KR100573655B1 - 이온 전도성 매트릭스, 상기 매트릭스를 포함하는 막 및 복합 전극, 상기 막 또는 전극의 캐스팅 또는 제조 방법, 및 상기 막 또는 전극을 포함하는 전기화학 전지, 연료 전지 및 수 전해조 - Google Patents

이온 전도성 매트릭스, 상기 매트릭스를 포함하는 막 및 복합 전극, 상기 막 또는 전극의 캐스팅 또는 제조 방법, 및 상기 막 또는 전극을 포함하는 전기화학 전지, 연료 전지 및 수 전해조 Download PDF

Info

Publication number
KR100573655B1
KR100573655B1 KR1020007009294A KR20007009294A KR100573655B1 KR 100573655 B1 KR100573655 B1 KR 100573655B1 KR 1020007009294 A KR1020007009294 A KR 1020007009294A KR 20007009294 A KR20007009294 A KR 20007009294A KR 100573655 B1 KR100573655 B1 KR 100573655B1
Authority
KR
South Korea
Prior art keywords
matrix
solvent
membrane
aqueous electrolyte
electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
KR1020007009294A
Other languages
English (en)
Korean (ko)
Other versions
KR20010034536A (ko
Inventor
엠마누엘 펠레드
타이르 두브데바니
아비 멜만
Original Assignee
텔-아비브 유니버시티 퓨처 테크놀로지 디벨롭먼트 엘.피.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from IL12341998A external-priority patent/IL123419A/xx
Priority claimed from IL12683098A external-priority patent/IL126830A/en
Application filed by 텔-아비브 유니버시티 퓨처 테크놀로지 디벨롭먼트 엘.피. filed Critical 텔-아비브 유니버시티 퓨처 테크놀로지 디벨롭먼트 엘.피.
Publication of KR20010034536A publication Critical patent/KR20010034536A/ko
Application granted granted Critical
Publication of KR100573655B1 publication Critical patent/KR100573655B1/ko
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0404—Methods of deposition of the material by coating on electrode collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
    • H01M50/497—Ionic conductivity
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/075—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound
    • C25B11/077—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound the compound being a non-noble metal oxide
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B13/00—Diaphragms; Spacing elements
    • C25B13/04—Diaphragms; Spacing elements characterised by the material
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • C25B9/23—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms comprising ion-exchange membranes in or on which electrode material is embedded
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
    • H01M10/38—Construction or manufacture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00—Hybrid cells; Manufacture thereof
    • H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
    • H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0407—Methods of deposition of the material by coating on an electrolyte layer
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0409—Methods of deposition of the material by a doctor blade method, slip-casting or roller coating
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0411—Methods of deposition of the material by extrusion
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/043—Processes of manufacture in general involving compressing or compaction
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/403—Manufacturing processes of separators, membranes or diaphragms
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/411—Organic material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/411—Organic material
    • H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/431—Inorganic material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/443—Particulate material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/446—Composite material consisting of a mixture of organic and inorganic materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
    • H01M50/491—Porosity
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/04—Cells with aqueous electrolyte
    • H01M6/06—Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0289—Means for holding the electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1046—Mixtures of at least one polymer and at least one additive
    • H01M8/1051—Non-ion-conducting additives, e.g. stabilisers, SiO2 or ZrO2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1081—Polymeric electrolyte materials characterised by the manufacturing processes starting from solutions, dispersions or slurries exclusively of polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Composite Materials (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Inert Electrodes (AREA)
  • Conductive Materials (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Primary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Fuel Cell (AREA)
KR1020007009294A 1998-02-24 1999-02-22 이온 전도성 매트릭스, 상기 매트릭스를 포함하는 막 및 복합 전극, 상기 막 또는 전극의 캐스팅 또는 제조 방법, 및 상기 막 또는 전극을 포함하는 전기화학 전지, 연료 전지 및 수 전해조 Expired - Lifetime KR100573655B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
IL12341998A IL123419A (en) 1998-02-24 1998-02-24 Proton conductive matrixes and their uses
IL123419 1998-02-24
IL12683098A IL126830A (en) 1998-10-30 1998-10-30 Ion conductive matrixes and their uses
IL126830 1998-10-30
PCT/IL1999/000109 WO1999044245A1 (en) 1998-02-24 1999-02-22 Ion conductive matrixes and their use

Publications (2)

