JPS6126945B2 - - Google Patents
Info
- Publication number
- JPS6126945B2 JPS6126945B2 JP56028396A JP2839681A JPS6126945B2 JP S6126945 B2 JPS6126945 B2 JP S6126945B2 JP 56028396 A JP56028396 A JP 56028396A JP 2839681 A JP2839681 A JP 2839681A JP S6126945 B2 JPS6126945 B2 JP S6126945B2
- Authority
- JP
- Japan
- Prior art keywords
- titanium oxide
- weight
- parts
- thermoplastic resin
- yellowing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 23
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 22
- 229920005992 thermoplastic resin Polymers 0.000 claims description 19
- 239000003963 antioxidant agent Substances 0.000 claims description 15
- 230000003078 antioxidant effect Effects 0.000 claims description 9
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 5
- 229920000098 polyolefin Polymers 0.000 claims description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- 238000004383 yellowing Methods 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 7
- 238000002156 mixing Methods 0.000 description 6
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 5
- 239000008116 calcium stearate Substances 0.000 description 5
- 235000013539 calcium stearate Nutrition 0.000 description 5
- -1 ethylene, propylene Chemical group 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 150000008301 phosphite esters Chemical class 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000012760 heat stabilizer Substances 0.000 description 3
- 239000011256 inorganic filler Substances 0.000 description 3
- 229910003475 inorganic filler Inorganic materials 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 238000005453 pelletization Methods 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000011342 resin composition Substances 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229920001384 propylene homopolymer Polymers 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2839681A JPS57143351A (en) | 1981-03-02 | 1981-03-02 | Thermoplastic resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2839681A JPS57143351A (en) | 1981-03-02 | 1981-03-02 | Thermoplastic resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57143351A JPS57143351A (en) | 1982-09-04 |
| JPS6126945B2 true JPS6126945B2 (de) | 1986-06-23 |
Family
ID=12247494
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2839681A Granted JPS57143351A (en) | 1981-03-02 | 1981-03-02 | Thermoplastic resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS57143351A (de) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0751655B2 (ja) * | 1986-09-30 | 1995-06-05 | 三菱化学株式会社 | 熱可塑性樹脂組成物 |
| JPS63118373A (ja) * | 1986-11-07 | 1988-05-23 | Idemitsu Petrochem Co Ltd | 熱可塑性樹脂組成物 |
| JP2710321B2 (ja) * | 1987-12-28 | 1998-02-10 | 電気化学工業株式会社 | 耐候性に優れた樹脂組成物 |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1150969A (en) * | 1965-12-27 | 1969-05-07 | Phillips Petroleum Co | Stabilizer Composition for Olefin Polymers |
| JPS5035096A (de) * | 1973-08-01 | 1975-04-03 | ||
| JPS5052152A (de) * | 1973-08-27 | 1975-05-09 | ||
| JPS5088144A (de) * | 1973-10-11 | 1975-07-15 | ||
| JPS50139836A (de) * | 1974-04-27 | 1975-11-08 | ||
| JPS51109050A (de) * | 1975-02-20 | 1976-09-27 | Ciba Geigy | |
| JPS5373245A (en) * | 1976-12-13 | 1978-06-29 | Mitsubishi Monsanto Chem Co | Inorganic filler-containing resin compositions having improved thermal stability |
| US4185004A (en) * | 1977-04-27 | 1980-01-22 | Phillips Petroleum Company | Multi-component stabilizing system for pigmented polyolefins |
| US4187212A (en) * | 1975-02-20 | 1980-02-05 | Ciba-Geigy Corporation | Stabilization systems from triarylphosphites and phenols |
| JPS5610535A (en) * | 1979-07-06 | 1981-02-03 | Mitsubishi Petrochem Co Ltd | Inorganic filler-containing olefin polymer composition |
-
1981
- 1981-03-02 JP JP2839681A patent/JPS57143351A/ja active Granted
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1150969A (en) * | 1965-12-27 | 1969-05-07 | Phillips Petroleum Co | Stabilizer Composition for Olefin Polymers |
| JPS5035096A (de) * | 1973-08-01 | 1975-04-03 | ||
| JPS5052152A (de) * | 1973-08-27 | 1975-05-09 | ||
| JPS5088144A (de) * | 1973-10-11 | 1975-07-15 | ||
| JPS50139836A (de) * | 1974-04-27 | 1975-11-08 | ||
| JPS51109050A (de) * | 1975-02-20 | 1976-09-27 | Ciba Geigy | |
| US4187212A (en) * | 1975-02-20 | 1980-02-05 | Ciba-Geigy Corporation | Stabilization systems from triarylphosphites and phenols |
| JPS5373245A (en) * | 1976-12-13 | 1978-06-29 | Mitsubishi Monsanto Chem Co | Inorganic filler-containing resin compositions having improved thermal stability |
| US4185004A (en) * | 1977-04-27 | 1980-01-22 | Phillips Petroleum Company | Multi-component stabilizing system for pigmented polyolefins |
| JPS5610535A (en) * | 1979-07-06 | 1981-02-03 | Mitsubishi Petrochem Co Ltd | Inorganic filler-containing olefin polymer composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS57143351A (en) | 1982-09-04 |
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