TR200003584T2 - Vinil asetat katalizörü - Google Patents
Vinil asetat katalizörüInfo
- Publication number
- TR200003584T2 TR200003584T2 TR2000/03584T TR200003584T TR200003584T2 TR 200003584 T2 TR200003584 T2 TR 200003584T2 TR 2000/03584 T TR2000/03584 T TR 2000/03584T TR 200003584 T TR200003584 T TR 200003584T TR 200003584 T2 TR200003584 T2 TR 200003584T2
- Authority
- TR
- Turkey
- Prior art keywords
- vinyl acetate
- catalyst
- gold
- potassium
- catalytically effective
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 title abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract 2
- 239000010931 gold Substances 0.000 abstract 2
- 229910052737 gold Inorganic materials 0.000 abstract 2
- 229910052700 potassium Inorganic materials 0.000 abstract 2
- 239000011591 potassium Substances 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/396—Distribution of the active metal ingredient
- B01J35/397—Egg shell like
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Etilen, oksijen ve asetik asitin reaksiyonu sonucu vinil asetat üretimine yönelik bir katalizör olup, gözenekli bir suport içerir ve bunun gözenekli satihlarinin üzerine metalik paladyum ve altinin katalitik yönden etkili miktarlari depozitlenir, ve sözü geçen katalizör gözenekli satihlari önceden redüklenmis metalik paladyumun katalitik yönden etkili bir miktarini ihtiva eden gözenekli bir suportun bir potasyum orat solüsyonu ile emprenye edilmesini, ve potasyum oratin katalitik yönden etkili bir metalik altin miktarina redüklenmesini içeren etaplar ile hazirlanir. Alternatif tecessümler de tarif edilmektedir.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/088,978 US6350900B1 (en) | 1998-06-02 | 1998-06-02 | Vinyl acetate catalyst comprising metallic palladium and gold prepared with potassium aurate |
Publications (1)
Publication Number | Publication Date |
---|---|
TR200003584T2 true TR200003584T2 (tr) | 2001-06-21 |
Family
ID=22214627
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TR2000/03584T TR200003584T2 (tr) | 1998-06-02 | 1999-05-19 | Vinil asetat katalizörü |
Country Status (27)
Country | Link |
---|---|
US (2) | US6350900B1 (tr) |
EP (1) | EP1091802B1 (tr) |
JP (1) | JP4610736B2 (tr) |
KR (1) | KR100575967B1 (tr) |
CN (1) | CN1116109C (tr) |
AR (1) | AR018395A1 (tr) |
AT (1) | ATE272443T1 (tr) |
AU (1) | AU753815B2 (tr) |
BR (1) | BR9910750B1 (tr) |
CA (1) | CA2333097C (tr) |
CZ (1) | CZ295988B6 (tr) |
DE (1) | DE69919169T2 (tr) |
ES (1) | ES2226388T3 (tr) |
HU (1) | HUP0102638A3 (tr) |
ID (1) | ID26891A (tr) |
MY (1) | MY121382A (tr) |
NO (2) | NO322595B1 (tr) |
NZ (1) | NZ508272A (tr) |
PE (1) | PE20000470A1 (tr) |
RU (1) | RU2216401C2 (tr) |
SA (1) | SA99200245B1 (tr) |
SK (1) | SK284905B6 (tr) |
TR (1) | TR200003584T2 (tr) |
TW (1) | TW476667B (tr) |
UA (1) | UA69410C2 (tr) |
WO (1) | WO1999062632A1 (tr) |
ZA (1) | ZA200006639B (tr) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6794332B2 (en) * | 2000-07-07 | 2004-09-21 | Saudi Basic Industries Corporation | Highly selective shell impregnated catalyst of improved space time yield for production of vinyl acetate |
US6534438B1 (en) * | 2000-07-26 | 2003-03-18 | Bp Chemicals Limited | Catalyst composition |
