KR100575967B1 - 칼륨 오레이트로 제조된, 금속 팔라듐 및 금을 포함하는비닐 아세테이트 제조용 촉매 - Google Patents

칼륨 오레이트로 제조된, 금속 팔라듐 및 금을 포함하는비닐 아세테이트 제조용 촉매 Download PDF

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Publication number
KR100575967B1
KR100575967B1 KR1020007013491A KR20007013491A KR100575967B1 KR 100575967 B1 KR100575967 B1 KR 100575967B1 KR 1020007013491 A KR1020007013491 A KR 1020007013491A KR 20007013491 A KR20007013491 A KR 20007013491A KR 100575967 B1 KR100575967 B1 KR 100575967B1
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South Korea
Prior art keywords
catalyst
palladium
gold
support
solution
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English (en)
Korean (ko)
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KR20010052457A (ko
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왕타오
브루사드제리에이
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셀라니즈 인터내셔날 코포레이션
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Publication of KR20010052457A publication Critical patent/KR20010052457A/ko
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020007013491A 1998-06-02 1999-05-19 칼륨 오레이트로 제조된, 금속 팔라듐 및 금을 포함하는비닐 아세테이트 제조용 촉매 Expired - Fee Related KR100575967B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/088,978 1998-06-02
US09/088,978 US6350900B1 (en) 1998-06-02 1998-06-02 Vinyl acetate catalyst comprising metallic palladium and gold prepared with potassium aurate

Publications (2)

Publication Number Publication Date
KR20010052457A KR20010052457A (ko) 2001-06-25
KR100575967B1 true KR100575967B1 (ko) 2006-05-02

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KR1020007013491A Expired - Fee Related KR100575967B1 (ko) 1998-06-02 1999-05-19 칼륨 오레이트로 제조된, 금속 팔라듐 및 금을 포함하는비닐 아세테이트 제조용 촉매

Country Status (27)

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US (2) US6350900B1 (enExample)
EP (1) EP1091802B1 (enExample)
JP (1) JP4610736B2 (enExample)
KR (1) KR100575967B1 (enExample)
CN (1) CN1116109C (enExample)
AR (1) AR018395A1 (enExample)
AT (1) ATE272443T1 (enExample)
AU (1) AU753815B2 (enExample)
BR (1) BR9910750B1 (enExample)
CA (1) CA2333097C (enExample)
CZ (1) CZ295988B6 (enExample)
DE (1) DE69919169T2 (enExample)
ES (1) ES2226388T3 (enExample)
HU (1) HUP0102638A3 (enExample)
ID (1) ID26891A (enExample)
MY (1) MY121382A (enExample)
NO (2) NO322595B1 (enExample)
NZ (1) NZ508272A (enExample)
PE (1) PE20000470A1 (enExample)
RU (1) RU2216401C2 (enExample)
SA (1) SA99200245B1 (enExample)
SK (1) SK284905B6 (enExample)
TR (1) TR200003584T2 (enExample)
TW (1) TW476667B (enExample)
UA (1) UA69410C2 (enExample)
WO (1) WO1999062632A1 (enExample)
ZA (1) ZA200006639B (enExample)

