KR100375460B1 - 전기 접속용 도전 패드를 형성하기 위한 방법 및 형성된 도전 패드 - Google Patents
전기 접속용 도전 패드를 형성하기 위한 방법 및 형성된 도전 패드 Download PDFInfo
- Publication number
- KR100375460B1 KR100375460B1 KR10-2001-0005797A KR20010005797A KR100375460B1 KR 100375460 B1 KR100375460 B1 KR 100375460B1 KR 20010005797 A KR20010005797 A KR 20010005797A KR 100375460 B1 KR100375460 B1 KR 100375460B1
- Authority
- KR
- South Korea
- Prior art keywords
- copper pad
- layer
- pad surface
- kpa
- protective layer
- Prior art date
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- 238000000034 method Methods 0.000 title claims abstract description 87
- 239000010949 copper Substances 0.000 claims abstract description 123
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 119
- 229910052802 copper Inorganic materials 0.000 claims abstract description 118
- 239000010410 layer Substances 0.000 claims abstract description 70
- 239000011241 protective layer Substances 0.000 claims abstract description 58
- 239000012790 adhesive layer Substances 0.000 claims abstract description 43
- 229910052796 boron Inorganic materials 0.000 claims abstract description 35
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 28
- 229910000679 solder Inorganic materials 0.000 claims abstract description 28
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 24
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910000510 noble metal Inorganic materials 0.000 claims abstract description 22
- 239000011574 phosphorus Substances 0.000 claims abstract description 22
- 229910018104 Ni-P Inorganic materials 0.000 claims abstract description 20
- 229910018536 Ni—P Inorganic materials 0.000 claims abstract description 20
- 229910001092 metal group alloy Inorganic materials 0.000 claims abstract description 20
- 230000006911 nucleation Effects 0.000 claims abstract description 17
- 238000010899 nucleation Methods 0.000 claims abstract description 17
- -1 Ni-WP Inorganic materials 0.000 claims abstract description 12
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 11
- 230000008021 deposition Effects 0.000 claims abstract description 10
- 229910052737 gold Inorganic materials 0.000 claims abstract description 8
- 229910009038 Sn—P Inorganic materials 0.000 claims abstract description 7
- 229910020674 Co—B Inorganic materials 0.000 claims abstract description 6
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 5
- 229910052709 silver Inorganic materials 0.000 claims abstract description 5
- 239000003929 acidic solution Substances 0.000 claims abstract description 3
- 238000000151 deposition Methods 0.000 claims description 33
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 26
- 239000000243 solution Substances 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 6
- 239000004327 boric acid Substances 0.000 claims description 6
- 238000007772 electroless plating Methods 0.000 claims description 6
- 239000002105 nanoparticle Substances 0.000 claims description 6
- 239000000758 substrate Substances 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000007654 immersion Methods 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- 229910000577 Silicon-germanium Inorganic materials 0.000 claims description 4
- LEVVHYCKPQWKOP-UHFFFAOYSA-N [Si].[Ge] Chemical compound [Si].[Ge] LEVVHYCKPQWKOP-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 claims description 3
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 claims description 3
- 239000008366 buffered solution Substances 0.000 claims description 3
- 229910001429 cobalt ion Inorganic materials 0.000 claims description 3
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 3
- YPTUAQWMBNZZRN-UHFFFAOYSA-N dimethylaminoboron Chemical compound [B]N(C)C YPTUAQWMBNZZRN-UHFFFAOYSA-N 0.000 claims description 3
- 238000001746 injection moulding Methods 0.000 claims description 3
- 229940046892 lead acetate Drugs 0.000 claims description 3
- 229910001453 nickel ion Inorganic materials 0.000 claims description 3
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims description 3
- 238000007650 screen-printing Methods 0.000 claims description 3
- 229910001379 sodium hypophosphite Inorganic materials 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 2
- 239000012212 insulator Substances 0.000 claims description 2
- 230000004888 barrier function Effects 0.000 abstract description 23
- 238000009792 diffusion process Methods 0.000 abstract description 16
- 239000010970 precious metal Substances 0.000 abstract description 10
- 239000000956 alloy Substances 0.000 abstract description 6
- 229910045601 alloy Inorganic materials 0.000 abstract description 5
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 238000005137 deposition process Methods 0.000 abstract 1
- 239000002356 single layer Substances 0.000 abstract 1
- 239000010931 gold Substances 0.000 description 26
- 235000012431 wafers Nutrition 0.000 description 18
- 229910052782 aluminium Inorganic materials 0.000 description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 11
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000005530 etching Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- 229910052702 rhenium Inorganic materials 0.000 description 3
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 3
- 229910052707 ruthenium Inorganic materials 0.000 description 3
- 239000010944 silver (metal) Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000001465 metallisation Methods 0.000 description 2
- 238000005272 metallurgy Methods 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 238000005219 brazing Methods 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002355 dual-layer Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- MUJIDPITZJWBSW-UHFFFAOYSA-N palladium(2+) Chemical compound [Pd+2] MUJIDPITZJWBSW-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L24/00—Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
