JP7661894B2 - クロロプレン重合体を含む組成物、成形体、および、成形体の製造方法 - Google Patents
クロロプレン重合体を含む組成物、成形体、および、成形体の製造方法 Download PDFInfo
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- JP7661894B2 JP7661894B2 JP2021570046A JP2021570046A JP7661894B2 JP 7661894 B2 JP7661894 B2 JP 7661894B2 JP 2021570046 A JP2021570046 A JP 2021570046A JP 2021570046 A JP2021570046 A JP 2021570046A JP 7661894 B2 JP7661894 B2 JP 7661894B2
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- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- RQPNXPWEGVCPCX-UHFFFAOYSA-N 3-sulfanylbutanoic acid Chemical compound CC(S)CC(O)=O RQPNXPWEGVCPCX-UHFFFAOYSA-N 0.000 description 1
- PTPQZNNAUUSACC-UHFFFAOYSA-N 3-sulfanylpentanoic acid Chemical compound CCC(S)CC(O)=O PTPQZNNAUUSACC-UHFFFAOYSA-N 0.000 description 1
- MDWVSAYEQPLWMX-UHFFFAOYSA-N 4,4'-Methylenebis(2,6-di-tert-butylphenol) Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 MDWVSAYEQPLWMX-UHFFFAOYSA-N 0.000 description 1
- UJAWGGOCYUPCPS-UHFFFAOYSA-N 4-(2-phenylpropan-2-yl)-n-[4-(2-phenylpropan-2-yl)phenyl]aniline Chemical compound C=1C=C(NC=2C=CC(=CC=2)C(C)(C)C=2C=CC=CC=2)C=CC=1C(C)(C)C1=CC=CC=C1 UJAWGGOCYUPCPS-UHFFFAOYSA-N 0.000 description 1
- NEAFWRKPYYJETG-UHFFFAOYSA-N 4-sulfanylpentanoic acid Chemical compound CC(S)CCC(O)=O NEAFWRKPYYJETG-UHFFFAOYSA-N 0.000 description 1
- JAJIPIAHCFBEPI-UHFFFAOYSA-M 9,10-dioxoanthracene-1-sulfonate Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2S(=O)(=O)[O-] JAJIPIAHCFBEPI-UHFFFAOYSA-M 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 229920001174 Diethylhydroxylamine Polymers 0.000 description 1
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- OUBMGJOQLXMSNT-UHFFFAOYSA-N N-isopropyl-N'-phenyl-p-phenylenediamine Chemical compound C1=CC(NC(C)C)=CC=C1NC1=CC=CC=C1 OUBMGJOQLXMSNT-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 206010074268 Reproductive toxicity Diseases 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000006236 Super Abrasion Furnace Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000013475 authorization Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- AJDUHBRBJZYLBM-UHFFFAOYSA-N bis(1-sulfanylethyl) benzene-1,2-dicarboxylate Chemical compound CC(S)OC(=O)C1=CC=CC=C1C(=O)OC(C)S AJDUHBRBJZYLBM-UHFFFAOYSA-N 0.000 description 1
- REHHYKMCNPOHOP-UHFFFAOYSA-N bis(2-methyl-3-sulfanylpropyl) benzene-1,2-dicarboxylate Chemical compound SCC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)CS REHHYKMCNPOHOP-UHFFFAOYSA-N 0.000 description 1
- GBWNXMASAKCHQP-UHFFFAOYSA-N bis(2-sulfanylpropyl) benzene-1,2-dicarboxylate Chemical compound CC(S)COC(=O)C1=CC=CC=C1C(=O)OCC(C)S GBWNXMASAKCHQP-UHFFFAOYSA-N 0.000 description 1
- CFOLPWIGJLXQPE-UHFFFAOYSA-N bis(3-sulfanylbutyl) benzene-1,2-dicarboxylate Chemical compound CC(S)CCOC(=O)C1=CC=CC=C1C(=O)OCCC(C)S CFOLPWIGJLXQPE-UHFFFAOYSA-N 0.000 description 1
- ULBTUVJTXULMLP-UHFFFAOYSA-N butyl octadecanoate Chemical group CCCCCCCCCCCCCCCCCC(=O)OCCCC ULBTUVJTXULMLP-UHFFFAOYSA-N 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 229920003193 cis-1,4-polybutadiene polymer Polymers 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 1
- PGAXJQVAHDTGBB-UHFFFAOYSA-N dibutylcarbamothioylsulfanyl n,n-dibutylcarbamodithioate Chemical compound CCCCN(CCCC)C(=S)SSC(=S)N(CCCC)CCCC PGAXJQVAHDTGBB-UHFFFAOYSA-N 0.000 description 1