JP4421201B2 (ja) * | 2002-03-27 | 2010-02-24 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 触媒を調製する方法、触媒、および触媒の使用 |
AU2004311903B2 (en) | 2003-12-19 | 2008-08-21 | Celanese International Corporation | Rhodium containing catalysts |
CA2547318C (en) * | 2003-12-19 | 2010-11-02 | Celanese International Corporation | Layered support material for catalysts |
TW201236755A (en) * | 2003-12-19 | 2012-09-16 | Celanese Int Corp | Halide free precursors for catalysts |
RU2422433C2 (ru) * | 2004-12-20 | 2011-06-27 | Селаниз Интернэшнл Корпорейшн | Модифицированные материалы носителей для катализаторов |
US8227369B2 (en) | 2005-05-25 | 2012-07-24 | Celanese International Corp. | Layered composition and processes for preparing and using the composition |
US9078428B2 (en) | 2005-06-28 | 2015-07-14 | Transmedics, Inc. | Systems, methods, compositions and solutions for perfusing an organ |
DE102007025223A1 (de) * | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
DE102007025442B4 (de) * | 2007-05-31 | 2023-03-02 | Clariant International Ltd. | Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator |
DE102007025362A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
DE102007025358A1 (de) * | 2007-05-31 | 2009-01-08 | Süd-Chemie AG | Verfahren zur Herstellung eines mit Pd und/oder Au beladenen Schalenkatalysators |
DE102007025444A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
DE102007025443A1 (de) | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung |
DE102007025315A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Katalysator zur selektiven Hydrierung acetylenischer Kohlenwasserstoffe und Verfahren zu seiner Herstellung |
DE202008017277U1 (de) | 2008-11-30 | 2009-04-30 | Süd-Chemie AG | Katalysatorträger |
DE102011101459A1 (de) | 2011-05-13 | 2012-11-15 | Süd-Chemie AG | Verfahren zur Herstellung eines metallhaltigen Schalenkatalysators ohne Zwischenkalzinierung |
DE102012003232A1 (de) | 2012-02-20 | 2013-08-22 | Clariant Produkte (Deutschland) Gmbh | Nachvergoldung von Pd-Au-gecoateten Schalenkatalysatoren |
DE102012003236A1 (de) | 2012-02-20 | 2013-08-22 | Clariant Produkte (Deutschland) Gmbh | Vorvergoldung von Pd-Au-gecoateten Schalenkatalysatoren |
DE102012008714A1 (de) | 2012-05-03 | 2013-11-07 | Clariant Produkte (Deutschland) Gmbh | Vorimprägnierung von Schalenkatalysatoren mit einem Acetat |
DE102012008715A1 (de) | 2012-05-03 | 2013-11-07 | Clariant Produkte (Deutschland) Gmbh | Herstellung von Schalenkatalysatoren in einer Beschichtungsvorrichtung |
DE102013015436A1 (de) | 2012-09-19 | 2014-03-20 | Clariant International Ltd. | Kupfer-promotierter Schalenkatalysator zur Herstellung von Alkenylcarbonsäureestern |
WO2016198561A1 (en) | 2015-06-12 | 2016-12-15 | Evonik Degussa Gmbh | Electroless deposition of au-pd bimetallic catalysts for alkenyl acetate production |
TW202204039A (zh) * | 2020-06-11 | 2022-02-01 | 美商瑟蘭斯國際股份有限公司 | 用於乙酸乙烯酯製造之催化劑的製備方法 |
CN115181059B (zh) * | 2022-07-18 | 2023-10-20 | 苏州诚和医药化学有限公司 | 3-甲基-4-氧代哌啶-1-羧酸酯的生产工艺 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1286021B (de) | 1967-04-18 | 1969-01-02 | Knapsack Ag | Verfahren zur Herstellung von Estern von Carbonsaeuren mit ungesaettigten Alkoholen |
