KR100780481B1 - 활성탄소-다종금속 복합체의 제조방법 - Google Patents
활성탄소-다종금속 복합체의 제조방법 Download PDFInfo
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- KR100780481B1 KR100780481B1 KR1020060038836A KR20060038836A KR100780481B1 KR 100780481 B1 KR100780481 B1 KR 100780481B1 KR 1020060038836 A KR1020060038836 A KR 1020060038836A KR 20060038836 A KR20060038836 A KR 20060038836A KR 100780481 B1 KR100780481 B1 KR 100780481B1
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- Prior art keywords
- activated carbon
- metal
- metals
- polymetal
- composite
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 111
- 239000002184 metal Substances 0.000 title claims abstract description 111
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 98
- 238000002360 preparation method Methods 0.000 title 1
- 238000000034 method Methods 0.000 claims abstract description 36
- 238000007747 plating Methods 0.000 claims abstract description 36
- 239000002131 composite material Substances 0.000 claims abstract description 29
- 150000002739 metals Chemical class 0.000 claims abstract description 26
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 22
- 239000000956 alloy Substances 0.000 claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 claims abstract description 8
- 239000011149 active material Substances 0.000 claims abstract description 6
- 239000007772 electrode material Substances 0.000 claims abstract description 6
- 238000009713 electroplating Methods 0.000 claims description 15
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 229910052709 silver Inorganic materials 0.000 claims description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims description 2
- 229910052707 ruthenium Inorganic materials 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 229910052723 transition metal Inorganic materials 0.000 claims description 2
- 150000003624 transition metals Chemical class 0.000 claims description 2
- 230000001988 toxicity Effects 0.000 claims 1
- 231100000419 toxicity Toxicity 0.000 claims 1
- 150000003839 salts Chemical class 0.000 abstract description 7
- 239000007788 liquid Substances 0.000 abstract description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000356 contaminant Substances 0.000 abstract description 4
- 239000000446 fuel Substances 0.000 abstract description 4
- 239000001257 hydrogen Substances 0.000 abstract description 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 4
- 239000003990 capacitor Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 230000009257 reactivity Effects 0.000 abstract description 3
- 238000003860 storage Methods 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- 229910001092 metal group alloy Inorganic materials 0.000 description 18
- 239000010949 copper Substances 0.000 description 16
- 239000012153 distilled water Substances 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical group O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 11
- 239000011148 porous material Substances 0.000 description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 9
- 229920000049 Carbon (fiber) Polymers 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 238000006722 reduction reaction Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- 238000000151 deposition Methods 0.000 description 3
- 239000002923 metal particle Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 101710134784 Agnoprotein Proteins 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 238000003321 atomic absorption spectrophotometry Methods 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- OHVLMTFVQDZYHP-UHFFFAOYSA-N 1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-2-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]ethanone Chemical compound N1N=NC=2CN(CCC=21)C(CN1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)=O OHVLMTFVQDZYHP-UHFFFAOYSA-N 0.000 description 1