- H01L24/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L24/42—Wire connectors; Manufacturing methods related thereto
- H01L24/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L24/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1603—Process or apparatus coating on selected surface areas
- C23C18/1607—Process or apparatus coating on selected surface areas by direct patterning
- C23C18/1608—Process or apparatus coating on selected surface areas by direct patterning from pretreatment step, i.e. selective pre-treatment
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1646—Characteristics of the product obtained
- C23C18/165—Multilayered product
- C23C18/1651—Two or more layers only obtained by electroless plating
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/1803—Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces
- C23C18/1824—Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces by chemical pretreatment
- C23C18/1827—Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces by chemical pretreatment only one step pretreatment
- C23C18/1831—Use of metal, e.g. activation, sensitisation with noble metals
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/1803—Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces
- C23C18/1824—Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces by chemical pretreatment
- C23C18/1837—Multistep pretreatment
- C23C18/1844—Multistep pretreatment with use of organic or inorganic compounds other than metals, first
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/32—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
- C23C18/34—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/32—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
- C23C18/34—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents
- C23C18/36—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents using hypophosphites
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/50—Assembly of semiconductor devices using processes or apparatus not provided for in a single one of the subgroups H01L21/06 - H01L21/326, e.g. sealing of a cap to a base of a container
- H01L21/60—Attaching or detaching leads or other conductive members, to be used for carrying current to or from the device in operation
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/532—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body characterised by the materials
- H01L23/53204—Conductive materials
- H01L23/53209—Conductive materials based on metals, e.g. alloys, metal silicides
- H01L23/53228—Conductive materials based on metals, e.g. alloys, metal silicides the principal metal being copper
- H01L23/53238—Additional layers associated with copper layers, e.g. adhesion, barrier, cladding layers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L24/00—Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
- H01L24/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L24/02—Bonding areas ; Manufacturing methods related thereto
- H01L24/03—Manufacturing methods
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L24/00—Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
- H01L24/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L24/02—Bonding areas ; Manufacturing methods related thereto
- H01L24/04—Structure, shape, material or disposition of the bonding areas prior to the connecting process
- H01L24/05—Structure, shape, material or disposition of the bonding areas prior to the connecting process of an individual bonding area
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L24/00—Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
- H01L24/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L24/10—Bump connectors ; Manufacturing methods related thereto
- H01L24/11—Manufacturing methods
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K13/00—Apparatus or processes specially adapted for manufacturing or adjusting assemblages of electric components
- H05K13/06—Wiring by machine
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/22—Secondary treatment of printed circuits
- H05K3/24—Reinforcing the conductive pattern
- H05K3/244—Finish plating of conductors, especially of copper conductors, e.g. for pads or lands
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/54—Contact plating, i.e. electroless electrochemical plating
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
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Abstract
향상된 확산 장벽 및 접착 특성을 갖는 전기 접속용 구리 패드면을 제공하기 위한 방법이 제공된다. 이 방법에서, 우선 산성 용액에서 세정된 구리 패드면이 제공된다. 그 다음, 인 또는 붕소-함유 금속 합금으로 된 보호층이 구리 패드면 상에 피착되고, 귀금속의 접착층이 보호층의 상부상에 피착된다. 보호층은 단일층일 수도 있고, Ni-P, Co-P, Co-W-P, Co-Sn-P, Ni-W-P, Co-B, Ni-B, Co-Sn-B, Co-W-B, 및 Ni-W-B와 같이 인 또는 붕소-함유 급속 합금으로 형성된 서로 밀접하게 결합된 2개 이상의 층들일 수도 있다. 보호층에 대한 적절한 두께는 약 1000Å 내지 10000Å이며, 양호하게는 약 3000Å내지 7000Å이다. 접착층은, 두께가 약 500Å 내지 약 4000Å정도이고 양호하게는 1000Å 내지 2000Å정도인 Au, Pt, Pd, 및 Ag와 같은 귀금속으로 형성될 수 있다. 대안으로, 보호층의 무전해 피착 이전에 Pd로 된 핵형성층이 구리 도전 패드면과 보호층 사이에 피착된다. 대안으로, 무전해 Au 피착 공정에 의해 접착층의 상부에 추가적인 귀금속층이 피착되어 최종 귀금속층의 두께를 약 2000Å 내지 12000Å정도, 양호하게는, 약 4000Å 내지 6000Å정도로 증가시킨다. 본 발명은, 구리 패드면, 인 또는 붕소-함유 금속 합금으로된 보호층, 및 보호층의 상부에 피착된 귀금속의 접착층을 포함하며 그 상부에 전기 접속부를 형성하기 위한 도전 패드도 역시 공개한다. 나아가, 본 발명은 접착층의 상부에 일체로 형성된 전기 접속부, 즉, 와이어접합 또는 땜납 범프를 갖는 도전 패드를 포함하는 전기 구조물에도 역시 관련되어 있다.
Description
본 발명은 전기 접속용 도전 패드(conductive pad) 및 형성된 패드에 관한 것으로, 보다 구체적으로는 와이어접합(wirebond) 또는 땜납 범프(solder bump)에대한 전기 접속용 도전성 구리 패드면을 형성하기 위한 방법 및 형성된 도전성 구리 패드에 관한 것이다.
반도체 장치의 제조시에, 집적 회로(IC) 칩은 최종 공정 단계에서 패키지로 조립될 것이다. 그 다음 조립된 패키지는 대규모 회로의 일부로서 인쇄 회로 기판(printed circuit board)에 접속될 수 있다. 집적 회로 칩과의 전기적 통신을 이루기 위해, IC 칩상의 복수개의 접합 패드들을 와이어 접합 공정이나 땜납 범프 공정을 사용하여 외부 회로에 접속시킬 수도 있다.
