JP7121237B2 - 閾値シフトの低減のためのシリコン窒化プロセス - Google Patents

閾値シフトの低減のためのシリコン窒化プロセス Download PDF

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JP7121237B2
JP7121237B2 JP2018567698A JP2018567698A JP7121237B2 JP 7121237 B2 JP7121237 B2 JP 7121237B2 JP 2018567698 A JP2018567698 A JP 2018567698A JP 2018567698 A JP2018567698 A JP 2018567698A JP 7121237 B2 JP7121237 B2 JP 7121237B2
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silicon nitride
nitride layer
nitrogen
substrate
rich
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JP2019519937A (ja
JP2019519937A5 (enExample
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ステファン デラス ニコラス
ティピルネニ ナヴィーン
セアップ リー ドン
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テキサス インスツルメンツ インコーポレイテッド
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    • HELECTRICITY
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    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02107Forming insulating materials on a substrate
    • H01L21/02225Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
    • H01L21/0226Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process
    • H01L21/02263Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase
    • H01L21/02271Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition
    • H01L21/0228Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition deposition by cyclic CVD, e.g. ALD, ALE, pulsed CVD
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    • H01L21/02109Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
    • H01L21/02112Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
    • H01L21/02123Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon
    • H01L21/0217Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material being a silicon nitride not containing oxygen, e.g. SixNy or SixByNz
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    • H01L21/02109Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
    • H01L21/022Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates the layer being a laminate, i.e. composed of sublayers, e.g. stacks of alternating high-k metal oxides
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    • H01L21/02107Forming insulating materials on a substrate
    • H01L21/02109Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
    • H01L21/02205Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates the layer being characterised by the precursor material for deposition
    • H01L21/02208Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates the layer being characterised by the precursor material for deposition the precursor containing a compound comprising Si
    • H01L21/02211Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates the layer being characterised by the precursor material for deposition the precursor containing a compound comprising Si the compound being a silane, e.g. disilane, methylsilane or chlorosilane
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    • H01L21/02225Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
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    • H01L21/02263Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase
    • H01L21/02271Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition
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    • H01L21/02518Deposited layers
    • H01L21/02521Materials
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    • H01L21/0254Nitrides
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    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/28008Making conductor-insulator-semiconductor electrodes
    • H01L21/28264Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being a III-V compound
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    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/01Manufacture or treatment
    • H10D30/021Manufacture or treatment of FETs having insulated gates [IGFET]
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    • H10D30/00Field-effect transistors [FET]
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    • H10D30/47FETs having zero-dimensional [0D], one-dimensional [1D] or two-dimensional [2D] charge carrier gas channels having 2D charge carrier gas channels, e.g. nanoribbon FETs or high electron mobility transistors [HEMT]
    • H10D30/471High electron mobility transistors [HEMT] or high hole mobility transistors [HHMT]
    • H10D30/475High electron mobility transistors [HEMT] or high hole mobility transistors [HHMT] having wider bandgap layer formed on top of lower bandgap active layer, e.g. undoped barrier HEMTs such as i-AlGaN/GaN HEMTs
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    • H10D64/00Electrodes of devices having potential barriers
    • H10D64/60Electrodes characterised by their materials
    • H10D64/66Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes
    • H10D64/68Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes characterised by the insulator, e.g. by the gate insulator
    • H10D64/681Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes characterised by the insulator, e.g. by the gate insulator having a compositional variation, e.g. multilayered
    • H10D64/685Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes characterised by the insulator, e.g. by the gate insulator having a compositional variation, e.g. multilayered being perpendicular to the channel plane
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    • H10D64/00Electrodes of devices having potential barriers
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    • H10D64/68Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes characterised by the insulator, e.g. by the gate insulator
    • H10D64/693Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes characterised by the insulator, e.g. by the gate insulator the insulator comprising nitrogen, e.g. nitrides, oxynitrides or nitrogen-doped materials
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    • H10D62/8503Nitride Group III-V materials, e.g. AlN or GaN

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Formation Of Insulating Films (AREA)
  • Insulated Gate Type Field-Effect Transistor (AREA)
JP2018567698A 2016-06-23 2017-06-23 閾値シフトの低減のためのシリコン窒化プロセス Active JP7121237B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US15/191,500 US9741557B1 (en) 2016-06-23 2016-06-23 Silicon nitride process for reduction of threshold shift
US15/191,500 2016-06-23
PCT/US2017/039150 WO2017223541A1 (en) 2016-06-23 2017-06-23 Silicon nitride process for reduction of threshold shift

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JP2019519937A JP2019519937A (ja) 2019-07-11
JP2019519937A5 JP2019519937A5 (enExample) 2020-07-30
JP7121237B2 true JP7121237B2 (ja) 2022-08-18

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US (1) US9741557B1 (enExample)
JP (1) JP7121237B2 (enExample)
CN (1) CN109219887B (enExample)
WO (1) WO2017223541A1 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016066641A (ja) * 2014-09-22 2016-04-28 株式会社東芝 半導体装置及び半導体装置の製造方法
US11037851B2 (en) * 2019-08-30 2021-06-15 Applied Materials, Inc. Nitrogen-rich silicon nitride films for thin film transistors
US11819847B2 (en) 2020-07-20 2023-11-21 Applied Materials, Inc. Nanofluidic device with silicon nitride membrane

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008205392A (ja) 2007-02-22 2008-09-04 Fujitsu Ltd 半導体装置及びその製造方法
JP2009200306A (ja) 2008-02-22 2009-09-03 Eudyna Devices Inc 半導体装置の製造方法
US20110298060A1 (en) 2010-06-02 2011-12-08 International Business Machines Corporation Interface structure for channel mobility improvement in high-k metal gate stack
JP2015103780A (ja) 2013-11-28 2015-06-04 ルネサスエレクトロニクス株式会社 半導体装置および半導体装置の製造方法

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US5972804A (en) * 1997-08-05 1999-10-26 Motorola, Inc. Process for forming a semiconductor device
US6709928B1 (en) * 2001-07-31 2004-03-23 Cypress Semiconductor Corporation Semiconductor device having silicon-rich layer and method of manufacturing such a device
JP2004111447A (ja) * 2002-09-13 2004-04-08 Handotai Rikougaku Kenkyu Center:Kk 半導体装置及びその製造方法
KR100560654B1 (ko) * 2004-01-08 2006-03-16 삼성전자주식회사 질화실리콘막을 형성을 위한 질소화합물 및 이를 이용한질화실리콘 막의 형성방법
CN102915952B (zh) * 2011-08-04 2014-11-05 中芯国际集成电路制造(上海)有限公司 一种半导体器件的制造方法
CN103632968B (zh) * 2012-08-21 2016-10-05 中芯国际集成电路制造(上海)有限公司 晶体管及其形成方法
US9614105B2 (en) * 2013-04-22 2017-04-04 Cypress Semiconductor Corporation Charge-trap NOR with silicon-rich nitride as a charge trap layer

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008205392A (ja) 2007-02-22 2008-09-04 Fujitsu Ltd 半導体装置及びその製造方法
JP2009200306A (ja) 2008-02-22 2009-09-03 Eudyna Devices Inc 半導体装置の製造方法
US20110298060A1 (en) 2010-06-02 2011-12-08 International Business Machines Corporation Interface structure for channel mobility improvement in high-k metal gate stack
JP2015103780A (ja) 2013-11-28 2015-06-04 ルネサスエレクトロニクス株式会社 半導体装置および半導体装置の製造方法

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JP2019519937A (ja) 2019-07-11
CN109219887A (zh) 2019-01-15
US9741557B1 (en) 2017-08-22
WO2017223541A1 (en) 2017-12-28
CN109219887B (zh) 2022-11-01

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