JPS6219745B2 - - Google Patents
Info
- Publication number
- JPS6219745B2 JPS6219745B2 JP54170458A JP17045879A JPS6219745B2 JP S6219745 B2 JPS6219745 B2 JP S6219745B2 JP 54170458 A JP54170458 A JP 54170458A JP 17045879 A JP17045879 A JP 17045879A JP S6219745 B2 JPS6219745 B2 JP S6219745B2
- Authority
- JP
- Japan
- Prior art keywords
- photoreceptor
- weight
- disazo pigment
- parts
- charge
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 108091008695 photoreceptors Proteins 0.000 claims description 70
- 125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 claims description 2
- 125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 claims description 2
- 125000002541 furyl group Chemical group 0.000 claims description 2
- 125000001624 naphthyl group Chemical group 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 125000001725 pyrenyl group Chemical group 0.000 claims description 2
- 125000004076 pyridyl group Chemical group 0.000 claims description 2
- 125000001544 thienyl group Chemical group 0.000 claims description 2
- 239000000049 pigment Substances 0.000 description 61
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 49
- 239000010410 layer Substances 0.000 description 45
- 239000002800 charge carrier Substances 0.000 description 24
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 22
- 239000000126 substance Substances 0.000 description 12
- 239000002609 medium Substances 0.000 description 11
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 11
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 9
- 239000011230 binding agent Substances 0.000 description 9
- 239000006185 dispersion Substances 0.000 description 9
- 239000004480 active ingredient Substances 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 229920006267 polyester film Polymers 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 5
- 229920001225 polyester resin Polymers 0.000 description 5
- 239000004645 polyester resin Substances 0.000 description 5
- 239000006163 transport media Substances 0.000 description 5
- VHQGURIJMFPBKS-UHFFFAOYSA-N 2,4,7-trinitrofluoren-9-one Chemical compound [O-][N+](=O)C1=CC([N+]([O-])=O)=C2C3=CC=C([N+](=O)[O-])C=C3C(=O)C2=C1 VHQGURIJMFPBKS-UHFFFAOYSA-N 0.000 description 4
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 description 4
- 229920000515 polycarbonate Polymers 0.000 description 4
- 239000004417 polycarbonate Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- YLQWCDOCJODRMT-UHFFFAOYSA-N fluoren-9-one Chemical group C1=CC=C2C(=O)C3=CC=CC=C3C2=C1 YLQWCDOCJODRMT-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- QNLZIZAQLLYXTC-UHFFFAOYSA-N 1,2-dimethylnaphthalene Chemical compound C1=CC=CC2=C(C)C(C)=CC=C21 QNLZIZAQLLYXTC-UHFFFAOYSA-N 0.000 description 2
- KBSPJIWZDWBDGM-UHFFFAOYSA-N 1-Methylpyrene Chemical compound C1=C2C(C)=CC=C(C=C3)C2=C2C3=CC=CC2=C1 KBSPJIWZDWBDGM-UHFFFAOYSA-N 0.000 description 2
- TURIHPLQSRVWHU-UHFFFAOYSA-N 2-phenylnaphthalene Chemical compound C1=CC=CC=C1C1=CC=C(C=CC=C2)C2=C1 TURIHPLQSRVWHU-UHFFFAOYSA-N 0.000 description 2
- UZGVMZRBRRYLIP-UHFFFAOYSA-N 4-[5-[4-(diethylamino)phenyl]-1,3,4-oxadiazol-2-yl]-n,n-diethylaniline Chemical compound C1=CC(N(CC)CC)=CC=C1C1=NN=C(C=2C=CC(=CC=2)N(CC)CC)O1 UZGVMZRBRRYLIP-UHFFFAOYSA-N 0.000 description 2
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 2
- 239000004419 Panlite Substances 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 238000000862 absorption spectrum Methods 0.000 description 2
- -1 chloroethylcarbazole-formaldehyde Chemical compound 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- HSMFKWKHZVFTPZ-UHFFFAOYSA-N 1,3,7,9-tetranitro-5-oxidobenzo[c]cinnolin-5-ium Chemical compound C1=C([N+]([O-])=O)C=C2C3=C([N+]([O-])=O)C=C([N+](=O)[O-])C=C3[N+]([O-])=NC2=C1[N+]([O-])=O HSMFKWKHZVFTPZ-UHFFFAOYSA-N 0.000 description 1
- PMBBBTMBKMPOQF-UHFFFAOYSA-N 1,3,7-trinitrodibenzothiophene 5,5-dioxide Chemical compound O=S1(=O)C2=CC([N+](=O)[O-])=CC=C2C2=C1C=C([N+]([O-])=O)C=C2[N+]([O-])=O PMBBBTMBKMPOQF-UHFFFAOYSA-N 0.000 description 1
- WQGWMEKAPOBYFV-UHFFFAOYSA-N 1,5,7-trinitrothioxanthen-9-one Chemical compound C1=CC([N+]([O-])=O)=C2C(=O)C3=CC([N+](=O)[O-])=CC([N+]([O-])=O)=C3SC2=C1 WQGWMEKAPOBYFV-UHFFFAOYSA-N 0.000 description 1
- HYGLETVERPVXOS-UHFFFAOYSA-N 1-bromopyrene Chemical compound C1=C2C(Br)=CC=C(C=C3)C2=C2C3=CC=CC2=C1 HYGLETVERPVXOS-UHFFFAOYSA-N 0.000 description 1
- ZWAMZDRREBOHIO-UHFFFAOYSA-N 1-ethylpyrene Chemical compound C1=C2C(CC)=CC=C(C=C3)C2=C2C3=CC=CC2=C1 ZWAMZDRREBOHIO-UHFFFAOYSA-N 0.000 description 1
- KCIJNJVCFPSUBQ-UHFFFAOYSA-N 1-pyren-1-ylethanone Chemical compound C1=C2C(C(=O)C)=CC=C(C=C3)C2=C2C3=CC=CC2=C1 KCIJNJVCFPSUBQ-UHFFFAOYSA-N 0.000 description 1
- TYUPTZLMOSZOAV-UHFFFAOYSA-N 2,4,10-trinitro-6-oxidobenzo[c]cinnolin-6-ium Chemical compound C1=CC([N+]([O-])=O)=C2C3=CC([N+](=O)[O-])=CC([N+]([O-])=O)=C3N=[N+]([O-])C2=C1 TYUPTZLMOSZOAV-UHFFFAOYSA-N 0.000 description 1
- JOERSAVCLPYNIZ-UHFFFAOYSA-N 2,4,5,7-tetranitrofluoren-9-one Chemical compound O=C1C2=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C2C2=C1C=C([N+](=O)[O-])C=C2[N+]([O-])=O JOERSAVCLPYNIZ-UHFFFAOYSA-N 0.000 description 1
- RBFUXCYPJKXNMP-UHFFFAOYSA-N 2,4,7-trinitrophenanthrene-9,10-dione Chemical compound [O-][N+](=O)C1=CC([N+]([O-])=O)=C2C3=CC=C([N+](=O)[O-])C=C3C(=O)C(=O)C2=C1 RBFUXCYPJKXNMP-UHFFFAOYSA-N 0.000 description 1
- HJCNIHXYINVVFF-UHFFFAOYSA-N 2,6,8-trinitroindeno[1,2-b]thiophen-4-one Chemical compound O=C1C2=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C2C2=C1C=C([N+](=O)[O-])S2 HJCNIHXYINVVFF-UHFFFAOYSA-N 0.000 description 1
- VMQHOWOVMXIROE-UHFFFAOYSA-N 2,8-dinitrodibenzothiophene Chemical compound C1=C([N+]([O-])=O)C=C2C3=CC([N+](=O)[O-])=CC=C3SC2=C1 VMQHOWOVMXIROE-UHFFFAOYSA-N 0.000 description 1
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical group C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- POJAQDYLPYBBPG-UHFFFAOYSA-N 2-(2,4,7-trinitrofluoren-9-ylidene)propanedinitrile Chemical compound [O-][N+](=O)C1=CC([N+]([O-])=O)=C2C3=CC=C([N+](=O)[O-])C=C3C(=C(C#N)C#N)C2=C1 POJAQDYLPYBBPG-UHFFFAOYSA-N 0.000 description 1
- MFAWABLKXSRSOR-UHFFFAOYSA-N 2-(6,8-dinitroindeno[1,2-b]thiophen-4-ylidene)propanedinitrile Chemical compound [O-][N+](=O)C1=CC([N+](=O)[O-])=CC2=C1C(SC=C1)=C1C2=C(C#N)C#N MFAWABLKXSRSOR-UHFFFAOYSA-N 0.000 description 1
- FSMZNCMGDPVHDF-UHFFFAOYSA-N 2-bromo-6,8-dinitro-4h-indeno[1,2-b]thiophene Chemical compound [O-][N+](=O)C1=CC([N+](=O)[O-])=CC2=C1C(SC(Br)=C1)=C1C2 FSMZNCMGDPVHDF-UHFFFAOYSA-N 0.000 description 1
- IIKVAWLYHHZRGV-UHFFFAOYSA-N 2-carbazol-9-ylethanol Chemical compound C1=CC=C2N(CCO)C3=CC=CC=C3C2=C1 IIKVAWLYHHZRGV-UHFFFAOYSA-N 0.000 description 1
- WGRSVHBSCVGKDP-UHFFFAOYSA-N 2-ethyl-9h-carbazole-1-carbaldehyde Chemical compound C1=CC=C2C3=CC=C(CC)C(C=O)=C3NC2=C1 WGRSVHBSCVGKDP-UHFFFAOYSA-N 0.000 description 1
- XMPQJGTYEXSTIY-UHFFFAOYSA-N 2-indeno[1,2-b]thiophen-4-ylidenepropanedinitrile Chemical compound C12=CC=CC=C2C(=C(C#N)C#N)C2=C1SC=C2 XMPQJGTYEXSTIY-UHFFFAOYSA-N 0.000 description 1
- GXLYVLHWXVRVKI-UHFFFAOYSA-N 2-nitrodibenzothiophene Chemical compound C1=CC=C2C3=CC([N+](=O)[O-])=CC=C3SC2=C1 GXLYVLHWXVRVKI-UHFFFAOYSA-N 0.000 description 1
- AJEAHBZZHSLIQP-UHFFFAOYSA-N 2-nitrofluoren-9-one Chemical compound C1=CC=C2C(=O)C3=CC([N+](=O)[O-])=CC=C3C2=C1 AJEAHBZZHSLIQP-UHFFFAOYSA-N 0.000 description 1
- YOCSZWYTDFWNMT-UHFFFAOYSA-N 2-nitroindeno[1,2-b]thiophen-4-one Chemical compound O=C1C2=CC=CC=C2C2=C1C=C([N+](=O)[O-])S2 YOCSZWYTDFWNMT-UHFFFAOYSA-N 0.000 description 1
- KEHIOHQUZQSPCO-UHFFFAOYSA-N 2-nitroindeno[2,1-b]thiophen-4-one Chemical compound C12=CC=CC=C2C(=O)C2=C1C=C([N+](=O)[O-])S2 KEHIOHQUZQSPCO-UHFFFAOYSA-N 0.000 description 1
- KLLLJCACIRKBDT-UHFFFAOYSA-N 2-phenyl-1H-indole Chemical compound N1C2=CC=CC=C2C=C1C1=CC=CC=C1 KLLLJCACIRKBDT-UHFFFAOYSA-N 0.000 description 1
- NOXSEPQGTKXPOK-UHFFFAOYSA-N 3,7,9-trinitro-5-oxidobenzo[c]cinnolin-5-ium Chemical compound C1=C([N+]([O-])=O)C=C2C3=CC=C([N+](=O)[O-])C=C3[N+]([O-])=NC2=C1[N+]([O-])=O NOXSEPQGTKXPOK-UHFFFAOYSA-N 0.000 description 1
