JP6881892B2 - 固体電解質、全固体電池及び固体電解質の製造方法 - Google Patents
固体電解質、全固体電池及び固体電解質の製造方法 Download PDFInfo
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- JP6881892B2 JP6881892B2 JP2015255090A JP2015255090A JP6881892B2 JP 6881892 B2 JP6881892 B2 JP 6881892B2 JP 2015255090 A JP2015255090 A JP 2015255090A JP 2015255090 A JP2015255090 A JP 2015255090A JP 6881892 B2 JP6881892 B2 JP 6881892B2
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- solid electrolyte
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- 239000007784 solid electrolyte Substances 0.000 title claims description 60
- 238000004519 manufacturing process Methods 0.000 title claims description 16
- 239000000203 mixture Substances 0.000 claims description 32
- 229910052708 sodium Inorganic materials 0.000 claims description 15
- 229910052744 lithium Inorganic materials 0.000 claims description 14
- 239000011521 glass Substances 0.000 claims description 12
- 229910052717 sulfur Inorganic materials 0.000 claims description 12
- 229910018091 Li 2 S Inorganic materials 0.000 claims description 11
- 238000002441 X-ray diffraction Methods 0.000 claims description 9
- 239000007774 positive electrode material Substances 0.000 claims description 9
- 229910052700 potassium Inorganic materials 0.000 claims description 8
- 239000007773 negative electrode material Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 5
- 239000002241 glass-ceramic Substances 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 230000009477 glass transition Effects 0.000 claims description 3
- 238000003801 milling Methods 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 229910018035 Li 1-x M1 Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 description 44
- 230000000052 comparative effect Effects 0.000 description 32
- 239000013078 crystal Substances 0.000 description 19
- 150000001768 cations Chemical class 0.000 description 14
- 239000000463 material Substances 0.000 description 12
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 10
- 238000003701 mechanical milling Methods 0.000 description 10
- 229910052783 alkali metal Inorganic materials 0.000 description 9
- 150000001340 alkali metals Chemical class 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 239000003153 chemical reaction reagent Substances 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 238000000691 measurement method Methods 0.000 description 6
- 239000008188 pellet Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 239000002134 carbon nanofiber Substances 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 5
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 4
- 239000011149 active material Substances 0.000 description 4
- 239000004020 conductor Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- -1 sodium halide Chemical class 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000002388 carbon-based active material Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 description 2
- 229910001416 lithium ion Inorganic materials 0.000 description 2
- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- ZKATWMILCYLAPD-UHFFFAOYSA-N niobium pentoxide Chemical compound O=[Nb](=O)O[Nb](=O)=O ZKATWMILCYLAPD-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000002203 sulfidic glass Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910002986 Li4Ti5O12 Inorganic materials 0.000 description 1
- 229910002995 LiNi0.8Co0.15Al0.05O2 Inorganic materials 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- QTHKJEYUQSLYTH-UHFFFAOYSA-N [Co]=O.[Ni].[Li] Chemical compound [Co]=O.[Ni].[Li] QTHKJEYUQSLYTH-UHFFFAOYSA-N 0.000 description 1