GB1333449A (en) * | 1970-11-20 | 1973-10-10 | Hoechst Ag | Process for the oxacylation of olefins in the gaseous phase |
DE2509251C3 (de) * | 1975-03-04 | 1978-07-13 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung eines Palladiumkatalysators |
US4048096A (en) * | 1976-04-12 | 1977-09-13 | E. I. Du Pont De Nemours And Company | Surface impregnated catalyst |
US5179057A (en) | 1991-05-06 | 1993-01-12 | Union Carbide Chemicals & Plastics Technology Corporation | Catalysts for alkenyl alkanoate production |
US5332710A (en) | 1992-10-14 | 1994-07-26 | Hoechst Celanese Corporation | Vinyl acetate catalyst preparation method |
US5314858A (en) | 1992-10-14 | 1994-05-24 | Hoechst Celanese Corporation | Vinyl acetate catalyst preparation method |
DE4323981C1 (de) * | 1993-07-16 | 1995-03-09 | Hoechst Ag | Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat |
CA2135021A1 (en) * | 1993-11-19 | 1995-05-20 | David J. Gulliver | Process for the preparation of catalysts for use in the production of vinyl acetate |
US6034030A (en) * | 1994-02-22 | 2000-03-07 | Celanese International Corporation | Vinyl acetate catalyst preparation method |
DE19501891C1 (de) * | 1995-01-23 | 1996-09-26 | Degussa | Verfahren zur Herstellung eines Trägerkatalysators und seine Verwendung für die Produktion von Vinylacetat |
IN188013B (tr) * | 1995-05-23 | 2002-08-10 | Hoechst Celanese Corp | |
US6022823A (en) * | 1995-11-07 | 2000-02-08 | Millennium Petrochemicals, Inc. | Process for the production of supported palladium-gold catalysts |
US5691267A (en) * | 1996-04-16 | 1997-11-25 | Hoechst Celanese Corporation | Two step gold addition method for preparing a vinyl acetate catalyst |
SA97180048B1 (ar) | 1996-05-24 | 2005-12-21 | هوكست سيلانس كوربوريشن | محفز بلاديوم - ذهب palladium gold ثنائي المعدن متغاير الخواص heterogeneous bimetallic vinyl acetate لإنتاج أسيتات فينيل |
US5693586A (en) | 1996-06-28 | 1997-12-02 | Hoechst Celanese Corporation | Palladium-gold catalyst for vinyl acetate production |
US6015769A (en) * | 1998-06-02 | 2000-01-18 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium, gold and copper supported on a carrier and prepared with potassium aurate |
-
1997
- 1997-05-19 ID IDW20002497A patent/ID26891A/id unknown
-
1998
- 1998-06-02 US US09/088,978 patent/US6350900B1/en not_active Expired - Lifetime
-
1999
- 1999-05-10 PE PE1999000384A patent/PE20000470A1/es not_active Application Discontinuation
- 1999-05-13 TW TW088107762A patent/TW476667B/zh not_active IP Right Cessation
- 1999-05-19 CN CN99806902A patent/CN1116109C/zh not_active Expired - Fee Related
- 1999-05-19 DE DE69919169T patent/DE69919169T2/de not_active Expired - Lifetime
- 1999-05-19 RU RU2000133240/04A patent/RU2216401C2/ru not_active IP Right Cessation
- 1999-05-19 EP EP99924326A patent/EP1091802B1/en not_active Expired - Lifetime
- 1999-05-19 ES ES99924326T patent/ES2226388T3/es not_active Expired - Lifetime
- 1999-05-19 BR BRPI9910750-3A patent/BR9910750B1/pt not_active IP Right Cessation
- 1999-05-19 AT AT99924326T patent/ATE272443T1/de active
- 1999-05-19 AU AU40852/99A patent/AU753815B2/en not_active Ceased
- 1999-05-19 WO PCT/US1999/010992 patent/WO1999062632A1/en active IP Right Grant
- 1999-05-19 TR TR2000/03584T patent/TR200003584T2/tr unknown
