KR100815101B1 - 올레핀의 중합반응용 예비중합된 촉매 성분 - Google Patents
올레핀의 중합반응용 예비중합된 촉매 성분 Download PDFInfo
- Publication number
- KR100815101B1 KR100815101B1 KR1020027000347A KR20027000347A KR100815101B1 KR 100815101 B1 KR100815101 B1 KR 100815101B1 KR 1020027000347 A KR1020027000347 A KR 1020027000347A KR 20027000347 A KR20027000347 A KR 20027000347A KR 100815101 B1 KR100815101 B1 KR 100815101B1
- Authority
- KR
- South Korea
- Prior art keywords
- catalyst component
- prepolymerized
- polymerization
- catalyst
- olefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 102
- 238000006116 polymerization reaction Methods 0.000 title claims description 56
- 150000001336 alkenes Chemical class 0.000 title claims description 11
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims description 7
- 239000011949 solid catalyst Substances 0.000 claims abstract description 21
- 150000003609 titanium compounds Chemical class 0.000 claims abstract description 19
- 239000004711 α-olefin Substances 0.000 claims abstract description 15
- 239000011777 magnesium Substances 0.000 claims abstract description 13
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 11
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims abstract description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 42
- 239000005977 Ethylene Substances 0.000 claims description 41
- 239000010936 titanium Substances 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 29
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 23
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 23
- 238000006243 chemical reaction Methods 0.000 claims description 20
- 229910052719 titanium Inorganic materials 0.000 claims description 19
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 15
- 150000001875 compounds Chemical class 0.000 claims description 15
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 13
- 150000002430 hydrocarbons Chemical group 0.000 claims description 10
- 229930195733 hydrocarbon Natural products 0.000 claims description 9
- 239000004215 Carbon black (E152) Substances 0.000 claims description 7
- 229910052736 halogen Inorganic materials 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 150000002367 halogens Chemical class 0.000 claims description 5
- 239000011148 porous material Substances 0.000 claims description 5
- 230000000707 stereoselective effect Effects 0.000 claims description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 4
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 claims description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 2
- XWJMQJGSSGDJSY-UHFFFAOYSA-N 4-methyloct-1-ene Chemical compound CCCCC(C)CC=C XWJMQJGSSGDJSY-UHFFFAOYSA-N 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 abstract description 30
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract description 8
- 239000010419 fine particle Substances 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000009257 reactivity Effects 0.000 abstract description 3
- 229920001038 ethylene copolymer Polymers 0.000 abstract description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 80
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 20
- -1 titanium halide alkoxides Chemical class 0.000 description 20
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 14
- 239000000047 product Substances 0.000 description 14
- 238000002360 preparation method Methods 0.000 description 13
- 230000000694 effects Effects 0.000 description 11
- 238000003756 stirring Methods 0.000 description 11
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 10
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 10
- 239000000460 chlorine Substances 0.000 description 9
- 229920001903 high density polyethylene Polymers 0.000 description 9
- 239000004700 high-density polyethylene Substances 0.000 description 9
- 239000007788 liquid Substances 0.000 description 9
- 238000011282 treatment Methods 0.000 description 9
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 229910001220 stainless steel Inorganic materials 0.000 description 8
- 239000010935 stainless steel Substances 0.000 description 8
