JPH0416774B2 - - Google Patents
Info
- Publication number
- JPH0416774B2 JPH0416774B2 JP56106412A JP10641281A JPH0416774B2 JP H0416774 B2 JPH0416774 B2 JP H0416774B2 JP 56106412 A JP56106412 A JP 56106412A JP 10641281 A JP10641281 A JP 10641281A JP H0416774 B2 JPH0416774 B2 JP H0416774B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- silver halide
- silver
- coating
- emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- -1 silver halide Chemical class 0.000 claims description 60
- 229910052709 silver Inorganic materials 0.000 claims description 52
- 239000004332 silver Substances 0.000 claims description 52
- 238000000576 coating method Methods 0.000 claims description 37
- 239000011248 coating agent Substances 0.000 claims description 36
- 239000000839 emulsion Substances 0.000 claims description 26
- 239000000463 material Substances 0.000 claims description 23
- 230000001235 sensitizing effect Effects 0.000 claims description 20
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 13
- 230000005070 ripening Effects 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 description 21
- 239000000975 dye Substances 0.000 description 20
- 230000035945 sensitivity Effects 0.000 description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 239000000123 paper Substances 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 108010010803 Gelatin Proteins 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical class C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 206010070834 Sensitisation Diseases 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 229920000159 gelatin Polymers 0.000 description 4
- 239000008273 gelatin Substances 0.000 description 4
- 235000019322 gelatine Nutrition 0.000 description 4
- 235000011852 gelatine desserts Nutrition 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 230000008313 sensitization Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000003672 processing method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 2
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 2
- ONBQEOIKXPHGMB-VBSBHUPXSA-N 1-[2-[(2s,3r,4s,5r)-3,4-dihydroxy-5-(hydroxymethyl)oxolan-2-yl]oxy-4,6-dihydroxyphenyl]-3-(4-hydroxyphenyl)propan-1-one Chemical compound O[C@@H]1[C@H](O)[C@@H](CO)O[C@H]1OC1=CC(O)=CC(O)=C1C(=O)CCC1=CC=C(O)C=C1 ONBQEOIKXPHGMB-VBSBHUPXSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 229940126142 compound 16 Drugs 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- WJRBRSLFGCUECM-UHFFFAOYSA-N hydantoin Chemical compound O=C1CNC(=O)N1 WJRBRSLFGCUECM-UHFFFAOYSA-N 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 239000004848 polyfunctional curative Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 150000003455 sulfinic acids Chemical class 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- GHYOCDFICYLMRF-UTIIJYGPSA-N (2S,3R)-N-[(2S)-3-(cyclopenten-1-yl)-1-[(2R)-2-methyloxiran-2-yl]-1-oxopropan-2-yl]-3-hydroxy-3-(4-methoxyphenyl)-2-[[(2S)-2-[(2-morpholin-4-ylacetyl)amino]propanoyl]amino]propanamide Chemical compound C1(=CCCC1)C[C@@H](C(=O)[C@@]1(OC1)C)NC([C@H]([C@@H](C1=CC=C(C=C1)OC)O)NC([C@H](C)NC(CN1CCOCC1)=O)=O)=O GHYOCDFICYLMRF-UTIIJYGPSA-N 0.000 description 1
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical class C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 1
- AICIYIDUYNFPRY-UHFFFAOYSA-N 1,3-dihydro-2H-imidazol-2-one Chemical group O=C1NC=CN1 AICIYIDUYNFPRY-UHFFFAOYSA-N 0.000 description 1
- ODIRBFFBCSTPTO-UHFFFAOYSA-N 1,3-selenazole Chemical class C1=C[se]C=N1 ODIRBFFBCSTPTO-UHFFFAOYSA-N 0.000 description 1
- ZOBPZXTWZATXDG-UHFFFAOYSA-N 1,3-thiazolidine-2,4-dione Chemical compound O=C1CSC(=O)N1 ZOBPZXTWZATXDG-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- FYBFGAFWCBMEDG-UHFFFAOYSA-N 1-[3,5-di(prop-2-enoyl)-1,3,5-triazinan-1-yl]prop-2-en-1-one Chemical compound C=CC(=O)N1CN(C(=O)C=C)CN(C(=O)C=C)C1 FYBFGAFWCBMEDG-UHFFFAOYSA-N 0.000 description 1
- JAAIPIWKKXCNOC-UHFFFAOYSA-N 1h-tetrazol-1-ium-5-thiolate Chemical compound SC1=NN=NN1 JAAIPIWKKXCNOC-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- 125000003504 2-oxazolinyl group Chemical class O1C(=NCC1)* 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- GCSVNNODDIEGEX-UHFFFAOYSA-N 2-sulfanylidene-1,3-oxazolidin-4-one Chemical compound O=C1COC(=S)N1 GCSVNNODDIEGEX-UHFFFAOYSA-N 0.000 description 1
- UGWULZWUXSCWPX-UHFFFAOYSA-N 2-sulfanylideneimidazolidin-4-one Chemical group O=C1CNC(=S)N1 UGWULZWUXSCWPX-UHFFFAOYSA-N 0.000 description 1
- RVBUGGBMJDPOST-UHFFFAOYSA-N 2-thiobarbituric acid Chemical compound O=C1CC(=O)NC(=S)N1 RVBUGGBMJDPOST-UHFFFAOYSA-N 0.000 description 1