- HFCVPDYCRZVZDF-UHFFFAOYSA-N [Li+].[Co+2].[Ni+2].[O-][Mn]([O-])(=O)=O Chemical compound [Li+].[Co+2].[Ni+2].[O-][Mn]([O-])(=O)=O HFCVPDYCRZVZDF-UHFFFAOYSA-N 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- NDPGDHBNXZOBJS-UHFFFAOYSA-N aluminum lithium cobalt(2+) nickel(2+) oxygen(2-) Chemical compound [Li+].[O--].[O--].[O--].[O--].[Al+3].[Co++].[Ni++] NDPGDHBNXZOBJS-UHFFFAOYSA-N 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 229910021383 artificial graphite Inorganic materials 0.000 description 1
- 239000006258 conductive agent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- QHGJSLXSVXVKHZ-UHFFFAOYSA-N dilithium;dioxido(dioxo)manganese Chemical compound [Li+].[Li+].[O-][Mn]([O-])(=O)=O QHGJSLXSVXVKHZ-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910021385 hard carbon Inorganic materials 0.000 description 1
- 238000002847 impedance measurement Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- CASZBAVUIZZLOB-UHFFFAOYSA-N lithium iron(2+) oxygen(2-) Chemical compound [O-2].[Fe+2].[Li+] CASZBAVUIZZLOB-UHFFFAOYSA-N 0.000 description 1
- URIIGZKXFBNRAU-UHFFFAOYSA-N lithium;oxonickel Chemical compound [Li].[Ni]=O URIIGZKXFBNRAU-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910021382 natural graphite Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 229910021384 soft carbon Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0562—Solid materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
- H01M10/0585—Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Secondary Cells (AREA)
- Conductive Materials (AREA)
- Glass Compositions (AREA)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2015255090A JP6881892B2 (ja) | 2015-12-25 | 2015-12-25 | 固体電解質、全固体電池及び固体電解質の製造方法 |
KR1020160070973A KR102561098B1 (ko) | 2015-12-25 | 2016-06-08 | 고체 전해질, 및 이를 포함하는 리튬 전지 |
US15/354,614 US11245131B2 (en) | 2015-12-25 | 2016-11-17 | Solid electrolyte and lithium battery including the same |
US17/551,299 US11955602B2 (en) | 2015-12-25 | 2021-12-15 | Solid electrolyte and lithium battery including the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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JP2015255090A JP6881892B2 (ja) | 2015-12-25 | 2015-12-25 | 固体電解質、全固体電池及び固体電解質の製造方法 |
Publications (2)
Publication Number | Publication Date |
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JP2017117753A JP2017117753A (ja) | 2017-06-29 |
JP6881892B2 true JP6881892B2 (ja) | 2021-06-02 |
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JP2015255090A Active JP6881892B2 (ja) | 2015-12-25 | 2015-12-25 | 固体電解質、全固体電池及び固体電解質の製造方法 |
Country Status (2)
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JP (1) | JP6881892B2 (ko) |
KR (1) | KR102561098B1 (ko) |
Families Citing this family (34)
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JP2017199631A (ja) * | 2016-04-28 | 2017-11-02 | 出光興産株式会社 | 硫化物固体電解質、電極合材及びリチウムイオン電池 |
KR20200000849A (ko) * | 2017-05-24 | 2020-01-03 | 시온 파워 코퍼레이션 | 이온 전도성 화합물 및 관련 용도 |
CN109786814A (zh) * | 2017-11-14 | 2019-05-21 | 三星电子株式会社 | 用于全固态二次电池的固体电解质、复合电极、全固态二次电池和制备固体电解质的方法 |
CN111344812B (zh) * | 2017-11-14 | 2022-07-22 | 出光兴产株式会社 | 含金属元素的硫化物类固体电解质及其制造方法 |
US10985407B2 (en) | 2017-11-21 | 2021-04-20 | Samsung Electronics Co., Ltd. | All-solid-state secondary battery including anode active material alloyable with lithium and method of charging the same |
EP3736829A4 (en) | 2018-01-05 | 2021-03-10 | Panasonic Intellectual Property Management Co., Ltd. | SOLID ELECTROLYTE MATERIAL AND BATTERY |
JP7253707B2 (ja) | 2018-01-05 | 2023-04-07 | パナソニックIpマネジメント株式会社 | 固体電解質材料、および、電池 |
EP3736897A4 (en) | 2018-01-05 | 2021-03-17 | Panasonic Intellectual Property Management Co., Ltd. | SOLID ELECTROLYTE MATERIAL AND BATTERY |