- YRXRGRLSHSSUNF-UHFFFAOYSA-N 3,7-dinitrodibenzothiophene 5,5-dioxide Chemical compound C1=C([N+]([O-])=O)C=C2S(=O)(=O)C3=CC([N+](=O)[O-])=CC=C3C2=C1 YRXRGRLSHSSUNF-UHFFFAOYSA-N 0.000 description 1
- AEFDIOODLJMOML-UHFFFAOYSA-N 3,7-dinitrodibenzothiophene 5-oxide Chemical compound C1=C([N+]([O-])=O)C=C2S(=O)C3=CC([N+](=O)[O-])=CC=C3C2=C1 AEFDIOODLJMOML-UHFFFAOYSA-N 0.000 description 1
- YPRJLDUOGDQQAK-UHFFFAOYSA-N 3-nitrodibenzothiophene 5,5-dioxide Chemical compound C1=CC=C2S(=O)(=O)C3=CC([N+](=O)[O-])=CC=C3C2=C1 YPRJLDUOGDQQAK-UHFFFAOYSA-N 0.000 description 1
- BBSNLPXHXFJCJE-UHFFFAOYSA-N 3-nitrodibenzothiophene 5-oxide Chemical compound C1=CC=C2S(=O)C3=CC([N+](=O)[O-])=CC=C3C2=C1 BBSNLPXHXFJCJE-UHFFFAOYSA-N 0.000 description 1
- MLEBCZSWVARRML-UHFFFAOYSA-N 4-(2,5-diphenyl-1,3-oxazol-4-yl)-n,n-diethylaniline Chemical compound C1=CC(N(CC)CC)=CC=C1C1=C(C=2C=CC=CC=2)OC(C=2C=CC=CC=2)=N1 MLEBCZSWVARRML-UHFFFAOYSA-N 0.000 description 1
- CLQYLLIGYDFCGY-UHFFFAOYSA-N 4-(2-anthracen-9-ylethenyl)-n,n-diethylaniline Chemical compound C1=CC(N(CC)CC)=CC=C1C=CC1=C(C=CC=C2)C2=CC2=CC=CC=C12 CLQYLLIGYDFCGY-UHFFFAOYSA-N 0.000 description 1
- BZKRKPGZABEOSM-XMHGGMMESA-N 4-[(e)-2-[3-[4-(diethylamino)phenyl]-2-phenyl-3,4-dihydropyrazol-5-yl]ethenyl]-n,n-diethylaniline Chemical compound C1=CC(N(CC)CC)=CC=C1\C=C\C1=NN(C=2C=CC=CC=2)C(C=2C=CC(=CC=2)N(CC)CC)C1 BZKRKPGZABEOSM-XMHGGMMESA-N 0.000 description 1
- YCHDSDSNBXYNHE-UHFFFAOYSA-N 4-[3-[4-(diethylamino)phenyl]-1h-1,2,4-triazol-5-yl]-n,n-diethylaniline Chemical compound C1=CC(N(CC)CC)=CC=C1C1=NN=C(C=2C=CC(=CC=2)N(CC)CC)N1 YCHDSDSNBXYNHE-UHFFFAOYSA-N 0.000 description 1
- SBMCZDLOXDWNIN-UHFFFAOYSA-N 4-[bis[4-(diethylamino)phenyl]methyl]-n,n-diethylaniline Chemical compound C1=CC(N(CC)CC)=CC=C1C(C=1C=CC(=CC=1)N(CC)CC)C1=CC=C(N(CC)CC)C=C1 SBMCZDLOXDWNIN-UHFFFAOYSA-N 0.000 description 1
- IXAFAYIIDHDJHN-UHFFFAOYSA-N 4-methylpyrene Natural products C1=CC=C2C(C)=CC3=CC=CC4=CC=C1C2=C34 IXAFAYIIDHDJHN-UHFFFAOYSA-N 0.000 description 1
- RGHDGRGJOSPDHW-UHFFFAOYSA-N 8-benzyl-1-(4-chlorophenyl)-1,3,8-triazaspiro[4.5]decan-4-one Chemical compound C1=CC(Cl)=CC=C1N1C2(CCN(CC=3C=CC=CC=3)CC2)C(=O)NC1 RGHDGRGJOSPDHW-UHFFFAOYSA-N 0.000 description 1
- CVSBRGRSQUGIKO-UHFFFAOYSA-N 9-(2-chloroethyl)carbazole Chemical compound C1=CC=C2N(CCCl)C3=CC=CC=C3C2=C1 CVSBRGRSQUGIKO-UHFFFAOYSA-N 0.000 description 1
- PLAZXGNBGZYJSA-UHFFFAOYSA-N 9-ethylcarbazole Chemical compound C1=CC=C2N(CC)C3=CC=CC=C3C2=C1 PLAZXGNBGZYJSA-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000004840 adhesive resin Substances 0.000 description 1
- 229920006223 adhesive resin Polymers 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- HFACYLZERDEVSX-UHFFFAOYSA-N benzidine Chemical compound C1=CC(N)=CC=C1C1=CC=C(N)C=C1 HFACYLZERDEVSX-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- WSOJIQBCVMSHLB-UHFFFAOYSA-N indeno[1,2-b]thiophen-4-one Chemical compound C12=CC=CC=C2C(=O)C2=C1SC=C2 WSOJIQBCVMSHLB-UHFFFAOYSA-N 0.000 description 1
- FFQQXIVOSCLQKP-UHFFFAOYSA-N indeno[2,1-b]thiophen-4-one Chemical compound O=C1C2=CC=CC=C2C2=C1SC=C2 FFQQXIVOSCLQKP-UHFFFAOYSA-N 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 150000003071 polychlorinated biphenyls Chemical group 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001470 polyketone Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920006215 polyvinyl ketone Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- RCYFOPUXRMOLQM-UHFFFAOYSA-N pyrene-1-carbaldehyde Chemical compound C1=C2C(C=O)=CC=C(C=C3)C2=C2C3=CC=CC2=C1 RCYFOPUXRMOLQM-UHFFFAOYSA-N 0.000 description 1
- 150000003334 secondary amides Chemical class 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- AUHHYELHRWCWEZ-UHFFFAOYSA-N tetrachlorophthalic anhydride Chemical compound ClC1=C(Cl)C(Cl)=C2C(=O)OC(=O)C2=C1Cl AUHHYELHRWCWEZ-UHFFFAOYSA-N 0.000 description 1
- ODHXBMXNKOYIBV-UHFFFAOYSA-N triphenylamine Chemical compound C1=CC=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 ODHXBMXNKOYIBV-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B56/00—Azo dyes containing other chromophoric systems
- C09B56/02—Azomethine-azo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B35/00—Disazo and polyazo dyes of the type A<-D->B prepared by diazotising and coupling
- C09B35/02—Disazo dyes
- C09B35/039—Disazo dyes characterised by the tetrazo component
- C09B35/34—Disazo dyes characterised by the tetrazo component the tetrazo component being heterocyclic
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0664—Dyes
- G03G5/0675—Azo dyes
- G03G5/0679—Disazo dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Photoreceptors In Electrophotography (AREA)
Description
æ¬çºæã¯é»ååççšã®æå
äœã«é¢ããæŽã«è©³ã
ãã¯æå¹æåãšããŠãžã¹ã¢ãŸé¡æãå«æããæå
å±€ãæããæ°èŠãªæå äœã«é¢ããã åŸæ¥ãå°é»æ§æ¯æäœäžã«ã¢ãŸé¡æãæå¹æåãš
ããŠå«æããæå å±€ãèšããé»ååççšæå äœãš
ããŠã¯äŸãã°ã¢ãã¢ãŸé¡æãçšãããã®ïŒç¹å ¬æ
44â16474å·å ¬å ±ïŒããã³ãžãžã³ç³»ã®ãžã¹ã¢ãŸé¡
æãçšãããã®ïŒç¹éæ47â37543å·å ¬å ±ïŒçã
å ¬ç¥ã§ããããããã®ã¢ãŸé¡æã¯åè¿°ã®ããã«æ
å å±€ã®æå¹æåãšããŠç¢ºãã«æçšãªææã§ã¯ãã
ããé»ååçããã»ã¹ã®ç¹ããæå äœã«å¯Ÿãã
çš®ã ã®èŠæ±ãèæ ®ãããšãæªã ãããã®èŠæ±ãå
åã«æºè¶³ãããã®ãåŸãããŠããªãã®ãå®æ ã§ã
ããåŸã€ãŠã¢ãŸé¡æã«éãããæå¹æåãšããŠå
ãé¡æãåºç¯å²ã«éžæãåŸãããã«å€çš®é¡ã«ãã
ããšã¯æŽã«éèŠãªããšã§ãããããã«ãã€ãŠåã
ãŠããçš®ã®ããã»ã¹ã«é©åãªæå äœãæäŸããã
ãšãå¯èœãšãªããå³ã¡ãé»ååçããã»ã¹ã«ãã
ãŠã¯æå äœã®æå¹æåãšããŠåãåŸãé¡æã®çš®é¡
ã¯ã§ããã ãå€ãããšãæãŸããã æ¬çºæã®ç¬¬äžã®ç®çã¯åçš®ã®é»ååçããã»ã¹
ã«æå¹æåãšããŠåãåŸãæ°èŠãªãžã¹ã¢ãŸé¡æã
å«ãé»ååççšæå äœãæäŸããããšã§ããã æ¬çºæã®ç¬¬äºã®ç®çã¯æå¹æåãšããŠåãåŸã
ãžã¹ã¢ãŸé¡æãåºç¯ã«éžæãåŸãé»ååççšæå
äœãæäŸããããšã§ããã æ¬çºæã®ç¬¬äžã®ç®çã¯åè¿°ã®ãããªãžã¹ã¢ãŸé¡
æãå«ãæ°ããªé«æ床ãé«å¯ææ§ã®é»ååçæå
äœãæäŸããããšã§ããã æ¬çºæè ãã¯äžçŸ€ã®ãžã¹ã¢ãŸé¡æã補é ããã
ããã®æå äœãžã®å¿çšãæ€èšããçµæãäžèšäžè¬
åŒã§è¡šãããããã«ãªã¬ãã³éªšæ Œãæãããžã¹ã¢
ãŸé¡æãæå äœã®ããããæå¹æåãšããŠåãåŸ
ãããšãç¥èŠããæ¬çºæãå®æãããã®ã§ããã å³ã¡æ¬çºæã¯å°é»æ§æ¯æäœäžã«ãäžèšäžè¬åŒ ïŒäœãåŒäžArã¯çœ®æåã¯é眮æã®ããšãã«
åºã眮æåã¯é眮æã®ãããã«åºãã¢ã³ããªã«
åºããã¬ãã«åºãããªãžã«åºãããšãã«åºãããª
ã«åºåã³ã«ã«ããŸãªã«åºãè¡šããïŒ ã§ç€ºããããžã¹ã¢ãŸé¡æãæå¹æåãšããŠå«æã
ãæå å±€ãæããããšãç¹åŸŽãšããé»ååççšæ
å äœãæäŸãããã®ã§ããã 以äžã«æ¬çºæã§äœ¿çšãããåèšäžè¬åŒã®ååç©
ã®å ·äœäŸãæ§é åŒã§ç€ºãã
ãã¯æå¹æåãšããŠãžã¹ã¢ãŸé¡æãå«æããæå
å±€ãæããæ°èŠãªæå äœã«é¢ããã åŸæ¥ãå°é»æ§æ¯æäœäžã«ã¢ãŸé¡æãæå¹æåãš
ããŠå«æããæå å±€ãèšããé»ååççšæå äœãš
ããŠã¯äŸãã°ã¢ãã¢ãŸé¡æãçšãããã®ïŒç¹å ¬æ
44â16474å·å ¬å ±ïŒããã³ãžãžã³ç³»ã®ãžã¹ã¢ãŸé¡
æãçšãããã®ïŒç¹éæ47â37543å·å ¬å ±ïŒçã
å ¬ç¥ã§ããããããã®ã¢ãŸé¡æã¯åè¿°ã®ããã«æ
å å±€ã®æå¹æåãšããŠç¢ºãã«æçšãªææã§ã¯ãã
ããé»ååçããã»ã¹ã®ç¹ããæå äœã«å¯Ÿãã
çš®ã ã®èŠæ±ãèæ ®ãããšãæªã ãããã®èŠæ±ãå
åã«æºè¶³ãããã®ãåŸãããŠããªãã®ãå®æ ã§ã
ããåŸã€ãŠã¢ãŸé¡æã«éãããæå¹æåãšããŠå
ãé¡æãåºç¯å²ã«éžæãåŸãããã«å€çš®é¡ã«ãã
ããšã¯æŽã«éèŠãªããšã§ãããããã«ãã€ãŠåã
ãŠããçš®ã®ããã»ã¹ã«é©åãªæå äœãæäŸããã
ãšãå¯èœãšãªããå³ã¡ãé»ååçããã»ã¹ã«ãã
ãŠã¯æå äœã®æå¹æåãšããŠåãåŸãé¡æã®çš®é¡
ã¯ã§ããã ãå€ãããšãæãŸããã æ¬çºæã®ç¬¬äžã®ç®çã¯åçš®ã®é»ååçããã»ã¹
ã«æå¹æåãšããŠåãåŸãæ°èŠãªãžã¹ã¢ãŸé¡æã
å«ãé»ååççšæå äœãæäŸããããšã§ããã æ¬çºæã®ç¬¬äºã®ç®çã¯æå¹æåãšããŠåãåŸã
ãžã¹ã¢ãŸé¡æãåºç¯ã«éžæãåŸãé»ååççšæå
äœãæäŸããããšã§ããã æ¬çºæã®ç¬¬äžã®ç®çã¯åè¿°ã®ãããªãžã¹ã¢ãŸé¡
æãå«ãæ°ããªé«æ床ãé«å¯ææ§ã®é»ååçæå
äœãæäŸããããšã§ããã æ¬çºæè ãã¯äžçŸ€ã®ãžã¹ã¢ãŸé¡æã補é ããã
ããã®æå äœãžã®å¿çšãæ€èšããçµæãäžèšäžè¬
åŒã§è¡šãããããã«ãªã¬ãã³éªšæ Œãæãããžã¹ã¢
ãŸé¡æãæå äœã®ããããæå¹æåãšããŠåãåŸ
ãããšãç¥èŠããæ¬çºæãå®æãããã®ã§ããã å³ã¡æ¬çºæã¯å°é»æ§æ¯æäœäžã«ãäžèšäžè¬åŒ ïŒäœãåŒäžArã¯çœ®æåã¯é眮æã®ããšãã«
åºã眮æåã¯é眮æã®ãããã«åºãã¢ã³ããªã«
åºããã¬ãã«åºãããªãžã«åºãããšãã«åºãããª
ã«åºåã³ã«ã«ããŸãªã«åºãè¡šããïŒ ã§ç€ºããããžã¹ã¢ãŸé¡æãæå¹æåãšããŠå«æã
ãæå å±€ãæããããšãç¹åŸŽãšããé»ååççšæ
å äœãæäŸãããã®ã§ããã 以äžã«æ¬çºæã§äœ¿çšãããåèšäžè¬åŒã®ååç©
ã®å ·äœäŸãæ§é åŒã§ç€ºãã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãããã®ããžã¹ã¢ãŸé¡æã¯ç¹éæ54â22834å·
å ¬å ±ã«èšèŒã®ïŒâãã«ãªã¬ãã³âïŒïŒïŒâãã¹ãž
ã¢ãŸããŠã ãã¹ããã©ãã«ãªããã¬ãŒããšãå
é¡æã«å¯Ÿå¿ããã«ããã©ãŒãšãé©åœãªææ©æº¶åªã
äŸãã°ïŒ®ïŒïŒ®âãžã¡ãã«ãã«ã ã¢ããïŒDMFïŒ
äžã§ãã¢ã«ã«ãªã®ååšäžã«ãããªã³ã°ããããšã«
ãã容æã«è£œé ããããšãåºæ¥ãããŸãããã§äœ¿
çšãããã«ããã©ãŒã¯Franzenãã®æ¹æ³ïŒJ.