- 229910052801 chlorine Inorganic materials 0.000 description 6
- 239000007791 liquid phase Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000008096 xylene Substances 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 239000003153 chemical reaction reagent Substances 0.000 description 5
- 238000007429 general method Methods 0.000 description 5
- 235000011147 magnesium chloride Nutrition 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 229920001384 propylene homopolymer Polymers 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000012798 spherical particle Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- XZIKSWMNFLIAQP-UHFFFAOYSA-N tris(2,4,4-trimethylpentyl)alumane Chemical compound CC(C)(C)CC(C)C[Al](CC(C)CC(C)(C)C)CC(C)CC(C)(C)C XZIKSWMNFLIAQP-UHFFFAOYSA-N 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000012685 gas phase polymerization Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000007790 solid phase Substances 0.000 description 3
- 238000004438 BET method Methods 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 229910003902 SiCl 4 Inorganic materials 0.000 description 2
- 125000005234 alkyl aluminium group Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 150000008282 halocarbons Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 2
- 230000000415 inactivating effect Effects 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000004707 linear low-density polyethylene Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000000877 morphologic effect Effects 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 2
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 2
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 2
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 2
- 229920001866 very low density polyethylene Polymers 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- 239000005046 Chlorosilane Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004708 Very-low-density polyethylene Substances 0.000 description 1
- 238000002083 X-ray spectrum Methods 0.000 description 1
- 238000006653 Ziegler-Natta catalysis Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 150000005840 aryl radicals Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical class Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229940078552 o-xylene Drugs 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
- C08F4/6491—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon
- C08F4/6492—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon containing aliphatic unsaturation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
- C08F4/6555—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof and magnesium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/656—Pretreating with metals or metal-containing compounds with silicon or compounds thereof
- C08F4/6567—Pretreating with metals or metal-containing compounds with silicon or compounds thereof and aluminium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00201702.8 | 2000-05-12 | ||
| EP00201702 | 2000-05-12 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20020025952A KR20020025952A (ko) | 2002-04-04 |
| KR100815101B1 true KR100815101B1 (ko) | 2008-03-20 |
Family
ID=8171489
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020027000347A Expired - Lifetime KR100815101B1 (ko) | 2000-05-12 | 2001-05-07 | 올레핀의 중합반응용 예비중합된 촉매 성분 |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US7223711B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP1268583B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP5122054B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR100815101B1 (cg-RX-API-DMAC7.html) |
| CN (1) | CN1210319C (cg-RX-API-DMAC7.html) |
| AT (1) | ATE440871T1 (cg-RX-API-DMAC7.html) |
| AU (1) | AU782724B2 (cg-RX-API-DMAC7.html) |
| BR (1) | BR0106426B1 (cg-RX-API-DMAC7.html) |
| CA (1) | CA2379053A1 (cg-RX-API-DMAC7.html) |
| DE (1) | DE60139676D1 (cg-RX-API-DMAC7.html) |
| ES (1) | ES2330192T3 (cg-RX-API-DMAC7.html) |
| HU (1) | HUP0203867A3 (cg-RX-API-DMAC7.html) |
| MX (1) | MXPA02000435A (cg-RX-API-DMAC7.html) |
| PL (1) | PL201765B1 (cg-RX-API-DMAC7.html) |