- QBWKPGNFQQJGFY-QLFBSQMISA-N 3-[(1r)-1-[(2r,6s)-2,6-dimethylmorpholin-4-yl]ethyl]-n-[6-methyl-3-(1h-pyrazol-4-yl)imidazo[1,2-a]pyrazin-8-yl]-1,2-thiazol-5-amine Chemical compound N1([C@H](C)C2=NSC(NC=3C4=NC=C(N4C=C(C)N=3)C3=CNN=C3)=C2)C[C@H](C)O[C@H](C)C1 QBWKPGNFQQJGFY-QLFBSQMISA-N 0.000 description 1
- PXDAXYDMZCYZNH-UHFFFAOYSA-N 3-methyl-2h-1,3-benzothiazole Chemical compound C1=CC=C2N(C)CSC2=C1 PXDAXYDMZCYZNH-UHFFFAOYSA-N 0.000 description 1
- XYVMOLOUBJBNBF-UHFFFAOYSA-N 3h-1,3-oxazol-2-one Chemical group OC1=NC=CO1 XYVMOLOUBJBNBF-UHFFFAOYSA-N 0.000 description 1
- CZWWCTHQXBMHDA-UHFFFAOYSA-N 3h-1,3-thiazol-2-one Chemical group OC1=NC=CS1 CZWWCTHQXBMHDA-UHFFFAOYSA-N 0.000 description 1
- MVVFUAACPKXXKJ-UHFFFAOYSA-N 4,5-dihydro-1,3-selenazole Chemical class C1CN=C[Se]1 MVVFUAACPKXXKJ-UHFFFAOYSA-N 0.000 description 1
- ZNBNBTIDJSKEAM-UHFFFAOYSA-N 4-[7-hydroxy-2-[5-[5-[6-hydroxy-6-(hydroxymethyl)-3,5-dimethyloxan-2-yl]-3-methyloxolan-2-yl]-5-methyloxolan-2-yl]-2,8-dimethyl-1,10-dioxaspiro[4.5]decan-9-yl]-2-methyl-3-propanoyloxypentanoic acid Chemical compound C1C(O)C(C)C(C(C)C(OC(=O)CC)C(C)C(O)=O)OC11OC(C)(C2OC(C)(CC2)C2C(CC(O2)C2C(CC(C)C(O)(CO)O2)C)C)CC1 ZNBNBTIDJSKEAM-UHFFFAOYSA-N 0.000 description 1
- OSCDSXOFFGCLQA-UHFFFAOYSA-N 4-n-ethyl-2-methylbenzene-1,4-diamine;sulfuric acid Chemical compound OS(O)(=O)=O.CCNC1=CC=C(N)C(C)=C1 OSCDSXOFFGCLQA-UHFFFAOYSA-N 0.000 description 1
- 125000002373 5 membered heterocyclic group Chemical group 0.000 description 1
- CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 description 1
- 125000004070 6 membered heterocyclic group Chemical group 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229910021612 Silver iodide Inorganic materials 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229940123464 Thiazolidinedione Drugs 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- LJOOWESTVASNOG-UFJKPHDISA-N [(1s,3r,4ar,7s,8s,8as)-3-hydroxy-8-[2-[(4r)-4-hydroxy-6-oxooxan-2-yl]ethyl]-7-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-yl] (2s)-2-methylbutanoate Chemical compound C([C@H]1[C@@H](C)C=C[C@H]2C[C@@H](O)C[C@@H]([C@H]12)OC(=O)[C@@H](C)CC)CC1C[C@@H](O)CC(=O)O1 LJOOWESTVASNOG-UFJKPHDISA-N 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- XCFIVNQHHFZRNR-UHFFFAOYSA-N [Ag].Cl[IH]Br Chemical compound [Ag].Cl[IH]Br XCFIVNQHHFZRNR-UHFFFAOYSA-N 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 1
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 1
- 150000001450 anions Chemical group 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- HNYOPLTXPVRDBG-UHFFFAOYSA-N barbituric acid Chemical group O=C1CC(=O)NC(=O)N1 HNYOPLTXPVRDBG-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 125000003785 benzimidazolyl group Chemical class N1=C(NC2=C1C=CC=C2)* 0.000 description 1
- AMTXUWGBSGZXCJ-UHFFFAOYSA-N benzo[e][1,3]benzoselenazole Chemical class C1=CC=C2C(N=C[se]3)=C3C=CC2=C1 AMTXUWGBSGZXCJ-UHFFFAOYSA-N 0.000 description 1
- KXNQKOAQSGJCQU-UHFFFAOYSA-N benzo[e][1,3]benzothiazole Chemical class C1=CC=C2C(N=CS3)=C3C=CC2=C1 KXNQKOAQSGJCQU-UHFFFAOYSA-N 0.000 description 1
- WMUIZUWOEIQJEH-UHFFFAOYSA-N benzo[e][1,3]benzoxazole Chemical class C1=CC=C2C(N=CO3)=C3C=CC2=C1 WMUIZUWOEIQJEH-UHFFFAOYSA-N 0.000 description 1
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical class C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 125000002603 chloroethyl group Chemical group [H]C([*])([H])C([H])([H])Cl 0.000 description 1
- 229940125797 compound 12 Drugs 0.000 description 1
- 229940125782 compound 2 Drugs 0.000 description 1
- 229940125846 compound 25 Drugs 0.000 description 1
- 229940127204 compound 29 Drugs 0.000 description 1
- 229940126214 compound 3 Drugs 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 125000004663 dialkyl amino group Chemical group 0.000 description 1
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000000031 ethylamino group Chemical group [H]C([H])([H])C([H])([H])N([H])[*] 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229910000378 hydroxylammonium sulfate Inorganic materials 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000002916 oxazoles Chemical class 0.000 description 1
- COWNFYYYZFRNOY-UHFFFAOYSA-N oxazolidinedione Chemical compound O=C1COC(=O)N1 COWNFYYYZFRNOY-UHFFFAOYSA-N 0.000 description 1
- 125000004095 oxindolyl group Chemical group N1(C(CC2=CC=CC=C12)=O)* 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical group O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 150000003549 thiazolines Chemical class 0.000 description 1
- RBRCCWBAMGPRSN-UHFFFAOYSA-N thieno[2,3-d][1,3]thiazole Chemical class S1C=NC2=C1C=CS2 RBRCCWBAMGPRSN-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- JLGLQAWTXXGVEM-UHFFFAOYSA-N triethylene glycol monomethyl ether Chemical compound COCCOCCOCCO JLGLQAWTXXGVEM-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/28—Sensitivity-increasing substances together with supersensitising substances
