JPH0657730B2 - オレフイン重合固体触媒成分の製造法 - Google Patents
オレフイン重合固体触媒成分の製造法Info
- Publication number
- JPH0657730B2 JPH0657730B2 JP60073674A JP7367485A JPH0657730B2 JP H0657730 B2 JPH0657730 B2 JP H0657730B2 JP 60073674 A JP60073674 A JP 60073674A JP 7367485 A JP7367485 A JP 7367485A JP H0657730 B2 JPH0657730 B2 JP H0657730B2
- Authority
- JP
- Japan
- Prior art keywords
- mineral oil
- solid
- amount
- hydrocarbon
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- 239000011949 solid catalyst Substances 0.000 title claims description 10
- 150000001336 alkenes Chemical class 0.000 title claims description 6
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims description 6
- 239000002480 mineral oil Substances 0.000 claims description 43
- 235000010446 mineral oil Nutrition 0.000 claims description 43
- 229930195733 hydrocarbon Natural products 0.000 claims description 29
- 150000002430 hydrocarbons Chemical class 0.000 claims description 28
- 239000004215 Carbon black (E152) Substances 0.000 claims description 26
- 239000007788 liquid Substances 0.000 claims description 22
- 239000007787 solid Substances 0.000 claims description 18
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 238000009835 boiling Methods 0.000 claims description 10
- 239000011148 porous material Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims description 6
- 238000001704 evaporation Methods 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 230000008020 evaporation Effects 0.000 claims description 5
- 150000004703 alkoxides Chemical group 0.000 claims description 4
- 150000008282 halocarbons Chemical class 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- 239000000047 product Substances 0.000 claims description 3
- 239000012265 solid product Substances 0.000 claims description 3
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 claims description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 2
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 239000011541 reaction mixture Substances 0.000 claims description 2
- 230000002140 halogenating effect Effects 0.000 claims 2
- 125000005843 halogen group Chemical group 0.000 claims 1
- 239000012263 liquid product Substances 0.000 claims 1
- 239000003054 catalyst Substances 0.000 description 37
- 230000000694 effects Effects 0.000 description 14
- 239000000843 powder Substances 0.000 description 13
- 238000006116 polymerization reaction Methods 0.000 description 11
- 239000002002 slurry Substances 0.000 description 10
- 239000010936 titanium Substances 0.000 description 10
- 229910052719 titanium Inorganic materials 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 8
- -1 magnesium halide Chemical class 0.000 description 8
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 7
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000012188 paraffin wax Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000002685 polymerization catalyst Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000012967 coordination catalyst Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000002195 soluble material Substances 0.000 description 2
- 230000000707 stereoselective effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- RVDLHGSZWAELAU-UHFFFAOYSA-N 5-tert-butylthiophene-2-carbonyl chloride Chemical compound CC(C)(C)C1=CC=C(C(Cl)=O)S1 RVDLHGSZWAELAU-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000002879 Lewis base Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000002367 halogens Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229920001580 isotactic polymer Polymers 0.000 description 1
- 150000007527 lewis bases Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229920000576 tactic polymer Polymers 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/903—Monomer polymerized in presence of transition metal containing catalyst and hydrocarbon additive affecting polymer properties of catalyst activity