| RU (1) | RU2278124C2 (cg-RX-API-DMAC7.html) |
| TW (1) | TW552276B (cg-RX-API-DMAC7.html) |
| WO (1) | WO2001085803A2 (cg-RX-API-DMAC7.html) |
| ZA (1) | ZA200110412B (cg-RX-API-DMAC7.html) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10317398A1 (de) * | 2003-04-15 | 2004-11-04 | Basell Polyolefine Gmbh | Katalysatorsysteme vom Typ der Ziegler-Natta-Katalysatoren und ein Verfahren zu deren Herstellung |
| DE10317395A1 (de) * | 2003-04-15 | 2004-11-04 | Basell Polyolefine Gmbh | Katalysatorsysteme vom Typ der Ziegler-Natta-Katalysatoren und ein Verfahren zu deren Herstellung |
| US20070004814A1 (en) * | 2003-04-17 | 2007-01-04 | Basell Polyolefine Gmbh | Process for preparing porous polymers and polymers thereof |
| EP1518866A1 (en) * | 2003-09-29 | 2005-03-30 | Basell Poliolefine Italia S.P.A. | Process for the preparation of porous ethylene polymers |
| JP4885130B2 (ja) * | 2004-06-18 | 2012-02-29 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | オレフィン重合用触媒成分の製造方法 |
| KR100797213B1 (ko) * | 2006-05-30 | 2008-01-23 | 삼성토탈 주식회사 | 아릴옥시기가 포함된 올레핀/알파올레핀 공중합용 촉매의 제조방법 및 이로부터 제조된 촉매를 이용한 올레핀/알파올레핀 공중합방법 |
| ATE455801T1 (de) | 2006-08-03 | 2010-02-15 | Basell Polyolefine Gmbh | Verfahren zur endbehandlung von polyolefin |
| CN101583634B (zh) * | 2006-12-22 | 2012-12-05 | 巴塞尔聚烯烃意大利有限责任公司 | 用于烯烃聚合的催化剂组分以及由其获得的催化剂 |
| EP2121773B1 (en) * | 2006-12-22 | 2016-11-23 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
| EP2718335B1 (en) * | 2011-06-09 | 2020-01-22 | Basell Poliolefine Italia S.r.l. | Pre-polymerized catalyst components for the polymerization of olefins |
| WO2014007765A1 (en) * | 2012-07-02 | 2014-01-09 | Irpc Public Company Limited | A catalyst for olefin polymerization and a method for the preparation thereof |
| WO2014134193A1 (en) * | 2013-02-27 | 2014-09-04 | Equistar Chemicals, Lp | Polyethylene processes and compositions thereof |
| EP2816062A1 (en) * | 2013-06-18 | 2014-12-24 | Basell Poliolefine Italia S.r.l. | Pre-polymerized catalyst components for the polymerization of olefins |
| US10308737B2 (en) * | 2014-09-30 | 2019-06-04 | Borealis Ag | Process for polymerising ultra-high molecular weight polyethylene |
| US10619035B2 (en) | 2015-06-26 | 2020-04-14 | Basell Polyolefine Gmbh | Polyethylene composition for films |
| KR102340690B1 (ko) | 2018-09-20 | 2021-12-17 | 바젤 폴리올레핀 게엠베하 | 필름용 폴리에틸렌 조성물 |
| CN121586735A (zh) | 2023-08-01 | 2026-02-27 | 巴塞尔聚烯烃股份有限公司 | 聚乙烯工艺及其组合物 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1255575A (en) * | 1969-02-21 | 1971-12-01 | Chisso Corp | Method for producing polymers of ethylene |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL162661B (nl) | 1968-11-21 | 1980-01-15 | Montedison Spa | Werkwijze om een katalysator te bereiden voor de poly- merisatie van alkenen-1. |
| YU35844B (en) | 1968-11-25 | 1981-08-31 | Montedison Spa | Process for obtaining catalysts for the polymerization of olefines |
| GB1603724A (en) | 1977-05-25 | 1981-11-25 | Montedison Spa | Components and catalysts for the polymerisation of alpha-olefins |
| IT1098272B (it) | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| US4325837A (en) | 1980-08-12 | 1982-04-20 | Phillips Petroleum Company | Catalyst, method of producing the catalyst, and polymerization process employing the catalyst |
| DZ520A1 (fr) | 1982-03-24 | 2004-09-13 | Union Carbide Corp | Procédé perfectionné pour accroitre le rendement espace temps d'une réaction de polymérisation exothermique en lit fluidisé. |
| JPH078890B2 (ja) * | 1985-07-25 | 1995-02-01 | 三井石油化学工業株式会社 | オレフインの連続重合法 |
| JPH0826097B2 (ja) * | 1986-08-04 | 1996-03-13 | 三菱化学株式会社 | 超高分子量ポリエチレンの製造法 |
| IT1230134B (it) | 1989-04-28 | 1991-10-14 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine. |
| US5556820A (en) * | 1989-12-28 | 1996-09-17 | Idemitsu Petrochemical Co., Ltd. | Catalyst component for olefin polymerization and process for producing polyolefins |
| DE4114833A1 (de) * | 1990-05-16 | 1991-11-28 | Basf Ag | Ziegler-natta-katalysatorsysteme mit siliciumorganischen verbindungen |
| IT1246614B (it) * | 1991-06-03 | 1994-11-24 | Himont Inc | Procedimento per la polimerizzazione in fase gas delle olefine |
