JPH04500814A - ゼオライト上におけるナフタレンの選択的シクロアルキル化 - Google Patents
ゼオライト上におけるナフタレンの選択的シクロアルキル化Info
- Publication number
- JPH04500814A JPH04500814A JP2509920A JP50992090A JPH04500814A JP H04500814 A JPH04500814 A JP H04500814A JP 2509920 A JP2509920 A JP 2509920A JP 50992090 A JP50992090 A JP 50992090A JP H04500814 A JPH04500814 A JP H04500814A
- Authority
- JP
- Japan
- Prior art keywords
- naphthalene
- zeolite
- temperature
- reaction
- product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
- C07C2/861—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only halogen as hetero-atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
- C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
- C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Saccharide Compounds (AREA)
- Catalysts (AREA)
- Pyrane Compounds (AREA)
- Artificial Filaments (AREA)
- Ultra Sonic Daignosis Equipment (AREA)
- Fats And Perfumes (AREA)
Abstract
Description
Claims (14)
- 1.少なくとも1つの脂環式基をもってナフタレンをシクロアルキル化する方法 において、a)触媒として、6,7オングストローム以上の細孔開口と、2,5 以上のシリカ/アルミナ比と、3%以下のアルカリイオン残留率とを有するフォ ージャサイト構造の少なくとも1種のゼオライトを使用する事、b)反応は前記 ゼオライトを反応媒質中に懸濁させて、20℃〜250℃の温度で、最高30バ ールの圧のもとに、固液不均一相で不連続的に実施される事、およびc)アルキ ル化剤/ナフタレンのモル比は少なくとも1に等しい事を特徴とする方法。
- 2.ゼオライトは1%以下のアルカリイオン残留率を有する事を特徴とする請求 項1に記載の方法。
- 3.前記温度が少なくとも50℃、最高220℃に等しい事を特徴とする請求項 1または2のいずれかに記載の方法。
- 4.アルキル化は本質的にまたは完全にモノアルキル化である事を特徴とする請 求項3に記載の方法。
- 5.温度は少なくとも50℃、最高140℃とする事を特徴とする請求項4に記 載の方法。
- 6.アルキル化は本質的にまたは完全にジアルキル化である事を特徴とする請求 項3に記載の方法。
- 7.温度は140℃以上、最高220℃に等しい事を特徴とする請求項6に記載 の方法。
- 8.シクロアルキル化はシクロヘキシル化である事を特徴とする請求項1乃至7 のいずれかに記載の方法。
- 9.ジシクロヘキシルー2,6ナフタレンを得る事のできる事を特徴とする請求 項8に記載の方法。
- 10.請求項1乃至9のいずれかに記載の方法によって得られたシクロアルキル 化ナフタレン。
- 11.少なくとも1つのシクロヘキシル基を含むナフタレンである事を特徴とす る請求項10に記載の生成物。
- 12.モノシクロヘキシルナフタレンである事を特徴とする請求項11に記載の 生成物。
- 13.ジシクロヘキシルナフタレンである事を特徴とする請求項11に記載の生 成物。
- 14.ジシクロヘキシルー2,6ナフタレンである事を特徴とする請求項13に 記載の生成物。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR89/10322 | 1989-07-26 | ||
FR8910322A FR2650273B1 (fr) | 1989-07-26 | 1989-07-26 | Cycloalkylation de composes aromatiques sur zeolithes |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH04500814A true JPH04500814A (ja) | 1992-02-13 |
JP2856907B2 JP2856907B2 (ja) | 1999-02-10 |
Family
ID=9384331
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2509920A Expired - Fee Related JP2856907B2 (ja) | 1989-07-26 | 1990-07-23 | ゼオライト上におけるナフタレンの選択的シクロアルキル化 |
Country Status (12)
Country | Link |
---|---|
US (1) | US5292978A (ja) |
EP (1) | EP0435984B1 (ja) |
JP (1) | JP2856907B2 (ja) |
KR (1) | KR0182611B1 (ja) |
AT (1) | ATE120165T1 (ja) |
AU (1) | AU631673B2 (ja) |
BR (1) | BR9006869A (ja) |
CA (1) | CA2034503C (ja) |
DE (1) | DE69018048T2 (ja) |
ES (1) | ES2070326T3 (ja) |
FR (1) | FR2650273B1 (ja) |
WO (1) | WO1991001959A1 (ja) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2659648B1 (fr) * | 1990-03-13 | 1993-02-12 | Michelin Rech Tech | Procede pour preparer un produit aromatique alkyle avec une zeolithe d'alkylation et une zeolithe de dealkylation. |
FR2778577B1 (fr) | 1998-05-18 | 2000-07-13 | Look Fixations Sa | Vis de reglage de precompression pour fixation de ski |
US9238599B2 (en) | 2011-12-07 | 2016-01-19 | Exxonmobil Chemical Patents Inc. | Alkylaromatic process |
