status event code: A-5-5-R10-R13-asn-PN2301 St.27 status event code: A-5-5-R10-R11-asn-PN2301 |
|
| PC1903 | Unpaid annual fee |
St.27 status event code: A-4-4-U10-U13-oth-PC1903 Not in force date: 20201208 Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE |
|
| PC1903 | Unpaid annual fee |
St.27 status event code: N-4-6-H10-H13-oth-PC1903 Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE Not in force date: 20201208 |