JPS6019033A - 中空マイクロバル−ンおよびその製法 - Google Patents

中空マイクロバル−ンおよびその製法

Info

Publication number
JPS6019033A
JPS6019033A JP58127384A JP12738483A JPS6019033A JP S6019033 A JPS6019033 A JP S6019033A JP 58127384 A JP58127384 A JP 58127384A JP 12738483 A JP12738483 A JP 12738483A JP S6019033 A JPS6019033 A JP S6019033A
Authority
JP
Japan
Prior art keywords
resin
microballoon
vinylidene chloride
hollow
thermosetting resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP58127384A
Other languages
English (en)
Japanese (ja)
Other versions
JPH0379060B2 (enExample
Inventor
Kikuo Niinuma
新沼 喜久夫
Yoshifumi Morimoto
森本 善文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Matsumoto Yushi Seiyaku Co Ltd
Original Assignee
Matsumoto Yushi Seiyaku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsumoto Yushi Seiyaku Co Ltd filed Critical Matsumoto Yushi Seiyaku Co Ltd
Priority to JP58127384A priority Critical patent/JPS6019033A/ja
Priority to SE8403671A priority patent/SE465812B/sv
Priority to US06/630,125 priority patent/US4582756A/en
Publication of JPS6019033A publication Critical patent/JPS6019033A/ja
Publication of JPH0379060B2 publication Critical patent/JPH0379060B2/ja
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02Making microcapsules or microballoons
    • B01J13/20After-treatment of capsule walls, e.g. hardening
    • B01J13/22Coating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/32Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/22Expanded, porous or hollow particles
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/18Spheres
    • C08L2205/20Hollow spheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/18Homopolymers or copolymers of nitriles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249953Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249971Preformed hollow element-containing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249953Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249971Preformed hollow element-containing
    • Y10T428/249972Resin or rubber element
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/254Polymeric or resinous material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991Coated
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991Coated
    • Y10T428/2998Coated including synthetic resin or polymer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31786Of polyester [e.g., alkyd, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • Y10T428/31909Next to second addition polymer from unsaturated monomers
    • Y10T428/31913Monoolefin polymer
    • Y10T428/3192Next to vinyl or vinylidene chloride polymer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • Y10T428/31909Next to second addition polymer from unsaturated monomers
    • Y10T428/31928Ester, halide or nitrile of addition polymer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31942Of aldehyde or ketone condensation product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacturing Of Micro-Capsules (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
JP58127384A 1983-07-12 1983-07-12 中空マイクロバル−ンおよびその製法 Granted JPS6019033A (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP58127384A JPS6019033A (ja) 1983-07-12 1983-07-12 中空マイクロバル−ンおよびその製法
SE8403671A SE465812B (sv) 1983-07-12 1984-07-11 Mikrokapsel och dess framstaellning
US06/630,125 US4582756A (en) 1983-07-12 1984-07-12 Organic microballoon

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58127384A JPS6019033A (ja) 1983-07-12 1983-07-12 中空マイクロバル−ンおよびその製法

Publications (2)

Publication Number Publication Date
JPS6019033A true JPS6019033A (ja) 1985-01-31
JPH0379060B2 JPH0379060B2 (enExample) 1991-12-17

Family

ID=14958655

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58127384A Granted JPS6019033A (ja) 1983-07-12 1983-07-12 中空マイクロバル−ンおよびその製法

Country Status (3)

Country Link
US (1) US4582756A (enExample)
JP (1) JPS6019033A (enExample)
SE (1) SE465812B (enExample)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01218629A (ja) * 1988-02-29 1989-08-31 Japan Synthetic Rubber Co Ltd 中空ポリマー微粒子の製造法
JPH06240040A (ja) * 1993-02-16 1994-08-30 Dainichiseika Color & Chem Mfg Co Ltd 複合マイクロバルーン及びその製造方法
JPH076684A (ja) * 1993-06-17 1995-01-10 Sony Chem Corp ヒューズ抵抗組成物及びヒューズ抵抗器
WO1999037706A1 (fr) * 1998-01-26 1999-07-29 Kureha Kagaku Kogyo K.K. Microspheres expansibles et leur procede de production
WO2001023081A1 (fr) * 1999-09-29 2001-04-05 Matsumoto Yushi-Seiyaku Co., Ltd. Procede de fabrication de microcapsules thermoexpansibles
JP2005206765A (ja) * 2004-01-26 2005-08-04 Sanyo Chem Ind Ltd 熱膨張性マイクロカプセルおよび中空樹脂粒子
JP2008503608A (ja) * 2004-06-17 2008-02-07 ヘンケル コーポレーション 熱的クラッドされた超低密度微小球
JP2012500303A (ja) * 2008-08-13 2012-01-05 ピーピージー インダストリーズ オハイオ,インコーポレイテッド 軽量粒子および軽量粒子を含む組成物
JP2012504181A (ja) * 2008-09-30 2012-02-16 ヘンケル コーポレイション 不燃性の中空ポリマー微小球
JP2012149173A (ja) * 2011-01-19 2012-08-09 Sekisui Chem Co Ltd 発泡成形体
JP2013504763A (ja) * 2009-09-16 2013-02-07 スフィリテック・リミテッド 中空微粒子体
CN110167666A (zh) * 2016-10-19 2019-08-23 界面咨询有限责任公司 牺牲微球
JP2019196420A (ja) * 2018-05-07 2019-11-14 信越化学工業株式会社 ロール用液状高連泡シリコーンゴムスポンジ組成物及びシリコーンゴムスポンジ
EP3716373A1 (en) 2019-03-29 2020-09-30 Sumitomo Rubber Industries, Ltd. Sulfur-based active material
WO2021201088A1 (ja) * 2020-03-31 2021-10-07 株式会社トクヤマ Cmp研磨パッド用中空マイクロバルーン