- PQVHMOLNSYFXIJ-UHFFFAOYSA-N 4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]pyrazole-3-carboxylic acid Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C=1C(=NN(C=1)CC(N1CC2=C(CC1)NN=N2)=O)C(=O)O PQVHMOLNSYFXIJ-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 241000283690 Bos taurus Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000002156 adsorbate Substances 0.000 description 1
- 230000004931 aggregating effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- -1 secondary batteries Substances 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/54—Electroplating of non-metallic surfaces
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/20—Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
- B01D39/2055—Carbonaceous material
- B01D39/2058—Carbonaceous material the material being particulate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/20—Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
- B01D39/2055—Carbonaceous material
- B01D39/2065—Carbonaceous material the material being fibrous
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/04—Additives and treatments of the filtering material
- B01D2239/0407—Additives and treatments of the filtering material comprising particulate additives, e.g. adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/04—Additives and treatments of the filtering material
- B01D2239/0471—Surface coating material
- B01D2239/0478—Surface coating material on a layer of the filter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/10—Filtering material manufacturing
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical Kinetics & Catalysis (AREA)
- Geology (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Electroplating Methods And Accessories (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Carbon And Carbon Compounds (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Inert Electrodes (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Abstract
Description
구 분 | 도금시간 | 전류밀도 (A/㎡) | 금속 종류 | 금속 담지량 (중량%*) | 비표면적 (㎡/g) |
비교예 1 | - | - | - | 0 | 2120 |
실시예 1 | 5 초 | 0.1 | Pt/Ru | 0.06/0.04 | 2070 |
실시예 2 | 20 초 | 1.0 | Cu/Cr | 2.6/1.8 | 1920 |
실시예 3 | 30 초 | 2.0 | Cu/Ag | 4.5/2.3 | 1880 |
실시예 4 | 2 분 | 3.0 | Cu/Fe | 6.0/5.1 | 1710 |
실시예 5 | 5 분 | 3.0 | Ag/Ni | 5.2/8.7 | 1650 |
실시예 6 | 90 초 | 3.0 | Cu/Ni | 2.2/5.8 | 1860 |
실시예 7 | 10 초 | 1.0 | Pt/Co | 0.2/0.9 | 1950 |
실시예 8 | 5 분 | 5.0 | Al/Fe | 7.5/20.8 | 1410 |
실시예 9 | 10 분 | 5 | Ag/Cr/Pt | 12.5/6.5/0.1 | 1660 |
실시예 10 | 15 분 | 6.0 | Cu/Cr/Fe | 65.2/7.4/21.2 | 910 |
실시예 11 | 8 분 | 5.0 | Co/Cr/Al | 4.2/2.1/12.5 | 1810 |
실시예 12 | 20 분 | 6.0 | Al/Cr/Fe | 30.5/5.1/80.1 | 830 |
실시예 13 | 30 분 | 6.0 | Cu/Ni/Ag | 112.3/61.0/28.5 | 610 |
비교예 2 | 침적 30초 | - | CuSO4 (0.5 M) AgNO3 (0.5 M) | 1.2/0.9 | 1730 |
비교예 3 | 각각 30분 | 6.0 | Pt/Ru | 82.5/65.0 | 730 |
*:활성탄소에 대하여 금속이 담지된 양 |
Claims (8)
- 2종 이상의 금속으로 이루어진 합금판이 설치된 양극과, 두 개의 전도성 망 사이에 활성탄소가 압착되어 고정된 음극으로 구성된 전극을 이용하여 도금을 수행하되,1초 ∼ 30분 범위의 시간과 0.1 ∼ 4 A/m2 범위의 전류밀도하에서 전기도금을 수행하여,상기 활성탄소 표면에, 2종이상의 금속이 동시에 도입된 복합체를 형성하는 것을 특징으로 하는 활성탄소-다종금속 복합체의 제조방법.
- 삭제
- 제 1 항에 있어서, 상기 활성탄소는 분말상, 조립상, 파쇄상, 필터상 및 섬유상의 형태를 유지하는 활성탄 또는 활성탄소섬유인 것을 특징으로 하는 활성탄소-다종금속 복합체의 제조방법.
- 삭제
- 제 1 항에 있어서, 상기 활성탄 표면에 도입된 금속은 Cu, Ni, Ag, Al, Fe, Co, Cr, Pt, Ru 및 Sn 중에서 선택된 2종 이상의 전이금속인 것을 특징으로 하는 활성탄소-다종금속 복합체의 제조방법.
- 제 1 항에 있어서, 상기 도입된 금속의 함량이 활성탄소 무게대비 0.1 ∼ 200 중량% 범위인 것을 특징으로 하는 활성탄소-다종금속 복합체의 제조방법.
- 청구항 1, 3, 5 및 6 중에서 선택된 어느 한 항의 제조방법으로 제조된 활성탄소-다종금속 복합체가 포함되어 이루어진 독성제거용 필터.