전형적인 IC 칩에서, 트랜지스터와 같은 능동형 회로 소자, 저항등은 칩의 중앙부, 즉, 액티브 영역(active region)에 위치하는 반면, 접합 패드는 후속된 접합 공정에서 능동 회로 소자들이 손상되지 않도록 액티브 영역의 주변에 정렬된다. 와이어 접합 공정이 수행될 때, 이 공정은 금 또는 알루니늄 와이어를 초음파 에너지를 이용하여 용융시켜 칩상의 접합 패드에 접합시키는 단계를 포함한다. 접합이 형성된 후 와이어가 접합 패드로부터 잡아당겨진다(pulling away). 와이어 잡아당김 공정은 종종 접합 패드 들림(lift-off)이라 알려진 결함을 유발한다. 이러한 결함은 금 와이어를 접합 패드에 부착시키는 공정 동안에 높은 수준의 응력이 접합 패드에 작용하기 때문에, 즉, 하부층들에 대해 부실하게 접착된 층들상에 비교적 크고 무거운 접합부가 위치하기 때문에 발생한다.
예를 들어, 층들간 접착에 영향을 미치는 한 요인은, 후속된 고온 공정 동안에 하부에 놓인 도전층들 내로 알루미늄이 확산하는 것을 방지하기 위해 TiN으로 형성된 확산 장벽층(diffusion barrier layer)을 일반적으로 이용한다는 점이다.이용되는 확산 장벽층, 즉, TiN, TiW 또는 다른 적절한 합금들은 접합 패드 내의 하부 산화물층에 대해 강한 접착력을 가지지 않는다. 이것은 접합 패드 들림 결함을 초래하는 한 요인이 된다. 높은 접합 응력 및 높은 당김력과 같은 다른 이유들도 역시 들림 문제에 기여한다. 대부분의 들림 문제는 실리콘 도전층과 절연층(즉, SiO2)층간의 계면에서 발생한다.
전기적 접속을 형성하기 위한 알루미늄 또는 금 와이어에 의한 와이어접합 공정외에, 접합 패드로부터 제2 레벨 패키징이나 회로 보드로 전자 신호를 전송하기 위해 패키지에 칩을 부착시키는데 있어서, 땜납 범프(a.k.a "C4") 공정이 이용되어 왔다. 땜납 범프 공정은 IBM사에 의해 거의 독점적으로 이용되어 온 반면, 대부분의 IC 산업계는 와이어접합 기술을 사용해왔다. 종래의 와이어접합 공정에서, 칩 표면상의 접합 패드는 표준 툴 및 고도로 자동화된 툴에 의한 알루미늄 또는 금 와이어의 부착을 용이하게 해주는 알루미늄으로 형성된다. 그러나, 최근 IC칩 BEOL(Back-end-of-line)의 모든 배선이 구리 배선으로 이루어지는 구리 기술의 도입과 더불어, 땜납 범프 및 알루미늄 또는 구리 와이어접합 양쪽 모두를 구리 접합 패드상에서의 직접적인 처리를 통해 수행하거나, Cu 패드상에 패터닝된 적절한 Al 캡을 추가하되 Al과 Cu사이에 적절한 박막 장벽 금속을 삽입하여 이들간의 상호확산을 방지하도록 하는 방법(즉, 본 명세서에서 참고용으로 인용하는 "Robust Interconnect Structure"라는 제목으로 1999년 5월 19일 출원된 IBM 특허출원 도켓번호 FI 999-078)에 의해 수행하여 왔다.
구리 패드상에서의 직접적인 와이어접합은 용이하게 수행될 수 없는데, 이는 순수한 구리상에서 알루미늄이나 구리 와이어에 의해 형성된 와이어접합은 부식, 산화 및 열적 확산 문제에 놓이기 쉽기 때문이다. 구리 패드로의 직접적인 와이어접합은 신뢰성이 없으며 실패하기 쉽다. Al 패드 캡 기술은 피착외에도 리쏘그래픽 패턴(마스크) 및 에칭 싸이클을 요하기 때문에 비용이 상당히 든다. 따라서, 구리 접합 패드, 즉, IC 산업 분야에서 이용될 수 있는 구리칩상의 접합 패드의 와이어 접합시에 마스크를 사용하지 않는 해결책을 제공하는 것은 상업적으로 상당히 중요하다.
따라서, 종래 방법의 결점이나 단점을 갖지 않는 전기 접속용의 도전성 패드면을 제공하기 위한 방법을 제공하는 것이다.
본 발명의 또 다른 목적은 와이어접합이나 땜납 범프 공정중 어느 하나에 의해 전기 접속용 도전패드면을 준비하기 위한 방법을 제공하는 것이다.
본 발명의 역시 또 다른 목적은, 추가적인 포토마스크 및 에칭 단계를 요하지 않고 구리 패드면 상에 먼저 보호층을 형성한 다음 접착층을 형성함으로써 전기 접속용 구리 패드면을 제공하기 위한 방법을 제공하는 것이다(본 명세서에서 참고용으로 인용된 "Self-Aligned Corrosion Stop for Copper C4 and Wirebond"라는 제목으로 1999년 5월 14일 출원된 IBM사의 특허출원 도켓번호 Fu998-181호).
본 발명의 역시 또 다른 목적은 먼저 구리 패드면 상에 인 또는 붕소-함유 금속 합금으로 만들어진 보호막층을 피착함으로써, 전기 접속용 구리 패드면을 제공하기 위한 방법을 제공하는 것이다.
본 발명의 역시 또 다른 목적은 구리 패드면 상에 앞서 형성된 보호층의 상부에 귀금속(noble metal)의 접착층을 피착시켜 전기 접속용 구리 패드면을 제공하기 위한 방법을 제공하는 것이다.