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US6534438B1 (en) 2000-07-26 2003-03-18 Bp Chemicals Limited Catalyst composition
JP4421201B2 (ja) * 2002-03-27 2010-02-24 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒を調製する方法、触媒、および触媒の使用
CN100464843C (zh) * 2003-12-19 2009-03-04 国际人造丝公司 含铑的催化剂
TW200539941A (en) * 2003-12-19 2005-12-16 Celanese Int Corp Methods of making alkenyl alkanoates
UA94207C2 (ru) * 2003-12-19 2011-04-26 Селаниз Интернэшнл Корпорейшн Процесс изготовления катализатора или предкатализатора, пригодного для получения алкенилалканоатов, композиция катализатора или предкатализатора для алкенилалканоатов и процесс получения алкенилалканоатов
WO2005065821A1 (en) * 2003-12-19 2005-07-21 Celanese International Corporation Layered support material for catalysts
UA95442C2 (ru) 2004-12-20 2011-08-10 Селаниз Интернешнл Корпорейшн Модифицированные материалы носителей для катализаторов
US8227369B2 (en) * 2005-05-25 2012-07-24 Celanese International Corp. Layered composition and processes for preparing and using the composition
US9078428B2 (en) 2005-06-28 2015-07-14 Transmedics, Inc. Systems, methods, compositions and solutions for perfusing an organ
DE102007025362A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025315A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG Katalysator zur selektiven Hydrierung acetylenischer Kohlenwasserstoffe und Verfahren zu seiner Herstellung
DE102007025444A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025443A1 (de) 2007-05-31 2008-12-04 Süd-Chemie AG Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025442B4 (de) * 2007-05-31 2023-03-02 Clariant International Ltd. Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator
DE102007025358A1 (de) * 2007-05-31 2009-01-08 Süd-Chemie AG Verfahren zur Herstellung eines mit Pd und/oder Au beladenen Schalenkatalysators
DE102007025223A1 (de) * 2007-05-31 2008-12-04 Süd-Chemie AG Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE202008017277U1 (de) 2008-11-30 2009-04-30 Süd-Chemie AG Katalysatorträger
RU2422201C1 (ru) * 2009-10-13 2011-06-27 Открытое акционерное общество "Государственный научно-исследовательский и проектный институт редкометаллической промышленности "Гиредмет" Способ получения катализатора синтеза винилацетата
DE102011101459A1 (de) 2011-05-13 2012-11-15 Süd-Chemie AG Verfahren zur Herstellung eines metallhaltigen Schalenkatalysators ohne Zwischenkalzinierung
DE102012003232A1 (de) 2012-02-20 2013-08-22 Clariant Produkte (Deutschland) Gmbh Nachvergoldung von Pd-Au-gecoateten Schalenkatalysatoren
DE102012003236A1 (de) 2012-02-20 2013-08-22 Clariant Produkte (Deutschland) Gmbh Vorvergoldung von Pd-Au-gecoateten Schalenkatalysatoren
DE102012008715A1 (de) 2012-05-03 2013-11-07 Clariant Produkte (Deutschland) Gmbh Herstellung von Schalenkatalysatoren in einer Beschichtungsvorrichtung
DE102012008714A1 (de) 2012-05-03 2013-11-07 Clariant Produkte (Deutschland) Gmbh Vorimprägnierung von Schalenkatalysatoren mit einem Acetat
DE102013015436A1 (de) 2012-09-19 2014-03-20 Clariant International Ltd. Kupfer-promotierter Schalenkatalysator zur Herstellung von Alkenylcarbonsäureestern
WO2016198561A1 (en) 2015-06-12 2016-12-15 Evonik Degussa Gmbh Electroless deposition of au-pd bimetallic catalysts for alkenyl acetate production
TW202204039A (zh) * 2020-06-11 2022-02-01 美商瑟蘭斯國際股份有限公司 用於乙酸乙烯酯製造之催化劑的製備方法
CN115181059B (zh) * 2022-07-18 2023-10-20 苏州诚和医药化学有限公司 3-甲基-4-氧代哌啶-1-羧酸酯的生产工艺