- 청구항 1, 3, 5 및 6 중에서 선택된 어느 한 항의 제조방법으로 제조된 활성탄소-다종금속 복합체가 포함되어 이루어진 전극재료용 활물질.
Priority Applications (3)
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KR1020060038836A KR100780481B1 (ko) | 2006-04-28 | 2006-04-28 | 활성탄소-다종금속 복합체의 제조방법 |
US11/789,483 US8748337B2 (en) | 2006-04-28 | 2007-04-25 | Preparation method of multi-metals / activated carbon composites |
JP2007119115A JP5167687B2 (ja) | 2006-04-28 | 2007-04-27 | 活性炭素−多種金属複合体の製造方法 |
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KR100780481B1 true KR100780481B1 (ko) | 2007-11-28 |
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Families Citing this family (7)
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KR100907334B1 (ko) * | 2008-01-04 | 2009-07-13 | 성균관대학교산학협력단 | 알루미늄과 탄소재료 간의 공유결합을 형성하는 방법, 알루미늄과 탄소재료 복합체를 제조하는 방법 및 그 방법에 의하여 제조된 알루미늄과 탄소재료 복합체 |
KR101022857B1 (ko) | 2008-01-16 | 2011-03-17 | 인하대학교 산학협력단 | 수소저장용 전이금속 도금된 다공성 탄소나노섬유 복합체의제조방법 |
JPWO2012029162A1 (ja) * | 2010-09-02 | 2013-10-28 | 地方独立行政法人大阪府立産業技術総合研究所 | 水素発生用電極の製造方法及び水素発生用電極 |
KR101155915B1 (ko) | 2010-09-13 | 2012-06-20 | 삼성에스디아이 주식회사 | 리튬 이차 전지 |
CN112941552B (zh) * | 2021-01-27 | 2024-04-09 | 云南电网有限责任公司电力科学研究院 | 一种多孔炭负载钌催化剂及其制备方法 |
WO2023200610A2 (en) * | 2022-04-01 | 2023-10-19 | Ionic Solutions Ltd. | Non-gas-emitting electrodes for use in electrodialysis and electrodionization desalination systems |
CN115582125B (zh) * | 2022-10-09 | 2023-08-22 | 常州大学 | 一种用于催化臭氧高级氧化的复合材料、制备方法及应用 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05305218A (ja) * | 1992-04-28 | 1993-11-19 | Kooken:Kk | 消臭方法及び消臭材・消臭素材 |
KR20040075463A (ko) * | 2003-02-21 | 2004-08-30 | 한국화학연구원 | 항균성 활성탄소 및 이의 제조방법 |
Family Cites Families (26)
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US4321240A (en) * | 1976-09-08 | 1982-03-23 | Carus Chemical Company | Treatment of gaseous effluent |
JPS59159999A (ja) | 1983-03-02 | 1984-09-10 | Kuraray Co Ltd | 無機粉粒体の電気メツキ方法 |
JPH0284540A (ja) | 1988-06-09 | 1990-03-26 | Mitsubishi Rayon Co Ltd | 非晶質合金を被覆した炭素繊維 |
JPH08120482A (ja) * | 1994-10-24 | 1996-05-14 | Satosen Co Ltd | 抗菌性めっき製品 |
JPH08311683A (ja) * | 1995-05-19 | 1996-11-26 | Satosen Co Ltd | 抗菌性に優れためっき製品 |
JP3469754B2 (ja) | 1997-09-30 | 2003-11-25 | 三洋電機株式会社 | 水素吸蔵合金電極 |
JPH11193495A (ja) * | 1997-11-04 | 1999-07-21 | Daido Steel Co Ltd | 抗菌性金属板とその製造方法 |
WO2000004362A2 (en) * | 1998-06-05 | 2000-01-27 | The Penn State Research Foundation | Method of screening compositions for electrocatalytic activity |