본 발명의 역시 또 다른 목적은 보호층의 피착 이전에 구리 패드면상에 귀금속의 핵형성층(nucleation layer)을 피착하는 단계를 더 포함하는 전기 접속용 구리 패드면을 제공하기 위한 방법을 제공하는 것이다.
본 발명의 역시 또 다른 목적은 와이어접합 또는 땜납 범프를 이용한 전기 접속부를 제공하기 위해 그 상부에 구리 패드면과, 구리 패드면상의 보호층과, 보호층 상부상의 접착층을 포함하는 전기 접속부를 형성하기 위한 도전 패드를 제공하는 것이다.
본 발명의 역시 또 다른 목적은 구리 패드면, 구리 패드면상의 보호층, 보호층 상부상의 접착층, 및 접착층과 일체로 형성된 와이어접합 또는 땜납 범프로 된 전기 접속부를 포함하는 전기 접속을 제공하기 위한 전기 구조물을 제공하는 것이다.
본 발명에 따르면, 와이어접합 또는 땜납 범프를 이용한 전기 접속용 구리 패드면을 제공하기 위한 방법 및 이 방법에 의해 형성된 장치가 제공된다.
양호한 실시예에서, 전기 접속용 구리 패드면을 제공하기 위한 방법은, 먼저 구리 패드면을 제공하는 단계와, 구리 패드면상에 인 또는 붕소-함유 금속 합금의 보호층을 피착하는 단계와, 보호층의 상부상에 귀금속의 접착층을 피착하는 단계에의해 수행될 수 있다.
전기 접속용 구리 패드면을 제공하기 위한 방법은, 보호층의 피착 이전에 구리 패드면상에 귀금속의 핵형성층을 피착하는 단계를 더 포함한다. 이 방법은 산성 용액 내에서 구리 패드면을 세척하는 단계와, 귀금속의 핵형성층을 구리 패드면상에 피착하는 단계를 더 포함한다. 핵형성층은 팔라듐 또는 팔라듐 나노입자(nanoparticle)를 피착해서 형성할 수 있다. 루테늄(ruthenium)이나 레늄(rhenium)과 같은 다른 귀금속의 나노입자들도 사용될 수 있지만 Pd 나노입자가 가장 흔하게 사용된다. 이 방법은 핵형성층이 피착된 후 구리 패드면을 물로 린스(rinse)하는 단계, 또는 무전해 도금법(electroless plating technique)에 의해 보호층을 피착하는 단계를 더 포함할 수 있다. 보호층을 피착하는 단계는 코발트 이온(cobalt ion), 텅스텐산염 이온(tungstate ion), 붕산(boric acid), 구연산염 이온(citrate ion), 초산납(lead acetate), 차아인산염(hypophosphite)을 포함하는 무전해조(electroless bath)의 가열되고 버퍼링된 용액에 구리 패드면을 접촉시키는 단계와, 그 후, 니켈 이온, 구연산염 이온, 붕산, 나트륨 차아인산염(sodium hypophosphite) 또는 디메틸 아미노 보레인(dimethyl amino borane)을 포함하는 가열된 무전해액(heated electroless solution)에 구리 패드면을 접촉시키는 단계를 더 포함할 수도 있다.
전기 접속용 구리 패드면을 제공하기 위한 방법에서, 접착층은 Au, Pt, Pd, 및 Ag로 구성된 그룹으로부터 선택된 금속으로 형성될 수 있다. 접착층은 IC를 침잠 Au 용액(immersion Au solution) 내에 침잠시킴으로써 형성될 수 있다. 접착층은 두께가 대략 500Å 내지 4000Å인 귀금속으로 형성될 수 있다. 인 또는 붕소 함유 금속 합금은 Ni-P, Co-P, Co-W-P, Co-Sn-P, Ni-W-P, Co-B, Ni-B, Co-Sn-B, Co-W-B, 및 Ni-W-B로 구성된 그룹으로부터 선택될 수 있다. 보호층은 두께가 대략 1000Å 내지 10000Å정도의 인 또는 붕소-함유 Co 또는 Ni 금속 합금으로 형성될 수 있다. 이 방법은 무전해 도금법에 의해 접착층의 상부에 귀금속을 피착하되 귀금속의 전체 두께가 2000Å 내지 12000Å정도 되도록 피착하는 단계를 더 포함할 수도 있다. 보호층은 각각이 인 또는 붕소-함유 금속 합금인 2개의 분리된 층을 더 포함할 수 있다. 예를 들어, 보호층은 Co-W-P 및 Ni-P의 복합층일 수도 있다. 또한 보호층은 Ni-P 또는 Co-W-P이고 접착층은 Au일 수도 있다. 또한 보호층은 Ni-P이고 접착층은 침잠(immersion) Au 또는 무전해(electroless) Pd일 수도 있다. 이 방법은 실리콘 웨이퍼, 실리콘-게르마늄 웨이퍼 또는 SOI(Silicon-On-Insulator) 기판상에 구리 패드를 형성하는 단계를 더 포함할 수도 있다.