- 1999-05-19 UA UA2000126910A patent/UA69410C2/uk unknown
- 1999-05-19 NZ NZ508272A patent/NZ508272A/en not_active IP Right Cessation
- 1999-05-19 CZ CZ20004503A patent/CZ295988B6/cs not_active IP Right Cessation
- 1999-05-19 KR KR1020007013491A patent/KR100575967B1/ko not_active IP Right Cessation
- 1999-05-19 CA CA002333097A patent/CA2333097C/en not_active Expired - Fee Related
- 1999-05-19 HU HU0102638A patent/HUP0102638A3/hu unknown
- 1999-05-19 JP JP2000551881A patent/JP4610736B2/ja not_active Expired - Fee Related
- 1999-05-19 SK SK1824-2000A patent/SK284905B6/sk not_active IP Right Cessation
- 1999-05-27 AR ARP990102502A patent/AR018395A1/es active IP Right Grant
- 1999-05-31 MY MYPI99002153A patent/MY121382A/en unknown
- 1999-06-09 SA SA99200245A patent/SA99200245B1/ar unknown
-
2000
- 2000-11-15 ZA ZA200006639A patent/ZA200006639B/en unknown
- 2000-12-01 NO NO20006120A patent/NO322595B1/no not_active IP Right Cessation
-
2001
- 2001-08-20 US US09/933,214 patent/US6486093B2/en not_active Expired - Lifetime
-
2006
- 2006-06-29 NO NO20063038A patent/NO326959B1/no not_active IP Right Cessation
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TR200003584T2 (tr) | Vinil asetat katalizörü | |
TR200003582T2 (tr) | Metalik paladyum,bakır ve altın içeren vinil asetat katalizörü | |
TR199903000T2 (tr) | Vinil asetat üretilmesi için paladyum ve altin içerikli katalizör. | |
TR200003534T2 (tr) | Metalik paladyum, bakır ve altın içeren vinil asetat katalizörü. | |
TR199801084T2 (tr) | Oksijenat dönüsümünde geçis metali ihtiva eden küçük gözenekli moleküler elekli katalizörlerin kullanimi. | |
ID20555A (id) | Proses-proses untuk menghasilkan alkohol tak jenuh | |
NZ505647A (en) | Magnesium, calcium, barium or zirconium used as a fourth metal catalyst in the production of vinyl acetate | |
TR199802558A2 (tr) | Gaz halinde vinil asetat hazirlamak için bir katalist. | |
UA66814C2 (uk) | Спосіб виробництва вінілацетату в присутності каталізатора, що містить паладій, золото і третій метал | |
BR0015079B1 (pt) | catalisador de acetato de vinila contendo paládio e ouro metálicos e preparado utilizando ação sÈnica. | |
TR200001116T2 (tr) | Metalik paladyum, altın, kuprik asetat içeren vinil asetat katalizörü. | |
NZ506085A (en) | Vinyl acetate catalyst preparation method | |
TR199802087T2 (tr) | Vinil asetat katalizörü hazirlamak için yöntem. | |
BR0015179A (pt) | Catalisador constituido de paládio metálico e ouro metálico que são úteis para a produção de acetato de vinila pela reação de etileno, oxigênio e ácido acético | |
TR199903008T2 (tr) | Paladyum-altin-bakir katalizörü kullanilan vinil asetat islemi. | |
DK0563414T3 (da) | Fremgangsmåde til fremstilling af en katalysator til produktion af alkenylalkanoater | |
FI99204B (fi) | Menetelmä 2-kinoksalinoliyhdisteen valmistamiseksi | |
DE60034792D1 (de) | Verfahren zur Herstellung von Katalysatoren | |
TH29979C3 (th) | ตัวเร่งปฏิกิริยาไวนิลแอซิเททที่ประกอบรวมด้วยเมแทลลิคแพลเลเดียมและโกลด์ที่เตรียมด้วยโพแทสเซียมออเรท | |
YU49185B (sh) | Postupak za proizvodnju vinil acetata, primenom katalizatora koji sadrži metalni paladijum i zlato i kupriacetat i postupak za pripremanje katalizatora za proizvodnju vinil acetata |