Prak.Chem.ãïŒã78ïŒ164ïŒã«åŸãïŒâãããã
ã·âïŒâããããšé žããã©ãžããšã¢ã«ããããäŸ
ãã°ã¢ã«ã³ãŒã«ãªã©ã®ææ©æº¶åªäžã§å ç±ããããš
ã«ãã容æã«è£œé ããããã®ã§ããã 以äžã«ãã®è£œé ã®å ·äœäŸã瀺ãã 補é äŸ ïŒâãã«ãªã¬ãã³âïŒïŒïŒâãã¹ãžã¢ãŸããŠã
ãã¹ããã©ãã«ãªããã¬ãŒã 2.04ïœãïŒâã·
ãããã·âïŒâããããšé žãã³ã¶ã«ããã©ãžã
2.90ïœãDMF300mlã«æº¶è§£ããããã«é ¢é žãããª
ãŠã 1.64ïœåã³æ°Ž14mlãããªã溶液ã宀枩ã«ãŠæ»Ž
äžããã滎äžçµäºåŸå枩床ã«ãŠïŒæéæ¹æããæ
åºããçµæ¶ãåãããæ®æž£ã«300mlã®DMFãå
ããŠ80âã§ïŒæéæ¹æããã®ã¡ãåã³çµæ¶ãå
ãããã®æäœãæŽã«ïŒåããè¿ãããæ°ŽæŽåŸä¹Ÿç¥
ããŠååç©No.ïŒã®ãžã¹ã¢ãŸé¡æ3.20ïœãéé»è²çµ
æ¶ãšããŠåŸãã å çŽ åæå€ èšç®å€ å®æž¬å€ ïŒ£ïŒ 72.40 72.20 ïŒšïŒ 3.97 3.89 ïŒ®ïŒ 13.79 13.51 èµ€å€ç·åžåã¹ãã¯ãã«ïŒKBrdiskïŒã第ïŒå³ã«
瀺ãã VcoïŒç¬¬ïŒã¢ããïŒ 1680 cm-1 VcoïŒãã«ãªã¬ãã³ïŒ 1725 cm-1 æ¬çºæã®æå äœã¯ä»¥äžã®ãããªãžã¹ã¢ãŸé¡æã
å«ããã®ã§ãããããããé¡æã®å¿çšã®ä»æ¹ã«ã
ã第ïŒãïŒå³ã®åœ¢æ ããšãããšãã§ããã第ïŒå³
ã®æå äœã¯å°é»æ§æ¯æäœïŒäžã«ãžã¹ã¢ãŸé¡æïŒ
ïŒããã§ã¯å å°é»æ§ç©è³ªãšããŠäœ¿çšãããïŒãæš¹
èçµçå€ïŒç³»æå å±€ïŒãèšãããã®ã§ããã第ïŒ
å³ã®æå äœã¯å°é»æ§æ¯æäœïŒäžã«ãžã¹ã¢ãŸé¡æïŒ
ïŒããã§ã¯é»è·æ äœçºçç©è³ªãšããŠäœ¿çšãããïŒ
ãé»è·ç§»ååªäœïŒé»è·ç§»åæ§ç©è³ªåã³æš¹èçµçå€
ã®æ··åç©ïŒïŒç³»æå å±€ïŒâ²ãèšãããã®ã§ããã
ãŸã第ïŒãïŒå³ã®æå äœã¯ç¬¬ïŒå³ã®æå äœã®å€åœ¢
ã§ãæå å±€ïŒâ³ïŒïŒã¯ãžã¹ã¢ãŸé¡æïŒãäž»äœãš
ããé»è·æ äœçºçå±€ïŒãšé»è·ç§»ååªäœã®å±€ïŒãšã
ããªã€ãŠããã ãããã®æå äœã«ãããåçµæåã¯ãåã 次ã®
ãããªçŸè±¡ã«ããæå äœã«å¯Ÿããå¹æããããã
ããŠãããã®ãšèããããã 第ïŒå³ã®æå äœã«ãããŠãžã¹ã¢ãŸé¡æã¯å å°é»
æ§ç©è³ªãšããŠäœçšããå æžè¡°ã«å¿ èŠãªé»è·æ äœã®
çæåã³ç§»åã¯é¡æç²åãä»ããŠè¡ãªãããã第
ïŒå³ã®æå äœã®å Žåã¯é»è·ç§»åæ§ç©è³ªã¯çµçå€
ïŒåã³å Žåã«ããå¯å¡å€ïŒãšå ±ã«é»è·ç§»ååªäœã
圢æããäžæ¹ãžã¹ã¢ãŸé¡æã¯é»è·æ äœçºçç©è³ªãš
ããŠäœçšããããã®é»è·ç§»ååªäœã¯ãžã¹ã¢ãŸé¡æ
ã®ãããªé»è·æ äœã®çæèœåã¯ãªããããžã¹ã¢ãŸ
é¡æããçºçããé»è·æ äœãåãå ¥ããããã移
åããèœåãæã€ãŠãããå³ã¡ç¬¬ïŒå³ã®æå äœã§
ã¯å æžè¡°ã«å¿ èŠãªé»è·æ äœã®çæã¯ãžã¹ã¢ãŸé¡æ
ã«ãã€ãŠè¡ãªãããäžæ¹ãé»è·æ äœã®ç§»åã¯äž»ã«
é»è·ç§»ååªäœã«ããè¡ãªããããããã§é»è·ç§»å
åªäœã«æŽã«èŠæ±ãããåºæ¬çæ¡ä»¶ã¯é»è·ç§»ååªäœ
ã®åžåæ³¢é·é åããžã¹ã¢ãŸé¡æã®äž»ã«å¯èŠéšã®åž
åæ³¢é·é åãšéãªããªãããšã§ãããããã¯ãžã¹
ã¢ãŸé¡æã«å¹çè¯ãé»è·æ äœãçºçãããããã«
é¡æè¡šé¢ãŸã§å ãééãããå¿ èŠãããããã§ã
ãããããäŸãã°ããç¹å®æ³¢é·ã ãã«æ床ãæã
ãæå äœã®å Žåã¯ãã®éãã§ã¯ãªããåŸã€ãŠé»è·
移ååªäœåã³ãžã¹ã¢ãŸé¡æã®äž¡è ã®åžåæ³¢é·ã¯å®
å šã«éè€ããªããã°ããã次ã«ç¬¬ïŒå³ã®æå äœã§
ã¯é»è·ç§»ååªäœå±€ãééããŠæ¥ãå ãé»è·æ äœçº
çå±€ã§ããæå å±€ïŒâ³ã«å°éãããã®éšåã®ãžã¹
ã¢ãŸé¡æã§é»è·æ äœã®çæãèµ·ãããäžæ¹ãé»è·
移ååªäœå±€ã¯é»è·æ äœã®æ³šå ¥ãåãããã®ç§»åã
è¡ãªããã®ã§ãå æžè¡°ã«å¿ èŠãªé»è·æ äœã®çæã¯
ãžã¹ã¢ãŸé¡æã§ããŸãé»è·æ äœã®ç§»åã¯é»è·ç§»å
åªäœã§ãšããã¡ã«ããºã ã¯ç¬¬ïŒå³ã«ç€ºããæå äœ
ã®å Žåãšåæ§ã§ãããããã§ããžã¹ã¢ãŸé¡æã¯é»
è·æ äœçºçç©è³ªã§ããããªãã第ïŒå³ã®æå äœã«
ãããé»è·ç§»åå±€åã³é»è·æ äœçºçå±€ã®äœçšæ©æ§
ã第ïŒå³ã®æå äœã®å Žåãšåãã§ããã 第ïŒå³ã®æå äœãäœæããã«ã¯ãžã¹ã¢ãŸé¡æã®
埮ç²åãçµçå€æº¶æ¶²äžã«åæ£ããåæ£æ¶²ãå°é»æ§
æ¯æäœäžã«å¡åžä¹Ÿç¥ããã°ããã第ïŒå³ã®æå äœ
ãäœæããã«ã¯ãžã¹ã¢ãŸé¡æã®åŸ®ç²åãé»è·ç§»å
æ§ç©è³ªåã³çµçå€ã溶解ãã溶液äžã«ãžã¹ã¢ãŸé¡
æã®åŸ®ç²åãåæ£ãããããããå°é»æ§æ¯æäœäž
ã«å¡åžä¹Ÿç¥ããã°ããããŸã第ïŒå³ã®æå äœã¯å°
é»æ§æ¯æäœäžã«ãžã¹ã¢ãŸé¡æãç空èžçãããã
æãã¯ãžã¹ã¢ãŸé¡æã®åŸ®ç²åãå¿ èŠããã°çµçå€
ã溶解ããé©åœãªæº¶åªäžã«æº¶è§£ãããããå°é»æ§
æ¯æäœäžã«éåžä¹Ÿç¥ããæŽã«å¿ èŠããã°äŸãã°ã
ãç æ©çã®æ¹æ³ã«ããè¡šé¢ä»äžããããèåã調
æŽããåŸããã®äžã«é»è·ç§»åæ§ç©è³ªåã³çµçå€ã
å«ã溶液ãå¡åžä¹Ÿç¥ããŠåŸãããããªã第ïŒå³ã®
æå äœã®å Žåã¯ç¬¬ïŒå³ã®æå äœã®äœææ³ã«ãããŠ
è圢æé åºãéã«ããã°ããããããã«ããŠãæ¬
çºæã§äœ¿çšããããžã¹ã¢ãŸé¡æã¯ããŒã«ãã«çã«
ããç²åŸïŒÎŒä»¥äžã奜ãŸããã¯ïŒÎŒä»¥äžã«ç²ç ã
ãŠçšãããããå¡åžæ³ã¯éåžžã®æ段ãäŸãã°ãã¯
ã¿ãŒãã¬ãŒããã¯ã€ã€ãŒããŒãªã©ã§è¡ãªããæå
å±€ã®åãã¯ç¬¬ïŒå³åã³ç¬¬ïŒå³ã®ãã®ã§ã¯çŽïŒã50
ÎŒã奜ãŸããã¯ïŒã20ÎŒã§ããããŸã第ïŒãïŒå³
ã®ãã®ã§ã¯é»è·æ äœçºçå±€ã®åã¿ã¯ãïŒÎŒä»¥äžã
奜ãŸããã¯ïŒÎŒä»¥äžããããé»è·ç§»ååªäœå±€ã®å
ãã¯çŽïŒã50ÎŒã奜ãŸããã¯ïŒã20ÎŒã§ããããŸ
ã第ïŒå³ã®æå äœã«ãããŠæå å±€äžã®ãžã¹ã¢ãŸé¡
æã®å²åã¯æå å±€ã«å¯Ÿã30ã70ééïŒ å¥œãŸããã¯
çŽ50ééïŒ ãé©åœã§ãããïŒåè¿°ã®ããã«ç¬¬ïŒå³
ã®æå äœã®å Žåã¯ããžã¹ã¢ãŸé¡æã¯å å°é»ç©è³ªãš
ããŠäœçšããå æžè¡°ã«å¿ èŠãªé»è·æ äœã®çæåã³
移åã¯é¡æç²åãä»ããŠè¡ãªãããã®ã§ãé¡æç²
åéã®æ¥è§Šã¯æå 局衚é¢ããæ¯æäœãŸã§é£ç¶ããŠ
ããããšãæãŸããããã®ããæå å±€ã«å ããé¡
æã®å²åã¯æ¯èŒçå€ãæ¹ã奜ãŸããããæå å±€ã®
匷床åã³æ床ãèæ ®ãããšãçŽ50ééïŒ ãã
ãïŒã第ïŒå³ã®æå äœã«ãããŠãæå å±€äžã®ãžã¹
ã¢ãŸé¡æã®å ããå²åã¯50ééïŒ ä»¥äžã奜ãŸãã
ã¯20ééïŒ ä»¥äžã§ããããŸãé»è·ç§»åæ§ç©è³ªã®å²
åã¯10ã95ééïŒ ã奜ãŸããã¯30ã90ééïŒ ã§ã
ãããŸã第ïŒãïŒå³ã®æå äœã«ãããé»è·ç§»ååª
äœå±€äžã®é»è·ç§»åç©è³ªã®å²åã¯ç¬¬ïŒå³ã®æå äœã®
æå å±€ã®å Žåãšåæ§ã10ã95ééïŒ ã奜ãŸããã¯
30ã90ééïŒ ã§ããããªã第ïŒãïŒå³ã®ãããã®
