JPS6153384B2 - - Google Patents
Info
- Publication number
- JPS6153384B2 JPS6153384B2 JP56085662A JP8566281A JPS6153384B2 JP S6153384 B2 JPS6153384 B2 JP S6153384B2 JP 56085662 A JP56085662 A JP 56085662A JP 8566281 A JP8566281 A JP 8566281A JP S6153384 B2 JPS6153384 B2 JP S6153384B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- thermoplastic resin
- titanium oxide
- antioxidant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920005992 thermoplastic resin Polymers 0.000 claims description 29
- 239000003963 antioxidant agent Substances 0.000 claims description 26
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 26
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 25
- 230000003078 antioxidant effect Effects 0.000 claims description 18
- 239000002530 phenolic antioxidant Substances 0.000 claims description 18
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 13
- 239000011574 phosphorus Substances 0.000 claims description 13
- 229910052698 phosphorus Inorganic materials 0.000 claims description 13
- 239000011342 resin composition Substances 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- -1 polypropylene Polymers 0.000 claims description 10
- 125000001424 substituent group Chemical group 0.000 claims description 10
- 150000003568 thioethers Chemical class 0.000 claims description 9
- 239000004743 Polypropylene Substances 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 5
- 229920000098 polyolefin Polymers 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 2
- 239000003112 inhibitor Substances 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims 1
- 238000004383 yellowing Methods 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 8
- 238000002156 mixing Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 4
- 239000008116 calcium stearate Substances 0.000 description 4
- 235000013539 calcium stearate Nutrition 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000011256 inorganic filler Substances 0.000 description 3
- 229910003475 inorganic filler Inorganic materials 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 238000013112 stability test Methods 0.000 description 3
- 229920002292 Nylon 6 Polymers 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- ONNZMLQGCCXZIS-UHFFFAOYSA-N 2-methyl-2-tetradecylhexadecanethioic S-acid Chemical compound CCCCCCCCCCCCCCC(C)(C(S)=O)CCCCCCCCCCCCCC ONNZMLQGCCXZIS-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005630 polypropylene random copolymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8566281A JPS57200455A (en) | 1981-06-05 | 1981-06-05 | Thermoplastic resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8566281A JPS57200455A (en) | 1981-06-05 | 1981-06-05 | Thermoplastic resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57200455A JPS57200455A (en) | 1982-12-08 |
| JPS6153384B2 true JPS6153384B2 (de) | 1986-11-17 |
Family
ID=13865032
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8566281A Granted JPS57200455A (en) | 1981-06-05 | 1981-06-05 | Thermoplastic resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS57200455A (de) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59113049A (ja) * | 1982-12-20 | 1984-06-29 | Unitika Ltd | 樹脂組成物 |
| DE3688241T2 (de) * | 1985-11-29 | 1993-09-16 | Ge Specialty Chem | Stabilisatorgemische auf phosphitbasis. |
| JPH0751655B2 (ja) * | 1986-09-30 | 1995-06-05 | 三菱化学株式会社 | 熱可塑性樹脂組成物 |
| JPS63118373A (ja) * | 1986-11-07 | 1988-05-23 | Idemitsu Petrochem Co Ltd | 熱可塑性樹脂組成物 |
| JPH07107111B2 (ja) * | 1987-07-14 | 1995-11-15 | 日本石油化学株式会社 | 安定性の改良されたポリオレフィン組成物 |
| JP2710321B2 (ja) * | 1987-12-28 | 1998-02-10 | 電気化学工業株式会社 | 耐候性に優れた樹脂組成物 |
| JPH02229853A (ja) * | 1989-03-03 | 1990-09-12 | Ube Ind Ltd | 給電部品材料組成物 |
| JP5977598B2 (ja) * | 2012-06-22 | 2016-08-24 | 旭化成株式会社 | ポリアミド樹脂組成物の流動性を改良する方法 |
Citations (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3322718A (en) * | 1963-08-23 | 1967-05-30 | Nat Distillers Chem Corp | Polyolefins stabilized with phosphites, phenols, and benzotriazoles |
| JPS491935A (de) * | 1972-04-25 | 1974-01-09 | ||
| US3824192A (en) * | 1969-08-29 | 1974-07-16 | A Dibattista | Stabilized system containing metal hydroxyalkyl phosphonic acid or phosphinic acid |
| JPS504379A (de) * | 1973-05-16 | 1975-01-17 | ||
| JPS5035096A (de) * | 1973-08-01 | 1975-04-03 | ||
| JPS5052152A (de) * | 1973-08-27 | 1975-05-09 | ||
| JPS5088144A (de) * | 1973-10-11 | 1975-07-15 | ||