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/598,616 US4548915A (en) | 1984-04-10 | 1984-04-10 | Olefin polymerization catalyst composition |
| US598616 | 1984-04-10 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60229906A JPS60229906A (ja) | 1985-11-15 |
| JPH0657730B2 true JPH0657730B2 (ja) | 1994-08-03 |
Family
ID=24396285
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60073674A Expired - Lifetime JPH0657730B2 (ja) | 1984-04-10 | 1985-04-09 | オレフイン重合固体触媒成分の製造法 |
Country Status (18)
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06104682B2 (ja) * | 1985-08-29 | 1994-12-21 | 三井石油化学工業株式会社 | チタン触媒成分の乾燥方法 |
| FR2597486B1 (fr) * | 1986-04-18 | 1992-09-11 | Chemopetrol Koncernova Ucelova | Catalyseur et procede pour la production de polymeres et de copolymeres de 1-alcenes. |
| US5236962A (en) * | 1989-04-28 | 1993-08-17 | Himont Incorporated | Crystalline propylene polymers and copolymers in the form of spherical particles at high porosity |
| GB8911611D0 (en) * | 1989-05-19 | 1989-07-05 | Shell Int Research | Viscosity modification of mineral oils |
| IT1241094B (it) * | 1990-03-30 | 1993-12-29 | Himont Inc | Polimeri del propilene iperpuri (capacitor grade) |
| CZ34998A3 (cs) * | 1997-02-17 | 1999-08-11 | Pcd Polymere Gesellschaft M. B. H. | Způsob přípravy pevného nosiče pro katalyzátory polymerace olefinů |
| TW396168B (en) * | 1997-08-28 | 2000-07-01 | Toho Titanium K K | Solid catalyst component and catalyst for polymerization of olefins |
| US5962361A (en) * | 1998-10-14 | 1999-10-05 | Union Carbide Chemicals & Plastics Technology Corporation | Methods of making and using catalyst precursor |
| BE1012364A3 (fr) * | 1998-12-22 | 2000-10-03 | Solvay | Procede pour la preparation d'une composition catalytique pour la polymerisation des alpha-olefines, composition catalytique obtenue et procede de polymerisation utilisant une telle composition catalytique |
| KR100389475B1 (ko) * | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | 에틸렌 중합 또는 공중합용 촉매의 제조 방법 |
| US6777366B2 (en) * | 2001-02-13 | 2004-08-17 | Fina Technology, Inc. | Method for the preparation of metallocene catalysts |
| US20030022786A1 (en) * | 2001-05-03 | 2003-01-30 | Epstein Ronald A. | Catalyst for propylene polymerization |
| JP2004527636A (ja) | 2001-05-29 | 2004-09-09 | ユニオン・カーバイド・ケミカルズ・アンド・プラスチックス・テクノロジー・コーポレーション | オレフィン重合触媒組成物及びその製造方法 |
| US6825146B2 (en) * | 2001-05-29 | 2004-11-30 | Union Carbide Chemicals & Plastics Technology Corporation | Olefin polymerization catalyst compositions and method of preparation |
| KR100999827B1 (ko) | 2002-06-14 | 2010-12-10 | 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크날러지 엘엘씨 | 촉매 조성물 및 전자 공여체의 혼합물을 사용하는 중합 방법 |
| US7202313B2 (en) * | 2003-03-28 | 2007-04-10 | Union Carbide Chemicals & Plastics Technology Corporation | Chromium-based catalysts in mineral oil for production of polyethylene |
| AU2004260929A1 (en) * | 2003-05-12 | 2005-02-10 | Union Carbide Chemicals & Plastics Technology Corporation | Process for control of polymer fines in a gas-phase polymerization |
| ES2335409T3 (es) * | 2003-06-24 | 2010-03-26 | UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY LLC | Composicion catalitica y proceso de polimerizacion usando mezcla de donadores y electrones de tipo silano. |
| EP1660545A1 (en) * | 2003-08-29 | 2006-05-31 | Dow Global Technologies Inc. | Method for making partially dried readily dispersible olefin polymerization procatalyst |
| KR101114748B1 (ko) | 2003-09-23 | 2012-03-05 | 다우 글로벌 테크놀로지스 엘엘씨 | 자가 제한 촉매 조성물 및 프로필렌 중합 방법 |
| CZ2006179A3 (cs) * | 2003-09-23 | 2007-01-31 | Dow Global Technologies Inc. | Kompozice katalyzátoru s interním donorem na bázi esteru momokarboxylové kyseliny a polymerační proces propylenu |
| US7393910B2 (en) * | 2003-09-23 | 2008-07-01 | Dow Global Technologies Inc. | Catalyst composition for ethylene polymerization |
| JP2007505983A (ja) * | 2003-09-23 | 2007-03-15 | ユニオン・カーバイド・ケミカルズ・アンド・プラスティックス・テクノロジー・コーポレイション | 混合された選択性制御剤を有する触媒組成物、及びプロピレン重合方法 |