æå äœã®äœæã«ãããŠãçµçå€ãšå ±ã«å¯å¡å€ã䜵
çšããããšãã§ããã æ¬çºæã®æå äœã«ãããŠå°é»æ§æ¯æäœãšããŠã¯
ã¢ã«ãããŠã çã®éå±æ¿åã¯éå±ç®ãã¢ã«ãããŠ
ã ãªã©ã®éå±ãèžçãããã©ã¹ããã¯ãã€ã«ã ã
æãã¯å°é»åŠçãæœããçŽçã䜿çšããããçµç
å€ãšããŠã¯ããªã¢ãããããªãŠã¬ã¿ã³ãããªãšã¹
ãã«ããšããã·æš¹èãããªã±ãã³ãããªã«ãŒãã
ãŒããªã©ã®çž®åæš¹èãããªããã«ã±ãã³ãããªã¹
ãã¬ã³ãããªââããã«ã«ã«ããŸãŒã«ãããªã¢
ã¯ãªã«ã¢ãããªã©ã®ããã«éåäœãªã©ãæããã
ããã絶çžæ§ã§äžã€æ¥çæ§ã®ããæš¹èã¯å šãŠäœ¿çš
ã§ãããå¯å¡å€ãšããŠã¯ããã²ã³åãã©ãã€ã³ã
ããªå¡©åãããšãã«ããžã¡ãã«ããã¿ã¬ã³ããžã
ãã«ãã¿ã¬ãŒããªã©ãæããããããŸãé»è·ç§»å
æ§ç©è³ªãšããŠã¯é«ååã®ãã®ã§ã¯ããªââãã
ã«ã«ã«ããŸãŒã«ãããã²ã³åããªãŒïŒ®âããã«ã«
ã«ããŸãŒã«ãããªããã«ãã¬ã³ãããªããã«ã€ã³
ããããããµãªã³ãããªããã«ãžãã³ãŸããªããš
ã³ãããªããã«ã¢ã³ãã©ã»ã³ãããªããã«ã¢ã¯ãª
ãžã³ãªã©ã®ããã«éåäœããã¬ã³ããã«ã ã¢ã«ã
ããæš¹èãããã ãã¬ã³ããã«ã ã¢ã«ãããæš¹
èããšãã«ã«ã«ããŸãŒã«ããã«ã ã¢ã«ãããæš¹
èãã¯ãããšãã«ã«ã«ããŸãŒã«ããã«ã ã¢ã«ãã
ãæš¹èãªã©ã®çž®åæš¹èãããŸãäœååïŒåéäœïŒ
ã®ãã®ã§ã¯ãã«ãªã¬ãã³ãïŒâãããâïŒâãã«
ãªã¬ãã³ãïŒïŒïŒïŒâãžãããâïŒâãã«ãªã¬ã
ã³ãïŒïŒïŒïŒïŒâããªãããâïŒâãã«ãªã¬ã
ã³ãïŒïŒïŒïŒïŒïŒïŒâããã©ãããâïŒâãã«ãª
ã¬ãã³ã4Hâã€ã³ãããïŒïŒïŒâïœãããªããš
ã³âïŒâãªã³ãïŒâãããâ4Hâã€ã³ãã
ãïŒïŒïŒâïœãããªããšã³âïŒâãªã³ãïŒïŒïŒïŒ
ïŒâããªãããâ4Hâã€ã³ãããïŒïŒïŒâïœã
ããªããšã³âïŒâãªã³ã8Hâã€ã³ãããïŒïŒïŒ
âïœãããªããšã³âïŒâãªã³ãïŒâãããâ8H
âã€ã³ãããïŒïŒïŒâïœãããªããšã³âïŒâãª
ã³ãïŒâããã âïŒïŒïŒâãžãããâ4Hâã€ã³
ãããïŒïŒïŒâïœãããªããšã³ãïŒïŒïŒâãžãã
ãâ4Hâã€ã³ãããïŒïŒïŒâïœãããªããšã³ã
ïŒâããããžãã³ãŸããªããšã³ãïŒïŒïŒâãžãã
ããžãã³ãŸããªããšã³ãïŒâããããžãã³ãŸããª
ããšã³âïŒâãªããµã€ããïŒïŒïŒâãžããããžã
ã³ãŸããªããšã³âïŒâãªããµã€ããïŒïŒïŒïŒïŒâ
ããªãããâãžãã³ãŸããªããšã³âïŒïŒïŒâãžãª
ããµã€ããïŒâãããâãžãã³ãŸããªããšã³â
ïŒïŒïŒâãžãªããµã€ããïŒïŒïŒâãžãããâãžã
ã³ãŸããªããšã³âïŒïŒïŒâãžãªããµã€ããïŒâãž
ã·ã¢ãã¡ãã¬ã³â4Hâã€ã³ãããïŒïŒïŒâïœã
ããªããšã³ãïŒïŒïŒâãžãããâïŒâãžã·ã¢ãã¡
ãã¬ã³â4Hâã€ã³ãããïŒïŒïŒâïœãããªããš
ã³ãïŒïŒïŒïŒïŒïŒïŒâããã©ããããã³ãŸãïœã
ã·ã³ããªã³âïŒâãªããµã€ããïŒïŒïŒïŒ10âããª
ããããã³ãŸãïœãã·ã³ããªã³âïŒâãªããµã€
ããïŒïŒïŒïŒïŒâããªããããã³ãŸãïœãã·ã³ã
ãªã³âïŒâãªããµã€ããïŒïŒïŒïŒïŒâããªããã
ããªããµã³ãã³ãïŒïŒïŒïŒïŒâããªãããâïŒïŒ
10âããšãã³ã¹ã¬ã³ããã³ãïŒïŒïŒâããããã
ã³ãã³ãŸãïœãã¢ã³ã¹ã©ã»ã³âïŒïŒ12âãžãªã³ã
ïŒïŒïŒïŒïŒâããªãããâïŒâãžã·ã¢ãã¡ãã¬ã³
ãã«ãªã¬ã³ãããã©ã¯ãã«ç¡æ°Žãã¿ã«é žãïŒâã
ãã ãã¬ã³ãïŒâã¡ãã«ãã¬ã³ãïŒâãšãã«ãã¬
ã³ãïŒâã¢ã»ãã«ãã¬ã³ãã«ã«ããŸãŒã«ãâãš
ãã«ã«ã«ããŸãŒã«ãâβâã¯ãããšãã«ã«ã«ã
ãŸãŒã«ãâβâããããã·ãšãã«ã«ã«ããŸãŒ
ã«ãïŒâããšãã«ã€ã³ããŒã«ãïŒâããšãã«ãã
ã¿ã¬ã³ãïŒïŒïŒâãã¹ïŒïŒâãžãšãã«ã¢ããããš
ãã«ïŒâïŒïŒïŒïŒïŒâãªããµãžã¢ãŸãŒã«ãïŒïŒïŒ
âãã¹ïŒïŒâãžãšãã«ã¢ããããšãã«ïŒïŒïŒïŒïŒ
ïŒâããªã¢ãŸãŒã«ãïŒâããšãã«âïŒâïŒïŒâãž
ãšãã«ã¢ããã¹ããªã«ïŒâïŒâïŒïŒâãžãšãã«ã¢
ããããšãã«ïŒãã©ãŸãªã³ãïŒâããšãã«âïŒâ
ïŒïŒâãžãšãã«ã¢ããããšãã«ïŒâïŒâããšãã«
ãªããµãŸãŒã«ãããªããšãã«ã¢ãã³ãããªã¹ïŒïŒ
âãžãšãã«ã¢ããããšãã«ïŒã¡ã¿ã³ãïŒïŒïŒâã
ã¹ïŒãžãã³ãžã«ã¢ããïŒâïŒâãšãã«ã«ã«ããŸãŒ
ã«ïŒâãšãã«ã«ã«ããŸãŒã«âïŒâã¢ã«ãããïŒâ
ã¡ãã«âãããšãã«ããã©ãŸã³ãªã©ãæããã
ãããããã®é»è·ç§»åæ§ç©è³ªã¯åç¬åã¯ïŒçš®ä»¥äž
æ··åããŠçšããããã ãªã以äžã®ããã«ããŠåŸãããæå äœã«ã¯ãã
ããå°é»æ§æ¯æäœãšæå å±€ã®éã«å¿ èŠã«å¿ããŠæ¥
çå±€åã¯ããªã€å±€ãèšããããšãã§ãããããã
ã®å±€ã«çšããããææãšããŠã¯ããªã¢ããããã
ãã»ã«ããŒã¹ãé žåã¢ã«ãããŠã ãªã©ãé©åœã§ã
ãŸãèåã¯ïŒÎŒä»¥äžã奜ãŸããã æ¬çºæã®æå äœãçšããŠè€åãè¡ãªãã«ã¯ãæ
å å±€é¢ã«åž¯é»ãé²å ãæœããåŸãçŸåãè¡ãªãã
å¿ èŠã«ãã€ãŠçŽãªã©ãžè»¢åãè¡ãããšã«ããéæ
ãããã æ¬çºæã®æå äœã¯äžè¬ã«æ床ãé«ãããŸãå¯æ
æ§ã«å¯ããªã©ã®ããããå©ç¹ãæããã 以äžã«å®æœäŸã瀺ãã å®æœäŸ ïŒ ããªãšã¹ãã«æš¹èïŒããŠãã³ç€Ÿè£œãããªãšã¹ã
ã«ã¢ããã·ãŒã49000ïŒïŒéééšãNo.ïŒã®ãžã¹ã¢
ãŸé¡æïŒéééšåã³ããã©ããããã©ã³26éééš
ãããŒã«ãã«äžã§ç²ç æ··åããåŸãããåæ£æ¶²
ããã¢ã«ãããŠã èžçããããªãšã¹ãã«ãã€ã«ã
äžã«ãã¯ã¿ãŒãã¬ãŒããçšããŠå¡åžã100âã§10
åé也ç¥ããŠåãïŒÎŒã®æå å±€ãæã€ã第ïŒå³ã®
圢æ ã®æå äœãåŸãã 次ã«ãã®æå äœã®æå å±€é¢ã«åžè²©ã®éé»è€åçŽ
è©Šéšè£ 眮ã«ããïŒ6KVã®ã³ããæŸé»ã20ç§è¡ã€ãŠ
æ£åž¯é»ãããåŸã20ç§éææã«æŸçœ®ãããã®æã®
è¡šé¢é»äœVpoïŒãã«ãïŒã枬å®ããã€ãã§ã¿ã³ã°
ã¹ãã³ã©ã³ãããããã®è¡šé¢ãç §åºŠ20ã«ãã¯ã¹ã«
ãªãããæå å±€ã«å ç §å°ãæœãããã®è¡šé¢é»äœã
Vpoã®ïŒïŒïŒã«ãªãè¿ã®æéïŒç§ïŒãæ±ããŠé²å
é1/2ïŒã«ãã¯ã¹ã»ç§ïŒãšããããã®çµæã¯
VpoïŒ720VïŒïŒ¥1/2ïŒ10ã«ãã¯ã¹ã»ç§ã§ãã€ãã å®æœäŸ ïŒã10 å®æœäŸïŒã«ãããŠNo.ïŒã®ãžã¹ã¢ãŸé¡æã®ä»£ãã«
äžèšè¡šïŒã«ç€ºãçªå·ã®ãžã¹ã¢ãŸé¡æã倫ã çšãã
ä»ã¯å®æœäŸïŒãšåãæå äœäœææ³ã«åŸã€ãŠæå äœ
ãäœæãã以äžãããã®æå äœã«ã€ããŠå®æœäŸïŒ
ãšåã枬å®ãè¡ãªãè¡šïŒã®çµæãåŸãã
å ¬å ±ã«èšèŒã®ïŒâãã«ãªã¬ãã³âïŒïŒïŒâãã¹ãž
ã¢ãŸããŠã ãã¹ããã©ãã«ãªããã¬ãŒããšãå
é¡æã«å¯Ÿå¿ããã«ããã©ãŒãšãé©åœãªææ©æº¶åªã
äŸãã°ïŒ®ïŒïŒ®âãžã¡ãã«ãã«ã ã¢ããïŒDMFïŒ
äžã§ãã¢ã«ã«ãªã®ååšäžã«ãããªã³ã°ããããšã«
ãã容æã«è£œé ããããšãåºæ¥ãããŸãããã§äœ¿
çšãããã«ããã©ãŒã¯Franzenãã®æ¹æ³ïŒJ.
