JPS62177063A - エピクロルヒドリン−プロピレンオキサイド系ゴム組成物 - Google Patents
エピクロルヒドリン−プロピレンオキサイド系ゴム組成物Info
- Publication number
- JPS62177063A JPS62177063A JP1903886A JP1903886A JPS62177063A JP S62177063 A JPS62177063 A JP S62177063A JP 1903886 A JP1903886 A JP 1903886A JP 1903886 A JP1903886 A JP 1903886A JP S62177063 A JPS62177063 A JP S62177063A
- Authority
- JP
- Japan
- Prior art keywords
- rubber
- mol
- epichlorohydrin
- weight
- propylene oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 46
- 239000005060 rubber Substances 0.000 title claims abstract description 46
- 239000000203 mixture Substances 0.000 title claims abstract description 38
- 229920001577 copolymer Polymers 0.000 claims abstract description 27
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 9
- 150000003377 silicon compounds Chemical class 0.000 claims abstract description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 7
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 125000000623 heterocyclic group Chemical group 0.000 claims abstract description 5
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000378 calcium silicate Substances 0.000 claims abstract description 4
- 229910052918 calcium silicate Inorganic materials 0.000 claims abstract description 4
- 235000012241 calcium silicate Nutrition 0.000 claims abstract description 4
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims abstract description 4
- FSBVERYRVPGNGG-UHFFFAOYSA-N dimagnesium dioxido-bis[[oxido(oxo)silyl]oxy]silane hydrate Chemical compound O.[Mg+2].[Mg+2].[O-][Si](=O)O[Si]([O-])([O-])O[Si]([O-])=O FSBVERYRVPGNGG-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000391 magnesium silicate Substances 0.000 claims abstract description 4
- 229910052919 magnesium silicate Inorganic materials 0.000 claims abstract description 4
- 235000019792 magnesium silicate Nutrition 0.000 claims abstract description 4
- 229920006295 polythiol Polymers 0.000 claims abstract description 4
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 8
- 239000000470 constituent Substances 0.000 claims description 5
- 230000032683 aging Effects 0.000 abstract description 12
- 238000002156 mixing Methods 0.000 abstract description 10
- 239000006087 Silane Coupling Agent Substances 0.000 abstract description 6
- 230000000704 physical effect Effects 0.000 abstract description 3
- XUNLTYLWCMUZFO-UHFFFAOYSA-N 1,4-dihydropyrazine-2,3-dithione Chemical compound S=C1NC=CNC1=S XUNLTYLWCMUZFO-UHFFFAOYSA-N 0.000 abstract 1
- 239000011243 crosslinked material Substances 0.000 abstract 1
- 241000238557 Decapoda Species 0.000 description 7
- 238000004132 cross linking Methods 0.000 description 7
- 230000007423 decrease Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000006229 carbon black Substances 0.000 description 4
- 229920001897 terpolymer Polymers 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000012744 reinforcing agent Substances 0.000 description 3
- WZRRRFSJFQTGGB-UHFFFAOYSA-N 1,3,5-triazinane-2,4,6-trithione Chemical compound S=C1NC(=S)NC(=S)N1 WZRRRFSJFQTGGB-UHFFFAOYSA-N 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000000370 acceptor Substances 0.000 description 2
- 230000003712 anti-aging effect Effects 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 239000001095 magnesium carbonate Substances 0.000 description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- BIGYLAKFCGVRAN-UHFFFAOYSA-N 1,3,4-thiadiazolidine-2,5-dithione Chemical compound S=C1NNC(=S)S1 BIGYLAKFCGVRAN-UHFFFAOYSA-N 0.000 description 1