- G03C1/29—Sensitivity-increasing substances together with supersensitising substances the supersensitising mixture being solely composed of dyes ; Combination of dyes, even if the supersensitising effect is not explicitly disclosed
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/10—Organic substances
- G03C1/12—Methine and polymethine dyes
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Description
æ¬çºæã¯ããã²ã³åéåçæå
ææã®è£œé æã«
ãããŠããã²ã³åéåçä¹³å€ã調補ããåŸæ¯æäœ
äžã«å¡åžãããŸã§ã®ããã²ã³åéåçä¹³å€å¡åžæ¶²
ã®çµæå®å šæ§ã®æ¹è¯ã«é¢ãããã®ã§ããã ããã²ã³åéåçæå ææã補é ããéã«ãå
å å¢æããç§åŠçææžã®ããã²ã³åéç²åã«ãã€
ã³ããŒãçé¢æŽ»æ§å€ã硬èå€ãã«ãã©ãŒãåªæå€
ãªã©ã®å皮添å å€ãæ··åãããŠãããã²ã³åéå
çä¹³å€å¡åžæ¶²ïŒä»¥äžå¡åžæ¶²ãšç§°ãïŒã調補ããã
å·¥çšãããããã®å¡åžæ¶²ãçš®ã ã®æ¹æ³ã§æ¯æäœäž
ã«å¡åžä¹Ÿç¥ãããŠããã²ã³åéåçæå ææãåº
æ¥äžãããšã¯ããç¥ãããŠããã åèšå¡åžæ¶²ã¯ã調補åŸäžå®ã®æž©åºŠã§æ°æéãã
æ°åæéã®çµéåŸå¡åžããããããã®æéäžã¯åº
æ¥äžãã€ãããã²ã³åéåçæå ææã®å質ã¯åžž
ã«äžå®ã§ãªããŠã¯ãªããªãããããåå å¢æãã
ãããã²ã³åéåä¹³å€ãå«ãå¡åžæ¶²ã¯æéããã€
ã«ã€ãæ床å€åã段調å€åãã«ããªäžæãªã©ãã²
ããããæ¹è¯ãæãŸããŠããã®ãçŸç¶ã§ããã ãã®å¡åžæ¶²ä¿åäžã®æ§èœå€åç¹ã«æ床å€åãé²
ãããã«äŸãã°å®å®å€ãšããŠç¥ãããŠããã¢ãŸãŒ
ã«é¡ãã¢ã¶ã€ã³ãã³ååç©çãæ·»å ããæ¹æ³ãé
å å€äŸãã°ãã€ããããã³é¡ãã¹ã«ãã€ã³é žé¡ç
ãæ·»å ããæ¹æ³ããããã¯ç¹éæ49â111629å·å ¬
å ±ã«èšèŒã®æ§ã«ããç¹å®ã®å ±éåäœãšèå å¢çœå€
ã䜵çšããæ¹æ³ãªã©ãææ¡ãããŠããããããã
ã®æè¡ãå åã«æå¹ã«ãã®å¹æãçºæ®ããããšã¯
ãããªãããããã€ãŠãæ¬çºæã®ç¬¬ïŒã®ç®çã¯ã
åžžã«äžå®ãªå質ãæããããã²ã³åéåçæå æ
æãæäŸããããšã«ãããããã«ç¬¬ïŒã®ç®çã¯é·
æéã«ãããçµæå€åããªãäºãããªãã¡æ§èœå€
åã極ããŠå°ãããå®å®ãªããã²ã³åéåçä¹³å€
å¡åžæ¶²ãæäŸããããšã«ããã æã ã¯ããã®çµæã«ãããå¡åžæ¶²ã®æ§èœå€åã®
é²æ¢ãç 究ããçµæãäžèšç®çã次ã®æ§ã«ããŠé
æãããäºãèŠãåºããããªãã¡å¢æè²çŽ ã§å¢æ
ãããæå æ§ããã²ã³åéç²åãå«æããä¹³å€ã«
ãã圢æãããå±€ãå°ãªããšãïŒã€æ¯æäœäžã«èš
ããŠãªããããã²ã³åéåçæå ææã®è£œé æ¹æ³
ã«ãããŠãæå æ§ããã²ã³åéç²åã®ç§åŠçæçµ
äºåŸå¡åžåã«ãåèšå¢æè²çŽ ãæŽã«ãå ã«æå æ§
ããã²ã³åéã«äœ¿çšããéã®ïŒã500ééïŒ ã溶
解ãã溶液ããåèšä¹³å€äžã«æ·»å ããããšã«ãã€
ãŠåèšç®çãéæãããäºãèŠãåºããã æ¬çºæã«çšãããã奜ãŸããå¢æè²çŽ ã¯æ¬¡ã®äž
è¬åŒïŒ»ïŒœãã§ç€ºãããååç©ã«ããè¡šã
ãããã åŒäžR1ïŒR2ããã³R3ã¯ããããã¢ã«ãã«åº
ïŒäŸãã°ã¡ãã«åºããšãã«åºããããã«åºçïŒã眮
æã¢ã«ãã«åºïŒäŸãã°ã¯ãããšãã«åºããããã
ã·ãšãã«åºãã¡ããã·ãšãã«åºãã¢ã»ããã·ãšã
ã«åºãã«ã«ããã·ã¡ãã«åºãã«ã«ããã·ãšãã«
åºããšããã·ã«ã«ããã«ã¡ãã«åºãã¹ã«ããšãã«
åºãã¹ã«ããããã«åºãã¹ã«ãããã«åºãβâã
ãããã·ãŒïœâã¹ã«ããããã«åºããµã«ããšãŒã
ãããã«åºãã¢ãªã«åºããã³ãžã«åºçïŒãŸãã¯ã¢
ãªãŒã«åºãïŒäŸãã°ããšãã«åºãã«ã«ããã·ããš
ãã«åºãã¹ã«ãããšãã«åºçïŒããéžã°ããåºã
è¡šããïŒL1ïŒL2ããã³L3ã¯ããããã¡ãã³åºãŸ
ãã¯çœ®æã¡ãã³åºïŒäŸãã°âCHïŒåºãâïŒCH3ïŒ
ïŒåºãâïŒC2H5ïŒïŒåºãâïŒCH2COOHïŒïŒåºã â
ãããŠããã²ã³åéåçä¹³å€ã調補ããåŸæ¯æäœ
äžã«å¡åžãããŸã§ã®ããã²ã³åéåçä¹³å€å¡åžæ¶²
ã®çµæå®å šæ§ã®æ¹è¯ã«é¢ãããã®ã§ããã ããã²ã³åéåçæå ææã補é ããéã«ãå
å å¢æããç§åŠçææžã®ããã²ã³åéç²åã«ãã€
ã³ããŒãçé¢æŽ»æ§å€ã硬èå€ãã«ãã©ãŒãåªæå€
ãªã©ã®å皮添å å€ãæ··åãããŠãããã²ã³åéå
çä¹³å€å¡åžæ¶²ïŒä»¥äžå¡åžæ¶²ãšç§°ãïŒã調補ããã
å·¥çšãããããã®å¡åžæ¶²ãçš®ã ã®æ¹æ³ã§æ¯æäœäž
ã«å¡åžä¹Ÿç¥ãããŠããã²ã³åéåçæå ææãåº
æ¥äžãããšã¯ããç¥ãããŠããã åèšå¡åžæ¶²ã¯ã調補åŸäžå®ã®æž©åºŠã§æ°æéãã
æ°åæéã®çµéåŸå¡åžããããããã®æéäžã¯åº
æ¥äžãã€ãããã²ã³åéåçæå ææã®å質ã¯åžž
ã«äžå®ã§ãªããŠã¯ãªããªãããããåå å¢æãã
ãããã²ã³åéåä¹³å€ãå«ãå¡åžæ¶²ã¯æéããã€
ã«ã€ãæ床å€åã段調å€åãã«ããªäžæãªã©ãã²
ããããæ¹è¯ãæãŸããŠããã®ãçŸç¶ã§ããã ãã®å¡åžæ¶²ä¿åäžã®æ§èœå€åç¹ã«æ床å€åãé²
ãããã«äŸãã°å®å®å€ãšããŠç¥ãããŠããã¢ãŸãŒ
ã«é¡ãã¢ã¶ã€ã³ãã³ååç©çãæ·»å ããæ¹æ³ãé
å å€äŸãã°ãã€ããããã³é¡ãã¹ã«ãã€ã³é žé¡ç
ãæ·»å ããæ¹æ³ããããã¯ç¹éæ49â111629å·å ¬
å ±ã«èšèŒã®æ§ã«ããç¹å®ã®å ±éåäœãšèå å¢çœå€
ã䜵çšããæ¹æ³ãªã©ãææ¡ãããŠããããããã
ã®æè¡ãå åã«æå¹ã«ãã®å¹æãçºæ®ããããšã¯
ãããªãããããã€ãŠãæ¬çºæã®ç¬¬ïŒã®ç®çã¯ã
åžžã«äžå®ãªå質ãæããããã²ã³åéåçæå æ
æãæäŸããããšã«ãããããã«ç¬¬ïŒã®ç®çã¯é·
æéã«ãããçµæå€åããªãäºãããªãã¡æ§èœå€
åã極ããŠå°ãããå®å®ãªããã²ã³åéåçä¹³å€
å¡åžæ¶²ãæäŸããããšã«ããã æã ã¯ããã®çµæã«ãããå¡åžæ¶²ã®æ§èœå€åã®
é²æ¢ãç 究ããçµæãäžèšç®çã次ã®æ§ã«ããŠé
æãããäºãèŠãåºããããªãã¡å¢æè²çŽ ã§å¢æ
ãããæå æ§ããã²ã³åéç²åãå«æããä¹³å€ã«
ãã圢æãããå±€ãå°ãªããšãïŒã€æ¯æäœäžã«èš
ããŠãªããããã²ã³åéåçæå ææã®è£œé æ¹æ³
ã«ãããŠãæå æ§ããã²ã³åéç²åã®ç§åŠçæçµ
äºåŸå¡åžåã«ãåèšå¢æè²çŽ ãæŽã«ãå ã«æå æ§
ããã²ã³åéã«äœ¿çšããéã®ïŒã500ééïŒ ã溶
解ãã溶液ããåèšä¹³å€äžã«æ·»å ããããšã«ãã€
ãŠåèšç®çãéæãããäºãèŠãåºããã æ¬çºæã«çšãããã奜ãŸããå¢æè²çŽ ã¯æ¬¡ã®äž
è¬åŒïŒ»ïŒœãã§ç€ºãããååç©ã«ããè¡šã
ãããã åŒäžR1ïŒR2ããã³R3ã¯ããããã¢ã«ãã«åº
ïŒäŸãã°ã¡ãã«åºããšãã«åºããããã«åºçïŒã眮
æã¢ã«ãã«åºïŒäŸãã°ã¯ãããšãã«åºããããã
ã·ãšãã«åºãã¡ããã·ãšãã«åºãã¢ã»ããã·ãšã
ã«åºãã«ã«ããã·ã¡ãã«åºãã«ã«ããã·ãšãã«
åºããšããã·ã«ã«ããã«ã¡ãã«åºãã¹ã«ããšãã«
åºãã¹ã«ããããã«åºãã¹ã«ãããã«åºãβâã
ãããã·ãŒïœâã¹ã«ããããã«åºããµã«ããšãŒã
ãããã«åºãã¢ãªã«åºããã³ãžã«åºçïŒãŸãã¯ã¢
ãªãŒã«åºãïŒäŸãã°ããšãã«åºãã«ã«ããã·ããš
ãã«åºãã¹ã«ãããšãã«åºçïŒããéžã°ããåºã
è¡šããïŒL1ïŒL2ããã³L3ã¯ããããã¡ãã³åºãŸ
ãã¯çœ®æã¡ãã³åºïŒäŸãã°âCHïŒåºãâïŒCH3ïŒ
ïŒåºãâïŒC2H5ïŒïŒåºãâïŒCH2COOHïŒïŒåºã â
ãåŒãïŒåºãâïŒC6H5ïŒïŒåºã