CN108516919B (zh) * | 2018-03-21 | 2021-04-13 | 吉林化工学院 | 一种萘的环已基衍生物的制备方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60143508A (ja) * | 1983-12-30 | 1985-07-29 | 日本石油化学株式会社 | 新規な電気絶縁油および油含浸電気機器 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE638756C (ja) * | ||||
US2229018A (en) * | 1938-09-29 | 1941-01-14 | Dow Chemical Co | Poly-cyclohexyl-naphthalenes |
US2904607A (en) * | 1957-01-29 | 1959-09-15 | Exxon Research Engineering Co | Alkylation of aromatics |
US3515680A (en) * | 1966-09-29 | 1970-06-02 | Air Prod & Chem | Contact masses containing faujasite |
US3513108A (en) * | 1967-11-30 | 1970-05-19 | Mobil Oil Corp | Hydrothermally stable catalyst and method for its preparation |
BE735729A (ja) * | 1968-07-09 | 1970-01-07 | ||
US3641177A (en) * | 1969-11-26 | 1972-02-08 | Exxon Research Engineering Co | Alkylation of aromatic hydrocarbons |
US3773652A (en) * | 1970-10-13 | 1973-11-20 | Texaco Development Corp | Jet fuel manufacture |
DE2208363A1 (de) * | 1972-02-23 | 1973-09-13 | Union Rheinische Braunkohlen | Verfahren zur alkylierung von naphthalin |
US3786106A (en) * | 1972-10-04 | 1974-01-15 | Phillips Petroleum Co | Cycloalkylaromatic production |
FR2659648B1 (fr) * | 1990-03-13 | 1993-02-12 | Michelin Rech Tech | Procede pour preparer un produit aromatique alkyle avec une zeolithe d'alkylation et une zeolithe de dealkylation. |
US5118896A (en) * | 1990-10-31 | 1992-06-02 | Amoco Corporation | Aromatic alkylation process using large macropore, small particle size, zeolite catalyst |
-
1989
- 1989-07-26 FR FR8910322A patent/FR2650273B1/fr not_active Expired - Lifetime
-
1990
- 1990-07-23 EP EP90910513A patent/EP0435984B1/fr not_active Expired - Lifetime
- 1990-07-23 BR BR909006869A patent/BR9006869A/pt not_active IP Right Cessation
- 1990-07-23 DE DE69018048T patent/DE69018048T2/de not_active Expired - Fee Related
- 1990-07-23 ES ES90910513T patent/ES2070326T3/es not_active Expired - Lifetime
- 1990-07-23 WO PCT/CH1990/000178 patent/WO1991001959A1/fr active IP Right Grant
- 1990-07-23 CA CA002034503A patent/CA2034503C/fr not_active Expired - Fee Related
- 1990-07-23 JP JP2509920A patent/JP2856907B2/ja not_active Expired - Fee Related
- 1990-07-23 US US07/656,152 patent/US5292978A/en not_active Expired - Lifetime
- 1990-07-23 AT AT90910513T patent/ATE120165T1/de not_active IP Right Cessation
- 1990-07-23 AU AU60307/90A patent/AU631673B2/en not_active Ceased
-
1991
- 1991-03-25 KR KR1019910700312A patent/KR0182611B1/ko not_active IP Right Cessation
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60143508A (ja) * | 1983-12-30 | 1985-07-29 | 日本石油化学株式会社 | 新規な電気絶縁油および油含浸電気機器 |
Also Published As
Publication number | Publication date |
---|---|
JP2856907B2 (ja) | 1999-02-10 |
AU6030790A (en) | 1991-03-11 |
BR9006869A (pt) | 1991-08-27 |
WO1991001959A1 (fr) | 1991-02-21 |
EP0435984B1 (fr) | 1995-03-22 |
ATE120165T1 (de) | 1995-04-15 |
KR920701085A (ko) | 1992-08-11 |
DE69018048D1 (de) | 1995-04-27 |
CA2034503A1 (fr) | 1991-01-27 |
KR0182611B1 (en) | 1999-05-15 |
AU631673B2 (en) | 1992-12-03 |
CA2034503C (fr) | 2001-04-24 |
DE69018048T2 (de) | 1995-08-03 |
FR2650273A1 (fr) | 1991-02-01 |
FR2650273B1 (fr) | 1992-12-24 |
EP0435984A1 (fr) | 1991-07-10 |
US5292978A (en) | 1994-03-08 |
ES2070326T3 (es) | 1995-06-01 |
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