| JP3044262B2 (ja) | 1991-07-02 | 2000-05-22 | 東ソー株式会社 | ポリオレフィンの製造方法 |
| IT1262935B (it) * | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
| FI95387C (fi) * | 1992-12-29 | 1996-01-25 | Borealis As | Menetelmä -olefiinien polymeroimiseksi sekä esipolymeroitu katalyyttikompositio ja menetelmä tämän valmistamiseksi |
| ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
| IT1264680B1 (it) * | 1993-07-07 | 1996-10-04 | Spherilene Srl | Catalizzatori supportati per la polimerizzazione delle olefine |
| TW354792B (en) | 1993-08-13 | 1999-03-21 | Mitsui Petrochemical Ind | Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer |
| IT1274016B (it) | 1994-02-21 | 1997-07-14 | Spherilene Srl | Processo per la polimerizzazione in fase gas delle a-olefine |
| EP0735056B1 (en) | 1995-03-28 | 1998-06-10 | Tonen Corporation | Catalyst for the polymerization of olefines and processes for the polymerization of olefines using the same |
| US6399533B2 (en) * | 1995-05-25 | 2002-06-04 | Basell Technology Company Bv | Compounds and catalysts for the polymerization of olefins |
| IL127230A (en) | 1997-03-29 | 2004-07-25 | Montell Technology Company Bv | Magnesium dichloride-alcohol adducts, process for their preparation and catalyst components obtained therefrom |
| KR100528310B1 (ko) * | 1998-03-23 | 2005-11-15 | 바셀 테크놀로지 캄파니 비이브이 | 올레핀 중합용 예비중합된 촉매 성분 |
| WO2000023480A1 (en) * | 1998-10-16 | 2000-04-27 | Saudi Basic Industries Corporation | Highly active, supported ziegler-natta catalyst systems for olefin polymerization, methods of making and using the same |
-
2001
- 2001-05-07 KR KR1020027000347A patent/KR100815101B1/ko not_active Expired - Lifetime
- 2001-05-07 MX MXPA02000435A patent/MXPA02000435A/es active IP Right Grant
- 2001-05-07 RU RU2002103381/04A patent/RU2278124C2/ru active
- 2001-05-07 AT AT01951489T patent/ATE440871T1/de active
- 2001-05-07 US US10/030,466 patent/US7223711B2/en not_active Expired - Lifetime
- 2001-05-07 AU AU72401/01A patent/AU782724B2/en not_active Ceased
- 2001-05-07 ES ES01951489T patent/ES2330192T3/es not_active Expired - Lifetime
- 2001-05-07 CA CA002379053A patent/CA2379053A1/en not_active Abandoned
- 2001-05-07 PL PL358716A patent/PL201765B1/pl unknown
- 2001-05-07 JP JP2001582401A patent/JP5122054B2/ja not_active Expired - Lifetime
- 2001-05-07 BR BRPI0106426-6A patent/BR0106426B1/pt not_active IP Right Cessation
- 2001-05-07 EP EP01951489A patent/EP1268583B1/en not_active Expired - Lifetime
- 2001-05-07 DE DE60139676T patent/DE60139676D1/de not_active Expired - Lifetime
- 2001-05-07 HU HU0203867A patent/HUP0203867A3/hu unknown
- 2001-05-07 CN CNB018012507A patent/CN1210319C/zh not_active Expired - Lifetime
- 2001-05-07 WO PCT/EP2001/005254 patent/WO2001085803A2/en not_active Ceased
- 2001-09-19 TW TW090123423A patent/TW552276B/zh not_active IP Right Cessation
- 2001-12-19 ZA ZA200110412A patent/ZA200110412B/xx unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1255575A (en) * | 1969-02-21 | 1971-12-01 | Chisso Corp | Method for producing polymers of ethylene |
Also Published As
| Publication number | Publication date |
|---|---|
| BR0106426A (pt) | 2002-04-02 |
| JP2003532760A (ja) | 2003-11-05 |
| TW552276B (en) | 2003-09-11 |
| EP1268583B1 (en) | 2009-08-26 |
| CA2379053A1 (en) | 2001-11-15 |
| KR20020025952A (ko) | 2002-04-04 |
| WO2001085803A2 (en) | 2001-11-15 |
| HUP0203867A3 (en) | 2010-01-28 |
| WO2001085803A3 (en) | 2002-07-18 |
| HUP0203867A2 (hu) | 2003-03-28 |
| CN1210319C (zh) | 2005-07-13 |
| BR0106426B1 (pt) | 2011-02-22 |
| US7223711B2 (en) | 2007-05-29 |
| CN1400979A (zh) | 2003-03-05 |
| ATE440871T1 (de) | 2009-09-15 |
| DE60139676D1 (de) | 2009-10-08 |
| ES2330192T3 (es) | 2009-12-07 |
| JP5122054B2 (ja) | 2013-01-16 |
| AU782724B2 (en) | 2005-08-25 |
| AU7240101A (en) | 2001-11-20 |
| RU2278124C2 (ru) | 2006-06-20 |
| MXPA02000435A (es) | 2002-07-02 |
| EP1268583A2 (en) | 2003-01-02 |
| PL358716A1 (en) | 2004-08-09 |
| PL201765B1 (pl) | 2009-05-29 |
| ZA200110412B (en) | 2003-03-19 |
| US20030040427A1 (en) | 2003-02-27 |
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