| ATE547438T1 (de) | 2003-09-23 | 2012-03-15 | Union Carbide Chem Plastic | Selbstlöschende katalysatorzusammensetzung mit monocarbonsäure als internem donator und propylenpolymerisationsverfahren |
| US7381779B2 (en) * | 2003-09-23 | 2008-06-03 | Dow Global Technologies Inc | Self limiting catalyst composition with dicarboxylic acid ester internal donor and propylene polymerization process |
| CN1938340A (zh) * | 2004-04-07 | 2007-03-28 | 联合碳化化学及塑料技术公司 | 烯烃聚合前催化剂组合物及其制备方法 |
| CA2740755C (en) | 2011-05-25 | 2019-01-15 | Nova Chemicals Corporation | Chromium catalysts for olefin polymerization |
| EP2610272B1 (en) * | 2011-12-30 | 2017-05-10 | Borealis AG | Catalyst component |
| JP7023322B2 (ja) * | 2020-05-27 | 2022-02-21 | 東邦チタニウム株式会社 | オレフィン類重合用触媒の製造方法 |
| CN116769082A (zh) * | 2023-06-20 | 2023-09-19 | 万华化学集团股份有限公司 | 一种耐沉降丙烯聚合用催化剂的制备方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55135105A (en) * | 1979-04-10 | 1980-10-21 | Mitsui Petrochem Ind Ltd | Titanium catalyst component for olefin polymerization |
| EP0019312B1 (en) * | 1979-04-30 | 1983-08-17 | Shell Internationale Researchmaatschappij B.V. | Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions |
| CA1141093A (en) * | 1979-05-17 | 1983-02-08 | Brian L. Goodall | Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions |
| DE3269975D1 (en) * | 1981-08-07 | 1986-04-24 | Ici Plc | Spraying solid |
| US4472521A (en) * | 1982-12-20 | 1984-09-18 | Stauffer Chemical Company | Supported catalyst for polymerization of olefins |
| IN163585B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1983-09-20 | 1988-10-15 | Shell Int Research |
-
1984
- 1984-04-10 US US06/598,616 patent/US4548915A/en not_active Expired - Lifetime
-
1985
- 1985-03-12 CA CA000476280A patent/CA1236822A/en not_active Expired
- 1985-03-13 IN IN210/DEL/85A patent/IN160759B/en unknown
- 1985-03-15 AT AT85200393T patent/ATE47716T1/de not_active IP Right Cessation
- 1985-03-15 DE DE8585200393T patent/DE3574021D1/de not_active Expired
- 1985-03-15 EP EP85200393A patent/EP0159736B1/en not_active Expired
- 1985-04-04 NZ NZ211685A patent/NZ211685A/en unknown
- 1985-04-08 KR KR1019850002354A patent/KR930001352B1/ko not_active Expired - Fee Related
- 1985-04-09 NO NO851402A patent/NO163332C/no unknown
- 1985-04-09 PT PT80253A patent/PT80253B/pt not_active IP Right Cessation
- 1985-04-09 JP JP60073674A patent/JPH0657730B2/ja not_active Expired - Lifetime
- 1985-04-09 ES ES542047A patent/ES8602853A1/es not_active Expired
- 1985-04-09 AU AU40923/85A patent/AU566633B2/en not_active Ceased
- 1985-04-09 BR BR8501658A patent/BR8501658A/pt not_active IP Right Cessation
- 1985-04-09 ZA ZA852599A patent/ZA852599B/xx unknown
- 1985-04-09 AR AR85300002A patent/AR242347A1/es active
- 1985-04-09 DD DD85274975A patent/DD232055A5/de not_active IP Right Cessation
-
1990
- 1990-08-09 HK HK624/90A patent/HK62490A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ES542047A0 (es) | 1985-12-01 |
| NO163332B (no) | 1990-01-29 |
| NZ211685A (en) | 1987-07-31 |
| KR930001352B1 (ko) | 1993-02-27 |
| KR850007438A (ko) | 1985-12-04 |
| NO163332C (no) | 1990-05-09 |
| DD232055A5 (de) | 1986-01-15 |
| IN160759B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1987-08-01 |
| ES8602853A1 (es) | 1985-12-01 |
| EP0159736A3 (en) | 1987-02-04 |
| PT80253A (en) | 1985-05-01 |
| ZA852599B (en) | 1985-11-27 |
| JPS60229906A (ja) | 1985-11-15 |
| ATE47716T1 (de) | 1989-11-15 |
| AU4092385A (en) | 1985-10-17 |
| EP0159736B1 (en) | 1989-11-02 |
| US4548915A (en) | 1985-10-22 |
| DE3574021D1 (en) | 1989-12-07 |
| AR242347A1 (es) | 1993-03-31 |
| AU566633B2 (en) | 1987-10-22 |
| CA1236822A (en) | 1988-05-17 |
| NO851402L (no) | 1985-10-11 |
| BR8501658A (pt) | 1985-12-10 |
| PT80253B (en) | 1986-11-20 |
| EP0159736A2 (en) | 1985-10-30 |
| HK62490A (en) | 1990-08-17 |
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