JPS55113730A - Preparation of acrolein and acrylic acid - Google Patents

Preparation of acrolein and acrylic acid

Info

Publication number
JPS55113730A
JPS55113730A JP2088779A JP2088779A JPS55113730A JP S55113730 A JPS55113730 A JP S55113730A JP 2088779 A JP2088779 A JP 2088779A JP 2088779 A JP2088779 A JP 2088779A JP S55113730 A JPS55113730 A JP S55113730A
Authority
JP
Japan
Prior art keywords
catalysts
activities
propylene
amounts
selectivities
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2088779A
Other languages
English (en)
Other versions
JPS6338331B2 (ja
Inventor
Yukishige Kadowaki
Kohei Sarumaru
Takeshi Shibano
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Petrochemical Co Ltd
Original Assignee
Mitsubishi Petrochemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Petrochemical Co Ltd filed Critical Mitsubishi Petrochemical Co Ltd
Priority to JP2088779A priority Critical patent/JPS55113730A/ja
Priority to DE19803006894 priority patent/DE3006894A1/de
Priority to GB8006356A priority patent/GB2044764B/en
Publication of JPS55113730A publication Critical patent/JPS55113730A/ja
Priority to US06/421,796 priority patent/US4837360A/en
Publication of JPS6338331B2 publication Critical patent/JPS6338331B2/ja
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8874—Gallium, indium or thallium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B01J35/19—
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
JP2088779A 1979-02-26 1979-02-26 Preparation of acrolein and acrylic acid Granted JPS55113730A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2088779A JPS55113730A (en) 1979-02-26 1979-02-26 Preparation of acrolein and acrylic acid
DE19803006894 DE3006894A1 (de) 1979-02-26 1980-02-23 Herstellung von acrolein und acrylsaeure
GB8006356A GB2044764B (en) 1979-02-26 1980-02-26 Process for producing acrolein and acrylic acid
US06/421,796 US4837360A (en) 1979-02-26 1982-09-23 Process for producing acrolein and acrylic acid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2088779A JPS55113730A (en) 1979-02-26 1979-02-26 Preparation of acrolein and acrylic acid

Publications (2)

Publication Number Publication Date
JPS55113730A true JPS55113730A (en) 1980-09-02
JPS6338331B2 JPS6338331B2 (ja) 1988-07-29

Family

ID=12039710

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2088779A Granted JPS55113730A (en) 1979-02-26 1979-02-26 Preparation of acrolein and acrylic acid

Country Status (4)

Country Link
US (1) US4837360A (ja)
JP (1) JPS55113730A (ja)
DE (1) DE3006894A1 (ja)
GB (1) GB2044764B (ja)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58119346A (ja) * 1982-01-06 1983-07-15 Nippon Shokubai Kagaku Kogyo Co Ltd プロピレン酸化用触媒
JPS63146841A (ja) * 1986-12-11 1988-06-18 Mitsubishi Petrochem Co Ltd アクリル酸の製造法
WO1991008185A1 (en) * 1989-12-06 1991-06-13 Nippon Shokubai Kagaku Kogyo Co., Ltd. Process for producing methacrolein and methacrylic acid
JPH07112125A (ja) * 1993-10-15 1995-05-02 Agency Of Ind Science & Technol 触媒反応方法および装置
EP1113238A2 (en) 1999-12-28 2001-07-04 Nippon Shokubai Co., Ltd. Shell and tube type heat exchanger
JP2003089671A (ja) * 2001-09-19 2003-03-28 Nippon Shokubai Co Ltd アクリル酸の製造方法
WO2005049536A1 (ja) * 2003-11-14 2005-06-02 Mitsubishi Chemical Corporation 不飽和アルデヒド及び不飽和カルボン酸の製造方法
KR100591048B1 (ko) * 2000-02-16 2006-06-19 가부시키가이샤 닛폰 쇼쿠바이 아크롤레인 및 아크릴산의 제조 방법
US7579501B2 (en) 2001-11-08 2009-08-25 Mitsubishi Chemical Corporation Composite oxide catalyst and method of producing the same
JP2009530400A (ja) * 2006-03-23 2009-08-27 ヴェロシス，インク． マイクロチャネルプロセス技術を用いてスチレンを作るためのプロセス
WO2015008815A1 (ja) * 2013-07-18 2015-01-22 日本化薬株式会社 不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
WO2017010159A1 (ja) * 2015-07-10 2017-01-19 日本化薬株式会社 不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
JP2021525652A (ja) * 2018-06-08 2021-09-27 マン・エナジー・ソリューションズ・エスイーＭａｎ Ｅｎｅｒｇｙ Ｓｏｌｕｔｉｏｎｓ Ｓｅ 触媒気相反応を実行するための方法、管束反応炉、および反応炉システム