전기 접속용 구리 패드를 제공하기 위한 방법은, 구리 패드면이 개개의 IC 칩상에 위치하는 웨이퍼를 다이싱(dicing)하는 단계와, 구리 패드면상에 와이어접합을 형성하는 단계를 더 포함할 수도 있다. 나아가, 이 방법은 구리 패드면이 IC칩들 내에 위치해 있는 웨이퍼를 다이싱하는 단계와, 전기 접속부를 형성하기 위해 구리 패드면상에 땜납 범프를 형성하는 단계를 더 포함할 수도 있다. 형성된 땜납 범프들은, 증발(evaporation), 도금(electro plating), 스크린 프린팅(screen printing) 또는 주입 몰딩 기법(injection molding technique)에 의한 Pb/Sn 땜납 볼(solder ball)이다.
본 발명은 구리 패드면, 구리 패드면 상의 인 또는 붕소 함유 금속 합금으로 된 보호층, 및 보호층 상부상의 귀금속 접착층을 그 상부에 포함하는 전기 접속부를 형성하기 위한 도전 패드에도 역시 관련되어 있다. 여기서, 접착층은 와이어접합 또는 땜납 범프로 전기 접속부를 제공한다.
그 상부에 전기 접속부를 형성하기 위한 도전 패드는 구리 패드면과 보호층 사이에 귀금속으로 된 핵형성층(nucleation layer)을 더 포함한다. 도전 패드는 구리 패드면과 보호층 사이에 팔라듐, 루테늄 또는 레늄 나노입자로된 핵형성층을 더 포함할 수 있다.
보호층은 Ni-P, Co-P, Co-W-P, Co-Sn-P, Ni-W-P, Co-B, Ni-B, Co-Sn-B, Co-W-B, 및 Ni-W-B로 구성된 그룹으로 선택된 물질로 형성될 수 있다. 보호층은 약 1000Å 내지 약 10000Å의 두께를 가지며, 양호하게는 약 3000Å의 두께를 가진다. 도전 패드는 약 2000Å 내지 12000Å 정도의 두께, 양호하게는 약 9000Å 정도의 두께의 귀금속층을 접착층 상부에 더 포함할 수 있다. 보호층은, 각각이 인 또는 붕소 함유 금속 합금으로 이루어진 밀착된 2개의 분리된 층을 더 포함할 수 있다. 2개의 분리된 층은 Co-W-P 및 Ni-P일 것이다. 접착층은 Au, Pt, Pd, 및 Ag로부터 선택된 층일 수 있다. 접착층은 약 500Å 내지 4000Å의 두께를 가진다. 보호층은 Ni-P, Co-W-P인 반면 접착층은 Au일 수도 있다. 또한, 보호층은 Ni-P인 반면, 보호층은 침잠 Au 또는 무전해 Pd일 수도 있다. 도전 패드는 실리콘 기판, 실리콘-게르마늄 기판 또는 SOI 웨이퍼 상에 형성될 수 있다. 전기 접속부는 와이어접합 또는 땜납 범프로 형성된다.
본 발명은 구리 패드면, 구리 패드면 상의 인 또는 붕소 함유 금속 합금으로된 보호층, 보호층 상부상의 귀금속 접착층, 및 접착층과 일체로된 전기 접속부를 포함하는 전기 접속부를 제공하기 위한 전기 구조물에도 역시 관련되어 있다. 전기 접속부는 와이어접합 또는 땜납 범프일 것이다.
전기 접속부를 제공하기 위한 전기 구조물은 구리 패드면과 보호층 사이에 귀금속의 핵형성층을 더 포함할 수 있다. 핵형성층은 팔라듐, 루테늄 또는 레늄 나노입자들로 구성될 수 있다. 접착층은 Au, Pt, Pd, 및 Ag로부터 선택된 금속으로 형성될 것이다. 보호층은 Ni-P, Co-P, Co-W-P, Co-Sn-P, Ni-W-P, Co-B, Ni-B, Co-Sn-B, Co-W-B, 및 Ni-W-B로 구성된 그룹으로 선택된 금속 합금으로 형성될 수 있다. 전기 구조물은 접착층의 상부상에 약 2000Å 내지 12000Å정도의 두께로 피착된 귀금속층을 더 포함할 수 있다. 전기 구조물은 실리콘 웨이퍼, 실리콘-게르마늄 웨이퍼, 또는 구리 패드가 위치하는 SOI 웨이퍼로된 기판을 더 포함할 수 있다.
도 1은 접속된 와이어접합을 그 상부에 갖는 본 발명의 구리 도전패드의 확대 단면도.
도 2는 그 상부에 땜납 범프가 형성된 본 발명의 구리 도전 패드의 확대 단면도.
<도면의 주요부분에 대한 부호의 설명>
12 : 구리 패드
14 : 구리패드면
16 : 확산장벽층
18 : 접착층
본 발명은 와이어접합 또는 땜납 범프에 의한 전기 접속용 구리 패드면을 제공하기 위한 방법을 공개한다. 본 발명은 그 상부에 전기 접속부를 형성하기 위한 구리 도전패드, 및 구리 패드면 상부상에 형성된 와이어접합 또는 땜납 범프를 포함하는 전기 접속부를 제공하기 위한 전기 구조물을 공개한다.
전기 접속용 구리 패드면을 제공하기 위한 방법에서, 먼저 구리 패드면이 제공된다. 그 다음, 인 또는 붕소-함유 금속 합금으로 된 보호층이 구리 패드면 상에 피착되고, 그 다음, 귀금속의 접착층이 보호층 상에 피착되어 와이어접합 또는 땜납 범프로 전기 접속부를 형성한다. 이 방법은 보호층의 피착 이전에 구리 패드면상에 팔라듐과 같은 귀금속의 핵형성층을 먼저 피착하는 단계를 더 포함할 수 있다. 핵형성층의 피착 이전에, 구리 패드면은 산성 용액(acid solution)에 의해 세정된다. 보호층은 인 또는 붕소 함유 금속 합금 또는 Ni-P, Co-W-P로 형성된다. 보호층은 약 1000Å 내지 10000Å의 두께로 형성되며, 양호하게는, 약 3000Å 내지 7000Å의 두께로 형성된다.
