JPS6173755A - 熱可塑性樹脂組成物 - Google Patents
熱可塑性樹脂組成物Info
- Publication number
- JPS6173755A JPS6173755A JP19558384A JP19558384A JPS6173755A JP S6173755 A JPS6173755 A JP S6173755A JP 19558384 A JP19558384 A JP 19558384A JP 19558384 A JP19558384 A JP 19558384A JP S6173755 A JPS6173755 A JP S6173755A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- polymer
- maleimide
- copolymer
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920005992 thermoplastic resin Polymers 0.000 title claims description 4
- 239000011342 resin composition Substances 0.000 title claims description 3
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 15
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 10
- 229920001971 elastomer Polymers 0.000 claims abstract description 9
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 claims abstract description 8
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 4
- -1 aromatic vinyl compound Chemical class 0.000 claims description 24
- 229920001577 copolymer Polymers 0.000 abstract description 27
- 239000000203 mixture Substances 0.000 abstract description 21
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 12
- 229920000642 polymer Polymers 0.000 abstract description 8
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract description 6
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 abstract description 5
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract description 4
- 239000002245 particle Substances 0.000 abstract description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract description 3
- 239000000306 component Substances 0.000 abstract 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 8
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 3
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 3
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 3
- 238000012662 bulk polymerization Methods 0.000 description 3
- 239000004816 latex Substances 0.000 description 3
- 229920000126 latex Polymers 0.000 description 3
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000010558 suspension polymerization method Methods 0.000 description 3
- 229920006032 ungrafted co-polymer Polymers 0.000 description 3
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- 238000010559 graft polymerization reaction Methods 0.000 description 2
- 239000002655 kraft paper Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 150000003440 styrenes Chemical class 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 1
- KYPOHTVBFVELTG-OWOJBTEDSA-N (e)-but-2-enedinitrile Chemical compound N#C\C=C\C#N KYPOHTVBFVELTG-OWOJBTEDSA-N 0.000 description 1
- KYPOHTVBFVELTG-UPHRSURJSA-N (z)-but-2-enedinitrile Chemical compound N#C\C=C/C#N KYPOHTVBFVELTG-UPHRSURJSA-N 0.000 description 1
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- WADCPEMKIBAJHH-UHFFFAOYSA-N 3,4-diphenylpyrrole-2,5-dione Chemical compound O=C1NC(=O)C(C=2C=CC=CC=2)=C1C1=CC=CC=C1 WADCPEMKIBAJHH-UHFFFAOYSA-N 0.000 description 1
- KUKHGIHFGSRZCM-UHFFFAOYSA-N 3-chloro-4-phenylpyrrole-2,5-dione Chemical compound O=C1NC(=O)C(Cl)=C1C1=CC=CC=C1 KUKHGIHFGSRZCM-UHFFFAOYSA-N 0.000 description 1