US6419837B1 (en) * | 1998-08-06 | 2002-07-16 | Umpqua Research Company | Process for destroying contaminants in contaminant-containing aqueous streams and catalysts used therefor |
MY136454A (en) | 2000-04-07 | 2008-10-31 | Shell Int Research | A process for producing hydrocarbons, and a catalyst suitable for use in the process |
JP2001357857A (ja) * | 2000-06-12 | 2001-12-26 | Asahi Glass Co Ltd | 固体高分子型燃料電池及びその製造方法 |
KR100331570B1 (ko) * | 2000-06-13 | 2002-04-06 | 윤종용 | 전기도금법을 이용한 반도체 메모리 소자의 커패시터제조방법 |
KR20020043946A (ko) * | 2000-12-05 | 2002-06-12 | 이근석 | 산화 촉매 및 그 제조방법, 그 산화 촉매를 재활용하는방법 및 그 산화 촉매를 이용한 폐수 처리 방법 |
EP1283274B1 (de) * | 2001-08-04 | 2007-10-31 | Umicore AG & Co. KG | Chlorarme Platin- und Platinlegierungspulver mit erhöhter spezifischer Oberfläche und Verfahren zu ihrer Herstellung unter Verwendung einer Nitratsalzschmelze |
KR100433822B1 (ko) * | 2002-01-17 | 2004-06-04 | 한국과학기술연구원 | 금속이 피복된 탄소 활물질, 이의 제조방법, 및 이를포함하는 금속-탄소 하이브리드 전극 및 리튬이차전지 |
JP2003226901A (ja) * | 2002-02-05 | 2003-08-15 | Hitachi Maxell Ltd | 二元系合金微粒子及びその製造方法 |
JP2003260360A (ja) | 2002-03-13 | 2003-09-16 | Toyota Motor Corp | 脱水素触媒および水素ガス生成装置 |
KR20030095695A (ko) | 2002-06-14 | 2003-12-24 | 한국화학연구원 | 활성탄 또는 활성탄소섬유/전이금속 복합체 및 이의제조방법 |
JP2004099960A (ja) * | 2002-09-09 | 2004-04-02 | Riyouko Hattori | 抗菌機能を有する立体形 |
KR100512476B1 (ko) | 2003-04-21 | 2005-09-06 | 한국화학연구원 | Cu/Ag/Cr/활성탄소 흡착제 및 이의 제조방법 |
KR100696463B1 (ko) * | 2003-09-27 | 2007-03-19 | 삼성에스디아이 주식회사 | 고농도 탄소 담지 촉매, 그 제조방법, 상기 촉매를 이용한촉매전극 및 이를 이용한 연료전지 |
JP2007516826A (ja) | 2003-12-12 | 2007-06-28 | シントロレウム コーポレイション | 改変された触媒担体 |
JP2005324156A (ja) * | 2004-05-17 | 2005-11-24 | Hitachi Maxell Ltd | 燃料電池用PtRu合金触媒の製造方法、燃料電池用PtRu合金触媒及び該触媒を用いたメタノール燃料電池 |
JP4507802B2 (ja) * | 2004-09-30 | 2010-07-21 | パナソニック株式会社 | 金属担持導電性粉体の製造方法およびそれを用いた触媒 |
JP5017638B2 (ja) * | 2005-06-10 | 2012-09-05 | 独立行政法人国立高等専門学校機構 | 抗菌性を有するSn−Cu合金薄膜形成品の製造方法およびこれによって製造された抗菌性を有するSn−Cu合金薄膜形成品 |
JP2007270049A (ja) | 2006-03-31 | 2007-10-18 | Nippon Oil Corp | 一酸化炭素の還元による炭化水素の製造方法 |
-
2006
- 2006-04-28 KR KR1020060038836A patent/KR100780481B1/ko active IP Right Grant
-
2007
- 2007-04-25 US US11/789,483 patent/US8748337B2/en active Active
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05305218A (ja) * | 1992-04-28 | 1993-11-19 | Kooken:Kk | 消臭方法及び消臭材・消臭素材 |
KR20040075463A (ko) * | 2003-02-21 | 2004-08-30 | 한국화학연구원 | 항균성 활성탄소 및 이의 제조방법 |
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