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3123521A1 (de) * 1981-06-13 1983-01-13 EC Erdölchemie GmbH, 5000 Köln Rieselfaehige, katalytische mischungen
JPS62234548A (ja) * 1986-03-24 1987-10-14 Mitsubishi Petrochem Co Ltd 複合酸化物触媒の製造法
SU1665870A3 (ru) * 1986-03-24 1991-07-23 Мицубиси Петрокемикал Компани Лимитед (Фирма) Способ приготовлени окисного катализатора дл окислени пропилена
CA1305178C (en) * 1986-08-21 1992-07-14 Gordon Gene Harkreader Anhydrous diluent process for the propylene oxidation reaction to acrolein and acrolein oxidation to acrylic acid
DE3930534A1 (de) * 1989-09-13 1991-03-21 Degussa Verfahren zur herstellung von acrolein durch katalytische gasphasenoxidation von propen
EP0441312B1 (en) * 1990-02-08 1995-02-01 Nippon Shokubai Kagaku Kogyo Co. Ltd. Process for producing methacrylic acid
US5206431A (en) * 1990-02-08 1993-04-27 Nippon Shokubai Kagaku Kogyo Co., Ltd. Process for producing methacrylic acid
JPH0784400B2 (ja) * 1990-04-03 1995-09-13 株式会社日本触媒 不飽和アルデヒドおよび不飽和酸の製造方法
DE4023239A1 (de) * 1990-07-21 1992-01-23 Basf Ag Verfahren zur katalytischen gasphasenoxidation von propen oder iso-buten zu acrolein oder methacrolein
US5210319A (en) * 1992-03-02 1993-05-11 Chuang Karl T One step carboxylic acid production process
EP0630879B2 (en) * 1993-06-25 2001-04-11 Sumitomo Chemical Company Limited Process for production of unsaturated aldehyde and unsaturated carboxylic acid
ES2135120T3 (es) * 1995-03-10 1999-10-16 Basf Ag Procedimiento de oxidacion en fase gaseosa de propileno a acroleina, acido acrilico, o su mezcla, realizada continuamente, catalizada por via heterogenea.
JP3775872B2 (ja) * 1996-12-03 2006-05-17 日本化薬株式会社 アクロレイン及びアクリル酸の製造方法
DE19902562A1 (de) 1999-01-22 2000-07-27 Basf Ag Verfahren zur Herstellung von Acrolein durch heterogen katalysierte Gasphasen-Partialoxidation von Propen
KR100569632B1 (ko) 1999-05-13 2006-04-10 가부시키가이샤 닛폰 쇼쿠바이 불포화 알데히드 및 불포화 카르복실산을 제조하기 위한촉매 및 이 촉매를 사용하여 불포화 알데히드 및 불포화카르복실산을 제조하기 위한 방법
JP4185217B2 (ja) * 1999-05-25 2008-11-26 株式会社日本触媒 複合酸化物触媒、並びに（メタ）アクロレインおよび（メタ）アクリル酸の製造方法
JP3943284B2 (ja) * 1999-05-27 2007-07-11 株式会社日本触媒 アクリル酸の製造方法
JP3943291B2 (ja) * 1999-08-04 2007-07-11 株式会社日本触媒 アクロレインおよびアクリル酸の製造方法
JP3943311B2 (ja) * 2000-05-19 2007-07-11 株式会社日本触媒 不飽和アルデヒドおよび不飽和カルボン酸の製造方法
JP4426069B2 (ja) 2000-06-12 2010-03-03 株式会社日本触媒 アクリル酸の製造方法
DE10046957A1 (de) * 2000-09-21 2002-04-11 Basf Ag Verfahren zur Herstellung eines Multimetalloxid-Katalysators, Verfahren zur Herstellung ungesättigter Aldehyde und/oder Carbonsäuren und Bandcalziniervorrichtung
ZA200200049B (en) 2001-01-25 2002-07-16 Nippon Catalytic Chem Ind Fixed-bed shell-and-tube reactor and its usage.
CN1599708A (zh) * 2001-12-27 2005-03-23 三菱化学株式会社 气相催化氧化法及(甲基)丙烯醛或(甲基)丙烯酸的制造方法
US6960684B2 (en) 2002-03-29 2005-11-01 Nippon Shokubai Co., Ltd. Production process for unsaturated aldehyde
US7045657B2 (en) 2002-04-03 2006-05-16 Nippon Shokubai Co., Ltd. Catalytic gas phase oxidation process
KR100553825B1 (ko) * 2003-09-01 2006-02-21 주식회사 엘지화학 고정층 촉매 부분 산화 반응기에서 개선된 제열 시스템을통한 불포화알데히드 및 불포화산의 제조 방법
KR100714606B1 (ko) * 2005-02-25 2007-05-07 주식회사 엘지화학 불포화 알데히드 및/또는 불포화 산의 제조방법
KR100677051B1 (ko) * 2005-03-18 2007-02-01 주식회사 엘지화학 올레핀으로부터 불포화산을 제조하는 방법
KR100868454B1 (ko) * 2005-07-08 2008-11-11 주식회사 엘지화학 고정층 촉매 부분산화 반응기에서 고효율의 불포화산의제조방법
JP4902991B2 (ja) * 2005-12-27 2012-03-21 三菱レイヨン株式会社 酸化物触媒の製造方法
CN105705229B (zh) 2013-11-07 2018-05-01 株式会社日本触媒 反应管用填充物、反应管及使用了该反应管的反应方法
KR102084768B1 (ko) * 2016-11-01 2020-03-04 주식회사 엘지화학 불포화 알데하이드 및 불포화 카르복실산의 제조 방법
CN110430938B (zh) * 2017-03-17 2023-09-08 三菱化学株式会社 催化氧化方法和共轭二烯的制造方法
DE102018113737A1 (de) * 2018-06-08 2019-12-12 Man Energy Solutions Se Verfahren und Reaktorsystem zur Durchführung katalytischer Gasphasenreaktionen
CN114289030A (zh) * 2021-11-12 2022-04-08 中海油天津化工研究设计院有限公司 一种丙烯氧化制丙烯醛催化剂的制备方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1256595A (ja) * 1969-06-24 1971-12-08
US3970702A (en) * 1970-07-03 1976-07-20 Sumitomo Chemical Company, Limited Catalytic process for the preparation of acrolein
DE2056614C3 (de) * 1970-11-18 1981-04-16 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Acrylsäure aus Propylen