âïŒC6H4COOHïŒïŒåºçïŒãè¡šãããZ1ïŒZ2ã¯
ããããïŒãŸãã¯ïŒå¡ã®ãããç°æ žïŒäŸãã°ãã
ã¢ãŸãªã³æ žããªããµãŸãªã³æ žãã»ã¬ããŸãªã³æ žã
ãã¢ãŸãŒã«æ žãã»ã¬ããŸãŒã«æ žããªããµãŸãŒã«
æ žããã³ãŸãã¢ãŸãŒã«æ žããã³ãŸãªããµãŸãŒã«
æ žããã³ãŸã€ãããŸãŒã«æ žãïŒïŒïŒâãžã¢ã«ãã«
ã€ã³ãã¬ãã³æ žãããããã¢ãŸãŒã«æ žãããããª
ããµãŸãŒã«æ žããããã»ã¬ããŸãŒã«æ žãããšãã
ã¢ãŸãŒã«æ žãïŒâããªãžã³æ žãïŒâããªãžã³æ žã
ïŒâãããªã³æ žãïŒâãããªã³æ žçïŒãå®æãã
ã«å¿ èŠãªåååã¯åå矀ãè¡šãããZ3ã¯çœ®æåº
ïŒäŸãã°ã¢ã«ãã«åºïŒãæããŠããŠãããïŒå¡ç°
ã圢æããã«å¿ èŠãªçåæ°ŽçŽ çŸ€ãè¡šããããã
ã³ïŒ±ã¯ããããã·ã¢ãåºãCOOR4åºãCOR4åºã
SO2R4åºãåºïŒR4ã¯ã¢ã«ãã«åºïŒQ1ããã³Q2ã¯
ãããã眮æãããã¯é眮æã®ã«ãªãªããµãŸãã³
ç°ããã©ãŸãã³ç°ããªãã·ã€ã³ããŒã«ç°ããã«ã
ããŒã«ç°ãïŒâããªãã«ãããŒã«é žãïŒïŒïŒâãª
ããµãŸãªãžã³ãžãªã³ãïŒïŒïŒâãã¢ãŸãªãžã³ãžãª
ã³ãïŒïŒïŒâã€ãããŸãªãžã³ãžãªã³ãïŒâããªâ
ïŒïŒïŒâãªããµãŸãªãžã³ãžãªã³ãïŒâããªâïŒïŒ
ïŒâãã¢ãŸãªãžã³ãžãªã³ãïŒâããªâïŒïŒïŒâã»
ã¬ããŸãªãžã³ãžãªã³ãïŒâããªâïŒïŒïŒâãã¢ãŸ
ãªãžã³ãžãªã³ãïŒâããªããã³ãã€ã³ç°ãïŒâãª
ããµãŸãªãã³ç°ãïŒâãã¢ãŸãªãã³ç°ãïŒâã€ã
ããŸãªãã³ç°ã圢æããã«å¿ èŠãªåå矀ãè¡šã
ããã¯æ°ŽçŽ ååãã¢ããåºãã¢ã«ãã«ã¢ããåº
ïŒäŸãã°ãšãã«ã¢ããåºçïŒããžã¢ã«ãã«ã¢ãã
åºãïŒäŸãã°ãžã¡ãã«ã¢ããåºçïŒããã²ã³åå
ïŒClïŒBrïŒïŒã¢ã«ã³ãã·åºïŒäŸãã°ãšããã·åº
çïŒãã¢ã«ãã«åºãïŒäŸãã°ã¡ãã«åºçïŒããéžã°
ããåºãè¡šãããm1ããã³m2ã¯ïŒãŸãã¯ïŒãè¡š
ãããn1ããã³n2ã¯ïŒïŒïŒãŸãã¯ïŒãè¡šããã
ã¯é žã¢ããªã³åºïŒäŸãã°ClïŒBrïŒïŒ©ïŒClOClïŒ
ããããïŒãŸãã¯ïŒå¡ã®ãããç°æ žïŒäŸãã°ãã
ã¢ãŸãªã³æ žããªããµãŸãªã³æ žãã»ã¬ããŸãªã³æ žã
ãã¢ãŸãŒã«æ žãã»ã¬ããŸãŒã«æ žããªããµãŸãŒã«
æ žããã³ãŸãã¢ãŸãŒã«æ žããã³ãŸãªããµãŸãŒã«
æ žããã³ãŸã€ãããŸãŒã«æ žãïŒïŒïŒâãžã¢ã«ãã«
ã€ã³ãã¬ãã³æ žãããããã¢ãŸãŒã«æ žãããããª
ããµãŸãŒã«æ žããããã»ã¬ããŸãŒã«æ žãããšãã
ã¢ãŸãŒã«æ žãïŒâããªãžã³æ žãïŒâããªãžã³æ žã
ïŒâãããªã³æ žãïŒâãããªã³æ žçïŒãå®æãã
ã«å¿ èŠãªåååã¯åå矀ãè¡šãããZ3ã¯çœ®æåº
ïŒäŸãã°ã¢ã«ãã«åºïŒãæããŠããŠãããïŒå¡ç°
ã圢æããã«å¿ èŠãªçåæ°ŽçŽ çŸ€ãè¡šããããã
ã³ïŒ±ã¯ããããã·ã¢ãåºãCOOR4åºãCOR4åºã
SO2R4åºãåºïŒR4ã¯ã¢ã«ãã«åºïŒQ1ããã³Q2ã¯
ãããã眮æãããã¯é眮æã®ã«ãªãªããµãŸãã³
ç°ããã©ãŸãã³ç°ããªãã·ã€ã³ããŒã«ç°ããã«ã
ããŒã«ç°ãïŒâããªãã«ãããŒã«é žãïŒïŒïŒâãª
ããµãŸãªãžã³ãžãªã³ãïŒïŒïŒâãã¢ãŸãªãžã³ãžãª
ã³ãïŒïŒïŒâã€ãããŸãªãžã³ãžãªã³ãïŒâããªâ
ïŒïŒïŒâãªããµãŸãªãžã³ãžãªã³ãïŒâããªâïŒïŒ
ïŒâãã¢ãŸãªãžã³ãžãªã³ãïŒâããªâïŒïŒïŒâã»
ã¬ããŸãªãžã³ãžãªã³ãïŒâããªâïŒïŒïŒâãã¢ãŸ
ãªãžã³ãžãªã³ãïŒâããªããã³ãã€ã³ç°ãïŒâãª
ããµãŸãªãã³ç°ãïŒâãã¢ãŸãªãã³ç°ãïŒâã€ã
ããŸãªãã³ç°ã圢æããã«å¿ èŠãªåå矀ãè¡šã
ããã¯æ°ŽçŽ ååãã¢ããåºãã¢ã«ãã«ã¢ããåº
ïŒäŸãã°ãšãã«ã¢ããåºçïŒããžã¢ã«ãã«ã¢ãã
åºãïŒäŸãã°ãžã¡ãã«ã¢ããåºçïŒããã²ã³åå
ïŒClïŒBrïŒïŒã¢ã«ã³ãã·åºïŒäŸãã°ãšããã·åº
çïŒãã¢ã«ãã«åºãïŒäŸãã°ã¡ãã«åºçïŒããéžã°
ããåºãè¡šãããm1ããã³m2ã¯ïŒãŸãã¯ïŒãè¡š
ãããn1ããã³n2ã¯ïŒïŒïŒãŸãã¯ïŒãè¡šããã
ã¯é žã¢ããªã³åºïŒäŸãã°ClïŒBrïŒïŒ©ïŒClOClïŒ
ãåŒãïŒCH3SO4ïŒC2H5SO4
çïŒãè¡šãããïœã¯ïŒãŸãã¯ïŒãè¡šããã
äœãååç©ãååå
å¡©ã圢æããå Žåïœã¯ïŒã
è¡šãããïŒ ä»¥äžãæ¬çºæã«ãããåèšäžè¬åŒã§ç€ºãããå¢
æè²çŽ ã®ä»£è¡šçãªå ·äœäŸã瀺ãããæ¬çºæã«äœ¿çš
ã§ããååç©ã¯ãããã«éå®ããããã®ã§ã¯ãª
ãã ïŒè²çŽ äŸäžèŠ§ïŒ æ¬çºæã«ä¿ããããã®å¢æè²çŽ ãããã²ã³åé
ç²åãå«æãã芪氎æ§ã³ãã€ãã«æ·»å ããã«ã¯æ°Ž
ãŸãã¯ãæ°Žãšä»»æã«æ··åå¯èœãªã¡ã¿ããŒã«ããšã¿
ããŒã«ãããçŽ åã¢ã«ã³ãŒã«ãïŒïŒïŒãã¿ã³ãžãª
ãŒã«ããžã¡ãã«ãã«ã ã¢ããããžãªããµã³ããã³
ãŒã³ãã¯ãããã«ã ãããªãžã³ããªã°ãã€ã³ãã¢
ã»ãã³ãããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒ
ãã«ãããªãšã¿ããŒã«ã¢ãã³ãã¡ãã«ã»ããœã«
ãããšãã«ã»ããœã«ããããšãã«ã»ããœã«ãçã®
ææ©æº¶åªã«æº¶è§£ããã®ã¡æ·»å ããã°ãããããã
ããåç¬ã«çšããŠãããããã¯ïŒçš®ä»¥äžçµåããŠ
çšããŠãããã æ¬çºæã«ãããŠä¹³å€ã®ç§åŠçæçµäºåŸå¡åžåã«
æ·»å ãããå¢æè²çŽ ã®éã«ã€ããŠãç§åŠå¡Ÿææã«
䜿çšããéã®ïŒééïŒ ä»¥äžã®å Žåã¯å¡åžæ¶²ã®çµæ
å®å šæ§ã«ã»ãšãã©å¹æããªããäžæ¹500ééïŒ ä»¥
äžã®å Žåã¯å¿ èŠä»¥äžã®æ床ã瀺ããã€çµæå®å šæ§
äžè¯ãšãªã€ãŠããŸãããããã€ãŠæ¬çºæã®ä¹³å€ã®
ç§åŠçæçµäºåŸãå¡åžåã«æ·»å ãããå¢æè²çŽ é
ã¯ç§åŠçææã«äœ¿çšããéã®ïŒã500ééïŒ ã§ã
ãã奜ãŸããã¯20ã300ééïŒ ã§ããã æ¬çºæã«çšããããããã²ã³åéä¹³å€ã¯å¡©å
éãèåéãæ²åéã®ã»ãã«æ··åããã²ã³åéäŸ
ãã°ãå¡©èåéãæ²èåéãå¡©æ²èåéçãé©çš
ããããšãã§ããããããã®ããã²ã³åéç²åã®
çæãåæ£ããã³ç©ççæã¯éåžžã®æ¹æ³æ¡ä»¶ã«ã
ã€ãŠè£œé ããããã®ã§ãããé æ··åæ³ãéæ··å
æ³ãããã«ãžãšããæ³ããã³ãããã®è€åããã
æ¹æ³ãå šã¢ã³ã¢ãã¢æ³ãããã¯éšåã¢ã³ã¢ãã¢
æ³ãã¢ã«ã«ãªæ³ãäžæ§æ³ãé žæ§æ³ããã³ãããã®
è€åãããæ¹æ³ãããã«ã¯åœæ°æ·»å æ³ãããã²ã³
å€ææ³ãåäžæ²æŸ±æ³ãªã©ãé©çšã§ãããç¹ã«ãé¢
æ°æ·»å æ³ã«ããåŸãããååæ£æ§ã®ããã²ã³åé
ç²åã«å¯ŸããŠã¯ãæ¬çºæã¯æå¹ã«çšãããããã
ãã²ã³åéç²åã®å¹³åçŽåŸã¯ç¹ã«åããªãã
0.01ÎŒã3ÎŒã奜ãŸããããããã¯å¥ã ã«åœ¢æãã
ïŒçš®ä»¥äžã®ããã²ã³åéä¹³å€ãæ··åããŠãããã æ¬çºæã«çšããããããã²ã³åéä¹³å€ã¯éåžžã®
æ¹æ³ãæ¡ä»¶ã«ãã€ãŠç§åŠå¢æããããšãã§ããã
ããªãã¡ãéé¯å¡©ãçšããéå¢ææ³ãéå ç©è³ªã
çšããéå å¢ææ³ãéã€ãªã³ãšåå¿ãããç¡«é»ã
å«ãååç©ãããããã掻æ§ãŒã©ãã³ãçšããç¡«
é»å¢ææ³ããŸãåšæ衚第æã«å±ãã貎éå±ã®å¡©
ãçšããå¢ææ³ãªã©ãçšããããšãã§ããã äžèšã®ããšãåŸãããããã²ã³åéä¹³å€ã«æå
ææã®ä¿åäžãããã¯ãçŸè±¡åŠçäžã§ã®æ床äœäž
ãã«ããªã®çºçãé²ãããã«çš®ã ã®ååç©ãæ·»å
ããããšãã§ããã ãããã®ååç©ã¯ãïŒâããããã·ãŒïŒâã¡ã
ã«âïŒïŒïŒïŒ3aïŒïŒâããã©ã¢ã¶ã€ã³ãã³ãïŒ
âã¡ãã«ãã³ãŸãã¢ãŸãŒã«ãïŒâããšãã«âïŒâ
ã¡ã«ã«ããããã©ãŸãŒã«ãã¯ããå€ãã®è€çŽ ç°å
åç©ãã¡ã«ã«ããååç©ãéå±å¡©é¡ãªã©ãç¥ãã
ãŠããã æ¬çºæã«æŒããŠã¯åçä¹³å€ã®çµåå€ãŸãã¯ä¿è·
ã³ãã€ããšããŠã¯ããŒã©ãã³ãçšããã®ãæå©ã§
ãããããã以å€ã®èŠªæ°Žæ§ã³ãã€ããçšããããš
ãã§ããã ããšãã°ãŒã©ãã³èªå°äœããŒã©ãã³ãšä»ã®é«å