Prak.Chem.ãïŒã78ïŒ164ïŒã«åŸãïŒâãããã
ã·âïŒâããããšé žããã©ãžããšã¢ã«ããããäŸ
ãã°ã¢ã«ã³ãŒã«ãªã©ã®ææ©æº¶åªäžã§å ç±ããããš
ã«ãã容æã«è£œé ããããã®ã§ããã 以äžã«ãã®è£œé ã®å ·äœäŸã瀺ãã 補é äŸ ïŒâãã«ãªã¬ãã³âïŒïŒïŒâãã¹ãžã¢ãŸããŠã
ãã¹ããã©ãã«ãªããã¬ãŒã 2.04ïœãïŒâã·
ãããã·âïŒâããããšé žãã³ã¶ã«ããã©ãžã
2.90ïœãDMF300mlã«æº¶è§£ããããã«é ¢é žãããª
ãŠã 1.64ïœåã³æ°Ž14mlãããªã溶液ã宀枩ã«ãŠæ»Ž
äžããã滎äžçµäºåŸå枩床ã«ãŠïŒæéæ¹æããæ
åºããçµæ¶ãåãããæ®æž£ã«300mlã®DMFãå
ããŠ80âã§ïŒæéæ¹æããã®ã¡ãåã³çµæ¶ãå
ãããã®æäœãæŽã«ïŒåããè¿ãããæ°ŽæŽåŸä¹Ÿç¥
ããŠååç©No.ïŒã®ãžã¹ã¢ãŸé¡æ3.20ïœãéé»è²çµ
æ¶ãšããŠåŸãã å çŽ åæå€ èšç®å€ å®æž¬å€ ïŒ£ïŒ 72.40 72.20 ïŒšïŒ 3.97 3.89 ïŒ®ïŒ 13.79 13.51 èµ€å€ç·åžåã¹ãã¯ãã«ïŒKBrdiskïŒã第ïŒå³ã«
瀺ãã VcoïŒç¬¬ïŒã¢ããïŒ 1680 cm-1 VcoïŒãã«ãªã¬ãã³ïŒ 1725 cm-1 æ¬çºæã®æå äœã¯ä»¥äžã®ãããªãžã¹ã¢ãŸé¡æã
å«ããã®ã§ãããããããé¡æã®å¿çšã®ä»æ¹ã«ã
ã第ïŒãïŒå³ã®åœ¢æ ããšãããšãã§ããã第ïŒå³
ã®æå äœã¯å°é»æ§æ¯æäœïŒäžã«ãžã¹ã¢ãŸé¡æïŒ
ïŒããã§ã¯å å°é»æ§ç©è³ªãšããŠäœ¿çšãããïŒãæš¹
èçµçå€ïŒç³»æå å±€ïŒãèšãããã®ã§ããã第ïŒ
å³ã®æå äœã¯å°é»æ§æ¯æäœïŒäžã«ãžã¹ã¢ãŸé¡æïŒ
ïŒããã§ã¯é»è·æ äœçºçç©è³ªãšããŠäœ¿çšãããïŒ
ãé»è·ç§»ååªäœïŒé»è·ç§»åæ§ç©è³ªåã³æš¹èçµçå€
ã®æ··åç©ïŒïŒç³»æå å±€ïŒâ²ãèšãããã®ã§ããã
ãŸã第ïŒãïŒå³ã®æå äœã¯ç¬¬ïŒå³ã®æå äœã®å€åœ¢
ã§ãæå å±€ïŒâ³ïŒïŒã¯ãžã¹ã¢ãŸé¡æïŒãäž»äœãš
ããé»è·æ äœçºçå±€ïŒãšé»è·ç§»ååªäœã®å±€ïŒãšã
ããªã€ãŠããã ãããã®æå äœã«ãããåçµæåã¯ãåã 次ã®
ãããªçŸè±¡ã«ããæå äœã«å¯Ÿããå¹æããããã
ããŠãããã®ãšèããããã 第ïŒå³ã®æå äœã«ãããŠãžã¹ã¢ãŸé¡æã¯å å°é»
æ§ç©è³ªãšããŠäœçšããå æžè¡°ã«å¿ èŠãªé»è·æ äœã®
çæåã³ç§»åã¯é¡æç²åãä»ããŠè¡ãªãããã第
ïŒå³ã®æå äœã®å Žåã¯é»è·ç§»åæ§ç©è³ªã¯çµçå€
ïŒåã³å Žåã«ããå¯å¡å€ïŒãšå ±ã«é»è·ç§»ååªäœã
圢æããäžæ¹ãžã¹ã¢ãŸé¡æã¯é»è·æ äœçºçç©è³ªãš
ããŠäœçšããããã®é»è·ç§»ååªäœã¯ãžã¹ã¢ãŸé¡æ
ã®ãããªé»è·æ äœã®çæèœåã¯ãªããããžã¹ã¢ãŸ
é¡æããçºçããé»è·æ äœãåãå ¥ããããã移
åããèœåãæã€ãŠãããå³ã¡ç¬¬ïŒå³ã®æå äœã§
ã¯å æžè¡°ã«å¿ èŠãªé»è·æ äœã®çæã¯ãžã¹ã¢ãŸé¡æ
ã«ãã€ãŠè¡ãªãããäžæ¹ãé»è·æ äœã®ç§»åã¯äž»ã«
é»è·ç§»ååªäœã«ããè¡ãªããããããã§é»è·ç§»å
åªäœã«æŽã«èŠæ±ãããåºæ¬çæ¡ä»¶ã¯é»è·ç§»ååªäœ
ã®åžåæ³¢é·é åããžã¹ã¢ãŸé¡æã®äž»ã«å¯èŠéšã®åž
åæ³¢é·é åãšéãªããªãããšã§ãããããã¯ãžã¹
ã¢ãŸé¡æã«å¹çè¯ãé»è·æ äœãçºçãããããã«
é¡æè¡šé¢ãŸã§å ãééãããå¿ èŠãããããã§ã
ãããããäŸãã°ããç¹å®æ³¢é·ã ãã«æ床ãæã
ãæå äœã®å Žåã¯ãã®éãã§ã¯ãªããåŸã€ãŠé»è·
移ååªäœåã³ãžã¹ã¢ãŸé¡æã®äž¡è ã®åžåæ³¢é·ã¯å®
å šã«éè€ããªããã°ããã次ã«ç¬¬ïŒå³ã®æå äœã§
ã¯é»è·ç§»ååªäœå±€ãééããŠæ¥ãå ãé»è·æ äœçº
çå±€ã§ããæå å±€ïŒâ³ã«å°éãããã®éšåã®ãžã¹
ã¢ãŸé¡æã§é»è·æ äœã®çæãèµ·ãããäžæ¹ãé»è·
移ååªäœå±€ã¯é»è·æ äœã®æ³šå ¥ãåãããã®ç§»åã
è¡ãªããã®ã§ãå æžè¡°ã«å¿ èŠãªé»è·æ äœã®çæã¯
ãžã¹ã¢ãŸé¡æã§ããŸãé»è·æ äœã®ç§»åã¯é»è·ç§»å
åªäœã§ãšããã¡ã«ããºã ã¯ç¬¬ïŒå³ã«ç€ºããæå äœ
ã®å Žåãšåæ§ã§ãããããã§ããžã¹ã¢ãŸé¡æã¯é»
è·æ äœçºçç©è³ªã§ããããªãã第ïŒå³ã®æå äœã«
ãããé»è·ç§»åå±€åã³é»è·æ äœçºçå±€ã®äœçšæ©æ§
ã第ïŒå³ã®æå äœã®å Žåãšåãã§ããã 第ïŒå³ã®æå äœãäœæããã«ã¯ãžã¹ã¢ãŸé¡æã®
埮ç²åãçµçå€æº¶æ¶²äžã«åæ£ããåæ£æ¶²ãå°é»æ§
æ¯æäœäžã«å¡åžä¹Ÿç¥ããã°ããã第ïŒå³ã®æå äœ
ãäœæããã«ã¯ãžã¹ã¢ãŸé¡æã®åŸ®ç²åãé»è·ç§»å
æ§ç©è³ªåã³çµçå€ã溶解ãã溶液äžã«ãžã¹ã¢ãŸé¡
æã®åŸ®ç²åãåæ£ãããããããå°é»æ§æ¯æäœäž
ã«å¡åžä¹Ÿç¥ããã°ããããŸã第ïŒå³ã®æå äœã¯å°
é»æ§æ¯æäœäžã«ãžã¹ã¢ãŸé¡æãç空èžçãããã
æãã¯ãžã¹ã¢ãŸé¡æã®åŸ®ç²åãå¿ èŠããã°çµçå€
ã溶解ããé©åœãªæº¶åªäžã«æº¶è§£ãããããå°é»æ§
æ¯æäœäžã«éåžä¹Ÿç¥ããæŽã«å¿ èŠããã°äŸãã°ã
ãç æ©çã®æ¹æ³ã«ããè¡šé¢ä»äžããããèåã調
æŽããåŸããã®äžã«é»è·ç§»åæ§ç©è³ªåã³çµçå€ã
å«ã溶液ãå¡åžä¹Ÿç¥ããŠåŸãããããªã第ïŒå³ã®
æå äœã®å Žåã¯ç¬¬ïŒå³ã®æå äœã®äœææ³ã«ãããŠ
è圢æé åºãéã«ããã°ããããããã«ããŠãæ¬
çºæã§äœ¿çšããããžã¹ã¢ãŸé¡æã¯ããŒã«ãã«çã«
ããç²åŸïŒÎŒä»¥äžã奜ãŸããã¯ïŒÎŒä»¥äžã«ç²ç ã
ãŠçšãããããå¡åžæ³ã¯éåžžã®æ段ãäŸãã°ãã¯
ã¿ãŒãã¬ãŒããã¯ã€ã€ãŒããŒãªã©ã§è¡ãªããæå
å±€ã®åãã¯ç¬¬ïŒå³åã³ç¬¬ïŒå³ã®ãã®ã§ã¯çŽïŒã50
ÎŒã奜ãŸããã¯ïŒã20ÎŒã§ããããŸã第ïŒãïŒå³
ã®ãã®ã§ã¯é»è·æ äœçºçå±€ã®åã¿ã¯ãïŒÎŒä»¥äžã
奜ãŸããã¯ïŒÎŒä»¥äžããããé»è·ç§»ååªäœå±€ã®å
ãã¯çŽïŒã50ÎŒã奜ãŸããã¯ïŒã20ÎŒã§ããããŸ
ã第ïŒå³ã®æå äœã«ãããŠæå å±€äžã®ãžã¹ã¢ãŸé¡
æã®å²åã¯æå å±€ã«å¯Ÿã30ã70ééïŒ å¥œãŸããã¯
çŽ50ééïŒ ãé©åœã§ãããïŒåè¿°ã®ããã«ç¬¬ïŒå³
ã®æå äœã®å Žåã¯ããžã¹ã¢ãŸé¡æã¯å å°é»ç©è³ªãš
ããŠäœçšããå æžè¡°ã«å¿ èŠãªé»è·æ äœã®çæåã³
移åã¯é¡æç²åãä»ããŠè¡ãªãããã®ã§ãé¡æç²
åéã®æ¥è§Šã¯æå 局衚é¢ããæ¯æäœãŸã§é£ç¶ããŠ
ããããšãæãŸããããã®ããæå å±€ã«å ããé¡
æã®å²åã¯æ¯èŒçå€ãæ¹ã奜ãŸããããæå å±€ã®
匷床åã³æ床ãèæ ®ãããšãçŽ50ééïŒ ãã
ãïŒã第ïŒå³ã®æå äœã«ãããŠãæå å±€äžã®ãžã¹
ã¢ãŸé¡æã®å ããå²åã¯50ééïŒ ä»¥äžã奜ãŸãã
ã¯20ééïŒ ä»¥äžã§ããããŸãé»è·ç§»åæ§ç©è³ªã®å²
åã¯10ã95ééïŒ ã奜ãŸããã¯30ã90ééïŒ ã§ã
ãããŸã第ïŒãïŒå³ã®æå äœã«ãããé»è·ç§»ååª
äœå±€äžã®é»è·ç§»åç©è³ªã®å²åã¯ç¬¬ïŒå³ã®æå äœã®
æå å±€ã®å Žåãšåæ§ã10ã95ééïŒ ã奜ãŸããã¯
30ã90ééïŒ ã§ããããªã第ïŒãïŒå³ã®ãããã®
æå äœã®äœæã«ãããŠãçµçå€ãšå ±ã«å¯å¡å€ã䜵
çšããããšãã§ããã æ¬çºæã®æå äœã«ãããŠå°é»æ§æ¯æäœãšããŠã¯
ã¢ã«ãããŠã çã®éå±æ¿åã¯éå±ç®ãã¢ã«ãããŠ
ã ãªã©ã®éå±ãèžçãããã©ã¹ããã¯ãã€ã«ã ã
æãã¯å°é»åŠçãæœããçŽçã䜿çšããããçµç
å€ãšããŠã¯ããªã¢ãããããªãŠã¬ã¿ã³ãããªãšã¹
ãã«ããšããã·æš¹èãããªã±ãã³ãããªã«ãŒãã
ãŒããªã©ã®çž®åæš¹èãããªããã«ã±ãã³ãããªã¹
ãã¬ã³ãããªââããã«ã«ã«ããŸãŒã«ãããªã¢
ã¯ãªã«ã¢ãããªã©ã®ããã«éåäœãªã©ãæããã
ããã絶çžæ§ã§äžã€æ¥çæ§ã®ããæš¹èã¯å šãŠäœ¿çš
ã§ãããå¯å¡å€ãšããŠã¯ããã²ã³åãã©ãã€ã³ã
ããªå¡©åãããšãã«ããžã¡ãã«ããã¿ã¬ã³ããžã
ãã«ãã¿ã¬ãŒããªã©ãæããããããŸãé»è·ç§»å
æ§ç©è³ªãšããŠã¯é«ååã®ãã®ã§ã¯ããªââãã
ã«ã«ã«ããŸãŒã«ãããã²ã³åããªãŒïŒ®âããã«ã«
ã«ããŸãŒã«ãããªããã«ãã¬ã³ãããªããã«ã€ã³
ããããããµãªã³ãããªããã«ãžãã³ãŸããªããš
ã³ãããªããã«ã¢ã³ãã©ã»ã³ãããªããã«ã¢ã¯ãª
ãžã³ãªã©ã®ããã«éåäœããã¬ã³ããã«ã ã¢ã«ã
ããæš¹èãããã ãã¬ã³ããã«ã ã¢ã«ãããæš¹
èããšãã«ã«ã«ããŸãŒã«ããã«ã ã¢ã«ãããæš¹
èãã¯ãããšãã«ã«ã«ããŸãŒã«ããã«ã ã¢ã«ãã
ãæš¹èãªã©ã®çž®åæš¹èãããŸãäœååïŒåéäœïŒ
ã®ãã®ã§ã¯ãã«ãªã¬ãã³ãïŒâãããâïŒâãã«
ãªã¬ãã³ãïŒïŒïŒïŒâãžãããâïŒâãã«ãªã¬ã
ã³ãïŒïŒïŒïŒïŒâããªãããâïŒâãã«ãªã¬ã
