AU562783B2 - Isomerization process using zeolite catalysts - Google Patents

Isomerization process using zeolite catalysts

Info

Publication number
AU562783B2
AU562783B2 AU14374/83A AU1437483A AU562783B2 AU 562783 B2 AU562783 B2 AU 562783B2 AU 14374/83 A AU14374/83 A AU 14374/83A AU 1437483 A AU1437483 A AU 1437483A AU 562783 B2 AU562783 B2 AU 562783B2
Authority
AU
Australia
Prior art keywords
zeolite catalysts
isomerization process
zeolite
highly siliceous
catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
AU14374/83A
Other versions
AU1437483A (en
Inventor
Rene Bernard Lapierre
Randall David Partiridge
Stephen Sui Fai Wong
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of AU1437483A publication Critical patent/AU1437483A/en
Application granted granted Critical
Publication of AU562783B2 publication Critical patent/AU562783B2/en
Anticipated expiration legal-status Critical
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C07C5/2791—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/06—Metal salts, or metal salts deposited on a carrier
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16J—PISTONS; CYLINDERS; SEALINGS
    • F16J15/00—Sealings
    • F16J15/02—Sealings between relatively-stationary surfaces
    • F16J15/06—Sealings between relatively-stationary surfaces with solid packing compressed between sealing surfaces
    • F16J15/08—Sealings between relatively-stationary surfaces with solid packing compressed between sealing surfaces with exclusively metal packing
    • F16J15/0818—Flat gaskets
    • F16J15/0825—Flat gaskets laminated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/12—Noble metals
    • B01J29/126—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7415—Zeolite Beta
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16J—PISTONS; CYLINDERS; SEALINGS
    • F16J15/00—Sealings
    • F16J15/02—Sealings between relatively-stationary surfaces
    • F16J15/06—Sealings between relatively-stationary surfaces with solid packing compressed between sealing surfaces
    • F16J15/08—Sealings between relatively-stationary surfaces with solid packing compressed between sealing surfaces with exclusively metal packing
    • F16J15/0818—Flat gaskets
    • F16J2015/0837—Flat gaskets with an edge portion folded over a second plate or shim
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16J—PISTONS; CYLINDERS; SEALINGS
    • F16J15/00—Sealings
    • F16J15/02—Sealings between relatively-stationary surfaces
    • F16J15/06—Sealings between relatively-stationary surfaces with solid packing compressed between sealing surfaces
    • F16J15/08—Sealings between relatively-stationary surfaces with solid packing compressed between sealing surfaces with exclusively metal packing
    • F16J15/0818—Flat gaskets
    • F16J2015/085—Flat gaskets without fold over

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Long chain (C7+) paraffins are isomerized over a large pore, highly siliceous zeolite catalyst such as zeolite Y or ZSM-20 having a structural silica:alumina ratio of at least 10:1; the use of such highly siliceous zeolites inhibits the degree of cracking and also permits weaker hydrogenation components such as palladium to be used in the catalysts.
AU14374/83A 1982-05-18 1983-05-09 Isomerization process using zeolite catalysts Expired AU562783B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US37942382A 1982-05-18 1982-05-18
US379423 1995-01-27

Publications (2)

Publication Number Publication Date
AU1437483A AU1437483A (en) 1983-11-24
AU562783B2 true AU562783B2 (en) 1987-06-18

Family

ID=23497213

Family Applications (1)

Application Number Title Priority Date Filing Date
AU14374/83A Expired AU562783B2 (en) 1982-05-18 1983-05-09 Isomerization process using zeolite catalysts

Country Status (20)