- ZLPORNPZJNRGCO-UHFFFAOYSA-N 3-methylpyrrole-2,5-dione Chemical compound CC1=CC(=O)NC1=O ZLPORNPZJNRGCO-UHFFFAOYSA-N 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- HDFGOPSGAURCEO-UHFFFAOYSA-N N-ethylmaleimide Chemical compound CCN1C(=O)C=CC1=O HDFGOPSGAURCEO-UHFFFAOYSA-N 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 238000005185 salting out Methods 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19558384A JPS6173755A (ja) | 1984-09-18 | 1984-09-18 | 熱可塑性樹脂組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19558384A JPS6173755A (ja) | 1984-09-18 | 1984-09-18 | 熱可塑性樹脂組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6173755A true JPS6173755A (ja) | 1986-04-15 |
| JPH0430982B2 JPH0430982B2 (enrdf_load_stackoverflow) | 1992-05-25 |
Family
ID=16343549
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19558384A Granted JPS6173755A (ja) | 1984-09-18 | 1984-09-18 | 熱可塑性樹脂組成物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6173755A (enrdf_load_stackoverflow) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62138510A (ja) * | 1985-12-11 | 1987-06-22 | Japan Synthetic Rubber Co Ltd | 共重合体の製造方法 |
| JPS62267350A (ja) * | 1986-05-14 | 1987-11-20 | Sumitomo Naugatuck Co Ltd | 外観および耐熱性に優れる成形用樹脂組成物 |
| JPS63122746A (ja) * | 1986-11-12 | 1988-05-26 | Sumitomo Naugatuck Co Ltd | 耐熱性共重合体組成物 |
| JPS63135441A (ja) * | 1986-11-27 | 1988-06-07 | Idemitsu Petrochem Co Ltd | 熱可塑性樹脂組成物 |
| JPH02138321A (ja) * | 1988-08-15 | 1990-05-28 | Mitsubishi Rayon Co Ltd | マレイミド系共重合体及びその製造方法 |
| JPH04120157A (ja) * | 1990-09-12 | 1992-04-21 | Asahi Chem Ind Co Ltd | 耐熱性に優れたブロー成形用樹脂組成物 |
| US5140067A (en) * | 1988-10-31 | 1992-08-18 | Mitsubishi Rayon Company Limited | Heat resistant and impact resistant resin composition |
| EP0721962A3 (en) * | 1995-01-13 | 1997-06-18 | Japan Synthetic Rubber Co Ltd | Rubber-modified thermoplastic resin and composition containing it |
| JP2001329026A (ja) * | 2000-05-23 | 2001-11-27 | Denki Kagaku Kogyo Kk | 高流動性マレイミド系共重合体 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS604544A (ja) * | 1983-06-24 | 1985-01-11 | Toray Ind Inc | 熱可塑性樹脂組成物 |
| JPS60135453A (ja) * | 1983-12-22 | 1985-07-18 | Mitsubishi Monsanto Chem Co | 熱可塑性樹脂組成物 |
| JPS6116955A (ja) * | 1984-07-03 | 1986-01-24 | Mitsubishi Monsanto Chem Co | 耐熱性耐衝撃性樹脂組成物 |
-
1984
- 1984-09-18 JP JP19558384A patent/JPS6173755A/ja active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS604544A (ja) * | 1983-06-24 | 1985-01-11 | Toray Ind Inc | 熱可塑性樹脂組成物 |
| JPS60135453A (ja) * | 1983-12-22 | 1985-07-18 | Mitsubishi Monsanto Chem Co | 熱可塑性樹脂組成物 |
| JPS6116955A (ja) * | 1984-07-03 | 1986-01-24 | Mitsubishi Monsanto Chem Co | 耐熱性耐衝撃性樹脂組成物 |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62138510A (ja) * | 1985-12-11 | 1987-06-22 | Japan Synthetic Rubber Co Ltd | 共重合体の製造方法 |
| JPS62267350A (ja) * | 1986-05-14 | 1987-11-20 | Sumitomo Naugatuck Co Ltd | 外観および耐熱性に優れる成形用樹脂組成物 |
| JPS63122746A (ja) * | 1986-11-12 | 1988-05-26 | Sumitomo Naugatuck Co Ltd | 耐熱性共重合体組成物 |
| JPS63135441A (ja) * | 1986-11-27 | 1988-06-07 | Idemitsu Petrochem Co Ltd | 熱可塑性樹脂組成物 |
| JPH02138321A (ja) * | 1988-08-15 | 1990-05-28 | Mitsubishi Rayon Co Ltd | マレイミド系共重合体及びその製造方法 |
| US5140067A (en) * | 1988-10-31 | 1992-08-18 | Mitsubishi Rayon Company Limited | Heat resistant and impact resistant resin composition |
| JPH04120157A (ja) * | 1990-09-12 | 1992-04-21 | Asahi Chem Ind Co Ltd | 耐熱性に優れたブロー成形用樹脂組成物 |
| EP0721962A3 (en) * | 1995-01-13 | 1997-06-18 | Japan Synthetic Rubber Co Ltd | Rubber-modified thermoplastic resin and composition containing it |
| JP2001329026A (ja) * | 2000-05-23 | 2001-11-27 | Denki Kagaku Kogyo Kk | 高流動性マレイミド系共重合体 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0430982B2 (enrdf_load_stackoverflow) | 1992-05-25 |
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