EP3736826A4 (en) | 2018-01-05 | 2021-03-10 | Panasonic Intellectual Property Management Co., Ltd. | SOLID ELECTROLYTE AND BATTERY |
WO2019135347A1 (ja) | 2018-01-05 | 2019-07-11 | パナソニックIpマネジメント株式会社 | 固体電解質材料、および、電池 |
CN111492443B (zh) | 2018-01-05 | 2022-04-29 | 松下知识产权经营株式会社 | 固体电解质材料和电池 |
EP3736833A4 (en) | 2018-01-05 | 2021-03-10 | Panasonic Intellectual Property Management Co., Ltd. | SOLID ELECTROLYTE MATERIAL AND BATTERY |
JP7281672B2 (ja) | 2018-01-05 | 2023-05-26 | パナソニックIpマネジメント株式会社 | 電池 |
WO2019135346A1 (ja) | 2018-01-05 | 2019-07-11 | パナソニックIpマネジメント株式会社 | 正極材料、および、電池 |
WO2019135343A1 (ja) | 2018-01-05 | 2019-07-11 | パナソニックIpマネジメント株式会社 | 固体電解質材料、および、電池 |
CN111587508A (zh) | 2018-01-26 | 2020-08-25 | 松下知识产权经营株式会社 | 电池 |
EP3745503A4 (en) | 2018-01-26 | 2021-03-10 | Panasonic Intellectual Property Management Co., Ltd. | POSITIVE ELECTRODE MATERIAL AND USING BATTERY |
JP7217432B2 (ja) | 2018-01-26 | 2023-02-03 | パナソニックIpマネジメント株式会社 | 正極材料およびそれを用いた電池 |
US11437643B2 (en) | 2018-02-20 | 2022-09-06 | Samsung Electronics Co., Ltd. | All-solid-state secondary battery |
US11127974B2 (en) | 2018-05-14 | 2021-09-21 | Samsung Electronics Co., Ltd. | Method of preparing sulfide-based solid electrolyte, sulfide-based solid electrolyte prepared therefrom, and solid secondary battery including the sulfide electrolyte |
JP7031553B2 (ja) * | 2018-10-12 | 2022-03-08 | トヨタ自動車株式会社 | 固体電解質 |
CN112368863A (zh) | 2018-11-29 | 2021-02-12 | 松下知识产权经营株式会社 | 负极材料、电池以及电池的制造方法 |
JP7429869B2 (ja) | 2018-11-29 | 2024-02-09 | パナソニックIpマネジメント株式会社 | 負極材料、および、電池 |
US11702337B2 (en) | 2019-09-27 | 2023-07-18 | Samsung Sdi Co., Ltd. | Solid ion conductor, solid electrolyte including the solid ion conductor, electrochemical cell including the solid ion conductor, and preparation method of the same |
KR20210044719A (ko) * | 2019-10-15 | 2021-04-23 | 한양대학교 에리카산학협력단 | 고체 전해질의 중간 생성물, 이를 이용한 고체 전해질, 이를 포함하는 이차 전지, 및 그들의 제조 방법 |
KR20210054817A (ko) | 2019-11-06 | 2021-05-14 | 삼성에스디아이 주식회사 | 고체 전해질, 이를 포함하는 전기화학전지 및 고체 전해질의 제조방법 |
EP3819964A1 (en) | 2019-11-07 | 2021-05-12 | Samsung SDI Co., Ltd. | Solid electrolyte, electrochemical cell including solid electrolyte, and method of preparing solid electrolyte |
KR102358150B1 (ko) * | 2019-11-25 | 2022-02-04 | 울산대학교 산학협력단 | Li2S-MaXb-P2S5 타입 고체 전해질 및 이를 포함하는 리튬 이온 배터리 |
CN115152068A (zh) | 2019-12-10 | 2022-10-04 | 株式会社杰士汤浅国际 | 固体电解质、锂离子蓄电元件和蓄电装置 |
EP4075450A4 (en) | 2019-12-11 | 2023-06-14 | Mitsui Mining & Smelting Co., Ltd. | SOLID SULFIDE ELECTROLYTE |
KR20210098246A (ko) | 2020-01-31 | 2021-08-10 | 삼성에스디아이 주식회사 | 전고체이차전지 및 그 제조방법 |
EP4180389A1 (en) * | 2020-07-07 | 2023-05-17 | Agc Inc. | Sulfide-based solid electrolyte used in lithium ion secondary battery, method for producing same, and lithium ion secondary battery |
KR20220039386A (ko) * | 2020-09-22 | 2022-03-29 | 삼성에스디아이 주식회사 | 고체이온전도체 화합물, 이를 포함하는 고체전해질, 이를 포함하는 전기화학 셀, 및 이의 제조방법 |
KR20220043754A (ko) * | 2020-09-29 | 2022-04-05 | 삼성에스디아이 주식회사 | 고체이온전도체 화합물, 이를 포함하는 고체전해질, 이를 포함하는 전기화학 셀, 및 이의 제조방법 |
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AU2011230239B2 (en) * | 2010-03-26 | 2014-01-16 | Tokyo Institute Of Technology | Sulfide solid electrolyte material, battery, and method for producing sulfide solid electrolyte material |
JP5888610B2 (ja) * | 2011-12-22 | 2016-03-22 | 国立大学法人東京工業大学 | 硫化物固体電解質材料、電池および硫化物固体電解質材料の製造方法 |
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JP6307262B2 (ja) * | 2013-12-17 | 2018-04-04 | 三星電子株式会社Samsung Electronics Co.,Ltd. | リチウムイオン二次電池およびリチウムイオン二次電池の製造方法 |
DE102014206829A1 (de) * | 2014-04-09 | 2015-10-15 | Robert Bosch Gmbh | Galvanisches Element |
JP6044588B2 (ja) * | 2014-05-15 | 2016-12-14 | トヨタ自動車株式会社 | 硫化物固体電解質材料、電池および硫化物固体電解質材料の製造方法 |
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