Country Link
EP (1) EP0094826B1 (en)
JP (1) JPS58210029A (en)
KR (1) KR900005096B1 (en)
AT (1) ATE18917T1 (en)
AU (1) AU562783B2 (en)
BR (1) BR8302594A (en)
CA (1) CA1219606A (en)
DE (1) DE3362760D1 (en)
DK (1) DK219983A (en)
ES (1) ES522484A0 (en)
FI (1) FI73367C (en)
GR (1) GR78564B (en)
IN (1) IN158364B (en)
MY (1) MY8700244A (en)
NO (1) NO831712L (en)
NZ (1) NZ204088A (en)
PH (1) PH17920A (en)
PT (1) PT76704B (en)
SG (1) SG77086G (en)
ZA (1) ZA833590B (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6204426B1 (en) * 1999-12-29 2001-03-20 Chevron U.S.A. Inc. Process for producing a highly paraffinic diesel fuel having a high iso-paraffin to normal paraffin mole ratio
US7279018B2 (en) 2002-09-06 2007-10-09 Fortum Oyj Fuel composition for a diesel engine
JP4848191B2 (en) * 2006-02-13 2011-12-28 Ｊｘ日鉱日石エネルギー株式会社 Method for hydrotreating synthetic oil
JP4908022B2 (en) * 2006-03-10 2012-04-04 Ｊｘ日鉱日石エネルギー株式会社 Method for producing hydrocarbon oil and hydrocarbon oil
US8581013B2 (en) 2008-06-04 2013-11-12 Syntroleum Corporation Biorenewable naphtha composition and methods of making same
US20090300971A1 (en) 2008-06-04 2009-12-10 Ramin Abhari Biorenewable naphtha
US8231804B2 (en) 2008-12-10 2012-07-31 Syntroleum Corporation Even carbon number paraffin composition and method of manufacturing same
JP5068299B2 (en) * 2009-10-19 2012-11-07 出光興産株式会社 Paraffin hydrocarbon isomerization catalyst production method and isomerization method
US9328303B2 (en) 2013-03-13 2016-05-03 Reg Synthetic Fuels, Llc Reducing pressure drop buildup in bio-oil hydroprocessing reactors
US8969259B2 (en) 2013-04-05 2015-03-03 Reg Synthetic Fuels, Llc Bio-based synthetic fluids

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1494314A (en) * 1974-01-03 1977-12-07 Shell Int Research Zeolite preparation process
JPS5121802B2 (en) * 1974-04-30 1976-07-05
BE840972A (en) * 1975-04-29 1976-10-21 HYDROCARBON CONVERSION
DD121924A1 (en) * 1975-09-22 1976-09-05
JPS5444000A (en) * 1977-09-14 1979-04-06 Matsushita Electric Ind Co Ltd Molding material for magnetic recording head element
GB2041397B (en) * 1979-01-23 1983-03-09 Mobil Oil Corp Reforming process
US4232181A (en) * 1979-06-28 1980-11-04 Norton Company Hydroisomerization of pentane utilizing Pd exchanged mordenite

Also Published As

Publication number Publication date
FI73367B (en) 1987-06-30
AU1437483A (en) 1983-11-24
MY8700244A (en) 1987-12-31
SG77086G (en) 1987-02-27
FI73367C (en) 1987-10-09
PT76704B (en) 1985-11-28
DE3362760D1 (en) 1986-05-07
JPS58210029A (en) 1983-12-07
PT76704A (en) 1983-06-01
KR840004778A (en) 1984-10-24
IN158364B (en) 1986-11-01
FI831726L (en) 1983-11-19
EP0094826B1 (en) 1986-04-02
PH17920A (en) 1985-01-31
NO831712L (en) 1983-11-21
DK219983A (en) 1983-11-19
EP0094826A1 (en) 1983-11-23
ZA833590B (en) 1984-12-24
CA1219606A (en) 1987-03-24
BR8302594A (en) 1984-01-17
JPH049773B2 (en) 1992-02-21
GR78564B (en) 1984-09-27
FI831726A0 (en) 1983-05-17
DK219983D0 (en) 1983-05-17
KR900005096B1 (en) 1990-07-19
ES8502070A1 (en) 1984-12-16
ES522484A0 (en) 1984-12-16
ATE18917T1 (en) 1986-04-15
NZ204088A (en) 1986-03-14

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Legal Events

Date Code Title Description
MK14 Patent ceased section 143(a) (annual fees not paid) or expired