본 발명은 먼저 구리 패드상에 복합 금속 장벽층을 피착하는 자기-정렬 선택적 기법(self-aligned selective technique)에 의해 전자칩 상에서의 구리 패드의 직접적 와이어접합을 허용하는 공정을 제공한다. 장벽층은 구리 표면을 확산과 부식으로부터 보호하고, 동시에 신뢰성있는 와이어접합 능력을 제공한다. 본 명세서에서 공개되는 공정은, 만족할만한 와이어접합 품질을 위해 다이싱되고 테스팅된 구리 웨이퍼 상에 장벽 야금(barrier metallurgy)을 피착하기 위해 사용될 수 있다.
본 발명은, 장벽 야금을 구리 표면 상에 순차적이고도 선택적으로 (마스크없이) 피착시킴과 동시에 구리 패드면의 보호와 신뢰성있는 와이어접합 특성을 허용하는 구리 패드상에서의 와이어접합 또는 땜납 범프를 달성한다. 따라서, 본 발명에 따르면 증발이나 스퍼터링에 의해 구리 패드상에 알루미늄층을 피착시키는 마스크형 대안들, 즉, 값비싼 방법들이 필요없다. 본 발명의 장벽층은 선택적이고 자기-정렬적인 무전해도금법(electroless plating technique)에 의해 피착될 수 있다. 따라서, 본 발명은 어떠한 포토프로세싱 단계들을 요구하지 않으며, 선택적으로 (마스크없는), 즉, 포토리쏘그래픽 단계 또는 값비싼 마스크 정렬 절차 또는 알루미늄의 RIE와 같은 값비싼 금속 에칭 단계들을 요구하지 않는다. 본 발명의 신규한 방법에 의해 제공되는 구리/장벽층들의 와이어접합 또는 땜납 범핑은, 구리에 대한 우수한 접착성과, 열처리하에서 장벽층을 통한 구리 원자의 확산 방지와, 구리 표면의 부식 방지와, 구리 패드에 부착되는 알루미늄 또는 금 와이어의 우수한 접착력 또는 당김 강도를 가능하게 해주는 장벽의 최종 상부면상의 귀금속 피착을 포함하는 다양한 공정 이점을 제공한다.
도 1에 도시된 바와 같은 본 발명의 신규한 방법에서, 구리칩 공정의 BEOL(back-end-of-line)에서 구리 패드(12)의 표면(14)는 일련의 화학적 공정들, 예를 들어, 제1 구리 확산 장벽층(16)의 무전해 피착(electroless deposition)에 의해 수정된다. 제1 확산 장벽층(16)은 Ni-P, Co-W-P, Co-Sn-P, Ni-W-P, Co-B, Ni-B, Co-Sn-B, Co-W-B, 및 Ni-W-B와 같은 인 또는 붕소-함유 합금과 같은 금속 합금 물질로 피착된다. 제1 확산 장벽층을 위한 적절한 두께는 약 1000Å 내지 10000Å 정도이며, 양호하게는 3000Å 내지 7000Å이다. 본 명세서에서, "약"이라는 용어는 평균값에서 ±10%범위의 값을 의미한다.
제1 확산 장벽층(16)이 피착된 후에, 침잠 Au 용액을 사용한 침잠 피착 기법(immersion deposition technique)에 의해 확산 장벽층(16)의 상부에 제2 층(18)이 피착된다. 제2 층(18)을 위한 적절한 두께는 약 500Å 내지 약 4000Å이며, 양호하게는, 약 1000Å 내지 2000Å 사이이다. 제1 확산 장벽층(16), 즉, 보호층과 제2 접착층(18)은 구리 보호 및 신뢰성있는 와이어접합 구조를 제공하는 이중층(dual-layer, 20)으로서 피착된다. 대안으로, 무전해 Au 피착 기법에 의해 (도1에는 도시되지 않은) 제3층이 제2 층(18)의 상부상에 피착되어 최종 Au층의 두께를 약 4000Å 내지 약 10000Å 정도, 양호하게는 약 4000Å 내지 6000Å정도로 증가시킨다. Au로 된 제3 층의 목적은 와이어접합 파리미터들을 더 용이하게 만들고 와이어접합 접착 강도를 더 크게 하는 것이다.
본 발명의 확산 장벽층(16)은 다음과 같은 예들로 형성될 수 있다.
예 A
이 예에서, Cu/Co-W-P(1000Å)/Ni-P(5000Å)/침잠 Au(2000Å)/무전해 Au(3000Å-5000Å)의 다중층 스택이 형성된다. 대응하는 확산 장벽 구조도 역시 붕소에 의해 대체된 인으로 형성될 수도 있다.
예 B
이 예에서, Cu/Ni-P(5000Å)/침잠 Au(1000-2000Å) 및 Cu/Co-W-P(5000Å)/침잠 Au(2000Å)으로 표현되는 독특한 구조(singular structure)가 제공된다. 인이 붕소에 의해 대체된 대응하는 와이어접합 구조가 역시 형성될 수 있다.