Publication Number Publication Date
KR20010034536A KR20010034536A (ko) 2001-04-25
KR100573655B1 true KR100573655B1 (ko) 2006-04-26

Family

ID=26323596

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020007009294A Expired - Lifetime KR100573655B1 (ko) 1998-02-24 1999-02-22 이온 전도성 매트릭스, 상기 매트릭스를 포함하는 막 및 복합 전극, 상기 막 또는 전극의 캐스팅 또는 제조 방법, 및 상기 막 또는 전극을 포함하는 전기화학 전지, 연료 전지 및 수 전해조

Country Status (8)

Country Link
US (1) US6811911B1 (https=)
EP (1) EP1066656B1 (https=)
JP (1) JP4937449B2 (https=)
KR (1) KR100573655B1 (https=)
AU (1) AU2636999A (https=)
CA (1) CA2320696C (https=)
DE (1) DE69943335D1 (https=)
WO (1) WO1999044245A1 (https=)

Families Citing this family (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19839217C2 (de) * 1998-08-28 2001-02-08 Fraunhofer Ges Forschung Pastöse Massen, Schichten und Schichtverbände, Zellen und Verfahren zur Herstellung
DE19964159B4 (de) * 1998-10-20 2005-08-11 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren zum Herstellen selbsttragender oder auf einem Substrat aufliegender, in elektrochemischen Bauelementen verwendbarer Schichten und Zwischenprodukte hierfür
EP1096591A1 (en) * 1999-10-26 2001-05-02 MERCK PATENT GmbH Polymer electrolyte membrane for use in lithium batteries
IL150645A0 (en) 2000-01-18 2003-02-12 Univ Ramot Fuel cell with proton conducting membrane
US6447943B1 (en) 2000-01-18 2002-09-10 Ramot University Authority For Applied Research & Industrial Development Ltd. Fuel cell with proton conducting membrane with a pore size less than 30 nm
US6432586B1 (en) 2000-04-10 2002-08-13 Celgard Inc. Separator for a high energy rechargeable lithium battery
CA2312213A1 (fr) * 2000-06-15 2001-12-15 Hydro-Quebec Nouveau procede pour preparation des electrodes et electrolytes pour les batteries li-ion
KR100373325B1 (ko) * 2000-12-05 2003-02-25 한국전자통신연구원 타이타니아 나노입자를 충전시킨 고분자 전해질 및 그제조방법
DE60228720D1 (de) 2001-07-18 2008-10-16 Univ Tel Aviv Future Tech Dev Brennstoffzelle mit protonenleitender membran und mit verbesserter wasser- und brennstoffhandhabung
JP4196597B2 (ja) * 2002-06-19 2008-12-17 新神戸電機株式会社 鉛蓄電池およびそれに用いるカーボン材料
TWI352252B (en) 2003-09-18 2011-11-11 Dainippon Ink & Chemicals Ionic conductor and electrochemical display elemen
DE102005017682A1 (de) * 2005-04-08 2006-10-12 Varta Microbattery Gmbh Galvanisches Element
US20080038447A1 (en) * 2005-07-21 2008-02-14 Yu-Ta Tu Fabricating method of electrode adhesive bicell
US20070125644A1 (en) * 2005-09-15 2007-06-07 Board Of Regents, The University Of Texas System Reduction of the loss of zinc by its reaction with oxygen in galvanized steel and batteries
US7838138B2 (en) * 2005-09-19 2010-11-23 3M Innovative Properties Company Fuel cell electrolyte membrane with basic polymer
US7517604B2 (en) * 2005-09-19 2009-04-14 3M Innovative Properties Company Fuel cell electrolyte membrane with acidic polymer
US7732045B2 (en) 2006-04-12 2010-06-08 Asahi Glass Company, Limited Film for membrane structure
US20080118848A1 (en) * 2006-11-16 2008-05-22 Electronics & Telecommunications Research Institute Aqeuous electrolyte composition and sealed-type primary film battery including electrolyte layer formed of the aqueous electrolyte composition
JP5274035B2 (ja) * 2007-03-27 2013-08-28 三洋電機株式会社 燃料電池
US8722226B2 (en) 2008-06-12 2014-05-13 24M Technologies, Inc. High energy density redox flow device
US9786944B2 (en) 2008-06-12 2017-10-10 Massachusetts Institute Of Technology High energy density redox flow device
