JP7024622B2 - 炭化珪素単結晶およびその製造方法 - Google Patents
炭化珪素単結晶およびその製造方法 Download PDFInfo
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- JP7024622B2 JP7024622B2 JP2018116384A JP2018116384A JP7024622B2 JP 7024622 B2 JP7024622 B2 JP 7024622B2 JP 2018116384 A JP2018116384 A JP 2018116384A JP 2018116384 A JP2018116384 A JP 2018116384A JP 7024622 B2 JP7024622 B2 JP 7024622B2
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- single crystal
- sic single
- heavy metal
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- 239000013078 crystal Substances 0.000 title claims description 167
- 229910010271 silicon carbide Inorganic materials 0.000 title claims description 138
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 title claims description 138
- 238000004519 manufacturing process Methods 0.000 title description 20
- 229910001385 heavy metal Inorganic materials 0.000 claims description 90
- 230000002093 peripheral effect Effects 0.000 claims description 22
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000010955 niobium Substances 0.000 claims description 8
- 229910052758 niobium Inorganic materials 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 229910052715 tantalum Inorganic materials 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 229910052796 boron Inorganic materials 0.000 claims description 4
- 230000005484 gravity Effects 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical group [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 73
- 238000010438 heat treatment Methods 0.000 description 37
- 235000012431 wafers Nutrition 0.000 description 28
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 description 26
- 230000000694 effects Effects 0.000 description 21
- 230000035882 stress Effects 0.000 description 13
- 230000002411 adverse Effects 0.000 description 12
- 239000002994 raw material Substances 0.000 description 12
- 230000007246 mechanism Effects 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 229910002804 graphite Inorganic materials 0.000 description 8
- 239000010439 graphite Substances 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 7
- 239000012535 impurity Substances 0.000 description 6
- 239000011810 insulating material Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- 238000005530 etching Methods 0.000 description 5
- UNASZPQZIFZUSI-UHFFFAOYSA-N methylidyneniobium Chemical compound [Nb]#C UNASZPQZIFZUSI-UHFFFAOYSA-N 0.000 description 5
- NFFIWVVINABMKP-UHFFFAOYSA-N methylidynetantalum Chemical compound [Ta]#C NFFIWVVINABMKP-UHFFFAOYSA-N 0.000 description 5
- 229910003468 tantalcarbide Inorganic materials 0.000 description 5
- 239000011651 chromium Substances 0.000 description 4
- 229910052741 iridium Inorganic materials 0.000 description 4
- 239000011572 manganese Substances 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- 230000035755 proliferation Effects 0.000 description 4
- 230000008646 thermal stress Effects 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 229910052721 tungsten Inorganic materials 0.000 description 4
- 229910052720 vanadium Inorganic materials 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 238000002109 crystal growth method Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 239000003870 refractory metal Substances 0.000 description 3
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000012159 carrier gas Substances 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000005489 elastic deformation Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 238000005092 sublimation method Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/10—Inorganic compounds or compositions
- C30B29/36—Carbides
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B25/00—Single-crystal growth by chemical reaction of reactive gases, e.g. chemical vapour-deposition growth
- C30B25/02—Epitaxial-layer growth
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B25/00—Single-crystal growth by chemical reaction of reactive gases, e.g. chemical vapour-deposition growth
- C30B25/02—Epitaxial-layer growth
- C30B25/18—Epitaxial-layer growth characterised by the substrate