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DE1286021B (de) 1967-04-18 1969-01-02 Knapsack Ag Verfahren zur Herstellung von Estern von Carbonsaeuren mit ungesaettigten Alkoholen
GB1333449A (en) * 1970-11-20 1973-10-10 Hoechst Ag Process for the oxacylation of olefins in the gaseous phase
DE2509251C3 (de) * 1975-03-04 1978-07-13 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung eines Palladiumkatalysators
US4048096A (en) * 1976-04-12 1977-09-13 E. I. Du Pont De Nemours And Company Surface impregnated catalyst
US5179057A (en) 1991-05-06 1993-01-12 Union Carbide Chemicals & Plastics Technology Corporation Catalysts for alkenyl alkanoate production
RU2061544C1 (ru) * 1992-01-31 1996-06-10 Бп Кемикалз Лимитед Катализатор для получения винилацетата
US5314858A (en) 1992-10-14 1994-05-24 Hoechst Celanese Corporation Vinyl acetate catalyst preparation method
US5332710A (en) 1992-10-14 1994-07-26 Hoechst Celanese Corporation Vinyl acetate catalyst preparation method
DE4323981C1 (de) * 1993-07-16 1995-03-09 Hoechst Ag Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat
CA2135021A1 (en) * 1993-11-19 1995-05-20 David J. Gulliver Process for the preparation of catalysts for use in the production of vinyl acetate
US6034030A (en) * 1994-02-22 2000-03-07 Celanese International Corporation Vinyl acetate catalyst preparation method
DE19501891C1 (de) * 1995-01-23 1996-09-26 Degussa Verfahren zur Herstellung eines Trägerkatalysators und seine Verwendung für die Produktion von Vinylacetat
IN188013B (enExample) * 1995-05-23 2002-08-10 Hoechst Celanese Corp
US6022823A (en) * 1995-11-07 2000-02-08 Millennium Petrochemicals, Inc. Process for the production of supported palladium-gold catalysts
US5691267A (en) * 1996-04-16 1997-11-25 Hoechst Celanese Corporation Two step gold addition method for preparing a vinyl acetate catalyst
SA97180048B1 (ar) 1996-05-24 2005-12-21 هوكست سيلانس كوربوريشن محفز بلاديوم - ذهب palladium gold ثنائي المعدن متغاير الخواص heterogeneous bimetallic vinyl acetate لإنتاج أسيتات فينيل
US5693586A (en) 1996-06-28 1997-12-02 Hoechst Celanese Corporation Palladium-gold catalyst for vinyl acetate production
US6015769A (en) * 1998-06-02 2000-01-18 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium, gold and copper supported on a carrier and prepared with potassium aurate

Also Published As

Publication number Publication date
AU4085299A (en) 1999-12-20
SK284905B6 (sk) 2006-02-02
HUP0102638A2 (hu) 2001-11-28
ATE272443T1 (de) 2004-08-15
NO20006120L (no) 2000-12-01
CA2333097C (en) 2005-02-22
HUP0102638A3 (en) 2002-12-28
ZA200006639B (en) 2001-11-15
CA2333097A1 (en) 1999-12-09
ID26891A (id) 2001-02-15
JP2002516747A (ja) 2002-06-11
CN1304331A (zh) 2001-07-18
EP1091802A1 (en) 2001-04-18
SA99200245B1 (ar) 2006-04-04
DE69919169T2 (de) 2005-09-08
SK18242000A3 (sk) 2001-08-06
AR018395A1 (es) 2001-11-14
NZ508272A (en) 2003-08-29
US20020013220A1 (en) 2002-01-31
NO322595B1 (no) 2006-10-30
AU753815B2 (en) 2002-10-31
MY121382A (en) 2006-01-28
KR20010052457A (ko) 2001-06-25
US6486093B2 (en) 2002-11-26
BR9910750B1 (pt) 2010-07-13
CZ295988B6 (cs) 2005-12-14
WO1999062632A1 (en) 1999-12-09
NO326959B1 (no) 2009-03-23
NO20063038L (no) 2000-12-01
CZ20004503A3 (cs) 2001-08-15
EP1091802B1 (en) 2004-08-04
NO20006120D0 (no) 2000-12-01
UA69410C2 (uk) 2004-09-15
JP4610736B2 (ja) 2011-01-12
US6350900B1 (en) 2002-02-26
BR9910750A (pt) 2001-02-13
PL344585A1 (en) 2001-11-05
DE69919169D1 (de) 2004-09-09
PE20000470A1 (es) 2000-06-05
ES2226388T3 (es) 2005-03-16
RU2216401C2 (ru) 2003-11-20
CN1116109C (zh) 2003-07-30
TR200003584T2 (tr) 2001-06-21
TW476667B (en) 2002-02-21

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