US11909077B2 (en) 2008-06-12 2024-02-20 Massachusetts Institute Of Technology High energy density redox flow device
US8968967B2 (en) * 2008-09-17 2015-03-03 Ballard Power Systems Inc. Fuel cell catalyst support with fluoride-doped metal oxides/phosphates and method of manufacturing same
US20110136047A1 (en) * 2008-09-19 2011-06-09 Belabbes Merzougui Fuel cell catalyst support with boron carbide-coated metal oxides/phosphates and method of manufacturing same
EP2396843A1 (en) 2009-02-10 2011-12-21 UTC Power Corporation Fuel cell catalyst with metal oxide/phosphate support structure and method of manufacturing same
JP5882888B2 (ja) * 2009-04-06 2016-03-09 ２４エム・テクノロジーズ・インコーポレイテッド２４Ｍ Ｔｅｃｈｎｏｌｏｇｉｅｓ， Ｉｎｃ． レドックスフロー電池を使用した燃料システム
CN104319410B (zh) * 2010-01-25 2017-01-11 雷蒙特亚特特拉维夫大学有限公司 在燃料电池堆内维持不同电解质和气体压力的方法
JP5535339B2 (ja) 2010-01-25 2014-07-02 ラモット アット テル−アヴィヴ ユニヴァーシテイ リミテッド 燃料電池、再生型燃料電池及び膜電極アセンブリ（ｍｅａ）
KR20130009750A (ko) 2010-01-25 2013-01-23 라모트 앳 텔-아비브 유니버시티 리미티드 전기화학 시스템 및 이의 작동 방법
EP2529441B1 (en) * 2010-01-25 2016-05-04 Ramot at Tel Aviv University, Ltd. Method of manufacturing proton-conducting membranes
MX2012008653A (es) 2010-01-25 2013-01-29 Univ Ramot Placas bipolares y apilados de celdas de combustible regenerativas que incluyen las mismas.
US7931985B1 (en) * 2010-11-08 2011-04-26 International Battery, Inc. Water soluble polymer binder for lithium ion battery
US8076026B2 (en) * 2010-02-05 2011-12-13 International Battery, Inc. Rechargeable battery using an aqueous binder
US20110143206A1 (en) * 2010-07-14 2011-06-16 International Battery, Inc. Electrode for rechargeable batteries using aqueous binder solution for li-ion batteries
US8102642B2 (en) * 2010-08-06 2012-01-24 International Battery, Inc. Large format ultracapacitors and method of assembly
CN102183862B (zh) * 2011-03-04 2012-12-19 华中科技大学 一种具有单基板结构的电致变色器件
WO2012125644A2 (en) 2011-03-13 2012-09-20 Porous Power Technologies Surface free energy based filled polymer microporous films
EP2836625B1 (en) 2012-04-13 2017-12-06 Danmarks Tekniske Universitet High performance reversible electrochemical cell for h2o electrolysis or conversion of co2 and h2o to fuel
US9484569B2 (en) 2012-06-13 2016-11-01 24M Technologies, Inc. Electrochemical slurry compositions and methods for preparing the same
US9362583B2 (en) 2012-12-13 2016-06-07 24M Technologies, Inc. Semi-solid electrodes having high rate capability
US8993159B2 (en) 2012-12-13 2015-03-31 24M Technologies, Inc. Semi-solid electrodes having high rate capability
EP2953190B1 (en) 2013-02-01 2019-05-22 Nippon Shokubai Co., Ltd. Electrode precursor, electrode, and battery
US9083034B2 (en) 2013-03-15 2015-07-14 Ford Global Technologies, Llc Treated battery separator
AU2016234205B2 (en) * 2015-03-18 2019-01-03 Asahi Kasei Kabushiki Kaisha Diaphragm for alkaline water electrolysis, alkaline water electrolysis apparatus, method for producing hydrogen, and method for producing diaphragm for alkaline water electrolysis
JP6765855B2 (ja) * 2015-10-29 2020-10-07 株式会社日本触媒 アニオン伝導性膜
WO2017124098A1 (en) 2016-01-15 2017-07-20 24M Technologies, Inc. Systems and methods for infusion mixing a slurry-based electrode
CN106637286B (zh) * 2016-12-21 2018-07-31 首都师范大学 负载型NiOOH电极材料及其制备方法和用途
US11272829B2 (en) 2019-04-02 2022-03-15 Dorai Home, Inc. Drying appliance
CN110257856B (zh) * 2019-07-22 2020-12-15 天津大学 复合电极及其制备方法和用途以及电催化全解水装置