- C30B25/20—Epitaxial-layer growth characterised by the substrate the substrate being of the same materials as the epitaxial layer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/90—Carbides
- C01B32/914—Carbides of single elements
- C01B32/956—Silicon carbide
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2018116384A JP7024622B2 (ja) | 2018-06-19 | 2018-06-19 | 炭化珪素単結晶およびその製造方法 |
| PCT/JP2019/023877 WO2019244834A1 (ja) | 2018-06-19 | 2019-06-17 | 炭化珪素単結晶およびその製造方法 |
| CN201980040774.8A CN112334607B (zh) | 2018-06-19 | 2019-06-17 | 碳化硅单晶及其制造方法 |
| US17/123,338 US11846040B2 (en) | 2018-06-19 | 2020-12-16 | Silicon carbide single crystal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2018116384A JP7024622B2 (ja) | 2018-06-19 | 2018-06-19 | 炭化珪素単結晶およびその製造方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2019218229A JP2019218229A (ja) | 2019-12-26 |
| JP2019218229A5 JP2019218229A5 (enExample) | 2020-10-15 |
| JP7024622B2 true JP7024622B2 (ja) | 2022-02-24 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018116384A Active JP7024622B2 (ja) | 2018-06-19 | 2018-06-19 | 炭化珪素単結晶およびその製造方法 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US11846040B2 (enExample) |
| JP (1) | JP7024622B2 (enExample) |
| CN (1) | CN112334607B (enExample) |
| WO (1) | WO2019244834A1 (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7393900B2 (ja) * | 2019-09-24 | 2023-12-07 | 一般財団法人電力中央研究所 | 炭化珪素単結晶ウェハ及び炭化珪素単結晶インゴットの製造方法 |
| JP7528432B2 (ja) * | 2019-12-09 | 2024-08-06 | 株式会社レゾナック | SiC基板及びSiC単結晶の製造方法 |
| CN114901875B (zh) | 2020-01-24 | 2024-05-10 | 日本碍子株式会社 | 含有稀土的SiC基板和SiC外延层的制造方法 |
| CN114761629B (zh) | 2020-01-24 | 2024-06-25 | 日本碍子株式会社 | 双轴取向SiC复合基板以及半导体器件用复合基板 |
| JP7749528B2 (ja) * | 2022-10-03 | 2025-10-06 | 一般財団法人電力中央研究所 | 炭化珪素単結晶インゴット、炭化珪素ウェハ及び炭化珪素単結晶の製造方法 |
| WO2024084910A1 (ja) * | 2022-10-19 | 2024-04-25 | 住友電気工業株式会社 | 炭化珪素基板、炭化珪素エピタキシャル基板の製造方法および炭化珪素半導体装置の製造方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002234800A (ja) | 2001-02-07 | 2002-08-23 | Denso Corp | 炭化珪素単結晶の製造方法および炭化珪素単結晶 |
| JP2006124247A (ja) | 2004-10-29 | 2006-05-18 | Shikusuon:Kk | 炭化珪素単結晶および炭化珪素基板 |
| WO2012029952A1 (ja) | 2010-09-02 | 2012-03-08 | 株式会社ブリヂストン | 炭化ケイ素単結晶の製造方法、炭化ケイ素単結晶、及び炭化ケイ素単結晶基板 |
| JP2012250864A (ja) | 2011-06-01 | 2012-12-20 | Sumitomo Electric Ind Ltd | 炭化珪素結晶インゴット、炭化珪素結晶ウエハおよび炭化珪素結晶インゴットの製造方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE217368T1 (de) * | 1997-01-22 | 2002-05-15 | Yury Alexandrovich Vodakov | Züchtung von siliziumkarbid einkristallen |
| US7563321B2 (en) | 2004-12-08 | 2009-07-21 | Cree, Inc. | Process for producing high quality large size silicon carbide crystals |
| US10167573B2 (en) * | 2010-11-26 | 2019-01-01 | Shin-Etsu Chemical Co., Ltd. | Method of producing SiC single crystal |
| JP2013173655A (ja) | 2012-02-27 | 2013-09-05 | Nagoya Institute Of Technology | 半導体結晶材料およびこれを用いた半導体素子 |
| EP2881499B1 (en) * | 2013-12-06 | 2020-03-11 | Shin-Etsu Chemical Co., Ltd. | Method for growing silicon carbide crystal |
| JP2016098120A (ja) | 2014-11-18 | 2016-05-30 | 株式会社デンソー | 炭化珪素単結晶インゴットおよび炭化珪素単結晶基板 |
| JP6706786B2 (ja) * | 2015-10-30 | 2020-06-10 | 一般財団法人電力中央研究所 | エピタキシャルウェハの製造方法、エピタキシャルウェハ、半導体装置の製造方法及び半導体装置 |
-
2018
- 2018-06-19 JP JP2018116384A patent/JP7024622B2/ja active Active
-
2019
- 2019-06-17 WO PCT/JP2019/023877 patent/WO2019244834A1/ja not_active Ceased
- 2019-06-17 CN CN201980040774.8A patent/CN112334607B/zh active Active
-
2020
- 2020-12-16 US US17/123,338 patent/US11846040B2/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002234800A (ja) | 2001-02-07 | 2002-08-23 | Denso Corp | 炭化珪素単結晶の製造方法および炭化珪素単結晶 |
| JP2006124247A (ja) | 2004-10-29 | 2006-05-18 | Shikusuon:Kk | 炭化珪素単結晶および炭化珪素基板 |
| WO2012029952A1 (ja) | 2010-09-02 | 2012-03-08 | 株式会社ブリヂストン | 炭化ケイ素単結晶の製造方法、炭化ケイ素単結晶、及び炭化ケイ素単結晶基板 |
| JP2012250864A (ja) | 2011-06-01 | 2012-12-20 | Sumitomo Electric Ind Ltd | 炭化珪素結晶インゴット、炭化珪素結晶ウエハおよび炭化珪素結晶インゴットの製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2019218229A (ja) | 2019-12-26 |
| CN112334607B (zh) | 2022-09-16 |
| US20210102311A1 (en) | 2021-04-08 |
| WO2019244834A1 (ja) | 2019-12-26 |
| CN112334607A (zh) | 2021-02-05 |
| US11846040B2 (en) | 2023-12-19 |
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