ã³ãïŒïŒïŒïŒïŒïŒïŒâããã©ãããâïŒâãã«ãª
ã¬ãã³ã4Hâã€ã³ãããïŒïŒïŒâïœãããªããš
ã³âïŒâãªã³ãïŒâãããâ4Hâã€ã³ãã
ãïŒïŒïŒâïœãããªããšã³âïŒâãªã³ãïŒïŒïŒïŒ
ïŒâããªãããâ4Hâã€ã³ãããïŒïŒïŒâïœã
ããªããšã³âïŒâãªã³ã8Hâã€ã³ãããïŒïŒïŒ
âïœãããªããšã³âïŒâãªã³ãïŒâãããâ8H
âã€ã³ãããïŒïŒïŒâïœãããªããšã³âïŒâãª
ã³ãïŒâããã âïŒïŒïŒâãžãããâ4Hâã€ã³
ãããïŒïŒïŒâïœãããªããšã³ãïŒïŒïŒâãžãã
ãâ4Hâã€ã³ãããïŒïŒïŒâïœãããªããšã³ã
ïŒâããããžãã³ãŸããªããšã³ãïŒïŒïŒâãžãã
ããžãã³ãŸããªããšã³ãïŒâããããžãã³ãŸããª
ããšã³âïŒâãªããµã€ããïŒïŒïŒâãžããããžã
ã³ãŸããªããšã³âïŒâãªããµã€ããïŒïŒïŒïŒïŒâ
ããªãããâãžãã³ãŸããªããšã³âïŒïŒïŒâãžãª
ããµã€ããïŒâãããâãžãã³ãŸããªããšã³â
ïŒïŒïŒâãžãªããµã€ããïŒïŒïŒâãžãããâãžã
ã³ãŸããªããšã³âïŒïŒïŒâãžãªããµã€ããïŒâãž
ã·ã¢ãã¡ãã¬ã³â4Hâã€ã³ãããïŒïŒïŒâïœã
ããªããšã³ãïŒïŒïŒâãžãããâïŒâãžã·ã¢ãã¡
ãã¬ã³â4Hâã€ã³ãããïŒïŒïŒâïœãããªããš
ã³ãïŒïŒïŒïŒïŒïŒïŒâããã©ããããã³ãŸãïœã
ã·ã³ããªã³âïŒâãªããµã€ããïŒïŒïŒïŒ10âããª
ããããã³ãŸãïœãã·ã³ããªã³âïŒâãªããµã€
ããïŒïŒïŒïŒïŒâããªããããã³ãŸãïœãã·ã³ã
ãªã³âïŒâãªããµã€ããïŒïŒïŒïŒïŒâããªããã
ããªããµã³ãã³ãïŒïŒïŒïŒïŒâããªãããâïŒïŒ
10âããšãã³ã¹ã¬ã³ããã³ãïŒïŒïŒâããããã
ã³ãã³ãŸãïœãã¢ã³ã¹ã©ã»ã³âïŒïŒ12âãžãªã³ã
ïŒïŒïŒïŒïŒâããªãããâïŒâãžã·ã¢ãã¡ãã¬ã³
ãã«ãªã¬ã³ãããã©ã¯ãã«ç¡æ°Žãã¿ã«é žãïŒâã
ãã ãã¬ã³ãïŒâã¡ãã«ãã¬ã³ãïŒâãšãã«ãã¬
ã³ãïŒâã¢ã»ãã«ãã¬ã³ãã«ã«ããŸãŒã«ãâãš
ãã«ã«ã«ããŸãŒã«ãâβâã¯ãããšãã«ã«ã«ã
ãŸãŒã«ãâβâããããã·ãšãã«ã«ã«ããŸãŒ
ã«ãïŒâããšãã«ã€ã³ããŒã«ãïŒâããšãã«ãã
ã¿ã¬ã³ãïŒïŒïŒâãã¹ïŒïŒâãžãšãã«ã¢ããããš
ãã«ïŒâïŒïŒïŒïŒïŒâãªããµãžã¢ãŸãŒã«ãïŒïŒïŒ
âãã¹ïŒïŒâãžãšãã«ã¢ããããšãã«ïŒïŒïŒïŒïŒ
ïŒâããªã¢ãŸãŒã«ãïŒâããšãã«âïŒâïŒïŒâãž
ãšãã«ã¢ããã¹ããªã«ïŒâïŒâïŒïŒâãžãšãã«ã¢
ããããšãã«ïŒãã©ãŸãªã³ãïŒâããšãã«âïŒâ
ïŒïŒâãžãšãã«ã¢ããããšãã«ïŒâïŒâããšãã«
ãªããµãŸãŒã«ãããªããšãã«ã¢ãã³ãããªã¹ïŒïŒ
âãžãšãã«ã¢ããããšãã«ïŒã¡ã¿ã³ãïŒïŒïŒâã
ã¹ïŒãžãã³ãžã«ã¢ããïŒâïŒâãšãã«ã«ã«ããŸãŒ
ã«ïŒâãšãã«ã«ã«ããŸãŒã«âïŒâã¢ã«ãããïŒâ
ã¡ãã«âãããšãã«ããã©ãŸã³ãªã©ãæããã
ãããããã®é»è·ç§»åæ§ç©è³ªã¯åç¬åã¯ïŒçš®ä»¥äž
æ··åããŠçšããããã ãªã以äžã®ããã«ããŠåŸãããæå äœã«ã¯ãã
ããå°é»æ§æ¯æäœãšæå å±€ã®éã«å¿ èŠã«å¿ããŠæ¥
çå±€åã¯ããªã€å±€ãèšããããšãã§ãããããã
ã®å±€ã«çšããããææãšããŠã¯ããªã¢ããããã
ãã»ã«ããŒã¹ãé žåã¢ã«ãããŠã ãªã©ãé©åœã§ã
ãŸãèåã¯ïŒÎŒä»¥äžã奜ãŸããã æ¬çºæã®æå äœãçšããŠè€åãè¡ãªãã«ã¯ãæ
å å±€é¢ã«åž¯é»ãé²å ãæœããåŸãçŸåãè¡ãªãã
å¿ èŠã«ãã€ãŠçŽãªã©ãžè»¢åãè¡ãããšã«ããéæ
ãããã æ¬çºæã®æå äœã¯äžè¬ã«æ床ãé«ãããŸãå¯æ
æ§ã«å¯ããªã©ã®ããããå©ç¹ãæããã 以äžã«å®æœäŸã瀺ãã å®æœäŸ ïŒ ããªãšã¹ãã«æš¹èïŒããŠãã³ç€Ÿè£œãããªãšã¹ã
ã«ã¢ããã·ãŒã49000ïŒïŒéééšãNo.ïŒã®ãžã¹ã¢
ãŸé¡æïŒéééšåã³ããã©ããããã©ã³26éééš
ãããŒã«ãã«äžã§ç²ç æ··åããåŸãããåæ£æ¶²
ããã¢ã«ãããŠã èžçããããªãšã¹ãã«ãã€ã«ã
äžã«ãã¯ã¿ãŒãã¬ãŒããçšããŠå¡åžã100âã§10
åé也ç¥ããŠåãïŒÎŒã®æå å±€ãæã€ã第ïŒå³ã®
圢æ ã®æå äœãåŸãã 次ã«ãã®æå äœã®æå å±€é¢ã«åžè²©ã®éé»è€åçŽ
è©Šéšè£ 眮ã«ããïŒ6KVã®ã³ããæŸé»ã20ç§è¡ã€ãŠ
æ£åž¯é»ãããåŸã20ç§éææã«æŸçœ®ãããã®æã®
è¡šé¢é»äœVpoïŒãã«ãïŒã枬å®ããã€ãã§ã¿ã³ã°
ã¹ãã³ã©ã³ãããããã®è¡šé¢ãç §åºŠ20ã«ãã¯ã¹ã«
ãªãããæå å±€ã«å ç §å°ãæœãããã®è¡šé¢é»äœã
Vpoã®ïŒïŒïŒã«ãªãè¿ã®æéïŒç§ïŒãæ±ããŠé²å
é1/2ïŒã«ãã¯ã¹ã»ç§ïŒãšããããã®çµæã¯
VpoïŒ720VïŒïŒ¥1/2ïŒ10ã«ãã¯ã¹ã»ç§ã§ãã€ãã å®æœäŸ ïŒã10 å®æœäŸïŒã«ãããŠNo.ïŒã®ãžã¹ã¢ãŸé¡æã®ä»£ãã«
äžèšè¡šïŒã«ç€ºãçªå·ã®ãžã¹ã¢ãŸé¡æã倫ã çšãã
ä»ã¯å®æœäŸïŒãšåãæå äœäœææ³ã«åŸã€ãŠæå äœ
ãäœæãã以äžãããã®æå äœã«ã€ããŠå®æœäŸïŒ
ãšåã枬å®ãè¡ãªãè¡šïŒã®çµæãåŸãã
ãè¡šã
å®æœäŸ 11
ããªãšã¹ãã«æš¹èïŒå®æœäŸïŒãšåãïŒ10éé
éšãïŒïŒïŒïŒïŒâããªãããâïŒâãã«ãªã¬ãã³
10éééšãNo.ïŒã®ãžã¹ã¢ãŸé¡æïŒéééšåã³ãã
ã©ããããã©ã³198éééšãããŒã«ãã«äžã§ç²ç
æ··åããåŸãããåæ£æ¶²ããã¢ã«ãããŠã ãèžç
ããããªãšã¹ãã«ãã€ã«ã äžã«ãã¯ã¿ãŒãã¬ãŒã
ãçšããŠå¡åžãã100âã§10åé也ç¥ããŠåã10
ÎŒã®æå å±€ãæã€ã第ïŒå³ã®åœ¢æ ã®æå äœãäœæ
ããã次ã«ãã®æå äœã®Vpoåã³ïŒ¥1/2ãåèšå®
æœäŸã§ïŒ6KVã®ã³ããæŸé»ãè¡ã€ããããã«â
6KVã®ã³ããæŸé»ãè¡ã€ã以å€ã¯å šãåæ§ã«æž¬å®
ããVpoïŒ480ãã«ãã1/2ïŒ15ã«ãã¯ã¹ã»ç§
ã®çµæãåŸãã å®æœäŸ 12ã20 å®æœäŸ11ã«ãããŠNo.ïŒã®ãžã¹ã¢ãŸé¡æã®ä»£ãã«
äžèšè¡šïŒã«ç€ºãçªå·ã®ãžã¹ã¢ãŸé¡æã倫ã çšããŠ
第ïŒå³ã®åœ¢æ ã®æå äœãäœæãã以äžå®æœäŸ11ãš
åãæ¹æ³ã§Vpoåã³ïŒ¥1/2ãæ±ãè¡šïŒã®çµæãåŸ
ãã
éšãïŒïŒïŒïŒïŒâããªãããâïŒâãã«ãªã¬ãã³
10éééšãNo.ïŒã®ãžã¹ã¢ãŸé¡æïŒéééšåã³ãã
ã©ããããã©ã³198éééšãããŒã«ãã«äžã§ç²ç
æ··åããåŸãããåæ£æ¶²ããã¢ã«ãããŠã ãèžç
ããããªãšã¹ãã«ãã€ã«ã äžã«ãã¯ã¿ãŒãã¬ãŒã
ãçšããŠå¡åžãã100âã§10åé也ç¥ããŠåã10
ÎŒã®æå å±€ãæã€ã第ïŒå³ã®åœ¢æ ã®æå äœãäœæ
ããã次ã«ãã®æå äœã®Vpoåã³ïŒ¥1/2ãåèšå®
æœäŸã§ïŒ6KVã®ã³ããæŸé»ãè¡ã€ããããã«â
6KVã®ã³ããæŸé»ãè¡ã€ã以å€ã¯å šãåæ§ã«æž¬å®
ããVpoïŒ480ãã«ãã1/2ïŒ15ã«ãã¯ã¹ã»ç§
ã®çµæãåŸãã å®æœäŸ 12ã20 å®æœäŸ11ã«ãããŠNo.ïŒã®ãžã¹ã¢ãŸé¡æã®ä»£ãã«
äžèšè¡šïŒã«ç€ºãçªå·ã®ãžã¹ã¢ãŸé¡æã倫ã çšããŠ
第ïŒå³ã®åœ¢æ ã®æå äœãäœæãã以äžå®æœäŸ11ãš
åãæ¹æ³ã§Vpoåã³ïŒ¥1/2ãæ±ãè¡šïŒã®çµæãåŸ
ãã
ãè¡šã
å®æœäŸ 21
ããªãšã¹ãã«æš¹èïŒå®æœäŸïŒãšåãïŒ10éé
éšãïŒïŒïŒâãã¹ïŒïŒâãžãšãã«ã¢ããããšã
ã«ïŒâïŒïŒïŒïŒïŒâãªããµãžã¢ãŸãŒã«10éééšã
No.ïŒã®ãžã¹ã¢ãŸé¡æïŒéééšåã³ããã©ãããã
ã©ã³198éééšãããŒã«ãã«äžã§ç²ç æ··åããåŸ
ãããåæ£æ¶²ããã¢ã«ãããŠã ãèžçããããªãš
ã¹ãã«ãã€ã«ã äžã«ãã¯ã¿ãŒãã¬ãŒããçšããŠå¡
åžãã120âã§10åé也ç¥ããŠåã10ÎŒã®æå å±€
ãæã€ç¬¬ïŒå³ã®åœ¢æ ã®æå äœãäœæããã以äžã
ã®æå äœã«ã€ããŠå®æœäŸïŒãšåã枬å®ãè¡ãªãã
VpoïŒ990ãã«ãã1/2ïŒ12ã«ãã¯ã¹ã»ç§ã®çµ
æãåŸãã å®æœäŸ 22ã30 å®æœäŸ21ã«ãããŠNo.ïŒã®ãžã¹ã¢ãŸé¡æã®ä»£ãã«
倫ã äžèšè¡šïŒã®ãžã¹ã¢ãŸé¡æãçšãä»ã¯å®æœäŸ21
ãšåãæ¹æ³ã§ç¬¬ïŒå³ã®åœ¢æ ã®æå äœãäœæãã以
äžå®æœäŸïŒãšåã枬å®ãè¡ããè¡šïŒã®çµæãåŸ
ãã
éšãïŒïŒïŒâãã¹ïŒïŒâãžãšãã«ã¢ããããšã
ã«ïŒâïŒïŒïŒïŒïŒâãªããµãžã¢ãŸãŒã«10éééšã
No.ïŒã®ãžã¹ã¢ãŸé¡æïŒéééšåã³ããã©ãããã
ã©ã³198éééšãããŒã«ãã«äžã§ç²ç æ··åããåŸ
ãããåæ£æ¶²ããã¢ã«ãããŠã ãèžçããããªãš
ã¹ãã«ãã€ã«ã äžã«ãã¯ã¿ãŒãã¬ãŒããçšããŠå¡
åžãã120âã§10åé也ç¥ããŠåã10ÎŒã®æå å±€
ãæã€ç¬¬ïŒå³ã®åœ¢æ ã®æå äœãäœæããã以äžã
ã®æå äœã«ã€ããŠå®æœäŸïŒãšåã枬å®ãè¡ãªãã
VpoïŒ990ãã«ãã1/2ïŒ12ã«ãã¯ã¹ã»ç§ã®çµ
æãåŸãã å®æœäŸ 22ã30 å®æœäŸ21ã«ãããŠNo.ïŒã®ãžã¹ã¢ãŸé¡æã®ä»£ãã«
