KR920701085A - 제올라이트상에서 나프탈렌의 선택적 사이클로알킬화 - Google Patents

제올라이트상에서 나프탈렌의 선택적 사이클로알킬화

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Publication number
KR920701085A
KR920701085A KR1019910700312A KR910700312A KR920701085A KR 920701085 A KR920701085 A KR 920701085A KR 1019910700312 A KR1019910700312 A KR 1019910700312A KR 910700312 A KR910700312 A KR 910700312A KR 920701085 A KR920701085 A KR 920701085A
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KR
South Korea
Prior art keywords
naphthalene
zeolite
product
temperature
pct
Prior art date
Application number
KR1019910700312A
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English (en)
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KR0182611B1 (en
Inventor
솔로포 조니스
모로 파트리쓰
제네스뜨 파트릭
피니엘 아니
Original Assignee
미쉘 에르띠에르
미슈렝 리쉐르쉬 에 테크니끄 에스. 아.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by 미쉘 에르띠에르, 미슈렝 리쉐르쉬 에 테크니끄 에스. 아. filed Critical 미쉘 에르띠에르
Publication of KR920701085A publication Critical patent/KR920701085A/ko
Application granted granted Critical
Publication of KR0182611B1 publication Critical patent/KR0182611B1/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/861—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only halogen as hetero-atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Saccharide Compounds (AREA)
  • Catalysts (AREA)
  • Pyrane Compounds (AREA)
  • Ultra Sonic Daignosis Equipment (AREA)
  • Fats And Perfumes (AREA)
  • Artificial Filaments (AREA)

Abstract

내용 없음

Description

제올라이트상에서 나프탈렌의 선택적 사이클로알킬화
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (14)

  1. a)기공 구멍이 6.7Å 이상이고 제올라이트의 실리카/알루미나 비율이 2.5이상이며 알칼리성 이온의 잔류 농도가 3%미만인 포자사이트 구조의 하나 이상의 제올라이트를 촉매로서 사용하며, b) 30bars의 압력하에 20내지 250℃의 온도에서 불균질한 액체/고체상에서 배치방식으로 반응을 수행하고, 제올라이트 또는 제올라이트들은 반응 매질에 현탁되며, c) 나프탈렌에 대한 알킬화제의 몰비가 적어도 1임을 특징으로 하여, 하나 이상의 사이클릭 그룹을 갖는 나플탈렌을 사이클로알킬화하는 방법.
  2. 제1항에 있어서, 제올라이트의 알칼리성 이온의 잔류농도가 1%미만임을 특징으로 하는 방법.
  3. 제1항 또는 제2항에 있어서, 온도가 50℃이상 내지 220℃이하임을 특징으로 하는 방법.
  4. 제3항에 있어서, 알킬화가 필수적으로 또는 전적으로 모노알킬화임을 특징으로 하는 벙법.
  5. 제4항에 있어서, 온도가 50℃ 이상 내지 140℃ 이하임을 특징으로 하는 방법.
  6. 제3항에 있어서, 알킬화가 필수적으로 또는 전적으로 디알킬화임을 특징으로 하는 방법.
  7. 제6항에 있어서, 온도가 140℃ 이상 내지 220℃ 이하임을 특징으로 하는 방법.
  8. 제1하 내지 제7항중의 어느 한 항에 있어서, 사이클로알킬이 사이클로헥실임을 특징으로 하는 방법.
  9. 제8항에 있어서, 2.6-디사이클로헥실나프탈렌을 수득함을 특징으로 하는 방법.
  10. 제1항 내지 제9항중의 어느 한 항에 따르는 방법으로 수득한 사이클로알킬화 나프탈렌.
  11. 제10항에 있어서, 나프탈렌이 하나 이상의 사이클로 헥실 그룹을 포함함을 특징으로 하는 생성물.
  12. 제11항에 있어서, 모노사이클로헥실 나프탈렌임을 특징으로 하는 생성물.
  13. 제11항에 있어서, 디사이클로헥실 나프탈렌임을 특징으로 하는 생성물.
  14. 제13항에 있어서, 2,6-디사이클로헥실 나프탈렌임을 특징으로 하는 생성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910700312A 1989-07-26 1991-03-25 Selective cycloalkylation naphthalene on zeolites KR0182611B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR8910322A FR2650273B1 (fr) 1989-07-26 1989-07-26 Cycloalkylation de composes aromatiques sur zeolithes
FR8910322 1989-07-26
PCT/CH1990/000178 WO1991001959A1 (fr) 1989-07-26 1990-07-23 Cycloalkylation selective du naphtalene sur zeolithes

