ES2135120T3 - Procedimiento de oxidacion en fase gaseosa de propileno a acroleina, acido acrilico, o su mezcla, realizada continuamente, catalizada por via heterogenea. - Google Patents

Procedimiento de oxidacion en fase gaseosa de propileno a acroleina, acido acrilico, o su mezcla, realizada continuamente, catalizada por via heterogenea.

Info

Publication number
ES2135120T3
ES2135120T3 ES96103150T ES96103150T ES2135120T3 ES 2135120 T3 ES2135120 T3 ES 2135120T3 ES 96103150 T ES96103150 T ES 96103150T ES 96103150 T ES96103150 T ES 96103150T ES 2135120 T3 ES2135120 T3 ES 2135120T3
Authority
ES
Spain
Prior art keywords
oxidation
mixture
gaseous phase
catalyzed
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96103150T
Other languages
English (en)
Inventor
Werner Dr Hefner
Otto Dr Machhammer
Hans-Peter Dr Neumann
Andreas Dr Tenten
Wilhelm Dr Ruppel
Herbert Dr Vogel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19508532A external-priority patent/DE19508532A1/de
Priority claimed from DE1995125506 external-priority patent/DE19525506A1/de
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2135120T3 publication Critical patent/ES2135120T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

UN PROCEDIMIENTO PARA LA OXIDACION EN FASE GASEOSA HETEROGENEAMENTE CATALIZADA Y CONTINUA DE PROPILENO PARA DAR ACROLEINA, ACIDO ACRILICO O SU MEZCLA EN UN REACTOR DE OXIDACION, CUYA MEZCLA DE GAS DE CARGA ES, ADEMAS DE PROPILENO Y OXIGENO MOLECULAR COMO OXIDANTE TAMBIEN HAY UN GAS DE DILUCION QUE SE COMPORTA COMO INERTE EN LAS CONDICIONES DE LA OXIDACION EN FASE GASEOSA HETEROGENEAMENTE CATALIZADA, Y AL MENOS UNA PARTE DE ESTE GAS INERTE SE SEPARA DE LA MEZCLA GASEOSA EN EL PROCESO CONTINUO, Y LUEGO COMO PARTE DEL GAS DE CARGA SE REUTILIZA, SIENDO EL GAS INERTE DE DILUCION EN MAS DEL 85 % EN VOLUMEN DE AL MENOS UN HIDROCARBURO SATURADO CON 1 A 5 ATOMOS DE C.
ES96103150T 1995-03-10 1996-03-01 Procedimiento de oxidacion en fase gaseosa de propileno a acroleina, acido acrilico, o su mezcla, realizada continuamente, catalizada por via heterogenea. Expired - Lifetime ES2135120T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19508532A DE19508532A1 (de) 1995-03-10 1995-03-10 Verfahren der kontinuierlich betriebenen heterogen katalysierten Gasphasenoxidation von Propylen zu Acrolein, Acrylsäure oder deren Gemisch
DE1995125506 DE19525506A1 (de) 1995-07-13 1995-07-13 Verfahren der kontinuierlich betriebenen heterogen katalysierten Gasphasenoxidation von Propylen zu Acrolein, Acrylsäure oder deren Gemisch

Publications (1)

Publication Number Publication Date
ES2135120T3 true ES2135120T3 (es) 1999-10-16

Family

ID=26013221

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96103150T Expired - Lifetime ES2135120T3 (es) 1995-03-10 1996-03-01 Procedimiento de oxidacion en fase gaseosa de propileno a acroleina, acido acrilico, o su mezcla, realizada continuamente, catalizada por via heterogenea.

Country Status (11)