倫ã äžèšè¡šïŒã®ãžã¹ã¢ãŸé¡æãçšãä»ã¯å®æœäŸ21
ãšåãæ¹æ³ã§ç¬¬ïŒå³ã®åœ¢æ ã®æå äœãäœæãã以
äžå®æœäŸïŒãšåã枬å®ãè¡ããè¡šïŒã®çµæãåŸ
ãã
ãè¡šã
å®æœäŸ 31
ããªââããã«ã«ã«ããŸãŒã«200éééšã
ïŒïŒïŒïŒïŒâããªãããâïŒâãã«ãªã¬ãã³33é
ééšãããªãšã¹ãã«æš¹èïŒå®æœäŸïŒãšåãïŒ20é
ééšåã³No.ïŒã®ãžã¹ã¢ãŸé¡æ20éééšãããã©ã
ãããã©ã³1780éééšã«å ããããŒã«ãã«äžã§ç²
ç æ··åããåŸãããåæ£æ¶²ããã¢ã«ãããŠã ãèž
çããããªãšã¹ãã«ãã€ã«ã äžã«ãã¯ã¿ãŒãã¬ãŒ
ãã§å¡åžãã100âã§10åéãã€ãã§120âã§ïŒå
é也ç¥ããåã13ÎŒã®æå å±€ãæãã第ïŒå³ã®åœ¢
æ ã®æå äœãäœæããå®æœäŸïŒãšåã枬å®ãè¡ãª
ã€ããšãããVpoïŒ1045ãã«ãã1/2ïŒïŒã«ã
ã¯ã¹ã»ç§ã®çµæãåŸãã å®æœäŸ 32ã40 å®æœäŸ31ã«ãããŠNo.ïŒã®ãžã¹ã¢ãŸé¡æã®ä»£ãã«
倫ã äžèšè¡šïŒã®ãžã¹ã¢ãŸé¡æãçšããŠç¬¬ïŒå³ã®åœ¢
æ ã®æå äœãäœæããå®æœäŸïŒãšåãæ¹æ³ã§Vpo
åã³ïŒ¥1/2ãæ±ãè¡šïŒã®çµæãåŸãã
ïŒïŒïŒïŒïŒâããªãããâïŒâãã«ãªã¬ãã³33é
ééšãããªãšã¹ãã«æš¹èïŒå®æœäŸïŒãšåãïŒ20é
ééšåã³No.ïŒã®ãžã¹ã¢ãŸé¡æ20éééšãããã©ã
ãããã©ã³1780éééšã«å ããããŒã«ãã«äžã§ç²
ç æ··åããåŸãããåæ£æ¶²ããã¢ã«ãããŠã ãèž
çããããªãšã¹ãã«ãã€ã«ã äžã«ãã¯ã¿ãŒãã¬ãŒ
ãã§å¡åžãã100âã§10åéãã€ãã§120âã§ïŒå
é也ç¥ããåã13ÎŒã®æå å±€ãæãã第ïŒå³ã®åœ¢
æ ã®æå äœãäœæããå®æœäŸïŒãšåã枬å®ãè¡ãª
ã€ããšãããVpoïŒ1045ãã«ãã1/2ïŒïŒã«ã
ã¯ã¹ã»ç§ã®çµæãåŸãã å®æœäŸ 32ã40 å®æœäŸ31ã«ãããŠNo.ïŒã®ãžã¹ã¢ãŸé¡æã®ä»£ãã«
倫ã äžèšè¡šïŒã®ãžã¹ã¢ãŸé¡æãçšããŠç¬¬ïŒå³ã®åœ¢
æ ã®æå äœãäœæããå®æœäŸïŒãšåãæ¹æ³ã§Vpo
åã³ïŒ¥1/2ãæ±ãè¡šïŒã®çµæãåŸãã
ãè¡šã
å®æœäŸ 41
No.ïŒã®ãžã¹ã¢ãŸé¡æïŒéééšåã³ããã©ããã
ãã©ã³98éééšãããŒã«ãã«äžã§ç²ç æ··åããåŸ
ãããåæ£æ¶²ããã¢ã«ãããŠã èžçããªãšã¹ãã«
ãã€ã«ã äžã«ãã¯ã¿ãŒãã¬ãŒãã§å¡åžããèªç¶ä¹Ÿ
ç¥ããŠåãïŒÎŒã®é»è·æ äœçºçå±€ã圢æããã
ããäžæ¹ãïŒïŒïŒïŒïŒâããªãããâïŒâãã«ãª
ã¬ãã³ïŒéééšãããªã«ãŒãããŒãã(æ ª)ãã€ãžã³
補ããã³ã©ã€ããïŒéééšåã³ããã©ãããã
ã©ã³46éééšãæ··åããŠåæ£æ¶²ãšãããããåèš
é»è·æ äœçºçå±€äžã«ãã¯ã¿ãŒãã¬ãŒãã§å¡åžãã
100âã§10åé也ç¥ããŠåã10ÎŒã®é»è·ç§»ååªäœ
å±€ã圢æãããã第ïŒå³ã®åœ¢æ ã®æå äœãåŸãã
äžèšã®ããã«ããŠåŸãæå äœã«ã€ããŠãå®æœäŸïŒ
ãšåæã«æž¬å®ããVpoã¯900ãã«ãã1/2ã¯10
ã«ãã¯ã¹ã»ç§ã®çµæãåŸãã å®æœäŸ 42ã50 å®æœäŸ41ã«ãããŠNo.ïŒã®ãžã¹ã¢ãŸé¡æã®ä»£ãã«
äžèšè¡šïŒã®ãžã¹ã¢ãŸé¡æã倫ã çšããä»ã¯åãæ¹
æ³ã§ç¬¬ïŒå³ã®åœ¢æ ã®æå äœãäœæããããããæ
å äœã®Vpoåã³ïŒ¥1/2ãè¡šïŒã«ç€ºãã
ãã©ã³98éééšãããŒã«ãã«äžã§ç²ç æ··åããåŸ
ãããåæ£æ¶²ããã¢ã«ãããŠã èžçããªãšã¹ãã«
ãã€ã«ã äžã«ãã¯ã¿ãŒãã¬ãŒãã§å¡åžããèªç¶ä¹Ÿ
ç¥ããŠåãïŒÎŒã®é»è·æ äœçºçå±€ã圢æããã
ããäžæ¹ãïŒïŒïŒïŒïŒâããªãããâïŒâãã«ãª
ã¬ãã³ïŒéééšãããªã«ãŒãããŒãã(æ ª)ãã€ãžã³
補ããã³ã©ã€ããïŒéééšåã³ããã©ãããã
ã©ã³46éééšãæ··åããŠåæ£æ¶²ãšãããããåèš
é»è·æ äœçºçå±€äžã«ãã¯ã¿ãŒãã¬ãŒãã§å¡åžãã
100âã§10åé也ç¥ããŠåã10ÎŒã®é»è·ç§»ååªäœ
å±€ã圢æãããã第ïŒå³ã®åœ¢æ ã®æå äœãåŸãã
äžèšã®ããã«ããŠåŸãæå äœã«ã€ããŠãå®æœäŸïŒ
ãšåæã«æž¬å®ããVpoã¯900ãã«ãã1/2ã¯10
ã«ãã¯ã¹ã»ç§ã®çµæãåŸãã å®æœäŸ 42ã50 å®æœäŸ41ã«ãããŠNo.ïŒã®ãžã¹ã¢ãŸé¡æã®ä»£ãã«
äžèšè¡šïŒã®ãžã¹ã¢ãŸé¡æã倫ã çšããä»ã¯åãæ¹
æ³ã§ç¬¬ïŒå³ã®åœ¢æ ã®æå äœãäœæããããããæ
å äœã®Vpoåã³ïŒ¥1/2ãè¡šïŒã«ç€ºãã
ãè¡šã
å®æœäŸ 51
No.ïŒã®ãžã¹ã¢ãŸé¡æïŒéééšåã³ããã©ããã
ãã©ã³98éééšãããŒã«ãã«äžã§ç²ç æ··åããåŸ
ãããåæ£æ¶²ãã¢ã«ãããŠã èžçããªãšã¹ãã«ã
ã€ã«ã äžã«ãã¯ã¿ãŒãã¬ãŒãã§å¡åžãèªç¶ä¹Ÿç¥ã
ãŠåãïŒÎŒã®é»è·æ äœçºçå±€ã圢æãããäžæ¹ã
ïŒâïŒïŒâãžãšãã«ã¢ããã¹ããªã«ïŒã¢ã³ãã©ã»
ã³ïŒéééšãããªã«ãŒãããŒãïŒå®æœäŸ41ã«å
ãïŒïŒéééšåã³ããã©ããããã©ã³46éééšã
æ··åããŠæº¶è§£ãããããåèšé»è·æ äœçºçå±€äžã«
ãã¯ã¿ãŒãã¬ãŒãã§å¡åžãã120âã§10åé也ç¥
ããŠåã10ÎŒã®é»è·ç§»ååªäœå±€ã圢æãããã第
ïŒå³ã®ç©å±€åæå äœãåŸããäžèšã®ããã«ããŠåŸ
ãæå äœã«ã€ããŠâ6KVã®ã³ããæŸé»ãè¡ãªã€ã
以å€ã¯å®æœäŸïŒãšåæ§ã«æž¬å®ãè¡ãããã®ãã®ã®
Vpoã¯1100ãã«ãã1/210ã«ãã¯ã¹ã»ç§ã®çµæ
ãåŸãã å®æœäŸ 52ã60 å®æœäŸ51ã«ãããŠNo.ïŒã®ãžã¹ã¢ãŸé¡æã®ä»£ãã«
äžèšè¡šïŒã®ãžã¹ã¢ãŸé¡æã倫ã çšããŠåæ§ãªæå
äœãäœæããããããæå äœã®Vpoåã³ïŒ¥1/2ã¯
è¡šïŒã®éãã§ããã
ãã©ã³98éééšãããŒã«ãã«äžã§ç²ç æ··åããåŸ
ãããåæ£æ¶²ãã¢ã«ãããŠã èžçããªãšã¹ãã«ã
ã€ã«ã äžã«ãã¯ã¿ãŒãã¬ãŒãã§å¡åžãèªç¶ä¹Ÿç¥ã
ãŠåãïŒÎŒã®é»è·æ äœçºçå±€ã圢æãããäžæ¹ã
ïŒâïŒïŒâãžãšãã«ã¢ããã¹ããªã«ïŒã¢ã³ãã©ã»
ã³ïŒéééšãããªã«ãŒãããŒãïŒå®æœäŸ41ã«å
ãïŒïŒéééšåã³ããã©ããããã©ã³46éééšã
æ··åããŠæº¶è§£ãããããåèšé»è·æ äœçºçå±€äžã«
ãã¯ã¿ãŒãã¬ãŒãã§å¡åžãã120âã§10åé也ç¥
ããŠåã10ÎŒã®é»è·ç§»ååªäœå±€ã圢æãããã第
ïŒå³ã®ç©å±€åæå äœãåŸããäžèšã®ããã«ããŠåŸ
ãæå äœã«ã€ããŠâ6KVã®ã³ããæŸé»ãè¡ãªã€ã
以å€ã¯å®æœäŸïŒãšåæ§ã«æž¬å®ãè¡ãããã®ãã®ã®
Vpoã¯1100ãã«ãã1/210ã«ãã¯ã¹ã»ç§ã®çµæ
ãåŸãã å®æœäŸ 52ã60 å®æœäŸ51ã«ãããŠNo.ïŒã®ãžã¹ã¢ãŸé¡æã®ä»£ãã«
äžèšè¡šïŒã®ãžã¹ã¢ãŸé¡æã倫ã çšããŠåæ§ãªæå
äœãäœæããããããæå äœã®Vpoåã³ïŒ¥1/2ã¯
è¡šïŒã®éãã§ããã
ãè¡šã
å®æœäŸ 61ã72
äžèšè¡šïŒã«ç€ºããžã¹ã¢ãŸé¡æ76éééšãããªãš
ã¹ãã«æš¹èãæ±æŽçŽ¡çžŸ(æ ª)補ãã€ãã³200ãã®ïŒïŒ
ããã©ããããã©ã³æº¶æ¶²1260éééšåã³ããã©ã
ãããã©ã³3700éééšãããŒã«ãã«ã§å åç²ç æ··
åããåŸãããåæ£æ¶²ãã¢ã«ãããŠã èžçããã
ãªãšã¹ãã«ãã€ã«ã äžã«35ÎŒïœã®ãŠãšããã®ã€ã
ãã§ãã¯ã¿ãŒãã¬ãŒããçšããŠå¡åžããèªç¶ä¹Ÿç¥
ããŠåãçŽïŒÎŒïœã®é»è·æ äœçºçå±€ã圢æããã
次ã«ãã®é»è·æ äœçºçå±€äžã«ãäžèšè¡šïŒã«ç€ºãé»
è·ç§»åç©è³ª10éééšãããªã«ãŒãããŒããåžäººå
æ(æ ª)補ãã³ã©ã€ãâ1300ã10éééšåã³ããã©
ããããã©ã³80éééšãããªã溶液ããŠãšããã®
ã€ãã200ÎŒïœã§ãã¯ã¿ãŒãã¬ãŒããçšããŠå¡åž
ãã80âã§ïŒåéã次ã«100âã§ïŒåé也ç¥ããŠ
åãçŽ20ÎŒïœã®é»è·ç§»ååªäœå±€ã圢æããŠç¬¬ïŒå³
ã®åœ¢æ ã®æå äœãäœæããã 次ã«ããããŠåŸãããæå äœã«ã€ããŠãæŽã«é²
å é1/10ïŒã«ãã¯ã¹ã»ç§ïŒãšããŠè¡šé¢é»äœã
ïŒïŒ10ã«æžè¡°ããã«èŠããæéãæ±ããä»ã®å®æœ
äŸ51ãšåæ§ãªæž¬å®ãè¡ãªããè¡šïŒã«ç€ºãçµæãåŸ
ãã
ã¹ãã«æš¹èãæ±æŽçŽ¡çžŸ(æ ª)補ãã€ãã³200ãã®ïŒïŒ
ããã©ããããã©ã³æº¶æ¶²1260éééšåã³ããã©ã
ãããã©ã³3700éééšãããŒã«ãã«ã§å åç²ç æ··
åããåŸãããåæ£æ¶²ãã¢ã«ãããŠã èžçããã
ãªãšã¹ãã«ãã€ã«ã äžã«35ÎŒïœã®ãŠãšããã®ã€ã
ãã§ãã¯ã¿ãŒãã¬ãŒããçšããŠå¡åžããèªç¶ä¹Ÿç¥
ããŠåãçŽïŒÎŒïœã®é»è·æ äœçºçå±€ã圢æããã
次ã«ãã®é»è·æ äœçºçå±€äžã«ãäžèšè¡šïŒã«ç€ºãé»
è·ç§»åç©è³ª10éééšãããªã«ãŒãããŒããåžäººå
æ(æ ª)補ãã³ã©ã€ãâ1300ã10éééšåã³ããã©
ããããã©ã³80éééšãããªã溶液ããŠãšããã®
ã€ãã200ÎŒïœã§ãã¯ã¿ãŒãã¬ãŒããçšããŠå¡åž