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL52462A (en) 1977-07-05 1979-11-30 Yeda Res & Dev Method of producing solute rejecting dynamic membrane filters and filters including such membranes
JPS57172927A (en) * 1981-03-20 1982-10-25 Asahi Glass Co Ltd Cation exchange membrane for electrolysis
US4529671A (en) 1981-09-07 1985-07-16 Hitachi, Ltd. Fuel cell
US4687715A (en) 1985-07-26 1987-08-18 Westinghouse Electric Corp. Zirconium pyrophosphate matrix layer for electrolyte in a fuel cell
JPS6348765A (ja) * 1986-08-19 1988-03-01 Japan Gore Tex Inc 燃料電池用電解質マトリクスおよびその製造法
JPS63187574A (ja) * 1987-01-29 1988-08-03 Japan Gore Tex Inc 燃料電池電極−マトリクス一体成形体及びその製法
WO1988009799A1 (en) * 1987-06-12 1988-12-15 Asahi Glass Company Ltd. Method for producing an alkali metal hydroxide
JPH06505756A (ja) 1990-09-20 1994-06-30 サイマット　リミテッド ポリマー膜
JPH04173856A (ja) * 1990-11-06 1992-06-22 Nok Corp 固体高分子電解質
JP3385554B2 (ja) * 1992-09-25 2003-03-10 政廣 渡辺 高分子固体電解質組成物及びその組成物を用いた電気化学セル
US5523181A (en) * 1992-09-25 1996-06-04 Masahiro Watanabe Polymer solid-electrolyte composition and electrochemical cell using the composition
JP3498321B2 (ja) * 1992-09-25 2004-02-16 田中貴金属工業株式会社 高分子固体電解質型燃料電池
US5456600A (en) 1992-11-09 1995-10-10 Ormco Corporation Coordinated orthodontic archwires and method of making same
DE4238688A1 (de) 1992-11-17 1994-05-19 Bosch Gmbh Robert Gesinterter Festelektrolyt mit hoher Sauerstoffionenleitfähigkeit
JPH09306527A (ja) * 1996-05-14 1997-11-28 Toshiba Corp 燃料電池
US5834136A (en) * 1996-06-17 1998-11-10 Valence Technology, Inc. Method of preparing polymeric electrolytes
US5643689A (en) 1996-08-28 1997-07-01 E.C.R.-Electro-Chemical Research Ltd. Non-liquid proton conductors for use in electrochemical systems under ambient conditions
JPH10270055A (ja) * 1997-03-25 1998-10-09 Mitsubishi Electric Corp 電気化学触媒並びにそれを用いた電気化学反応装置、電気化学素子、リン酸型燃料電池およびメタノール直接型燃料電池
US6025092A (en) * 1998-02-13 2000-02-15 E. I. Du Pont De Nemours And Company Fluorinated ionomers and their uses
US6124059A (en) * 1998-06-23 2000-09-26 Daramic, Inc. Separator for sealed lead accumulators
US6447909B1 (en) * 1999-01-14 2002-09-10 Sumitomo Metal Mining Co., Ltd. Transparent conductive layered structure and method of producing the same, and coating liquid for forming transparent conductive layer used in production of transparent conductive layered structure and method of producing the same

Also Published As

Publication number Publication date
CA2320696C (en) 2010-08-24
JP2002505506A (ja) 2002-02-19
WO1999044245A1 (en) 1999-09-02
EP1066656A1 (en) 2001-01-10
KR20010034536A (ko) 2001-04-25
JP4937449B2 (ja) 2012-05-23
CA2320696A1 (en) 1999-09-02
DE69943335D1 (de) 2011-05-19
AU2636999A (en) 1999-09-15
EP1066656B1 (en) 2011-04-06
EP1066656A4 (en) 2001-05-30
US6811911B1 (en) 2004-11-02