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JPH0813901B2 (ja) * 1990-02-19 1996-02-14 株式会社ホーネンコーポレーション 均一な粒子径を有する中空状のメラミン樹脂架橋粒子の製造法および架橋粒子
US5205290A (en) 1991-04-05 1993-04-27 Unger Evan C Low density microspheres and their use as contrast agents for computed tomography
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JP3659979B2 (ja) * 1992-04-15 2005-06-15 松本油脂製薬株式会社 熱膨張性マイクロカプセルとその製法
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JPH10508261A (ja) * 1994-09-06 1998-08-18 サーマセル テクノロジーズ,インコーポレイテッド 絶縁微小球および製造法
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FI991281A7 (fi) * 1999-06-04 2000-12-05 Neste Chemicals Oy Menetelmä onttojen polymeerihiukkasten pinnoittamiseksi hartsilla ja hartsilla pinnoitetut ontot polymeerihiukkaset
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JP5727986B2 (ja) * 2012-10-31 2015-06-03 ニチハ株式会社 建築板及びその製造方法
JP6181951B2 (ja) * 2013-03-19 2017-08-16 ニチハ株式会社 建築板、及び建築板の製造方法
CN104675009B (zh) * 2013-11-29 2019-03-12 日吉华株式会社 建筑板及其制造方法
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4912578A (enExample) * 1972-05-19 1974-02-04
JPS50138058A (enExample) * 1974-04-06 1975-11-04
JPS5114539A (en) * 1974-07-29 1976-02-05 Yamaha Motor Co Ltd Nainenkikanno shidosochi

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JPH01218629A (ja) * 1988-02-29 1989-08-31 Japan Synthetic Rubber Co Ltd 中空ポリマー微粒子の製造法
JPH06240040A (ja) * 1993-02-16 1994-08-30 Dainichiseika Color & Chem Mfg Co Ltd 複合マイクロバルーン及びその製造方法
JPH076684A (ja) * 1993-06-17 1995-01-10 Sony Chem Corp ヒューズ抵抗組成物及びヒューズ抵抗器
WO1999037706A1 (fr) * 1998-01-26 1999-07-29 Kureha Kagaku Kogyo K.K. Microspheres expansibles et leur procede de production
US6613810B1 (en) 1998-01-26 2003-09-02 Kureha Kagaku K.K. Expandable microspheres and process for producing the same
WO2001023081A1 (fr) * 1999-09-29 2001-04-05 Matsumoto Yushi-Seiyaku Co., Ltd. Procede de fabrication de microcapsules thermoexpansibles
US6365641B1 (en) 1999-09-29 2002-04-02 Matsumoto Yushi-Seiyaku Co Ltd Process for producing heat-expandable microcapsules
JP2005206765A (ja) * 2004-01-26 2005-08-04 Sanyo Chem Ind Ltd 熱膨張性マイクロカプセルおよび中空樹脂粒子
JP2008503608A (ja) * 2004-06-17 2008-02-07 ヘンケル コーポレーション 熱的クラッドされた超低密度微小球
JP2012500303A (ja) * 2008-08-13 2012-01-05 ピーピージー インダストリーズ オハイオ,インコーポレイテッド 軽量粒子および軽量粒子を含む組成物
JP2012504181A (ja) * 2008-09-30 2012-02-16 ヘンケル コーポレイション 不燃性の中空ポリマー微小球
JP2014224251A (ja) * 2008-09-30 2014-12-04 ヘンケル コーポレイションHenkel Corporation 不燃性の中空ポリマー微小球
JP2013504763A (ja) * 2009-09-16 2013-02-07 スフィリテック・リミテッド 中空微粒子体
JP2012149173A (ja) * 2011-01-19 2012-08-09 Sekisui Chem Co Ltd 発泡成形体
CN110167666A (zh) * 2016-10-19 2019-08-23 界面咨询有限责任公司 牺牲微球
JP2019533049A (ja) * 2016-10-19 2019-11-14 インターフェイシャル・コンサルタンツ・エルエルシー 犠牲的マイクロスフェア
US11254796B2 (en) 2016-10-19 2022-02-22 Interfacial Consultants Llc Sacrificial microspheres
CN110167666B (zh) * 2016-10-19 2023-03-10 界面咨询有限责任公司 牺牲微球
JP2019196420A (ja) * 2018-05-07 2019-11-14 信越化学工業株式会社 ロール用液状高連泡シリコーンゴムスポンジ組成物及びシリコーンゴムスポンジ
EP3716373A1 (en) 2019-03-29 2020-09-30 Sumitomo Rubber Industries, Ltd. Sulfur-based active material
US11094939B2 (en) 2019-03-29 2021-08-17 Sumitomo Rubber Industries, Ltd. Sulfur-based active material
WO2021201088A1 (ja) * 2020-03-31 2021-10-07 株式会社トクヤマ Cmp研磨パッド用中空マイクロバルーン
CN115379926A (zh) * 2020-03-31 2022-11-22 株式会社德山 Cmp抛光垫用中空微球

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US4582756A (en) 1986-04-15
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JPH0379060B2 (enExample) 1991-12-17
SE8403671D0 (sv) 1984-07-11
SE8403671L (sv) 1985-01-13

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