åãšã®ã°ã©ããããªããŒãããããã·ãšãã«ã»ã«
ããŒã¹ãã«ã«ããã·ã¡ãã«ã»ã«ããŒã¹ãã»ã«ããŒ
ã¹ç¡«é žãšã¹ãã«é¡çã®åŠãã»ã«ããŒã¹èªå°äœãã
ãªããã«ã¢ã«ã³ãŒã«ïŒããªããã«ã¢ã«ã³ãŒã«éšå
ã¢ã»ã¿ãŒã«ãããªââããã«ãããªãã³ãããª
ã¢ã¯ãªã«é žãããªã¡ã¿ã¯ãªã«é žãããªã¢ã¯ãªã«ã¢
ããçã®åäžãããã¯å ±éåäœã®åŠãå€çš®ã®åæ
芪氎æ§é«ååç©è³ªãçšããããšãã§ããã ãŸããæ¬çºæã®ããã²ã³åéä¹³å€å¡åžæ¶²ã«ã¯ã
å ¬ç¥ã®çŸè±¡ä¿é²å€ãçé¢æŽ»æ§å€ãæ¶æ³¡å€ã垯é»é²
æ¢å€ã硬èå€ãèç©æ§æ¹è¯å€ãæ±æé²æ¢å€ãé®®é
æ§åäžå€ãåªæå€ãå¢çœå€çã®æ·»å å€ãå«æãã
ãããšãã§ããã æ¬çºæã®ããã²ã³åéåçä¹³å€ã¯äžè¬ã«é©åœãª
æ¯æäœã«å¡åžä¹Ÿç¥ãããŠããã²ã³åéåçæå æ
æã補é ããããããã®æçšããããæ¯æäœãšã
ãŠã¯çŽãã¬ã©ã¹ãã»ã«ããŒãºã¢ã»ããŒããã»ã«ã
ãŒã¹ãã€ãã¬ãŒããããªãšã¹ãã«ãããªã¢ããã
ããªã¹ãã¬ã³çã®æ¯æäœãããã¯ãäŸãã°çŽãšã
ãªãªã¬ãã€ã³ïŒããªãšãã¬ã³ãããªãããã¬ã³
çïŒãšã®ã©ãããŒãäœçã®ïŒçš®ä»¥äžã®åºè³ªã®è²Œå
ããäœçãçšããããããããŠãã®æ¯æäœã¯ãã
ãã²ã³åéä¹³å€ã«å¯Ÿããæ¥çæ§ãæ¹è¯ããããã«
äžè¬çã«çš®ã ã®è¡šé¢æ¹è¯åŠçãè¡ãªãããäŸãã°
é»åè¡æåŠççã®è¡šé¢åŠçãããã¯äžåŒå±€ãèšã
ãäžåŒåŠçãè¡ãªããããã®ãçšããããã ãã®æ¯æäœäžã«ããã²ã³åéåçä¹³å€ãå¡åžä¹Ÿ
ç¥ããã«ã¯éåžžç¥ãããŠããå¡åžæ¹æ³äŸãã°æµžæŒ¬
å¡åžãããŒã©ãŒå¡åžãããŒãå¡åžãã«ãŒãã³ãã
ãŒå¡åžçã®æ¹æ³ã§å¡åžãã次ãã§ä¹Ÿç¥ãããã æ¬çºæã¯ãäžè¬çšããã²ã³åéã«ã©ãŒåçæå
ææãã¯ãããå転åŠççšãçŽæ¥å転çšãæ¡æ£è»¢
åçšãéè²çŽ æŒçœçšçã®ã«ã©ãŒæå ææã«é©çšã§
ããã°ããã§ãªããã«ãã©ãŒãé»åçºè²ããå Žå
ãããããç¡åè²ã«ãã©ãŒã®å Žåã«ã¯ãäžè¬çšã
ãã²ã³åéçœé»åçæå ææãã¬ã³ãã²ã³çšãå°
å·çšãèªç©ºçšãé»åç·èšé²çšãªã©ã«ããããŸã§ã®
æå ææã«é©çšããããšãã§ããã 以äžæ¬çºæã®å®æœäŸã瀺ãããæ¬çºæã¯ããã«
éå®ããããã®ã§ã¯ãªãã å®æœäŸ ïŒ åèšäŸç€ºååç©ïŒã«ç€ºãå¢æè²çŽ ãéïŒã¢ã«åœ
ã2.0Ã10-4ã¢ã«æ·»å ãããååŠçæçµäºæžã¿ã®
å¡©èåéä¹³å€ïŒ»ïŒ¡ïŒœã«ãäžèšã«ç€ºãã€ãšããŒçºè²
å€ãå«æããã€ãšããŒçºè²å€åæ£æ¶²ãæ·»å åŸãè¡š
âïŒïŒNo1ãïŒïŒã«ç€ºãæ§æã«ãŠæº¶è§£ããã溶液
ãæ·»å ããããã«ç¡¬èå€ãšããŠïŒ®ïŒNâ²ïŒNâ³âã
ãªã¢ã¯ãªãã€ã«â6Hââããªã¢ãžã³ã®ïŒïŒ ã¡
ã¿ããŒã«æº¶æ¶²10mlãå ããŠå¡åžæ¶²ïŒNo1ãïŒïŒã
調補ããã åæ§ã«åèšäŸç€ºååç©ïŒã«ç€ºãå¢æè²çŽ ãéïŒ
ã¢ã«åœã2.2Ã10-4ã¢ã«æ·»å ãããå¡©èåéä¹³å€
ã«ãŠå¡åžæ¶²ïŒNo4ãïŒïŒã調補ããã åæ§ã«åèšäŸç€ºååç©ïŒã«ç€ºãå¢æè²çŽ ãéïŒ
ã¢ã«åœã1.0Ã10-4ã¢ã«ããã³äŸç€ºååç©ïŒã«ç€º
ãå¢æè²çŽ ãéïŒã¢ã«åœã1.1Ã10-4ã¢ã«æ·»å ã
ããå¡©èåéä¹³å€ïŒ»ïŒ£ïŒœã«ãŠå¡åžæ¶²ïŒNo7ãïŒïŒ
ã調補ããã ã€ãšããŒçºè²å€
è¡šãããïŒ ä»¥äžãæ¬çºæã«ãããåèšäžè¬åŒã§ç€ºãããå¢
æè²çŽ ã®ä»£è¡šçãªå ·äœäŸã瀺ãããæ¬çºæã«äœ¿çš
ã§ããååç©ã¯ãããã«éå®ããããã®ã§ã¯ãª
ãã ïŒè²çŽ äŸäžèŠ§ïŒ æ¬çºæã«ä¿ããããã®å¢æè²çŽ ãããã²ã³åé
ç²åãå«æãã芪氎æ§ã³ãã€ãã«æ·»å ããã«ã¯æ°Ž
ãŸãã¯ãæ°Žãšä»»æã«æ··åå¯èœãªã¡ã¿ããŒã«ããšã¿
ããŒã«ãããçŽ åã¢ã«ã³ãŒã«ãïŒïŒïŒãã¿ã³ãžãª
ãŒã«ããžã¡ãã«ãã«ã ã¢ããããžãªããµã³ããã³
ãŒã³ãã¯ãããã«ã ãããªãžã³ããªã°ãã€ã³ãã¢
ã»ãã³ãããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒ
ãã«ãããªãšã¿ããŒã«ã¢ãã³ãã¡ãã«ã»ããœã«
ãããšãã«ã»ããœã«ããããšãã«ã»ããœã«ãçã®
ææ©æº¶åªã«æº¶è§£ããã®ã¡æ·»å ããã°ãããããã
ããåç¬ã«çšããŠãããããã¯ïŒçš®ä»¥äžçµåããŠ
çšããŠãããã æ¬çºæã«ãããŠä¹³å€ã®ç§åŠçæçµäºåŸå¡åžåã«
æ·»å ãããå¢æè²çŽ ã®éã«ã€ããŠãç§åŠå¡Ÿææã«
䜿çšããéã®ïŒééïŒ ä»¥äžã®å Žåã¯å¡åžæ¶²ã®çµæ
å®å šæ§ã«ã»ãšãã©å¹æããªããäžæ¹500ééïŒ ä»¥
äžã®å Žåã¯å¿ èŠä»¥äžã®æ床ã瀺ããã€çµæå®å šæ§
äžè¯ãšãªã€ãŠããŸãããããã€ãŠæ¬çºæã®ä¹³å€ã®
ç§åŠçæçµäºåŸãå¡åžåã«æ·»å ãããå¢æè²çŽ é
ã¯ç§åŠçææã«äœ¿çšããéã®ïŒã500ééïŒ ã§ã
ãã奜ãŸããã¯20ã300ééïŒ ã§ããã æ¬çºæã«çšããããããã²ã³åéä¹³å€ã¯å¡©å
éãèåéãæ²åéã®ã»ãã«æ··åããã²ã³åéäŸ
ãã°ãå¡©èåéãæ²èåéãå¡©æ²èåéçãé©çš
ããããšãã§ããããããã®ããã²ã³åéç²åã®
çæãåæ£ããã³ç©ççæã¯éåžžã®æ¹æ³æ¡ä»¶ã«ã
ã€ãŠè£œé ããããã®ã§ãããé æ··åæ³ãéæ··å
æ³ãããã«ãžãšããæ³ããã³ãããã®è€åããã
æ¹æ³ãå šã¢ã³ã¢ãã¢æ³ãããã¯éšåã¢ã³ã¢ãã¢
æ³ãã¢ã«ã«ãªæ³ãäžæ§æ³ãé žæ§æ³ããã³ãããã®
è€åãããæ¹æ³ãããã«ã¯åœæ°æ·»å æ³ãããã²ã³
å€ææ³ãåäžæ²æŸ±æ³ãªã©ãé©çšã§ãããç¹ã«ãé¢
æ°æ·»å æ³ã«ããåŸãããååæ£æ§ã®ããã²ã³åé
ç²åã«å¯ŸããŠã¯ãæ¬çºæã¯æå¹ã«çšãããããã
ãã²ã³åéç²åã®å¹³åçŽåŸã¯ç¹ã«åããªãã
0.01ÎŒã3ÎŒã奜ãŸããããããã¯å¥ã ã«åœ¢æãã
ïŒçš®ä»¥äžã®ããã²ã³åéä¹³å€ãæ··åããŠãããã æ¬çºæã«çšããããããã²ã³åéä¹³å€ã¯éåžžã®
æ¹æ³ãæ¡ä»¶ã«ãã€ãŠç§åŠå¢æããããšãã§ããã
ããªãã¡ãéé¯å¡©ãçšããéå¢ææ³ãéå ç©è³ªã
çšããéå å¢ææ³ãéã€ãªã³ãšåå¿ãããç¡«é»ã
å«ãååç©ãããããã掻æ§ãŒã©ãã³ãçšããç¡«
é»å¢ææ³ããŸãåšæ衚第æã«å±ãã貎éå±ã®å¡©
ãçšããå¢ææ³ãªã©ãçšããããšãã§ããã äžèšã®ããšãåŸãããããã²ã³åéä¹³å€ã«æå
ææã®ä¿åäžãããã¯ãçŸè±¡åŠçäžã§ã®æ床äœäž
ãã«ããªã®çºçãé²ãããã«çš®ã ã®ååç©ãæ·»å
ããããšãã§ããã ãããã®ååç©ã¯ãïŒâããããã·ãŒïŒâã¡ã
ã«âïŒïŒïŒïŒ3aïŒïŒâããã©ã¢ã¶ã€ã³ãã³ãïŒ
âã¡ãã«ãã³ãŸãã¢ãŸãŒã«ãïŒâããšãã«âïŒâ
ã¡ã«ã«ããããã©ãŸãŒã«ãã¯ããå€ãã®è€çŽ ç°å
åç©ãã¡ã«ã«ããååç©ãéå±å¡©é¡ãªã©ãç¥ãã
ãŠããã æ¬çºæã«æŒããŠã¯åçä¹³å€ã®çµåå€ãŸãã¯ä¿è·
ã³ãã€ããšããŠã¯ããŒã©ãã³ãçšããã®ãæå©ã§
ãããããã以å€ã®èŠªæ°Žæ§ã³ãã€ããçšããããš
ãã§ããã ããšãã°ãŒã©ãã³èªå°äœããŒã©ãã³ãšä»ã®é«å
åãšã®ã°ã©ããããªããŒãããããã·ãšãã«ã»ã«
ããŒã¹ãã«ã«ããã·ã¡ãã«ã»ã«ããŒã¹ãã»ã«ããŒ
ã¹ç¡«é žãšã¹ãã«é¡çã®åŠãã»ã«ããŒã¹èªå°äœãã
ãªããã«ã¢ã«ã³ãŒã«ïŒããªããã«ã¢ã«ã³ãŒã«éšå
ã¢ã»ã¿ãŒã«ãããªââããã«ãããªãã³ãããª
ã¢ã¯ãªã«é žãããªã¡ã¿ã¯ãªã«é žãããªã¢ã¯ãªã«ã¢
ããçã®åäžãããã¯å ±éåäœã®åŠãå€çš®ã®åæ
芪氎æ§é«ååç©è³ªãçšããããšãã§ããã ãŸããæ¬çºæã®ããã²ã³åéä¹³å€å¡åžæ¶²ã«ã¯ã
å ¬ç¥ã®çŸè±¡ä¿é²å€ãçé¢æŽ»æ§å€ãæ¶æ³¡å€ã垯é»é²
æ¢å€ã硬èå€ãèç©æ§æ¹è¯å€ãæ±æé²æ¢å€ãé®®é
æ§åäžå€ãåªæå€ãå¢çœå€çã®æ·»å å€ãå«æãã
ãããšãã§ããã æ¬çºæã®ããã²ã³åéåçä¹³å€ã¯äžè¬ã«é©åœãª
æ¯æäœã«å¡åžä¹Ÿç¥ãããŠããã²ã³åéåçæå æ