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6236739B2 (ja) * 1982-01-06 1987-08-08 Nippon Shokubai Kagaku Kogyo Kk
JPS58119346A (ja) * 1982-01-06 1983-07-15 Nippon Shokubai Kagaku Kogyo Co Ltd プロピレン酸化用触媒
JPS63146841A (ja) * 1986-12-11 1988-06-18 Mitsubishi Petrochem Co Ltd アクリル酸の製造法
WO1991008185A1 (en) * 1989-12-06 1991-06-13 Nippon Shokubai Kagaku Kogyo Co., Ltd. Process for producing methacrolein and methacrylic acid
JPH07112125A (ja) * 1993-10-15 1995-05-02 Agency Of Ind Science & Technol 触媒反応方法および装置
EP1113238A2 (en) 1999-12-28 2001-07-04 Nippon Shokubai Co., Ltd. Shell and tube type heat exchanger
JP2001194076A (ja) * 1999-12-28 2001-07-17 Nippon Shokubai Co Ltd 多管式熱交換器
KR100591048B1 (ko) * 2000-02-16 2006-06-19 가부시키가이샤 닛폰 쇼쿠바이 아크롤레인 및 아크릴산의 제조 방법
JP2003089671A (ja) * 2001-09-19 2003-03-28 Nippon Shokubai Co Ltd アクリル酸の製造方法
US7632777B2 (en) 2001-11-08 2009-12-15 Mitsubishi Chemical Corporation Composite oxide catalyst and method for preparation thereof
US7579501B2 (en) 2001-11-08 2009-08-25 Mitsubishi Chemical Corporation Composite oxide catalyst and method of producing the same
WO2005049536A1 (ja) * 2003-11-14 2005-06-02 Mitsubishi Chemical Corporation 不飽和アルデヒド及び不飽和カルボン酸の製造方法
JP2009530400A (ja) * 2006-03-23 2009-08-27 ヴェロシス，インク． マイクロチャネルプロセス技術を用いてスチレンを作るためのプロセス
WO2015008815A1 (ja) * 2013-07-18 2015-01-22 日本化薬株式会社 不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
US9440904B2 (en) 2013-07-18 2016-09-13 Nippon Kayaku Kabushiki Kaisha Method for producing unsaturated aldehyde and/or unsaturated carboxylic acid
WO2017010159A1 (ja) * 2015-07-10 2017-01-19 日本化薬株式会社 不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
JPWO2017010159A1 (ja) * 2015-07-10 2018-04-19 日本化薬株式会社 不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
JP2021525652A (ja) * 2018-06-08 2021-09-27 マン・エナジー・ソリューションズ・エスイーＭａｎ Ｅｎｅｒｇｙ Ｓｏｌｕｔｉｏｎｓ Ｓｅ 触媒気相反応を実行するための方法、管束反応炉、および反応炉システム
US11806707B2 (en) 2018-06-08 2023-11-07 Man Energy Solutions Se Method, tube bundle reactor and reactor system for carrying out catalytic gas phase reactions

Also Published As

Publication number Publication date
GB2044764B (en) 1983-05-11
GB2044764A (en) 1980-10-22
DE3006894A1 (de) 1980-09-04
DE3006894C2 (ja) 1992-01-23
US4837360A (en) 1989-06-06
JPS6338331B2 (ja) 1988-07-29

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