ãã80âã§ïŒåéã次ã«100âã§ïŒåé也ç¥ããŠ
åãçŽ20ÎŒïœã®é»è·ç§»ååªäœå±€ã圢æããŠç¬¬ïŒå³
ã®åœ¢æ ã®æå äœãäœæããã 次ã«ããããŠåŸãããæå äœã«ã€ããŠãæŽã«é²
å é1/10ïŒã«ãã¯ã¹ã»ç§ïŒãšããŠè¡šé¢é»äœã
ïŒïŒ10ã«æžè¡°ããã«èŠããæéãæ±ããä»ã®å®æœ
äŸ51ãšåæ§ãªæž¬å®ãè¡ãªããè¡šïŒã«ç€ºãçµæãåŸ
ãã
ãè¡šã
第ïŒãïŒå³ã¯å€«ã
äžäŸã®æ¬çºææå
äœã®æ¡å€§æ
é¢å³ã第ïŒå³ã¯No.ïŒã®èµ€å€ç·åžåã¹ãã¯ãã«ã§ã
ãã ïŒâŠå°é»æ§æ¯æäœãïŒïŒïŒâ²ïŒïŒâ³ïŒïŒâŠæå
å±€ãïŒâŠçµçå€ãïŒâŠãžã¹ã¢ãŸé¡æãïŒâŠé»è·ç§»
ååªäœãïŒâŠé»è·æ äœçºçå±€ãïŒâŠé»è·ç§»ååªäœ
å±€ã
é¢å³ã第ïŒå³ã¯No.ïŒã®èµ€å€ç·åžåã¹ãã¯ãã«ã§ã
ãã ïŒâŠå°é»æ§æ¯æäœãïŒïŒïŒâ²ïŒïŒâ³ïŒïŒâŠæå
å±€ãïŒâŠçµçå€ãïŒâŠãžã¹ã¢ãŸé¡æãïŒâŠé»è·ç§»
ååªäœãïŒâŠé»è·æ äœçºçå±€ãïŒâŠé»è·ç§»ååªäœ
å±€ã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ å°é»æ§æ¯æäœäžã«ãäžèšäžè¬åŒ ïŒäœãåŒäžArã¯çœ®æåã¯é眮æã®ããšãã«
åºã眮æåã¯é眮æã®ãããã«åºãã¢ã³ããªã«
åºããã¬ãã«åºãããªãžã«åºãããšãã«åºãããª
ã«åºåã³ã«ã«ããŸãªã«åºãè¡šãããïŒ ã§ç€ºããããžã¹ã¢ãŸé¡æãæå¹æåãšããŠå«æã
ãæå å±€ãæããããšãç¹åŸŽãšããé»ååççšæ
å äœã
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP17045879A JPS5694360A (en) | 1979-12-28 | 1979-12-28 | Electrophotographic receptor |
US06/217,305 US4327168A (en) | 1979-12-28 | 1980-12-17 | Electrophotographic element containing disazo pigment charge generating material |
DE19803049184 DE3049184A1 (de) | 1979-12-28 | 1980-12-24 | Elektrophotographisches element |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP17045879A JPS5694360A (en) | 1979-12-28 | 1979-12-28 | Electrophotographic receptor |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5694360A JPS5694360A (en) | 1981-07-30 |
JPS6219745B2 true JPS6219745B2 (ja) | 1987-04-30 |
Family
ID=15905304
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP17045879A Granted JPS5694360A (en) | 1979-12-28 | 1979-12-28 | Electrophotographic receptor |
Country Status (3)
Country | Link |
---|---|
US (1) | US4327168A (ja) |
JP (1) | JPS5694360A (ja) |
DE (1) | DE3049184A1 (ja) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4390608A (en) * | 1980-12-09 | 1983-06-28 | Ricoh Company, Ltd. | Layered charge generator/transport electrophotographic photoconductor uses bisazo pigment |
US4481271A (en) * | 1980-12-15 | 1984-11-06 | Ricoh Company, Ltd. | Layered electrophotographic photoconductor containing a hydrazone |
JPS58200242A (ja) * | 1982-05-19 | 1983-11-21 | Canon Inc | é»ååçæå äœ |
US4576886A (en) * | 1984-02-13 | 1986-03-18 | Konishiroku Photo Industry Co., Ltd. | Azo photoreceptor |
DE3582702D1 (de) * | 1984-06-15 | 1991-06-06 | Ciba Geigy Ag | Neue metallkomplexe, verfahren zu ihrer herstellung ihre verwendung zum faerben von hochmolekularem organischem material. |
JPS6148859A (ja) * | 1984-08-17 | 1986-03-10 | Konishiroku Photo Ind Co Ltd | æ£åž¯é»çšæå äœ |
JPS6156351A (ja) * | 1984-08-28 | 1986-03-22 | Konishiroku Photo Ind Co Ltd | æå äœ |
US4713307A (en) * | 1986-04-11 | 1987-12-15 | Xerox Corporation | Organic azo photoconductor imaging members |
US4797337A (en) * | 1987-07-27 | 1989-01-10 | Xerox Corporation | Disazo photoconductive imaging members |
EP0447078B1 (en) * | 1990-03-12 | 1994-09-28 | Thomson Consumer Electronics, Inc. | Method of electrophotographically manufacturing a luminescent screen assembly for a CRT |
US5413885A (en) * | 1993-12-22 | 1995-05-09 | Rca Thompson Licensing Corp. | Organic photoconductor for an electrophotographic screening process for a CRT |
JP3563916B2 (ja) * | 1996-04-26 | 2004-09-08 | ãã€ãã³æ ªåŒäŒç€Ÿ | é»ååçæå äœããã®é»ååçæå äœãçšããé»ååçè£ çœ®åã³ããã»ã¹ã«ãŒããªããž |
US6174637B1 (en) | 2000-01-19 | 2001-01-16 | Xerox Corporation | Electrophotographic imaging member and process of making |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4272598A (en) * | 1977-04-27 | 1981-06-09 | Ricoh Co., Ltd. | Electrophotographic material containing disazo compounds |
JPS6027017B2 (ja) * | 1977-07-08 | 1985-06-26 | æ ªåŒäŒç€Ÿãªã³ãŒ | é»ååççšæå äœ |
US4299896A (en) * | 1977-07-18 | 1981-11-10 | Ricoh Co., Ltd. | Electrophotographic sensitive materials containing a disazo pigment |
-
1979
- 1979-12-28 JP JP17045879A patent/JPS5694360A/ja active Granted
-
1980
- 1980-12-17 US US06/217,305 patent/US4327168A/en not_active Expired - Lifetime
- 1980-12-24 DE DE19803049184 patent/DE3049184A1/de active Granted
Also Published As
Publication number | Publication date |
---|---|
DE3049184A1 (de) | 1981-09-10 |
DE3049184C2 (ja) | 1989-11-02 |
US4327168A (en) | 1982-04-27 |
JPS5694360A (en) | 1981-07-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4260672A (en) | Electrophotographic sensitive element having a photoconductive disazo pigment | |
JPS6027014B2 (ja) | é»ååççšæå äœ | |
JPH0690523B2 (ja) | æå äœ | |
JPS6027018B2 (ja) | é»ååççšæå äœ | |
JPS6219745B2 (ja) | ||
JPS6027016B2 (ja) | é»ååçæå äœ | |
JPS6129498B2 (ja) | ||
JPS6129499B2 (ja) | ||
JPS6243175B2 (ja) | ||
JPH065389B2 (ja) | é»ååççšæå äœ | |
JPH0452459B2 (ja) | ||
JPS6029108B2 (ja) | é»ååççšæå äœ | |
JPS6219736B2 (ja) | ||
JPS6219743B2 (ja) | ||
JPS6219744B2 (ja) | ||
JP2611209B2 (ja) | æå äœ | |
JPS6122300B2 (ja) | ||
JPS6029107B2 (ja) | é»ååççšæå äœ | |
JPH0435068B2 (ja) | ||
JPS6219738B2 (ja) | ||
JPS6122301B2 (ja) | ||
JPS6219746B2 (ja) | ||
JPS6219742B2 (ja) | ||
JP2808329B2 (ja) | é»ååççšæå äœ | |
JPH0260173B2 (ja) |