Country Link
US (1) US5684188A (es)
EP (1) EP0731082B1 (es)
JP (1) JPH08245445A (es)
KR (1) KR960034157A (es)
CN (1) CN1062260C (es)
CA (1) CA2171415A1 (es)
CZ (1) CZ73496A3 (es)
DE (1) DE59602040D1 (es)
ES (1) ES2135120T3 (es)
ID (1) ID17854A (es)
SG (1) SG42369A1 (es)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE59600215D1 (de) * 1995-03-10 1998-07-02 Basf Ag Weiterverwendung des Verdünnungsgases aus der Gasphasen-Partialoxidation einer organischen Verbindung
DE19740253A1 (de) * 1997-09-12 1999-03-18 Basf Ag Verfahren zur fraktionierten Kondensation eines heißen Gasgemisches mit einem hohen Anteil nicht kondensierbarer Komponenten
SG81982A1 (en) * 1998-05-18 2001-07-24 Nippon Catalytic Chem Ind Method for production of acrolein and acrylic acid
DE19902562A1 (de) * 1999-01-22 2000-07-27 Basf Ag Verfahren zur Herstellung von Acrolein durch heterogen katalysierte Gasphasen-Partialoxidation von Propen
JP4160213B2 (ja) * 1999-08-23 2008-10-01 株式会社日本触媒 接触気相酸化反応用のガスの混合方法およびその装置
DE10028582A1 (de) * 2000-06-14 2001-12-20 Basf Ag Verfahren zur Herstellung von Acrolein oder Acrylsäure oder deren Gemischen aus Propan
DE10232482A1 (de) * 2002-07-17 2004-01-29 Basf Ag Verfahren zum sicheren Betreiben einer kontinuierlichen heterogen katalysierten Gasphasen-Partialoxidation wenigstens einer organischen Verbindung
ATE520640T1 (de) * 2004-07-01 2011-09-15 Basf Se Verfahren zur herstellung von acrylsäure durch heterogen katalysierte partielle gasphasen oxidation von propylen
KR101259649B1 (ko) * 2004-07-01 2013-04-30 바스프 에스이 프로필렌의 불균질 촉매화 부분 기상 산화를 사용한아크롤레인, 아크릴산 또는 그의 혼합물의 제조 방법
TWI351985B (en) * 2004-07-01 2011-11-11 Basf Ag Preparation of acrolein or acrylic acid or a mixtu
US7649111B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
US7851397B2 (en) 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7732367B2 (en) 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649112B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US8290626B2 (en) * 2007-09-10 2012-10-16 SD Lizenzverwertungsgesellschadt mbH & Co KG Chemical process optimization method that considers chemical process plant safety
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
JP6799582B2 (ja) * 2015-08-24 2020-12-16 ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ モノマー生成で使用するための材料の不活性度を決定する方法
EP3341350B1 (en) * 2015-08-24 2019-09-25 Rohm and Haas Company Method of determining the inertness of materials for use in monomer production
CN107282056B (zh) * 2016-04-13 2020-12-29 中国石油化工股份有限公司 丙烯氧化合成丙烯醛和丙烯酸的催化剂
EP3770145A1 (en) 2019-07-24 2021-01-27 Basf Se A process for the continuous production of either acrolein or acrylic acid as the target product from propene
CN111138266B (zh) * 2019-11-18 2023-07-14 中国寰球工程有限公司 丙烯酸或甲基丙烯酸的制备方法及其装置
CN111116335B (zh) * 2019-11-25 2023-05-23 中国寰球工程有限公司 丙烯醛或甲基丙烯醛的制备方法
CN114380677B (zh) * 2020-10-16 2023-12-19 万华化学集团股份有限公司 一种3-甲基-2-丁烯醛的制备方法

Family Cites Families (33)