æã補é ããããããã®æçšããããæ¯æäœãšã
ãŠã¯çŽãã¬ã©ã¹ãã»ã«ããŒãºã¢ã»ããŒããã»ã«ã
ãŒã¹ãã€ãã¬ãŒããããªãšã¹ãã«ãããªã¢ããã
ããªã¹ãã¬ã³çã®æ¯æäœãããã¯ãäŸãã°çŽãšã
ãªãªã¬ãã€ã³ïŒããªãšãã¬ã³ãããªãããã¬ã³
çïŒãšã®ã©ãããŒãäœçã®ïŒçš®ä»¥äžã®åºè³ªã®è²Œå
ããäœçãçšããããããããŠãã®æ¯æäœã¯ãã
ãã²ã³åéä¹³å€ã«å¯Ÿããæ¥çæ§ãæ¹è¯ããããã«
äžè¬çã«çš®ã ã®è¡šé¢æ¹è¯åŠçãè¡ãªãããäŸãã°
é»åè¡æåŠççã®è¡šé¢åŠçãããã¯äžåŒå±€ãèšã
ãäžåŒåŠçãè¡ãªããããã®ãçšããããã ãã®æ¯æäœäžã«ããã²ã³åéåçä¹³å€ãå¡åžä¹Ÿ
ç¥ããã«ã¯éåžžç¥ãããŠããå¡åžæ¹æ³äŸãã°æµžæŒ¬
å¡åžãããŒã©ãŒå¡åžãããŒãå¡åžãã«ãŒãã³ãã
ãŒå¡åžçã®æ¹æ³ã§å¡åžãã次ãã§ä¹Ÿç¥ãããã æ¬çºæã¯ãäžè¬çšããã²ã³åéã«ã©ãŒåçæå
ææãã¯ãããå転åŠççšãçŽæ¥å転çšãæ¡æ£è»¢
åçšãéè²çŽ æŒçœçšçã®ã«ã©ãŒæå ææã«é©çšã§
ããã°ããã§ãªããã«ãã©ãŒãé»åçºè²ããå Žå
ãããããç¡åè²ã«ãã©ãŒã®å Žåã«ã¯ãäžè¬çšã
ãã²ã³åéçœé»åçæå ææãã¬ã³ãã²ã³çšãå°
å·çšãèªç©ºçšãé»åç·èšé²çšãªã©ã«ããããŸã§ã®
æå ææã«é©çšããããšãã§ããã 以äžæ¬çºæã®å®æœäŸã瀺ãããæ¬çºæã¯ããã«
éå®ããããã®ã§ã¯ãªãã å®æœäŸ ïŒ åèšäŸç€ºååç©ïŒã«ç€ºãå¢æè²çŽ ãéïŒã¢ã«åœ
ã2.0Ã10-4ã¢ã«æ·»å ãããååŠçæçµäºæžã¿ã®
å¡©èåéä¹³å€ïŒ»ïŒ¡ïŒœã«ãäžèšã«ç€ºãã€ãšããŒçºè²
å€ãå«æããã€ãšããŒçºè²å€åæ£æ¶²ãæ·»å åŸãè¡š
âïŒïŒNo1ãïŒïŒã«ç€ºãæ§æã«ãŠæº¶è§£ããã溶液
ãæ·»å ããããã«ç¡¬èå€ãšããŠïŒ®ïŒNâ²ïŒNâ³âã
ãªã¢ã¯ãªãã€ã«â6Hââããªã¢ãžã³ã®ïŒïŒ ã¡
ã¿ããŒã«æº¶æ¶²10mlãå ããŠå¡åžæ¶²ïŒNo1ãïŒïŒã
調補ããã åæ§ã«åèšäŸç€ºååç©ïŒã«ç€ºãå¢æè²çŽ ãéïŒ
ã¢ã«åœã2.2Ã10-4ã¢ã«æ·»å ãããå¡©èåéä¹³å€
ã«ãŠå¡åžæ¶²ïŒNo4ãïŒïŒã調補ããã åæ§ã«åèšäŸç€ºååç©ïŒã«ç€ºãå¢æè²çŽ ãéïŒ
ã¢ã«åœã1.0Ã10-4ã¢ã«ããã³äŸç€ºååç©ïŒã«ç€º
ãå¢æè²çŽ ãéïŒã¢ã«åœã1.1Ã10-4ã¢ã«æ·»å ã
ããå¡©èåéä¹³å€ïŒ»ïŒ£ïŒœã«ãŠå¡åžæ¶²ïŒNo7ãïŒïŒ
ã調補ããã ã€ãšããŒçºè²å€
ãè¡šã
äžèšã®ããšã調補ãããå¡åžæ¶²ã調補åŸå³æãš
40âã§ïŒæéæŸçœ®åŸããã³40âã§ïŒæéæŸçœ®åŸã«
ããªãšãã¬ã³ã³ãŒãçŽäžã«å¡åžä¹Ÿç¥ãããã²ã³å
éåçæå ææãåŸãã ãããã®è©Šæãå æ¥é²å ãè¡ã€ãåŸãäžèšã«ç€º
ããåŠçæ¹æ³ã«åŸã€ãŠåŠç也ç¥åŸããµã¯ã©ã«ã©ãŒ
æ¿åºŠèšPDAâ60åïŒå°è¥¿å åçå·¥æ¥KK補ïŒãçš
ããŠã»ã³ã·ãã¡ããªãŒãè¡ããå³æå¡åžä¹Ÿç¥è©Šæ
ã®æ床ã100ãšããŠçžå¯Ÿæ床ãæ±ãããããã®çµ
æãè¡šâïŒã«ç€ºãã å°ãçŸååŠçæ¡ä»¶ã¯ä»¥äžã®éãã§å šãŠåæ§ã«è¡
ã€ãã åŠçå·¥çšïŒ32.8âïŒ åŠçæé çºè²çŸå ïŒå30ç§ æŒçœå®ç ïŒå30ç§ æ°ŽæŽ ïŒå30ç§ ä¹Ÿç¥ çºè²çŸå液çµæ âãšãã«ââβâã¡ã¿ã³ã¹ã«ãã³ã¢ãã ãšãã«âïŒâã¡ãã«âïŒâ ã¢ããã¢ããªã³ç¡«é žå¡© 4.0ïœ ããããã·ã«ã¢ãã³ã»ãµã«ããšãŒã 2.0ïœ çåã«ãªãŠã 25.0ïœ å¡©åãããªãŠã 0.1ïœ èåãããªãŠã 0.2ïœ ç¡æ°Žäºç¡«é žãããªãŠã 2.0ïœ ãã³ãžã«ã¢ã«ã³ãŒã« 10.0ml ããªãšãã¬ã³ã°ãªã³ãŒã« ïŒå¹³åéå床400ïŒ 3.0ml æ°Žãå ããŠïŒãšã æ°Žé žåãããªãŠã ãçšã㊠pH10.0ã«èª¿æŽããã æŒçœå®ç液çµæ ãšãã¬ã³ãžã¢ãã³ããã© é ¢é žéãããªãŠã å¡© 60.0ïœ ããªç¡«é žã¢ã³ã¢ããŠã 100.0ïœ éäºç¡«é žãããªãŠã 20.0ïœ ã¡ã¿éäºç¡«é žãããªãŠã 5.0ïœ æ°Žãå ããŠïŒãšã ç¡«é žãçšããŠpH7.0ã«èª¿æŽããã é žåéå é»äœâ70mV
40âã§ïŒæéæŸçœ®åŸããã³40âã§ïŒæéæŸçœ®åŸã«
ããªãšãã¬ã³ã³ãŒãçŽäžã«å¡åžä¹Ÿç¥ãããã²ã³å
éåçæå ææãåŸãã ãããã®è©Šæãå æ¥é²å ãè¡ã€ãåŸãäžèšã«ç€º
ããåŠçæ¹æ³ã«åŸã€ãŠåŠç也ç¥åŸããµã¯ã©ã«ã©ãŒ
æ¿åºŠèšPDAâ60åïŒå°è¥¿å åçå·¥æ¥KK補ïŒãçš
ããŠã»ã³ã·ãã¡ããªãŒãè¡ããå³æå¡åžä¹Ÿç¥è©Šæ
ã®æ床ã100ãšããŠçžå¯Ÿæ床ãæ±ãããããã®çµ
æãè¡šâïŒã«ç€ºãã å°ãçŸååŠçæ¡ä»¶ã¯ä»¥äžã®éãã§å šãŠåæ§ã«è¡
ã€ãã åŠçå·¥çšïŒ32.8âïŒ åŠçæé çºè²çŸå ïŒå30ç§ æŒçœå®ç ïŒå30ç§ æ°ŽæŽ ïŒå30ç§ ä¹Ÿç¥ çºè²çŸå液çµæ âãšãã«ââβâã¡ã¿ã³ã¹ã«ãã³ã¢ãã ãšãã«âïŒâã¡ãã«âïŒâ ã¢ããã¢ããªã³ç¡«é žå¡© 4.0ïœ ããããã·ã«ã¢ãã³ã»ãµã«ããšãŒã 2.0ïœ çåã«ãªãŠã 25.0ïœ å¡©åãããªãŠã 0.1ïœ èåãããªãŠã 0.2ïœ ç¡æ°Žäºç¡«é žãããªãŠã 2.0ïœ ãã³ãžã«ã¢ã«ã³ãŒã« 10.0ml ããªãšãã¬ã³ã°ãªã³ãŒã« ïŒå¹³åéå床400ïŒ 3.0ml æ°Žãå ããŠïŒãšã æ°Žé žåãããªãŠã ãçšã㊠pH10.0ã«èª¿æŽããã æŒçœå®ç液çµæ ãšãã¬ã³ãžã¢ãã³ããã© é ¢é žéãããªãŠã å¡© 60.0ïœ ããªç¡«é žã¢ã³ã¢ããŠã 100.0ïœ éäºç¡«é žãããªãŠã 20.0ïœ ã¡ã¿éäºç¡«é žãããªãŠã 5.0ïœ æ°Žãå ããŠïŒãšã ç¡«é žãçšããŠpH7.0ã«èª¿æŽããã é žåéå é»äœâ70mV
ãè¡šã
以äžè¡šâïŒã®ããšãæ¬çºæè©Šæã¯ãé·æéã«ã
ãã€ãŠå¡åžæ¶²ãçµæãããŠãåžžã«äžå®ãªæ床ãæ
ããŠããããšããããã å°ãããã²ã³åéç²åã®å¹³åç²åãµã€ãºã¯
0.7ÎŒmã§ããããã®ç²åºŠååžã¯ã極ããŠçãå¹³å
ç²åãµã€ãºããã®åãã¯Â±10ïŒ ä»¥å ã§ãã€ãã å®æœäŸ ïŒ åèšäŸç€ºååç©12ã«ç€ºãå¢æè²çŽ ãéïŒã¢ã«åœ
ã2.5Ã10-4ã¢ã«æ·»å ãããç§åŠçæçµäºæžã¿å¡©
èåéä¹³å€ã«äžèšã«ç€ºãããŒã³ã¿çºè²å€ãå«æã
ãããŒã³ã¿çºè²å€åæ£æ¶²ãæ·»å åŸè¡šâïŒã«ç€ºãæ§
æã«ãŠæº¶è§£ããã溶液ãæ·»å ããããã«ç¡¬èå€ãš
ããŠïŒ®ïŒNâ²ïŒNâ³âããªã¢ã¯ãªãã€ã«â6Hââ
ããªã¢ãžã³ã®ïŒïŒ ã¡ã¿ããŒã«æº¶æ¶²10mlãå ããŠå¡
åžæ¶²ã調補ããã ããŒã³ã¿çºè²å€
ãã€ãŠå¡åžæ¶²ãçµæãããŠãåžžã«äžå®ãªæ床ãæ
ããŠããããšããããã å°ãããã²ã³åéç²åã®å¹³åç²åãµã€ãºã¯
0.7ÎŒmã§ããããã®ç²åºŠååžã¯ã極ããŠçãå¹³å
ç²åãµã€ãºããã®åãã¯Â±10ïŒ ä»¥å ã§ãã€ãã å®æœäŸ ïŒ åèšäŸç€ºååç©12ã«ç€ºãå¢æè²çŽ ãéïŒã¢ã«åœ
ã2.5Ã10-4ã¢ã«æ·»å ãããç§åŠçæçµäºæžã¿å¡©
èåéä¹³å€ã«äžèšã«ç€ºãããŒã³ã¿çºè²å€ãå«æã
ãããŒã³ã¿çºè²å€åæ£æ¶²ãæ·»å åŸè¡šâïŒã«ç€ºãæ§
æã«ãŠæº¶è§£ããã溶液ãæ·»å ããããã«ç¡¬èå€ãš
ããŠïŒ®ïŒNâ²ïŒNâ³âããªã¢ã¯ãªãã€ã«â6Hââ
ããªã¢ãžã³ã®ïŒïŒ ã¡ã¿ããŒã«æº¶æ¶²10mlãå ããŠå¡
åžæ¶²ã調補ããã ããŒã³ã¿çºè²å€
ãè¡šã
äžèšã®ããšã調æŽãããå¡åžæ¶²ã調æŽåŸå³æãš
40âã§ïŒæéæŸçœ®åŸããã³40âã§ïŒæéæŸçœ®åŸã«
ããªãšãã¬ã³ã³ãŒãçŽäžã«å¡åžä¹Ÿç¥ãããã²ã³å
éåçæå ææãåŸãã ãããã®è©Šæãå æ¥é²å ãè¡ã€ãåŸãå®æœäŸâ
ïŒã«ç€ºããåŠçæ¹æ³ã«åŸã€ãŠçŸååŠç也ç¥åŸãå®
æœäŸâãšåæ§ã«çžå¯Ÿæ床ãæ±ããã ãããã®çµæãè¡šâïŒã«ç€ºãã
40âã§ïŒæéæŸçœ®åŸããã³40âã§ïŒæéæŸçœ®åŸã«
ããªãšãã¬ã³ã³ãŒãçŽäžã«å¡åžä¹Ÿç¥ãããã²ã³å