예 C
이 예에서, Cu/Ni-P(5000Å)/침잠 Au(1000-2000Å)/무전해 Pd로 된 다중층 스택이 제공된다. 인이 붕소에 의해 대체된 대응하는 와이어접합 구조가 역시 이용될 수도 있다.
본 발명의 신규한 방법을 실시함에 있어서, 다중층 구리 접촉 패드를 포함하는 구리 웨이퍼는, 먼저 구리 표면으로부터 산화물을 제거하기 위해 묽은 황산 용액에 침잠되는 세정 단계를 통해 처리된다. 그 다음, 웨이퍼는 구리 표면상에 다수의 Pd 금속 핵(nuclei)을 생성하기 위해 팔라듐 이온 용액에 침잠됨으로써 액티베이트된다. 그 다음, 웨이퍼는 기판 및 웨이퍼 표면의 패드간 영역으로부터 과도 Pd 핵을 제거하기 위해 구연산나트륨(sodium citrate) 또는 EDTA 용액내에서 린싱된다. 그 다음 웨이퍼는 본 발명의 무전해조(electroless bath)에서 침잠됨으로써 Co-P, Ni-P, Co-W-P, Co-Sn-P 및 인 대신 붕소를 포함하는 대응하는 합금층이 구리 표면 상에 피착된다. 여기서, 각각의 경우 구체적인 무전해조의 구성은 구리 표면 상에 피착되는 합금의 유형에 따라 다르며 고유할 것이다. 광범위한 린싱 처리후에, 웨이퍼는 상업적으로 이용가능한 침잠 Au 용액에 노출된다. 마지막으로, 원하는 구조에 따라, 약 3000Å 내지 약 5000Å의 두께를 갖는 무전해 Au 추가 최종층, 및/또는 대안적으로, 동일한 두께의 Pd층이 침잠 Au층상에 형성될 수 있다. 그 다음 성공적인 와이어접합(30) 또는 땜납 범프(40)이 도 1 및 2에 도시된 바와 같이 다중층 스택의 상부상에 형성된다.
본 발명의 무전해 도금법은, 코발트 이온, 붕산, 구연산염 이온, ppm 수준의 초산납 및 차아인산염을 포함하는 무전해조의 가열 버퍼링된 용액 내에 웨이퍼를 침잠시키고 (Pd 이온)에 의해 액티베이트시킴으로써 수행될 수 있다. 따라서 구리 패드 표면은, 1000-2000Å Co-P접착층으로 코팅되고 광범위한 워터 린싱(water rinsing)을 거친다. 그 다음 웨이퍼 표면은 니켈 이온, 구연산염 이온, 붕산 및 나트륨 차아인산염, 또는 디메틸 아미노 보레인을 포함하는 서로 다른 가열된 무전해 용액 내에 침잠된다. 여기서, 사용되는 무전해조에 따라 약 5000 내지 약 7000Å 두께의 NiP 또는 NiB 층이 구리 상에 피착되고 광범위한 워터 린싱을 거친다. 피착의 최종 단계에서, 웨이퍼 표면은 상업적으로 이용가능한 침잠 Au조(immersion Au bath) 내에 침잠되어 무전해 도금된 구리 패드면(14) 상에 약 1000Å 내지 약 2000Å 두께의 새로운 Au층을 피착시킨다.
도 2에 도시된 바와 같이, 땜납 범프(40)은, 증발, 전기 도금, 스크린 프린팅, 또는 주입 몰딩 기법등에 의해, Pb/Sn과 같은 납땜 재료로된 최외곽 Au층(18)의 상부 상에 피착된다.
본 발명이 예시적 방법으로 기술되었지만, 사용된 용어는 제한적인 의미가 아니라 설명을 위한 것임을 이해하여야 한다.
나아가, 본 발명이 양호한 실시예 및 대안적인 실시예의 관점에서 기술되었지만, 당업자는 본 발명의 다양한 다른 변형에 이러한 기법을 용이하게 적용할 수 있다는 것을 이해할 것이다.
구리에 대한 우수한 접착성과, 열처리하에서 장벽층을 통한 구리 원자의 확산 방지와, 구리 표면의 부식 방지와, 구리 패드에 부착되는 알루미늄 또는 금 와이어의 우수한 접착력 또는 당김 강도를 가능하게 해주는 장벽의 최종 상부면상의 귀금속 피착을 포함하는 다양한 공정 이점을 제공한다.
