JP6689969B2 - エステル化合物及びその用途 - Google Patents
エステル化合物及びその用途 Download PDFInfo
- Publication number
- JP6689969B2 JP6689969B2 JP2018520696A JP2018520696A JP6689969B2 JP 6689969 B2 JP6689969 B2 JP 6689969B2 JP 2018520696 A JP2018520696 A JP 2018520696A JP 2018520696 A JP2018520696 A JP 2018520696A JP 6689969 B2 JP6689969 B2 JP 6689969B2
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- JP
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- Prior art keywords
- compound
- trans
- dimethylcyclopropanecarboxylate
- cis
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003795 chemical substances by application Substances 0.000 claims description 75
- 239000000126 substance Substances 0.000 claims description 63
- 241000607479 Yersinia pestis Species 0.000 claims description 57
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 57
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 53
- 125000004432 carbon atom Chemical group C* 0.000 claims description 44
- 125000000217 alkyl group Chemical group 0.000 claims description 38
- 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 claims description 32
- 238000000034 method Methods 0.000 claims description 28
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 20
- 125000001494 2-propynyl group Chemical group [H]C#CC([H])([H])* 0.000 claims description 20
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims description 20
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 20
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 19
- 229910052801 chlorine Inorganic materials 0.000 claims description 18
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 18
- 125000001153 fluoro group Chemical group F* 0.000 claims description 14
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 13
- 239000004480 active ingredient Substances 0.000 claims description 13
- 229910052731 fluorine Inorganic materials 0.000 claims description 13
- 125000005843 halogen group Chemical group 0.000 claims description 7
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 6
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 6
- 125000001188 haloalkyl group Chemical group 0.000 claims description 6
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
- C07C69/743—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring of acids with a three-membered ring and with unsaturation outside the ring
- C07C69/747—Chrysanthemumic acid esters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
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JP2016140848 | 2016-07-15 | ||
PCT/JP2017/014800 WO2017208632A1 (ja) | 2016-05-31 | 2017-04-11 | エステル化合物及びその用途 |
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CN (1) | CN109195944B (zh) |
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JP7200845B2 (ja) * | 2018-10-23 | 2023-01-10 | 住友化学株式会社 | エステル化合物及びその用途 |
WO2020084846A1 (ja) * | 2018-10-23 | 2020-04-30 | 住友化学株式会社 | エステル化合物及びその用途 |
CN109384669A (zh) * | 2018-12-26 | 2019-02-26 | 江苏扬农化工股份有限公司 | 一种拟除虫菊酯化合物及其合成方法和应用 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS503370B1 (zh) * | 1966-10-26 | 1975-02-04 | ||
JPS49489B1 (zh) * | 1970-06-13 | 1974-01-08 | ||
IL41434A (en) * | 1973-01-30 | 1976-08-31 | Shell Int Research | Substituted benzyl esters of 2,2-dihalo cyclopropane-carboxylic acids,their preparation and insecticidal and acaricidal compositions containing them |
DE2658074C2 (de) * | 1976-12-22 | 1986-12-04 | Bayer Ag, 5090 Leverkusen | Cyclopropancarbonsäureester von halogenierten Benzylalkoholen, Verfahren zu ihrer Herstellung und ihre Verwendung zur Bekämpfung von Insekten und Akariden |
US4183950A (en) * | 1976-12-22 | 1980-01-15 | Bayer Aktiengesellschaft | Combating arthropods with 2,2-dimethyl-3-vinyl-cyclopropane carboxylic acid esters of halogenated benzyl alcohols |
US4375476A (en) * | 1980-10-14 | 1983-03-01 | Fmc Corporation | Insecticidal (2,6-dimethyl-3-substituted phenyl)methyl cyclopropanecarboxylates |
EP0060617A1 (en) * | 1981-03-18 | 1982-09-22 | Imperial Chemical Industries Plc | Fluorobenzyl cyclopropane carboxylates, their preparation, compositions and use as insecticides |
GB8522656D0 (en) * | 1985-09-13 | 1985-10-16 | Ici Plc | Fluoro alcohols |
FR2642421B1 (fr) * | 1989-01-30 | 1991-09-06 | Roussel Uclaf | Nouveaux derives de l'acide 2,2-dimethyl 3-(2-monohaloethenyl) cyclopropane carboxylique, leur procede de preparation et leur application comme medicaments |
JP3728967B2 (ja) * | 1998-02-26 | 2005-12-21 | 住友化学株式会社 | エステル化合物 |
MY118214A (en) * | 1998-02-26 | 2004-09-30 | Sumitomo Chemical Co | Ester of 2,2-dimethyl-cyclopropanecarboxylic acid and their use as pesticides |
JP4855325B2 (ja) * | 2007-04-18 | 2012-01-18 | 大日本除蟲菊株式会社 | ベンジルアルコールエステル誘導体を有効成分として含有する常温揮散性殺虫剤又は常温揮散性防虫剤。 |
CN100584817C (zh) * | 2008-10-14 | 2010-01-27 | 江苏扬农化工股份有限公司 | 拟除虫菊酯化合物及应用 |
CN104788315B (zh) * | 2010-01-21 | 2018-03-23 | 江苏扬农化工股份有限公司 | 可用于杀虫的酯化合物 |
-
2017
- 2017-04-07 TW TW106111755A patent/TWI663151B/zh active
- 2017-04-11 JP JP2018520696A patent/JP6689969B2/ja active Active
- 2017-04-11 CN CN201780029352.1A patent/CN109195944B/zh active Active
- 2017-04-11 WO PCT/JP2017/014800 patent/WO2017208632A1/ja active Application Filing
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TWI663151B (zh) | 2019-06-21 |
JPWO2017208632A1 (ja) | 2019-03-14 |
CN109195944B (zh) | 2022-06-14 |
WO2017208632A1 (ja) | 2017-12-07 |
CN109195944A (zh) | 2019-01-11 |
TW201742856A (zh) | 2017-12-16 |
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