éåçæå ææãåŸãã ãããã®è©Šæãå æ¥é²å ãè¡ã€ãåŸãå®æœäŸâ
ïŒã«ç€ºããåŠçæ¹æ³ã«åŸã€ãŠçŸååŠç也ç¥åŸãå®
æœäŸâãšåæ§ã«çžå¯Ÿæ床ãæ±ããã ãããã®çµæãè¡šâïŒã«ç€ºãã
ãè¡šã
以äžè¡šâïŒã®ããšãæ¬çºæè©Šæã¯å®æœäŸâïŒãš
åæ§ã«é·æã«ããã€ãŠå¡åžæ¶²ãçµæãããŠãåžžã«
äžå®ãªæ床ãæããŠããããšããããã å®æœäŸ ïŒ äŸç€ºååç©16ã«ç€ºãå¢æè²çŽ ãéïŒã¢ã«åœã
4.2Ã10-5ã¢ã«æ·»å ãããååŠçæçµäºæžã¿å¡©è
åéä¹³å€ïŒ»ïŒ¡ïŒœã«äžèšã«ç€ºãã·ã¢ã³çºè²å€ãå«æ
ããã·ã¢ã³çºè²å€åæ£æ¶²ãæ·»å åŸè¡šâïŒïŒNo1ã
ïŒïŒã«ç€ºãæ§æã«ãŠæº¶è§£ããã溶液ãæ·»å ããŠã
ãã«ç¡¬èå€ãšããŠïŒ®ïŒNâ²ïŒNâ³âããªã¢ã¯ãªãã€
ã«â6Hââããªã¢ãžã³ã®ïŒïŒ ã¡ã¿ããŒã«æº¶æ¶²
10mlãå ããŠå¡åžæ¶²ïŒNo1ãïŒïŒã調補ããã åæ§ã«äŸç€ºååç©25ã«ç€ºãå¢æè²çŽ ãéïŒã¢ã«
åœã4.0Ã10-5ã¢ã«æ·»å ãããå¡©èåéä¹³å€ïŒ»ïŒ¢ïŒœ
ã«ãŠå¡åžæ¶²ïŒNo4ãïŒïŒã調補ããã åæ§ã«äŸç€ºååç©16ã«ç€ºãå¢æè²çŽ ãéïŒã¢ã«
åœã1.4Ã10-5ã¢ã«ããã³äŸç€ºååç©29ã«ç€ºãå¢
æè²çŽ ãéïŒã¢ã«åœã2.0Ã10-5ã¢ã«æ·»å ããã
å¡©èåéä¹³å€ïŒ»ïŒ£ïŒœã«ãŠå¡åžæ¶²ïŒNo7ãïŒïŒã調
補ããã ã·ã¢ã³çºè²å€
åæ§ã«é·æã«ããã€ãŠå¡åžæ¶²ãçµæãããŠãåžžã«
äžå®ãªæ床ãæããŠããããšããããã å®æœäŸ ïŒ äŸç€ºååç©16ã«ç€ºãå¢æè²çŽ ãéïŒã¢ã«åœã
4.2Ã10-5ã¢ã«æ·»å ãããååŠçæçµäºæžã¿å¡©è
åéä¹³å€ïŒ»ïŒ¡ïŒœã«äžèšã«ç€ºãã·ã¢ã³çºè²å€ãå«æ
ããã·ã¢ã³çºè²å€åæ£æ¶²ãæ·»å åŸè¡šâïŒïŒNo1ã
ïŒïŒã«ç€ºãæ§æã«ãŠæº¶è§£ããã溶液ãæ·»å ããŠã
ãã«ç¡¬èå€ãšããŠïŒ®ïŒNâ²ïŒNâ³âããªã¢ã¯ãªãã€
ã«â6Hââããªã¢ãžã³ã®ïŒïŒ ã¡ã¿ããŒã«æº¶æ¶²
10mlãå ããŠå¡åžæ¶²ïŒNo1ãïŒïŒã調補ããã åæ§ã«äŸç€ºååç©25ã«ç€ºãå¢æè²çŽ ãéïŒã¢ã«
åœã4.0Ã10-5ã¢ã«æ·»å ãããå¡©èåéä¹³å€ïŒ»ïŒ¢ïŒœ
ã«ãŠå¡åžæ¶²ïŒNo4ãïŒïŒã調補ããã åæ§ã«äŸç€ºååç©16ã«ç€ºãå¢æè²çŽ ãéïŒã¢ã«
åœã1.4Ã10-5ã¢ã«ããã³äŸç€ºååç©29ã«ç€ºãå¢
æè²çŽ ãéïŒã¢ã«åœã2.0Ã10-5ã¢ã«æ·»å ããã
å¡©èåéä¹³å€ïŒ»ïŒ£ïŒœã«ãŠå¡åžæ¶²ïŒNo7ãïŒïŒã調
補ããã ã·ã¢ã³çºè²å€
ãè¡šã
äžèšã®ããšã調補ãããå¡åžæ¶²ã調補åŸå³æãš
40âã§ïŒæéæŸçœ®åŸã40âã§ïŒæéæŸçœ®åŸããã³
40âã§10æéæŸçœ®åŸã«ããªãšãã¬ã³ã³ãŒãçŽäžã«
å¡åžä¹Ÿç¥ãããã²ã³åéåçæå ææãåŸãã ãããã®è©Šæãå æ¥é²å ãè¡ã€ãåŸãå®æœäŸâ
ïŒã«ç€ºããåŠçæ¹æ³ã«åŸã€ãŠåŠç也ç¥åŸãå®æœäŸ
âïŒãšåæ§ã«çžå¯Ÿæ床ãæ±ããã ãããã®çµæãè¡šâïŒã«ç€ºãã
40âã§ïŒæéæŸçœ®åŸã40âã§ïŒæéæŸçœ®åŸããã³
40âã§10æéæŸçœ®åŸã«ããªãšãã¬ã³ã³ãŒãçŽäžã«
å¡åžä¹Ÿç¥ãããã²ã³åéåçæå ææãåŸãã ãããã®è©Šæãå æ¥é²å ãè¡ã€ãåŸãå®æœäŸâ
ïŒã«ç€ºããåŠçæ¹æ³ã«åŸã€ãŠåŠç也ç¥åŸãå®æœäŸ
âïŒãšåæ§ã«çžå¯Ÿæ床ãæ±ããã ãããã®çµæãè¡šâïŒã«ç€ºãã
ãè¡šã
ãè¡šã
以äžè¡šâïŒã®ããšãæ¬çºæè©Šæã¯å®æœäŸâïŒïŒ
ïŒãšåæ§ã«é·æã«ããã€ãŠå¡åžæ¶²ãçµæãããŠã
åžžã«äžå®ãªæ床ãæããŠããããšããããã å®æœäŸ ïŒ äžèšè¡šâïŒã«ç€ºãããã«ãå¡åžæ¶²ã«æ·»å ããå¢
æè²çŽ ã®éãå€åãã以å€ã¯å®æœäŸâïŒã®è©Šæ
No.6ãå®æœäŸâïŒã®è©ŠæNo.3ããã³å®æœäŸâïŒ
ã®è©ŠæNo.6ãšåäžã®æ§æã§å¡åžæ¶²ã調補ããã å®æœäŸâïŒãšåæ§ã«ãå¡åžæ¶²ã調補åŸå³æã40
âã»ïŒæéæŸçœ®åŸããã³40âã»ïŒæéæŸçœ®åŸã«ã
ãªãšãã¬ã³ã³ãŒãçŽäžã«å¡åžä¹Ÿç¥ããŠããã²ã³å
éåçæå ææè©Šæãäœæããé²å ã»çŸåããŠçž
察æ床ãæ±ãããçµæãè¡šâïŒã«ç€ºãã å¡åžæ¶²ã«æ·»å ããå¢æè²çŽ éãæ¬çºæã®ç¯å²ã§
ããïŒã500ïŒ ä»¥å€ã§ã¯ãå¡åžæ¶²çµæã«ããæ床
å€åã倧ããã
ïŒãšåæ§ã«é·æã«ããã€ãŠå¡åžæ¶²ãçµæãããŠã
åžžã«äžå®ãªæ床ãæããŠããããšããããã å®æœäŸ ïŒ äžèšè¡šâïŒã«ç€ºãããã«ãå¡åžæ¶²ã«æ·»å ããå¢
æè²çŽ ã®éãå€åãã以å€ã¯å®æœäŸâïŒã®è©Šæ
No.6ãå®æœäŸâïŒã®è©ŠæNo.3ããã³å®æœäŸâïŒ
ã®è©ŠæNo.6ãšåäžã®æ§æã§å¡åžæ¶²ã調補ããã å®æœäŸâïŒãšåæ§ã«ãå¡åžæ¶²ã調補åŸå³æã40
âã»ïŒæéæŸçœ®åŸããã³40âã»ïŒæéæŸçœ®åŸã«ã
ãªãšãã¬ã³ã³ãŒãçŽäžã«å¡åžä¹Ÿç¥ããŠããã²ã³å
éåçæå ææè©Šæãäœæããé²å ã»çŸåããŠçž
察æ床ãæ±ãããçµæãè¡šâïŒã«ç€ºãã å¡åžæ¶²ã«æ·»å ããå¢æè²çŽ éãæ¬çºæã®ç¯å²ã§
ããïŒã500ïŒ ä»¥å€ã§ã¯ãå¡åžæ¶²çµæã«ããæ床
å€åã倧ããã
Claims (1)
- ïŒ å¢æè²çŽ ã§å¢æãããæå æ§ããã²ã³åéç²
åãå«æããä¹³å€ã«ãã圢æãããå±€ãå°ãªããš
ãïŒã€æ¯æäœäžã«èšããŠãªããããã²ã³åéåç
æå ææã®è£œé æ¹æ³ã«ãããŠãæå æ§ããã²ã³å
éç²åã®ç§åŠçæçµäºåŸå¡åžåã«ãåèšå¢æè²çŽ
ãæŽã«ãå ã«æå æ§ããã²ã³åéã«äœ¿çšããéã®
ïŒã500ééïŒ ã溶解ãã溶液ããåèšä¹³å€äžã«
æ·»å ããããšãç¹åŸŽãšããããã²ã³åéåçæå
ææã®è£œé æ¹æ³ã
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56106412A JPS587629A (ja) | 1981-07-07 | 1981-07-07 | ããã²ã³åéåçæå ææã®è£œé æ¹æ³ |
| EP82303565A EP0069596B2 (en) | 1981-07-07 | 1982-07-07 | A method for production of a silver halide photographic light-sensitive material |
| DE8282303565T DE3274498D1 (en) | 1981-07-07 | 1982-07-07 | A method for production of a silver halide photographic light-sensitive material |
| US06/395,998 US4442201A (en) | 1981-07-07 | 1982-07-07 | Method for production of a silver halide photographic light-sensitive material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56106412A JPS587629A (ja) | 1981-07-07 | 1981-07-07 | ããã²ã³åéåçæå ææã®è£œé æ¹æ³ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS587629A JPS587629A (ja) | 1983-01-17 |
| JPH0416774B2 true JPH0416774B2 (ja) | 1992-03-25 |
Family
ID=14432951
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56106412A Granted JPS587629A (ja) | 1981-07-07 | 1981-07-07 | ããã²ã³åéåçæå ææã®è£œé æ¹æ³ |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4442201A (ja) |
| EP (1) | EP0069596B2 (ja) |
| JP (1) | JPS587629A (ja) |
| DE (1) | DE3274498D1 (ja) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4692401A (en) * | 1986-08-21 | 1987-09-08 | Eastman Kodak Company | Photographic emulsions and elements containing sensitizing dye in the form of host crystals |