- FVCOIAYSJZGECG-UHFFFAOYSA-N diethylhydroxylamine Chemical compound CCN(O)CC FVCOIAYSJZGECG-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- CUXZNAQNNKPICO-UHFFFAOYSA-L disodium;n-butyl-n-[butyl(carboxylato)amino]sulfanylcarbamate Chemical compound [Na+].[Na+].CCCCN(C([O-])=O)SN(C([O-])=O)CCCC CUXZNAQNNKPICO-UHFFFAOYSA-L 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- 238000002296 dynamic light scattering Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Natural products O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- KEZPMZSDLBJCHH-UHFFFAOYSA-N n-(4-anilinophenyl)-4-methylbenzenesulfonamide Chemical compound C1=CC(C)=CC=C1S(=O)(=O)NC(C=C1)=CC=C1NC1=CC=CC=C1 KEZPMZSDLBJCHH-UHFFFAOYSA-N 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- KVBGVZZKJNLNJU-UHFFFAOYSA-N naphthalene-2-sulfonic acid Chemical compound C1=CC=CC2=CC(S(=O)(=O)O)=CC=C21 KVBGVZZKJNLNJU-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical group CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229950000688 phenothiazine Drugs 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
- 235000019252 potassium sulphite Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000007696 reproductive toxicity Effects 0.000 description 1
- 231100000372 reproductive toxicity Toxicity 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 231100000615 substance of very high concern Toxicity 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- RYYOZMVTASIOCE-UHFFFAOYSA-L zinc;n-[carboxylato(ethyl)amino]sulfanyl-n-ethylcarbamate Chemical compound [Zn+2].CCN(C([O-])=O)SN(CC)C([O-])=O RYYOZMVTASIOCE-UHFFFAOYSA-L 0.000 description 1
- QLVOTGJLVIBNOO-UHFFFAOYSA-L zinc;n-butyl-n-[butyl(carboxylato)amino]sulfanylcarbamate Chemical compound [Zn+2].CCCCN(C([O-])=O)SN(C([O-])=O)CCCC QLVOTGJLVIBNOO-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L11/00—Compositions of homopolymers or copolymers of chloroprene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/08—Isoprene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2020000209 | 2020-01-06 | ||
| JP2020000209 | 2020-01-06 | ||
| PCT/JP2021/000053 WO2021141012A1 (ja) | 2020-01-06 | 2021-01-05 | クロロプレン重合体を含む組成物、成形体、および、成形体の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPWO2021141012A1 JPWO2021141012A1 (https=) | 2021-07-15 |
| JP7661894B2 true JP7661894B2 (ja) | 2025-04-15 |
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|---|---|---|---|
| JP2021570046A Active JP7661894B2 (ja) | 2020-01-06 | 2021-01-05 | クロロプレン重合体を含む組成物、成形体、および、成形体の製造方法 |
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| Country | Link |
|---|---|
| US (1) | US20230056113A1 (https=) |
| EP (1) | EP4089144A4 (https=) |
| JP (1) | JP7661894B2 (https=) |
| CN (1) | CN114929795B (https=) |
| WO (1) | WO2021141012A1 (https=) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002138165A (ja) | 2000-11-02 | 2002-05-14 | Denki Kagaku Kogyo Kk | クロロプレン系ゴム組成物 |
| JP2008533281A (ja) | 2005-03-14 | 2008-08-21 | ダウ グローバル テクノロジーズ インコーポレイティド | 塩素化エラストマー組成物のための改良された硬化システムおよび塩素化エラストマー組成物の硬化方法。 |
| JP2013177504A (ja) | 2012-02-28 | 2013-09-09 | Denki Kagaku Kogyo Kk | クロロプレン重合体組成物、その製造方法 |
| CN104804245A (zh) | 2015-04-21 | 2015-07-29 | 青岛承天伟业机械制造有限公司 | 一种轮胎橡胶 |