| JPS50139836A (de) * | 1974-04-27 | 1975-11-08 | ||
| JPS5111654A (de) * | 1974-07-18 | 1976-01-29 | Masakuni Kanai | |
| JPS51109050A (de) * | 1975-02-20 | 1976-09-27 | Ciba Geigy | |
| JPS5241779A (en) * | 1975-09-29 | 1977-03-31 | Nippon Kogaku Kk <Nikon> | Limit circuit of servo-device |
| GB1471665A (en) * | 1973-07-03 | 1977-04-27 | Ici Ltd | Dry strippable wall-coverings |
| JPS52106879A (en) * | 1976-03-04 | 1977-09-07 | Borg Warner | Production of mixed aromaticcaliphatic phosphites |
| JPS5329343A (en) * | 1976-09-01 | 1978-03-18 | Oshika Shinko Co | Adhesive composition |
| JPS5373245A (en) * | 1976-12-13 | 1978-06-29 | Mitsubishi Monsanto Chem Co | Inorganic filler-containing resin compositions having improved thermal stability |
| JPS5377238A (en) * | 1976-12-20 | 1978-07-08 | Tokuyama Soda Co Ltd | Polyolefin composition |
| JPS5425951A (en) * | 1977-07-29 | 1979-02-27 | Adeka Argus Chem Co Ltd | Synthetic resin composition |
| JPS54101846A (en) * | 1978-01-09 | 1979-08-10 | Ciba Geigy Ag | Polypropylene composition |
| US4185004A (en) * | 1977-04-27 | 1980-01-22 | Phillips Petroleum Company | Multi-component stabilizing system for pigmented polyolefins |
| JPS5554339A (en) * | 1978-10-13 | 1980-04-21 | American Cyanamid Co | Photoostable composition and photoostabilizer composition |
| US4209430A (en) * | 1978-11-24 | 1980-06-24 | Scm Corporation | Treatment of inorganic pigments |
| JPS5783539A (en) * | 1980-09-19 | 1982-05-25 | American Cyanamid Co | Polyolefin composition containing stabilized titanium dioxide pigment |
| JPS5783582A (en) * | 1980-09-18 | 1982-05-25 | Uniroyal Inc | Stabilizing composition and stabilized composition containing organic material and same |
| JPS5787449A (en) * | 1980-11-19 | 1982-05-31 | Hitachi Cable Ltd | Polyvinyl chloride composition |
-
1981
- 1981-06-05 JP JP8566281A patent/JPS57200455A/ja active Granted
Patent Citations (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3322718A (en) * | 1963-08-23 | 1967-05-30 | Nat Distillers Chem Corp | Polyolefins stabilized with phosphites, phenols, and benzotriazoles |
| US3824192A (en) * | 1969-08-29 | 1974-07-16 | A Dibattista | Stabilized system containing metal hydroxyalkyl phosphonic acid or phosphinic acid |
| JPS491935A (de) * | 1972-04-25 | 1974-01-09 | ||
| JPS504379A (de) * | 1973-05-16 | 1975-01-17 | ||
| GB1471665A (en) * | 1973-07-03 | 1977-04-27 | Ici Ltd | Dry strippable wall-coverings |
| JPS5035096A (de) * | 1973-08-01 | 1975-04-03 | ||
| JPS5052152A (de) * | 1973-08-27 | 1975-05-09 | ||
| JPS5088144A (de) * | 1973-10-11 | 1975-07-15 | ||
| JPS50139836A (de) * | 1974-04-27 | 1975-11-08 | ||
| JPS5111654A (de) * | 1974-07-18 | 1976-01-29 | Masakuni Kanai | |
| JPS51109050A (de) * | 1975-02-20 | 1976-09-27 | Ciba Geigy | |
| JPS5241779A (en) * | 1975-09-29 | 1977-03-31 | Nippon Kogaku Kk <Nikon> | Limit circuit of servo-device |
| JPS52106879A (en) * | 1976-03-04 | 1977-09-07 | Borg Warner | Production of mixed aromaticcaliphatic phosphites |
| JPS5329343A (en) * | 1976-09-01 | 1978-03-18 | Oshika Shinko Co | Adhesive composition |
| JPS5373245A (en) * | 1976-12-13 | 1978-06-29 | Mitsubishi Monsanto Chem Co | Inorganic filler-containing resin compositions having improved thermal stability |
| JPS5377238A (en) * | 1976-12-20 | 1978-07-08 | Tokuyama Soda Co Ltd | Polyolefin composition |
| US4185004A (en) * | 1977-04-27 | 1980-01-22 | Phillips Petroleum Company | Multi-component stabilizing system for pigmented polyolefins |
| JPS5425951A (en) * | 1977-07-29 | 1979-02-27 | Adeka Argus Chem Co Ltd | Synthetic resin composition |
| JPS54101846A (en) * | 1978-01-09 | 1979-08-10 | Ciba Geigy Ag | Polypropylene composition |
| JPS5554339A (en) * | 1978-10-13 | 1980-04-21 | American Cyanamid Co | Photoostable composition and photoostabilizer composition |
| US4209430A (en) * | 1978-11-24 | 1980-06-24 | Scm Corporation | Treatment of inorganic pigments |
| JPS5783582A (en) * | 1980-09-18 | 1982-05-25 | Uniroyal Inc | Stabilizing composition and stabilized composition containing organic material and same |
| JPS5783539A (en) * | 1980-09-19 | 1982-05-25 | American Cyanamid Co | Polyolefin composition containing stabilized titanium dioxide pigment |
| JPS5787449A (en) * | 1980-11-19 | 1982-05-31 | Hitachi Cable Ltd | Polyvinyl chloride composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS57200455A (en) | 1982-12-08 |
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