| US5126237A (en) * | 1989-08-18 | 1992-06-30 | Konica Corporation | Silver halide light-sensitive photographic material |
| JPH03219232A (ja) * | 1990-01-24 | 1991-09-26 | Konica Corp | åå å¢æãããããã²ã³åéåçæå ææ |
| US5500336A (en) * | 1990-11-27 | 1996-03-19 | Fuji Photo Film Co., Ltd. | Silver halide photographic material |
| US5219723A (en) * | 1991-10-10 | 1993-06-15 | Eastman Kodak Company | Green sensitizing dyes for variable contrast photographic elements |
| JP2684474B2 (ja) * | 1991-10-18 | 1997-12-03 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ã«ã©ãŒæ¡æ£è»¢åæå ææ |
| JP2787742B2 (ja) * | 1992-03-30 | 1998-08-20 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéåçæå ææ |
| US5925509A (en) * | 1995-09-29 | 1999-07-20 | Eastman Kodak Company | Photographic material having a red sensitized silver halide emulsion layer with improved heat sensitivity |
| US5922525A (en) * | 1996-04-08 | 1999-07-13 | Eastman Kodak Company | Photographic material having a red sensitized silver halide emulsion layer with improved heat sensitivity |
| US6120982A (en) * | 1995-09-29 | 2000-09-19 | Eastman Kodak Company | Red sensitizing dye combinations for high chloride emulsions |
| DE60143154D1 (de) | 2001-04-17 | 2010-11-11 | Fujifilm Corp | Photographisches Silberhalogenidmaterial enthaltend einen Methinfarbstoff |
| US7611829B2 (en) | 2004-01-30 | 2009-11-03 | Fujifilm Corporation | Silver halide color photographic light-sensitive material and color image-forming method |
| CN111045288B (zh) * | 2019-12-20 | 2023-09-19 | ä¹å¯å»çç§ææéå ¬åž | äžç§æ圱è¶çä¹³åçå¢ææ¹æ³åè¶çå¶å€ |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5526589A (en) * | 1979-02-27 | 1980-02-26 | Eastman Kodak Co | Adjusting silver halogenide emulaion |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1573596A (en) * | 1917-07-11 | 1926-02-16 | Kalmus Comstock & Wescott | Method of treating photographic emulsion and color-sensitizing composition |
| BE519979A (ja) * | 1952-05-15 | |||
| IT996288B (it) * | 1972-12-04 | 1975-12-10 | Polaroid Corp | Procedimento per formare cristalli di alogenuro di argento per emu sioni fotografiche |
| JPS5181612A (en) * | 1975-01-14 | 1976-07-17 | Konishiroku Photo Ind | Harogenkaginshashinkankozairyo |
| US4332888A (en) * | 1978-11-20 | 1982-06-01 | Polaroid Corporation | Method for stabilizing and spectrally sensitizing photosensitive silver halide emulsion |
| US4225666A (en) * | 1979-02-02 | 1980-09-30 | Eastman Kodak Company | Silver halide precipitation and methine dye spectral sensitization process and products thereof |
-
1981
- 1981-07-07 JP JP56106412A patent/JPS587629A/ja active Granted
-
1982
- 1982-07-07 US US06/395,998 patent/US4442201A/en not_active Expired - Lifetime
- 1982-07-07 DE DE8282303565T patent/DE3274498D1/de not_active Expired
- 1982-07-07 EP EP82303565A patent/EP0069596B2/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5526589A (en) * | 1979-02-27 | 1980-02-26 | Eastman Kodak Co | Adjusting silver halogenide emulaion |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3274498D1 (en) | 1987-01-15 |
| EP0069596A3 (en) | 1983-06-22 |
| EP0069596B2 (en) | 1990-09-12 |
| JPS587629A (ja) | 1983-01-17 |
| EP0069596B1 (en) | 1986-11-26 |
| EP0069596A2 (en) | 1983-01-12 |
| US4442201A (en) | 1984-04-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4659654A (en) | Silver halide photographic light-sensitive emulsion | |
| JPH0416774B2 (ja) | ||
| US4054457A (en) | Silver halide emulsions containing hexathiocane thiones as sensitizers | |
| JPS581414B2 (ja) | ããšã¯ã»ãããžããã²ã³ã«ã®ã³ããŠãŠã¶ã€ã ã»ã€ãŸãŠã㊠| |
| JPS5917818B2 (ja) | ããã²ã³åéåçæå ææ | |
| SU453852A3 (ru) | СвеÑПÑÑвÑÑвОÑелÑÐœÑй ÑПÑПгÑаÑОÑеÑкОй ЌаÑеÑОал | |
| US5302506A (en) | Silver halide photographic materials | |
| JP2846480B2 (ja) | ããã²ã³åéåçæå ææ | |
| JPS5948756A (ja) | ããã²ã³åéåçä¹³å€ã®è£œé æ¹æ³ | |
| JPH0464059B2 (ja) | ||
| JP2841220B2 (ja) | ããã²ã³åéãšãã«ãžã§ã³ã®å¢ææ³ | |
| JPH1055038A (ja) | ã¬ãŒã¶ãŒèšé²å»ççšããŒãã³ããŒææãšããŠäœ¿çšããããã®å¡©åéãªããã®æå æ§åçææäžã«é»åçã«è²¯èµãããå»ççšç»åãåçããæ¹æ³ | |
| JP3219211B2 (ja) | ããã²ã³åéåçæå ææ | |
| JPH0548462B2 (ja) | ||
| JP3380349B2 (ja) | åççšåå å¢æè²çŽ | |
| US4097285A (en) | Direct-positive photographic silver halide emulsion containing novel dye | |
| JP2000231173A (ja) | ã¡ãã³ååç©ãå«æããããã²ã³åéæå ææ | |
| JPH06230507A (ja) | ããã²ã³åéåçæå ææ | |
| JPS61169833A (ja) | ããã²ã³åéåçæå ææ | |
| JPH02264937A (ja) | ããã²ã³åéåçæå ææ | |
| JPS599658A (ja) | ããã²ã³åéåçæå ææã®è£œé æ¹æ³ | |
| JPH05100346A (ja) | ããã²ã³åéåçæå ææ | |
| JPH0528816B2 (ja) | ||
| JPH04199144A (ja) | ããã²ã³åéåçæå ææ | |
| JPH06222489A (ja) | ããã²ã³åéåçæå ææ |