Claims (24)
- 전기 접속용 구리 패드면을 제공하기 위한 방법에 있어서,구리 패드면을 제공하는 단계와,인 또는 붕소-함유 금속 합금으로된 보호층을 상기 구리 패드면상에 선택적으로 피착하는 단계와,귀금속으로 된 접착층을 상기 보호층의 상부에 선택적으로 피착하는 단계를 포함하는 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 제1항에 있어서, 상기 보호층의 피착 이전에 귀금속으로 된 핵형성층(nucleation layer)을 상기 구리 패드면 상에 선택적으로 피착하는 단계를 더 포함하는 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 제1항에 있어서,상기 구리 패드면을 산성 용액 내에서 세정하는 단계와,귀금속의 핵형성층을 상기 구리 패드면상에 선택적으로 피착하는 단계를 더 포함하는 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 제2항에 있어서, 상기 핵형성층은 팔라듐을 피착하여 형성되는 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 제3항에 있어서, 상기 핵형성층이 피착된 후에 상기 구리 패드면을 물로 린싱(rinsing)하는 단계를 더 포함하는 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 제1항에 있어서, 무전해 도금법(electroless plating technique)에 의해 상기 보호층을 피착하는 단계를 더 포함하는 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 제1항에 있어서, 상기 보호층을 피착하는 단계는코발트 이온(cobalt ion), 붕산(boric acid), 구연산염 이온(citrate ion), 초산납(lead acetate) 및 차아인산염(hypophosphite)을 포함하는 무전해조 내의 가열되고 버퍼링된 용액에 상기 구리 패드면을 접촉시키는 단계와,니켈 이온, 구연산염 이온, 붕산, 나트륨 차아인산염 또는 디메틸 아미노 보레인(dimethyl amino borane)을 포함하는 가열된 무전해 용액에 상기 구리 패드면을 접촉시키는 단계를 포함하는 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 제1항에 있어서, 상기 접착층은 Au, Pt, Pd, 및 Ag로 구성된 그룹으로 선택된 금속으로 형성되는 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 제1항에 있어서, 상기 접착층은 웨이퍼를 침잠 Au 용액 내에 침잠시킴으로써 형성되는 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 제1항에 있어서, 상기 접착층은 두께가 약 500Å 내지 4000Å인 귀금속으로 형성되는 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 제1항에 있어서, 상기 인 또는 붕소-함유 금속 합금은 Ni-P, Co-P, Co-W-P, Co-Sn-P, Ni-W-P, Co-B, Ni-B, Co-Sn-B, Co-W-B, 및 Ni-W-B로 구성된 그룹으로부터 선택되는 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 제1항에 있어서, 상기 보호층은, 두께가 약 1000Å 내지 10000Å인 인 또는 붕소-함유 금속 합금으로 형성되는 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 제1항에 있어서, 상기 접착층의 상부에 귀금속층을 무전해 도금법에 의해 피착하되 상기 귀금속층의 전체 두께가 약 2000Å 내지 12000Å가 되도록 하는 단계를 더 포함하는 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 제1항에 있어서, 상기 보호층은, 각각이 인 또는 붕소-함유 금속 합금으로된 2개의 분리된 층을 포함하는 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 제1항에 있어서, 상기 보호층은 Co-W-P 및 Ni-P의 복합층이고, 상기 접착층은 Au인 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 제1항에 있어서, 상기 보호층은 Ni-P 또는 Co-W-P이고, 상기 접착층은 Au인 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 제1항에 있어서, 상기 보호층은 Ni-P이고, 상기 접착층은 침잠 Au(immersion Au) 및 무전해 Pd(electroless Pd)인 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 제2항에 있어서, 상기 핵형성층을 위해 복수개의 Pd 나노입자(nanoparticle)를 피착하는 단계를 더 포함하는 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 제1항에 있어서, 상기 구리 패드면은, 실리콘 웨이퍼, 실리콘-게르마늄 웨이퍼, 및 SOI(Silicon-on-Insulator) 웨이퍼로 구성된 그룹으로부터 선택된 기판상에제공되는 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 제1항에 있어서,상기 구리 패드면이 개개의 IC칩들내에 위치하는 웨이퍼를 다이싱(dicing)하는 단계와,상기 구리 패드면상에 와이어접합(wirebond)을 형성하는 단계를 더 포함하는 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 제1항에 있어서,상기 구리 패드면이 IC칩들내에 위치하는 웨이퍼를 다이싱(dicing)하는 단계와,전기 접속부를 형성하기 위해 상기 구리 패드면상에 땜납 범프를(solder bump)를 형성하는 단계를 더 포함하는 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 제21항에 있어서, 상기 형성된 땜납 범프는 스크린 프린팅(screen printing) 또는 주입 몰딩 기법(injection molding technique)에 의한 Pb/Sn 땜납 볼(solder ball)인 전기 접속용 구리 패드면을 제공하기 위한 방법.
- 상부에 전기 접속부를 형성하기 위한 도전 패드에 있어서,구리 패드면과,상기 구리 패드면상의 인 또는 붕소-함유 금속 합금의 보호층과,상기 보호층 상부의 귀금속으로 된 접착층-상기 접착층은 와이어접합 또는 땜납 법프를 통해 전기 접속부를 제공함-을 포함하는 도전 패드.
- 전기 접속부를 제공하기 위한 전기 구조물에 있어서,구리 패드면과,상기 구리 패드면상의 인 또는 붕소-함유 금속 합금의 보호층과,상기 보호층 상부의 귀금속으로 된 접착층과,상기 접착층과 일체로 된 전기 접속부를 포함하는 전기 구조물.
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2000
- 2000-02-22 US US09/510,996 patent/US6335104B1/en not_active Expired - Lifetime
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- 2001-02-07 KR KR10-2001-0005797A patent/KR100375460B1/ko not_active IP Right Cessation
- 2001-02-08 JP JP2001032285A patent/JP3478804B2/ja not_active Expired - Fee Related
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- 2001-02-14 GB GB0103577A patent/GB2365622B/en not_active Expired - Fee Related
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GB2365622B (en) | 2004-08-11 |
SG90233A1 (en) | 2002-07-23 |
GB0103577D0 (en) | 2001-03-28 |
JP2001267356A (ja) | 2001-09-28 |
CN1311526A (zh) | 2001-09-05 |
GB2365622A (en) | 2002-02-20 |
CN100386857C (zh) | 2008-05-07 |
MY119885A (en) | 2005-07-29 |
US6335104B1 (en) | 2002-01-01 |
KR20010083160A (ko) | 2001-08-31 |
JP3478804B2 (ja) | 2003-12-15 |
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