- OHTWYWBEOQAXEQ-UHFFFAOYSA-N 1-phenyl-1,2,4-triazolidine-3,5-dithione Chemical compound N1=C(S)N=C(S)N1C1=CC=CC=C1 OHTWYWBEOQAXEQ-UHFFFAOYSA-N 0.000 description 1
- XSQHUYDRSDBCHN-UHFFFAOYSA-N 2,3-dimethyl-2-propan-2-ylbutanenitrile Chemical compound CC(C)C(C)(C#N)C(C)C XSQHUYDRSDBCHN-UHFFFAOYSA-N 0.000 description 1
- NLEGOBBGDOATPO-UHFFFAOYSA-N 5,5-dimethylimidazolidine-2,4-dithione Chemical compound CC1(C)NC(=S)NC1=S NLEGOBBGDOATPO-UHFFFAOYSA-N 0.000 description 1
- 239000004135 Bone phosphate Substances 0.000 description 1
- PDQAZBWRQCGBEV-UHFFFAOYSA-N Ethylenethiourea Chemical compound S=C1NCCN1 PDQAZBWRQCGBEV-UHFFFAOYSA-N 0.000 description 1
- 229910000003 Lead carbonate Inorganic materials 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910000004 White lead Inorganic materials 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
- 229910001863 barium hydroxide Inorganic materials 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 235000012255 calcium oxide Nutrition 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- PYSZASIZWHHPHJ-UHFFFAOYSA-L calcium;phthalate Chemical compound [Ca+2].[O-]C(=O)C1=CC=CC=C1C([O-])=O PYSZASIZWHHPHJ-UHFFFAOYSA-L 0.000 description 1
- XENVCRGQTABGKY-ZHACJKMWSA-N chlorohydrin Chemical compound CC#CC#CC#CC#C\C=C\C(Cl)CO XENVCRGQTABGKY-ZHACJKMWSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 229920005561 epichlorohydrin homopolymer Polymers 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 description 1
- OCWMFVJKFWXKNZ-UHFFFAOYSA-L lead(2+);oxygen(2-);sulfate Chemical compound [O-2].[O-2].[O-2].[Pb+2].[Pb+2].[Pb+2].[Pb+2].[O-]S([O-])(=O)=O OCWMFVJKFWXKNZ-UHFFFAOYSA-L 0.000 description 1
- YJOMWQQKPKLUBO-UHFFFAOYSA-L lead(2+);phthalate Chemical compound [Pb+2].[O-]C(=O)C1=CC=CC=C1C([O-])=O YJOMWQQKPKLUBO-UHFFFAOYSA-L 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N lead(II) oxide Inorganic materials [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- JFOJYGMDZRCSPA-UHFFFAOYSA-J octadecanoate;tin(4+) Chemical compound [Sn+4].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O JFOJYGMDZRCSPA-UHFFFAOYSA-J 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 150000003216 pyrazines Chemical class 0.000 description 1
- 125000001567 quinoxalinyl group Chemical class N1=C(C=NC2=CC=CC=C12)* 0.000 description 1
- 238000010057 rubber processing Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- NZMOFYDMGFQZLS-UHFFFAOYSA-N terazosin hydrochloride dihydrate Chemical compound [H+].O.O.[Cl-].N=1C(N)=C2C=C(OC)C(OC)=CC2=NC=1N(CC1)CCN1C(=O)C1CCCO1 NZMOFYDMGFQZLS-UHFFFAOYSA-N 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- XWKBMOUUGHARTI-UHFFFAOYSA-N tricalcium;diphosphite Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])[O-].[O-]P([O-])[O-] XWKBMOUUGHARTI-UHFFFAOYSA-N 0.000 description 1
- VMFOHNMEJNFJAE-UHFFFAOYSA-N trimagnesium;diphosphite Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])[O-].[O-]P([O-])[O-] VMFOHNMEJNFJAE-UHFFFAOYSA-N 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1903886A JPS62177063A (ja) | 1986-01-29 | 1986-01-29 | エピクロルヒドリン−プロピレンオキサイド系ゴム組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1903886A JPS62177063A (ja) | 1986-01-29 | 1986-01-29 | エピクロルヒドリン−プロピレンオキサイド系ゴム組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62177063A true JPS62177063A (ja) | 1987-08-03 |
| JPH0562147B2 JPH0562147B2 (enrdf_load_stackoverflow) | 1993-09-07 |
Family
ID=11988262