Publications (2)

Publication Number Publication Date
KR920701085A true KR920701085A (ko) 1992-08-11
KR0182611B1 KR0182611B1 (en) 1999-05-15

Family

ID=9384331

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019910700312A KR0182611B1 (en) 1989-07-26 1991-03-25 Selective cycloalkylation naphthalene on zeolites

Country Status (12)

Country Link
US (1) US5292978A (ko)
EP (1) EP0435984B1 (ko)
JP (1) JP2856907B2 (ko)
KR (1) KR0182611B1 (ko)
AT (1) ATE120165T1 (ko)
AU (1) AU631673B2 (ko)
BR (1) BR9006869A (ko)
CA (1) CA2034503C (ko)
DE (1) DE69018048T2 (ko)
ES (1) ES2070326T3 (ko)
FR (1) FR2650273B1 (ko)
WO (1) WO1991001959A1 (ko)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2659648B1 (fr) * 1990-03-13 1993-02-12 Michelin Rech Tech Procede pour preparer un produit aromatique alkyle avec une zeolithe d'alkylation et une zeolithe de dealkylation.
FR2778577B1 (fr) 1998-05-18 2000-07-13 Look Fixations Sa Vis de reglage de precompression pour fixation de ski
US9238599B2 (en) 2011-12-07 2016-01-19 Exxonmobil Chemical Patents Inc. Alkylaromatic process
CN108516919B (zh) * 2018-03-21 2021-04-13 吉林化工学院 一种萘的环已基衍生物的制备方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE638756C (ko) *
US2229018A (en) * 1938-09-29 1941-01-14 Dow Chemical Co Poly-cyclohexyl-naphthalenes
US2904607A (en) * 1957-01-29 1959-09-15 Exxon Research Engineering Co Alkylation of aromatics
US3515680A (en) * 1966-09-29 1970-06-02 Air Prod & Chem Contact masses containing faujasite
US3513108A (en) * 1967-11-30 1970-05-19 Mobil Oil Corp Hydrothermally stable catalyst and method for its preparation
FR2012553A1 (en) * 1968-07-09 1970-03-20 Shell Int Research Alkylated aromatic compounds
US3641177A (en) * 1969-11-26 1972-02-08 Exxon Research Engineering Co Alkylation of aromatic hydrocarbons
US3773652A (en) * 1970-10-13 1973-11-20 Texaco Development Corp Jet fuel manufacture
DE2208363A1 (de) * 1972-02-23 1973-09-13 Union Rheinische Braunkohlen Verfahren zur alkylierung von naphthalin
US3786106A (en) * 1972-10-04 1974-01-15 Phillips Petroleum Co Cycloalkylaromatic production
JPH0640442B2 (ja) * 1983-12-30 1994-05-25 日本石油化学株式会社 新規な電気絶縁油
FR2659648B1 (fr) * 1990-03-13 1993-02-12 Michelin Rech Tech Procede pour preparer un produit aromatique alkyle avec une zeolithe d'alkylation et une zeolithe de dealkylation.
US5118896A (en) * 1990-10-31 1992-06-02 Amoco Corporation Aromatic alkylation process using large macropore, small particle size, zeolite catalyst

Also Published As

Publication number Publication date
KR0182611B1 (en) 1999-05-15
DE69018048D1 (de) 1995-04-27
JPH04500814A (ja) 1992-02-13
JP2856907B2 (ja) 1999-02-10
CA2034503C (fr) 2001-04-24
ATE120165T1 (de) 1995-04-15
ES2070326T3 (es) 1995-06-01
EP0435984A1 (fr) 1991-07-10
BR9006869A (pt) 1991-08-27
US5292978A (en) 1994-03-08
FR2650273B1 (fr) 1992-12-24
DE69018048T2 (de) 1995-08-03
AU631673B2 (en) 1992-12-03
EP0435984B1 (fr) 1995-03-22
WO1991001959A1 (fr) 1991-02-21
CA2034503A1 (fr) 1991-01-27
FR2650273A1 (fr) 1991-02-01
AU6030790A (en) 1991-03-11

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