JPS6328132B2 - - Google Patents
Info
- Publication number
- JPS6328132B2 JPS6328132B2 JP5421778A JP5421778A JPS6328132B2 JP S6328132 B2 JPS6328132 B2 JP S6328132B2 JP 5421778 A JP5421778 A JP 5421778A JP 5421778 A JP5421778 A JP 5421778A JP S6328132 B2 JPS6328132 B2 JP S6328132B2
- Authority
- JP
- Japan
- Prior art keywords
- flame
- fiber
- carbonization
- carbon fiber
- strength
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 55
- 239000004917 carbon fiber Substances 0.000 claims description 55
- 239000000835 fiber Substances 0.000 claims description 35
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 30
- 238000003763 carbonization Methods 0.000 claims description 28
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 17
- 239000003063 flame retardant Substances 0.000 claims description 17
- 238000004519 manufacturing process Methods 0.000 claims description 11
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 7
- 229920002994 synthetic fiber Polymers 0.000 claims description 4
- 239000012209 synthetic fiber Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 description 33
- 238000009656 pre-carbonization Methods 0.000 description 12
- 239000013078 crystal Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 229910002804 graphite Inorganic materials 0.000 description 4
- 239000010439 graphite Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 239000007858 starting material Substances 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 229920002239 polyacrylonitrile Polymers 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 238000005087 graphitization Methods 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- VMSBGXAJJLPWKV-UHFFFAOYSA-N 2-ethenylbenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1C=C VMSBGXAJJLPWKV-UHFFFAOYSA-N 0.000 description 1
- -1 2-ethylhexyl Chemical group 0.000 description 1
- XEEYSDHEOQHCDA-UHFFFAOYSA-N 2-methylprop-2-ene-1-sulfonic acid Chemical compound CC(=C)CS(O)(=O)=O XEEYSDHEOQHCDA-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- UIERETOOQGIECD-UHFFFAOYSA-N Angelic acid Natural products CC=C(C)C(O)=O UIERETOOQGIECD-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical compound BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Inorganic Fibers (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5421778A JPS54147222A (en) | 1978-05-08 | 1978-05-08 | Production of high-performance carbon fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5421778A JPS54147222A (en) | 1978-05-08 | 1978-05-08 | Production of high-performance carbon fiber |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS54147222A JPS54147222A (en) | 1979-11-17 |
| JPS6328132B2 true JPS6328132B2 (enrdf_load_stackoverflow) | 1988-06-07 |
Family
ID=12964367
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5421778A Granted JPS54147222A (en) | 1978-05-08 | 1978-05-08 | Production of high-performance carbon fiber |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS54147222A (enrdf_load_stackoverflow) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009084390A1 (ja) | 2007-12-30 | 2009-07-09 | Toho Tenax Co., Ltd. | 耐炎化繊維と炭素繊維の製造方法 |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5711216A (en) * | 1980-06-18 | 1982-01-20 | Mitsubishi Rayon Co Ltd | Production of carbon fiber |
| JPS5716921A (en) * | 1980-07-02 | 1982-01-28 | Mitsubishi Rayon Co Ltd | Preparation of carbon fiber |
| JPS5721521A (en) * | 1980-07-14 | 1982-02-04 | Mitsubishi Rayon Co Ltd | Production of carbon fiber of high strength and elongation |
| JPS5725418A (en) * | 1980-07-16 | 1982-02-10 | Mitsubishi Rayon Co Ltd | Preparation of low-density carbon fiber |
| JPS58136834A (ja) * | 1982-02-03 | 1983-08-15 | Mitsubishi Rayon Co Ltd | 高性能炭素繊維の製造法 |
| JPS58144128A (ja) * | 1982-02-18 | 1983-08-27 | Mitsubishi Rayon Co Ltd | 高性能炭素繊維の製法 |
| JPS59106521A (ja) * | 1982-12-08 | 1984-06-20 | Toray Ind Inc | 優れた物性を有するアクリル系炭素繊維の製造法 |
| JPS59106522A (ja) * | 1982-12-08 | 1984-06-20 | Toray Ind Inc | 優れた性能を有するアクリル系炭素繊維束の製造方法 |
| JPS59150116A (ja) * | 1983-02-10 | 1984-08-28 | Mitsubishi Rayon Co Ltd | 高強度炭素繊維の製造方法 |
| KR870000533B1 (ko) * | 1984-05-18 | 1987-03-14 | 미쓰비시레이욘 가부시끼가이샤 | 탄소섬유의 제조방법 |
| JPS61119719A (ja) * | 1984-11-14 | 1986-06-06 | Toho Rayon Co Ltd | 高強度を有する炭素質繊維の製造法 |
| JPS62117818A (ja) * | 1985-11-18 | 1987-05-29 | Toray Ind Inc | 高強度、高弾性率炭素繊維およびその製造法 |
| JPS62117814A (ja) * | 1985-11-18 | 1987-05-29 | Toray Ind Inc | 高強度・高弾性率炭素繊維用アクリル系繊維プリカ−サおよびその製造法 |
| JPS6366317A (ja) * | 1986-09-08 | 1988-03-25 | Mitsubishi Rayon Co Ltd | 高配向ポリアクリロニトリル系繊維の製造法 |
| JP2004060126A (ja) * | 2002-07-31 | 2004-02-26 | Toho Tenax Co Ltd | 炭素繊維及びその製造方法 |
| CN110655737A (zh) * | 2019-10-16 | 2020-01-07 | 厦门欧势复材科技有限公司 | 一种耐冲击的碳纤维材料制备方法 |
-
1978
- 1978-05-08 JP JP5421778A patent/JPS54147222A/ja active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009084390A1 (ja) | 2007-12-30 | 2009-07-09 | Toho Tenax Co., Ltd. | 耐炎化繊維と炭素繊維の製造方法 |
| US8236273B2 (en) | 2007-12-30 | 2012-08-07 | Toho Tenax Co., Ltd. | Method of producing pre-oxidation fiber and carbon fiber |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS54147222A (en) | 1979-11-17 |
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