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1903886A Granted JPS62177063A (ja) | 1986-01-29 | 1986-01-29 | エピクロルヒドリン−プロピレンオキサイド系ゴム組成物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62177063A (enrdf_load_stackoverflow) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000302921A (ja) * | 1999-04-23 | 2000-10-31 | Sumitomo Rubber Ind Ltd | 導電性ゴム組成物及びこれを用いた導電性ベルト |
| WO2002046309A1 (fr) * | 2000-12-08 | 2002-06-13 | Zeon Corporation | Composition de caoutchouc halogene et caoutchouc vulcanise ainsi obtenu |
| TWI587188B (zh) * | 2013-01-10 | 2017-06-11 | Nissha Printing | Film-like pressure sensing sensor with adhesive layer and touch pad with the sensor, protective panel with touch input function and electronic machine |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54135843A (en) * | 1978-04-13 | 1979-10-22 | Nippon Zeon Co Ltd | Adherent rubber composition |
| JPS56109246A (en) * | 1980-02-04 | 1981-08-29 | Osaka Soda Co Ltd | Elastomer composition having excellent permanent compression set resistance |
| JPS5832653A (ja) * | 1981-08-20 | 1983-02-25 | Osaka Soda Co Ltd | 優れた耐酸敗ガソリン性を有する加硫用ゴム組成物 |
-
1986
- 1986-01-29 JP JP1903886A patent/JPS62177063A/ja active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54135843A (en) * | 1978-04-13 | 1979-10-22 | Nippon Zeon Co Ltd | Adherent rubber composition |
| JPS56109246A (en) * | 1980-02-04 | 1981-08-29 | Osaka Soda Co Ltd | Elastomer composition having excellent permanent compression set resistance |
| JPS5832653A (ja) * | 1981-08-20 | 1983-02-25 | Osaka Soda Co Ltd | 優れた耐酸敗ガソリン性を有する加硫用ゴム組成物 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000302921A (ja) * | 1999-04-23 | 2000-10-31 | Sumitomo Rubber Ind Ltd | 導電性ゴム組成物及びこれを用いた導電性ベルト |
| WO2002046309A1 (fr) * | 2000-12-08 | 2002-06-13 | Zeon Corporation | Composition de caoutchouc halogene et caoutchouc vulcanise ainsi obtenu |
| TWI587188B (zh) * | 2013-01-10 | 2017-06-11 | Nissha Printing | Film-like pressure sensing sensor with adhesive layer and touch pad with the sensor, protective panel with touch input function and electronic machine |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0562147B2 (enrdf_load_stackoverflow) | 1993-09-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3988287A (en) | Polyamide compositions | |
| JPH0424388B2 (enrdf_load_stackoverflow) | ||
| US5504141A (en) | Polyphenylene sulphide-based compositions with improved impact strength and process for preparing them | |
| JPS62177063A (ja) | エピクロルヒドリン−プロピレンオキサイド系ゴム組成物 | |
| JPS5891764A (ja) | ハロゲン含有ポリマ−の架橋 | |
| JPS61266458A (ja) | エピクロルヒドリン系ゴム組成物 | |
| JPS62227950A (ja) | エピクロルヒドリン系ゴム組成物 | |
| JP3170982B2 (ja) | エピクロルヒドリン系ポリマー加硫用組成物 | |
| JP2899929B2 (ja) | ゴム組成物 | |
| JP4154781B2 (ja) | 半導電性ゴム材料 | |
| KR100320642B1 (ko) | 가황성에피클로로히드린중합체조성물 | |
| US4268640A (en) | Curable composition of halogen-containing polymer | |
| JP3225728B2 (ja) | ブレンドゴム加硫用組成物 | |
| JPS61207458A (ja) | 耐衝撃性ポリエステル樹脂組成物 | |
| JP3235335B2 (ja) | エピクロルヒドリン系ポリマー加硫用組成物 | |
| JPS61179240A (ja) | ハロゲン含有ポリマ−の架橋方法 | |
| JP2005154686A (ja) | エピハロヒドリンゴム組成物 | |
| KR20230073597A (ko) | 가황성 염소화 폴리에틸렌 조성물 및 이로부터 제조된 가황물 | |
| JPH0641425A (ja) | ポリフェニレンスルフィド樹脂組成物 | |
| KR950006264B1 (ko) | 냉장고 도어의 가스킷용 폴리염화비닐수지조성물과 그의 제조방법 | |
| JPH1017852A (ja) | ２液型ポリサルファイド系シーリング材組成物 | |
| KR900003918B1 (ko) | 난연성 폴리에스테르-에테르블록공중합체 수지조성물 | |
| JPS63312334A (ja) | クロロスルホン化ポリエチレンエラストマ−組成物 | |
| JP3649304B2 (ja) | 耐熱性ポリエステルエラストマー組成物 | |
| JPH07145277A (ja) | 流動性改良剤 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |