JP7092076B2 - チタン基材、チタン基材の製造方法、及び、水電解用電極、水電解装置 - Google Patents
チタン基材、チタン基材の製造方法、及び、水電解用電極、水電解装置 Download PDFInfo
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- JP7092076B2 JP7092076B2 JP2019042773A JP2019042773A JP7092076B2 JP 7092076 B2 JP7092076 B2 JP 7092076B2 JP 2019042773 A JP2019042773 A JP 2019042773A JP 2019042773 A JP2019042773 A JP 2019042773A JP 7092076 B2 JP7092076 B2 JP 7092076B2
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
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- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
- C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
- C25B11/061—Metal or alloy
- C25B11/063—Valve metal, e.g. titanium
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C14/00—Alloys based on titanium
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/04—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
- C25B11/031—Porous electrodes
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- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/052—Electrodes comprising one or more electrocatalytic coatings on a substrate
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- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
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- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
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- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
- C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
- C25B11/061—Metal or alloy
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/075—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound
- C25B11/077—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound the compound being a non-noble metal oxide
- C25B11/0775—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound the compound being a non-noble metal oxide of the rutile type
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
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- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/026—Anodisation with spark discharge
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/26—Anodisation of refractory metals or alloys based thereon
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C26/00—Coating not provided for in groups C23C2/00 - C23C24/00
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16/979,002 US20200407858A1 (en) | 2018-03-12 | 2019-03-12 | Titanium base material, method for producing titanium base material, electrode for water electrolysis, and water electrolysis device |
| CN201980017686.6A CN111918983B (zh) | 2018-03-12 | 2019-03-12 | 钛基材、钛基材的制造方法及水电解用电极、水电解装置 |
| EP19766633.2A EP3767009A4 (en) | 2018-03-12 | 2019-03-12 | TITANIUM-BASED MATERIAL, PROCESS FOR THE PRODUCTION OF A TITANIUM-BASED MATERIAL, ELECTRODE FOR ELECTROLYSIS OF WATER AND DEVICE FOR ELECTROLYSIS OF WATER |
| PCT/JP2019/010073 WO2019176956A1 (ja) | 2018-03-12 | 2019-03-12 | チタン基材、チタン基材の製造方法、及び、水電解用電極、水電解装置 |
| JP2022008936A JP7227543B2 (ja) | 2018-03-12 | 2022-01-24 | チタン基材、チタン基材の製造方法、及び、水電解用電極、水電解装置 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2018044659 | 2018-03-12 | ||
| JP2018044659 | 2018-03-12 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2022008936A Division JP7227543B2 (ja) | 2018-03-12 | 2022-01-24 | チタン基材、チタン基材の製造方法、及び、水電解用電極、水電解装置 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2019157273A JP2019157273A (ja) | 2019-09-19 |
| JP2019157273A5 JP2019157273A5 (enExample) | 2021-12-23 |
| JP7092076B2 true JP7092076B2 (ja) | 2022-06-28 |
Family
ID=67995859
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019042773A Active JP7092076B2 (ja) | 2018-03-12 | 2019-03-08 | チタン基材、チタン基材の製造方法、及び、水電解用電極、水電解装置 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20200407858A1 (enExample) |
| EP (1) | EP3767009A4 (enExample) |
| JP (1) | JP7092076B2 (enExample) |
| CN (1) | CN111918983B (enExample) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017106601A1 (en) | 2015-12-16 | 2017-06-22 | Amastan Technologies Llc | Spheroidal dehydrogenated metals and metal alloy particles |
| US10987735B2 (en) | 2015-12-16 | 2021-04-27 | 6K Inc. | Spheroidal titanium metallic powders with custom microstructures |
| EP3810358A1 (en) | 2018-06-19 | 2021-04-28 | 6K Inc. | Process for producing spheroidized powder from feedstock materials |
| JP6939747B2 (ja) * | 2018-10-03 | 2021-09-22 | 株式会社豊田中央研究所 | 電極板 |
| CN114007782A (zh) | 2019-04-30 | 2022-02-01 | 6K有限公司 | 机械合金化的粉末原料 |
| JP2023512391A (ja) | 2019-11-18 | 2023-03-27 | シックスケー インコーポレイテッド | 球形粉体用の特異な供給原料及び製造方法 |
| CN113061926A (zh) * | 2019-12-14 | 2021-07-02 | 中国科学院大连化学物理研究所 | 一种用于pem水电解池的亚氧化钛阳极扩散层及其制备方法与应用 |
| US11590568B2 (en) | 2019-12-19 | 2023-02-28 | 6K Inc. | Process for producing spheroidized powder from feedstock materials |
| CN111003759A (zh) * | 2019-12-24 | 2020-04-14 | 广东省稀有金属研究所 | 含亚氧化钛中间层的涂层电极及其制备方法与应用以及电化学水处理设备 |
| EP4130343A4 (en) | 2020-03-26 | 2024-10-30 | Mitsubishi Materials Corporation | TITANIUM SUBSTRATE, METHOD FOR PRODUCING A TITANIUM SUBSTRATE, ELECTRODE FOR WATER ELECTROLYSIS AND WATER ELECTROLYSIS DEVICE |
| JP7494576B2 (ja) * | 2020-05-29 | 2024-06-04 | 堺化学工業株式会社 | 電極材料及びそれを用いた電極、水電解セル |
| AU2021297476A1 (en) | 2020-06-25 | 2022-12-15 | 6K Inc. | Microcomposite alloy structure |
| US11963287B2 (en) | 2020-09-24 | 2024-04-16 | 6K Inc. | Systems, devices, and methods for starting plasma |
| JP2023548325A (ja) | 2020-10-30 | 2023-11-16 | シックスケー インコーポレイテッド | 球状化金属粉末の合成のためのシステムおよび方法 |
| CN112250145B (zh) * | 2020-10-30 | 2021-11-30 | 南京理工大学 | 一种多孔钛基亚氧化钛纳米管二氧化铅电极的制备与应用 |
| JP7576260B2 (ja) | 2020-11-20 | 2024-10-31 | デノラ・ペルメレック株式会社 | アノードの加速評価方法 |
| AU2022206483A1 (en) | 2021-01-11 | 2023-08-31 | 6K Inc. | Methods and systems for reclamation of li-ion cathode materials using microwave plasma processing |
| JPWO2022202740A1 (enExample) * | 2021-03-26 | 2022-09-29 | ||
| JP7608930B2 (ja) * | 2021-03-29 | 2025-01-07 | 三菱マテリアル株式会社 | チタン基材、水電解用電極、および、固体高分子形水電解装置 |
| EP4313449A1 (en) | 2021-03-31 | 2024-02-07 | 6K Inc. | Systems and methods for additive manufacturing of metal nitride ceramics |
| JP7703878B2 (ja) * | 2021-03-31 | 2025-07-08 | 三菱マテリアル株式会社 | チタン基材、水電解用電極、および、固体高分子形水電解装置 |
| CN115161669B (zh) * | 2021-04-07 | 2023-06-09 | 中国科学院福建物质结构研究所 | 一种TiO2/RGO复合材料及其制备方法与应用 |
| CN113517129B (zh) * | 2021-08-16 | 2023-05-05 | 江西省科学院应用物理研究所 | 一种在钕铁硼表面制备耐蚀涂层的方法 |
| CN113546526B (zh) * | 2021-08-30 | 2022-07-05 | 大连海事大学 | 非对称中空纤维钛基膜及其制备方法 |
| CN114229964B (zh) * | 2021-11-23 | 2023-04-11 | 东莞理工学院 | 一种以Ti4O7为基底的表面刻蚀和氟化的阳极制备方法及应用 |
| WO2023229928A1 (en) | 2022-05-23 | 2023-11-30 | 6K Inc. | Microwave plasma apparatus and methods for processing materials using an interior liner |
| US12040162B2 (en) | 2022-06-09 | 2024-07-16 | 6K Inc. | Plasma apparatus and methods for processing feed material utilizing an upstream swirl module and composite gas flows |
| WO2024044498A1 (en) | 2022-08-25 | 2024-02-29 | 6K Inc. | Plasma apparatus and methods for processing feed material utilizing a powder ingress preventor (pip) |
| US12195338B2 (en) | 2022-12-15 | 2025-01-14 | 6K Inc. | Systems, methods, and device for pyrolysis of methane in a microwave plasma for hydrogen and structured carbon powder production |
| AU2024200339B2 (en) * | 2023-03-17 | 2025-11-20 | Kabushiki Kaisha Toshiba | Electrode, membrane electrode assembly, electrochemical cell, stack, and electrolyzer |
| CN119352062B (zh) * | 2024-12-23 | 2025-08-01 | 上海氢盛创合能源科技有限公司 | 一种钛基材双极板耐蚀抗氢脆复合涂层及其制备方法 |
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|---|---|---|---|---|
| US20050014066A1 (en) | 2003-06-19 | 2005-01-20 | Takayuki Shimamune | Electrode |
| JP2006527794A (ja) | 2003-06-19 | 2006-12-07 | アクゾ ノーベル エヌ.ブイ. | 電極 |
| JP2010138023A (ja) | 2008-12-10 | 2010-06-24 | Kyoto Univ | 金属酸化物の還元方法 |
| JP2010521590A (ja) | 2007-03-20 | 2010-06-24 | インドゥストリエ・デ・ノラ・ソチエタ・ペル・アツィオーニ | 電気化学セルとその操作方法 |
| US20120040254A1 (en) | 2010-08-10 | 2012-02-16 | Steven Amendola | Bifunctional (rechargeable) air electrodes |
| JP2012067336A (ja) | 2010-09-21 | 2012-04-05 | Masaaki Arai | 電解水の製造装置及びその製造方法 |
| CN104039450A (zh) | 2011-12-08 | 2014-09-10 | 新加坡国立大学 | 光催化的金属氧化物纳米材料、通过h2-等离子体进行处理的制造方法、用于水中的有机废物净化的用途 |
| CN105734642A (zh) | 2016-03-29 | 2016-07-06 | 上海博友金属制品有限公司 | 一种高强度、大比表面积钛黑涂层的制备方法 |
| JP2016201300A (ja) | 2015-04-13 | 2016-12-01 | トヨタ自動車株式会社 | 燃料電池用セパレータの製造方法及び燃料電池用セパレータ |
| CN107497413A (zh) | 2017-07-27 | 2017-12-22 | 东华大学 | 一种黑色二氧化钛涂层的制备方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1208942A (en) * | 1983-03-16 | 1986-08-05 | John Ambrose | Manufacturing of titanium anode substrates |
| DE69012091T2 (de) * | 1990-02-20 | 1994-12-22 | Atraverda Ltd | Elektrochemische Zelle und Verfahren. |
| LU88516A1 (de) * | 1993-07-21 | 1996-02-01 | Furukawa Electric Co Ltd | Sauerstoff erzeugende Elektrode und Verfahren dieselbe herzustellen |
| CN106958033B (zh) * | 2017-03-17 | 2019-03-26 | 南开大学 | Magnéli相TinO2n-1纳米管电极的制备方法 |
-
2019
- 2019-03-08 JP JP2019042773A patent/JP7092076B2/ja active Active
- 2019-03-12 EP EP19766633.2A patent/EP3767009A4/en not_active Withdrawn
- 2019-03-12 CN CN201980017686.6A patent/CN111918983B/zh active Active
- 2019-03-12 US US16/979,002 patent/US20200407858A1/en not_active Abandoned
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050014066A1 (en) | 2003-06-19 | 2005-01-20 | Takayuki Shimamune | Electrode |
| JP2006527794A (ja) | 2003-06-19 | 2006-12-07 | アクゾ ノーベル エヌ.ブイ. | 電極 |
| JP2010521590A (ja) | 2007-03-20 | 2010-06-24 | インドゥストリエ・デ・ノラ・ソチエタ・ペル・アツィオーニ | 電気化学セルとその操作方法 |
| JP2010138023A (ja) | 2008-12-10 | 2010-06-24 | Kyoto Univ | 金属酸化物の還元方法 |
| US20120040254A1 (en) | 2010-08-10 | 2012-02-16 | Steven Amendola | Bifunctional (rechargeable) air electrodes |
| JP2012067336A (ja) | 2010-09-21 | 2012-04-05 | Masaaki Arai | 電解水の製造装置及びその製造方法 |
| CN104039450A (zh) | 2011-12-08 | 2014-09-10 | 新加坡国立大学 | 光催化的金属氧化物纳米材料、通过h2-等离子体进行处理的制造方法、用于水中的有机废物净化的用途 |
| JP2016201300A (ja) | 2015-04-13 | 2016-12-01 | トヨタ自動車株式会社 | 燃料電池用セパレータの製造方法及び燃料電池用セパレータ |
| CN105734642A (zh) | 2016-03-29 | 2016-07-06 | 上海博友金属制品有限公司 | 一种高强度、大比表面积钛黑涂层的制备方法 |
| CN107497413A (zh) | 2017-07-27 | 2017-12-22 | 东华大学 | 一种黑色二氧化钛涂层的制备方法 |
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| Publication number | Publication date |
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| JP2019157273A (ja) | 2019-09-19 |
| EP3767009A4 (en) | 2021-12-08 |
| US20200407858A1 (en) | 2020-12-31 |
| CN111918983B (zh) | 2023-01-13 |
| CN111918983A (zh) | 2020-11-10 |
| EP3767009A1 (en) | 2021-01-20 |
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