| WO2017061441A1 (ja) | 2015-10-09 | 2017-04-13 | 株式会社ブリヂストン | タイヤトレッド用ゴム組成物及びタイヤ |
| WO2018078997A1 (ja) | 2016-10-26 | 2018-05-03 | 昭和電工株式会社 | ラジカル重合性樹脂組成物 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4357446A (en) * | 1980-03-03 | 1982-11-02 | Osaka Soda Co. Ltd. | Curable composition of halogen-containing polymer |
| JPS591546A (ja) * | 1982-06-28 | 1984-01-06 | Yokohama Rubber Co Ltd:The | ゴム組成物 |
| US5523355A (en) * | 1994-04-27 | 1996-06-04 | Denki Kagaku Kogyo Kabushiki Kaisha | Chloroprene rubber composition having a high damping performance and method for its production |
| JP4883476B2 (ja) * | 2005-06-21 | 2012-02-22 | ダイソー株式会社 | ハロゲン含有エラストマー加硫用組成物 |
| MX2014010525A (es) * | 2012-03-02 | 2014-11-25 | Denki Kagaku Kogyo Kk | Latex de policloropreno, composicion de latex de policloropreno y articulo moldeado. |
| JPWO2015136792A1 (ja) * | 2014-03-12 | 2017-04-06 | デンカ株式会社 | ゴム組成物及びその加硫物 |
| US20170292014A1 (en) * | 2014-10-28 | 2017-10-12 | Denka Company Limited | Chloroprene rubber composition, vulcanized molded article, and anti-vibration rubber |
| JP2016166271A (ja) * | 2015-03-09 | 2016-09-15 | 東ソー株式会社 | 動的特性に優れるクロロプレンゴム、その製造方法、及びその加硫物 |
| CN107429001B (zh) * | 2015-04-16 | 2021-05-28 | 昭和电工株式会社 | 橡胶用组合物及其用途 |
| CN106188707A (zh) * | 2015-05-04 | 2016-12-07 | 电气化学工业株式会社 | 氯丁二烯橡胶组合物、硫化成型体及其用途 |
| EP3156461B1 (en) * | 2015-10-13 | 2020-04-01 | Agfa Nv | Uv curable inkjet inks |
| EP3184583A1 (en) * | 2015-12-23 | 2017-06-28 | ARLANXEO Deutschland GmbH | Novel polychloroprene compositions |
| EP3556786B1 (en) | 2016-12-14 | 2021-04-21 | Denka Company Limited | Xanthogen-modified chloroprene rubber, rubber composition, and vulcanized molded body |
| EP4089143B1 (en) * | 2020-01-06 | 2025-07-23 | Resonac Corporation | Latex composition, molded body and method for producing molded body |
-
2021
- 2021-01-05 WO PCT/JP2021/000053 patent/WO2021141012A1/ja not_active Ceased
- 2021-01-05 JP JP2021570046A patent/JP7661894B2/ja active Active
- 2021-01-05 CN CN202180008181.0A patent/CN114929795B/zh active Active
- 2021-01-05 US US17/790,397 patent/US20230056113A1/en active Pending
- 2021-01-05 EP EP21738268.8A patent/EP4089144A4/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002138165A (ja) | 2000-11-02 | 2002-05-14 | Denki Kagaku Kogyo Kk | クロロプレン系ゴム組成物 |
| JP2008533281A (ja) | 2005-03-14 | 2008-08-21 | ダウ グローバル テクノロジーズ インコーポレイティド | 塩素化エラストマー組成物のための改良された硬化システムおよび塩素化エラストマー組成物の硬化方法。 |
| JP2013177504A (ja) | 2012-02-28 | 2013-09-09 | Denki Kagaku Kogyo Kk | クロロプレン重合体組成物、その製造方法 |
| CN104804245A (zh) | 2015-04-21 | 2015-07-29 | 青岛承天伟业机械制造有限公司 | 一种轮胎橡胶 |
| WO2017061441A1 (ja) | 2015-10-09 | 2017-04-13 | 株式会社ブリヂストン | タイヤトレッド用ゴム組成物及びタイヤ |
| WO2018078997A1 (ja) | 2016-10-26 | 2018-05-03 | 昭和電工株式会社 | ラジカル重合性樹脂組成物 |
Non-Patent Citations (1)
| Title |
|---|
| Keith Berry et al.，MECHANISM FOR CROSS-LINKING POLYCHLOROPRENE WITH ETHYLENE THIOUREA AND ZINC OXIDE，Rubber Chemistry and Technology，Vol. 88, No. 1，2015年，p.80-97 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2021141012A1 (ja) | 2021-07-15 |
| EP4089144A1 (en) | 2022-11-16 |
| CN114929795A (zh) | 2022-08-19 |
| CN114929795B (zh) | 2024-09-20 |
| JPWO2021141012A1 (https=) | 2021-07-15 |
| EP4089144A4 (en) | 2024-01-17 |
| US20230056113A1 (en) | 2023-02-23 |
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