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US3198750A (en) * 1962-12-26 1965-08-03 Standard Oil Co Mixed antimony oxide-uranium oxide oxidation catalyst
NL125238C (es) * 1962-06-11
US3251899A (en) * 1962-06-11 1966-05-17 Standard Oil Co Process for the dehydrogenation of olefins
DE2202734A1 (de) * 1964-07-09 1973-07-26 Rohm & Haas Verfahren zur herstellung von acrolein
GB1035147A (en) * 1964-11-25 1966-07-06 Nippon Catalytic Chem Ind Manufacture of unsaturated aliphatic carboxylic acids
US3428674A (en) * 1965-01-11 1969-02-18 Standard Oil Co Process of oxidation of olefins to unsaturated aldehydes and acids
US3308151A (en) * 1965-01-11 1967-03-07 Standard Oil Co Process for the oxidation of olefinammonia mixtures to unsaturated nitriles
FR1588807A (es) * 1968-05-13 1970-03-16
DE1793302A1 (de) * 1968-08-28 1971-07-01 Knapsack Ag Verfahren zur Herstellung von Acrylsaeure aus Propylen
NL6918448A (es) * 1968-12-16 1970-06-18
BE749305A (fr) * 1969-05-02 1970-10-01 Nippon Kayaku Kk Catalyseur d'oxydation et son utilisation (
CH557198A (de) * 1970-02-27 1974-12-31 Degussa Katalysator fuer die oxydation von (alpha),(beta)-ungesaettigten aldehyden zu (alpha),(beta)-ungesaettigten carbonsaeuren und verfahren zu seiner herstellung.
US3867345A (en) * 1970-02-27 1975-02-18 Degussa Method for the oxidizing alpha, beta-unsaturated aldehydes to alpha, beta-unsaturated carboxylic acids
DE2056614C3 (de) * 1970-11-18 1981-04-16 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Acrylsäure aus Propylen
DE2251364B2 (de) * 1971-10-22 1975-07-03 Asahi Glass Co. Ltd., Tokio Verfahren zur Herstellung von Acrylsäure bzw. Methacrylsäure aus Acrolein bzw. Methacrolein
DE2309657A1 (de) * 1973-02-27 1974-09-12 Basf Ag Verfahren zur herstellung von carbonsaeuren oder dicarbonsaeureanhydriden
DE2436818C3 (de) * 1974-07-31 1985-05-09 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Acrylsäure durch Oxidation von Propylen mit Sauerstoff enthaltenden Gasen in zwei getrennten Oxidationsstufen
US4049577A (en) * 1975-12-15 1977-09-20 The Dow Chemical Company Catalyst for making acrolein
JPS52108917A (en) * 1976-03-11 1977-09-12 Nippon Shokubai Kagaku Kogyo Co Ltd Preparation of acrylic acid by vapor-phase catalytic oxidation of prop ylene
AU514315B2 (en) * 1977-06-22 1981-02-05 Dow Chemical Company, The Catalyst and use thereof
US4224187A (en) * 1978-11-13 1980-09-23 Celanese Corporation Olefin oxidation catalyst and process for its preparation
US4267386A (en) * 1978-11-13 1981-05-12 Celanese Corporation Olefin oxidation catalyst
JPS55102536A (en) * 1979-01-30 1980-08-05 Mitsubishi Petrochem Co Ltd Preparation of acrylic acid
JPS55113730A (en) * 1979-02-26 1980-09-02 Mitsubishi Petrochem Co Ltd Preparation of acrolein and acrylic acid
EP0117146B1 (en) * 1983-02-22 1986-12-30 The Halcon Sd Group, Inc. Conversion of propane to acrylic acid
US5198578A (en) * 1986-07-17 1993-03-30 Union Carbide Chemicals Anhydrous diluents for the propylene oxidation reaction to acrolein and acrolein oxidation to acrylic acid
CA1299193C (en) * 1986-07-17 1992-04-21 Gordon Gene Harkreader Anhydrous diluents for the propylene oxidation reaction to acrolein and acrolein oxidation to acrylic acid
CA1305178C (en) * 1986-08-21 1992-07-14 Gordon Gene Harkreader Anhydrous diluent process for the propylene oxidation reaction to acrolein and acrolein oxidation to acrylic acid
AU606160B2 (en) * 1987-05-27 1991-01-31 Nippon Shokubai Kagaku Kogyo Co. Ltd. Process for production of acrylic acid
US5218146A (en) * 1987-05-27 1993-06-08 Nippon Shokubai Kagaku Kogyo Co., Ltd. Process for production of acrylic acid
CN1025731C (zh) * 1988-09-26 1994-08-24 联合碳化化学品及塑料有限公司 异丁烯氧化成异丁烯醛和异丁烯醛氧化成异丁烯酸的无水稀释剂
DE4431957A1 (de) * 1994-09-08 1995-03-16 Basf Ag Verfahren zur katalytischen Gasphasenoxidation von Propen zu Acrolein
DE4431949A1 (de) * 1994-09-08 1995-03-16 Basf Ag Verfahren zur katalytischen Gasphasenoxidation von Acrolein zu Acrylsäure

Also Published As

Publication number Publication date
CA2171415A1 (en) 1996-09-11
SG42369A1 (en) 1997-08-15
DE59602040D1 (de) 1999-07-08
ID17854A (id) 1998-01-29
JPH08245445A (ja) 1996-09-24
US5684188A (en) 1997-11-04
CN1062260C (zh) 2001-02-21
CN1139098A (zh) 1997-01-01
EP0731082A1 (de) 1996-09-11
KR960034157A (ko) 1996-10-22
CZ73496A3 (en) 1996-09-11
EP0731082B1 (de) 1999-06-02

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