Similar Documents

Publication Publication Date Title
KR100573655B1 (ko) 이온 전도성 매트릭스, 상기 매트릭스를 포함하는 막 및 복합 전극, 상기 막 또는 전극의 캐스팅 또는 제조 방법, 및 상기 막 또는 전극을 포함하는 전기화학 전지, 연료 전지 및 수 전해조
KR100446662B1 (ko) 연료 전지용 복합 폴리머 전해질 막 및 그의 제조방법
KR101817628B1 (ko) 가스 확산 전극, 이를 제조하는 방법, 이를 포함하는 막 전극 어셈블리 및 이를 포함하는 막전극 어셈블리를 제조하는 방법
JP5524330B2 (ja) 高分子複合電解質、高分子複合電解質を含む電池、およびそれを調製する方法
CA2264830C (en) Solid electrolyte composite for electrochemical reaction apparatus
JP4041422B2 (ja) 固体電解質及び該固体電解質を使用した電気化学システム
US20010024755A1 (en) Solid electrolyte composite for electrochemical reaction apparatus
JP2002505506A5 (https=)
JP2002522616A (ja) 向上した高分子型電気化学電池用の、スルホン化ポリ（フェニレンオキシド）に基づくブレンド膜
Teng et al. PTFE/SPEEK/PDDA/PSS composite membrane for vanadium redox flow battery application
WO2002054515A2 (en) Conductive polyamine-based electrolyte
JPH09293518A (ja) 薄膜状電解質および該電解質を用いた電池
KR20150088824A (ko) 중합체 및 전도성 염으로 코팅된 세퍼레이터 및 이를 사용하는 전기화학 소자
JP4132912B2 (ja) ゲル電解質とその製造方法とその利用
JPH0575835B2 (https=)
KR100800921B1 (ko) 전기 화학 캐패시터
KR100590967B1 (ko) 고온전도성 고분자 나노복합막과 이의 제조방법 및 이를이용한 막-전극 접합체 및 이를 포함하는고분자전해질연료전지
JP2008222957A (ja) アルキレンオキシドポリマーからなる多孔質膜とこれを基材とする高分子固体電解質
JP3752235B2 (ja) 電子部品用セパレータ
JP2007180444A (ja) 電気化学キャパシタ
KR102734348B1 (ko) 레독스 흐름전지용 이온교환막 및 이의 제조방법, 및 이를 포함하는 레독스 흐름전지
CN115732770B (zh) 一种柔性可自愈电解质膜及其制备方法、电池
CN101297001A (zh) 离子传导材料、固体聚合物电解质膜和燃料电池
JPH09320617A (ja) 高分子固体電解質の製造方法
IL126830A (en) Ion conductive matrixes and their uses

Legal Events

Date Code Title Description
PA0105 International application

Patent event date: 20000823

Patent event code: PA01051R01D

Comment text: International Patent Application

PG1501 Laying open of application
A201 Request for examination
PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 20040223

Comment text: Request for Examination of Application

N231 Notification of change of applicant
PN2301 Change of applicant

Patent event date: 20050418

Comment text: Notification of Change of Applicant

Patent event code: PN23011R01D

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

Comment text: Notification of reason for refusal

Patent event date: 20050929

Patent event code: PE09021S01D

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

Patent event code: PE07011S01D

Comment text: Decision to Grant Registration

Patent event date: 20060317

GRNT Written decision to grant
PR0701 Registration of establishment

Comment text: Registration of Establishment

Patent event date: 20060418

Patent event code: PR07011E01D

PR1002 Payment of registration fee

Payment date: 20060419

End annual number: 3

Start annual number: 1

PG1601 Publication of registration
PR1001 Payment of annual fee

Payment date: 20090413

Start annual number: 4

End annual number: 4

PR1001 Payment of annual fee

Payment date: 20100413

Start annual number: 5

End annual number: 5

PR1001 Payment of annual fee

Payment date: 20110412

Start annual number: 6

End annual number: 6

PR1001 Payment of annual fee

Payment date: 20120409

Start annual number: 7

End annual number: 7

FPAY Annual fee payment

Payment date: 20130404

Year of fee payment: 8

PR1001 Payment of annual fee

Payment date: 20130404

Start annual number: 8

End annual number: 8

FPAY Annual fee payment

Payment date: 20140410

Year of fee payment: 9

PR1001 Payment of annual fee

Payment date: 20140410

Start annual number: 9

End annual number: 9

FPAY Annual fee payment

Payment date: 20160407

Year of fee payment: 11

PR1001 Payment of annual fee

Payment date: 20160407

Start annual number: 11

End annual number: 11

FPAY Annual fee payment

Payment date: 20170406

Year of fee payment: 12

PR1001 Payment of annual fee

Payment date: 20170406

Start annual number: 12

End annual number: 12

FPAY Annual fee payment

Payment date: 20180406

Year of fee payment: 13

PR1001 Payment of annual fee

Payment date: 20180406

Start annual number: 13

End annual number: 13

EXPY Expiration of term
PC1801 Expiration of term

Termination date: 20190822

Termination category: Expiration of duration