JP6637441B2 - 空気電池用のアノード及び電解液 - Google Patents
空気電池用のアノード及び電解液 Download PDFInfo
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- JP6637441B2 JP6637441B2 JP2016565248A JP2016565248A JP6637441B2 JP 6637441 B2 JP6637441 B2 JP 6637441B2 JP 2016565248 A JP2016565248 A JP 2016565248A JP 2016565248 A JP2016565248 A JP 2016565248A JP 6637441 B2 JP6637441 B2 JP 6637441B2
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- electrolyte
- anode
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- aluminum
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- 239000003792 electrolyte Substances 0.000 title claims description 229
- 239000002245 particle Substances 0.000 claims description 25
- 229910000838 Al alloy Inorganic materials 0.000 claims description 20
- 239000003513 alkali Substances 0.000 claims description 18
- 229910052782 aluminium Inorganic materials 0.000 claims description 17
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 17
- 239000004094 surface-active agent Substances 0.000 claims description 17
- 239000002253 acid Substances 0.000 claims description 16
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 15
- 229910052726 zirconium Inorganic materials 0.000 claims description 15
- 239000000243 solution Substances 0.000 claims description 14
- 229910052708 sodium Inorganic materials 0.000 claims description 13
- 239000011734 sodium Substances 0.000 claims description 13
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 12
- 239000011159 matrix material Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- 229910052731 fluorine Inorganic materials 0.000 claims description 6
- 239000011737 fluorine Substances 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052794 bromium Inorganic materials 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical group [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- JMYBUNAHNWHHGK-UHFFFAOYSA-J [F-].[F-].[F-].[F-].F.[Al+3].[K+] Chemical compound [F-].[F-].[F-].[F-].F.[Al+3].[K+] JMYBUNAHNWHHGK-UHFFFAOYSA-J 0.000 claims description 3
- 239000011630 iodine Substances 0.000 claims description 3
- 229910052740 iodine Inorganic materials 0.000 claims description 3
- 239000011236 particulate material Substances 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- 239000011260 aqueous acid Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 150000001875 compounds Chemical group 0.000 claims 7
- 239000008151 electrolyte solution Substances 0.000 claims 4
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 2
- 239000013618 particulate matter Substances 0.000 claims 1
- 239000007789 gas Substances 0.000 description 31
- 238000010438 heat treatment Methods 0.000 description 29
- 238000006243 chemical reaction Methods 0.000 description 20
- 229910052751 metal Inorganic materials 0.000 description 19
- 239000002184 metal Substances 0.000 description 19
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 15
- 238000002844 melting Methods 0.000 description 15
- 230000008018 melting Effects 0.000 description 15
- 239000001301 oxygen Substances 0.000 description 15
- 229910052760 oxygen Inorganic materials 0.000 description 15
- 239000004020 conductor Substances 0.000 description 14
- 239000007788 liquid Substances 0.000 description 13
- 229910052736 halogen Inorganic materials 0.000 description 12
- 150000002367 halogens Chemical class 0.000 description 12
- 238000000926 separation method Methods 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 10
- 239000000446 fuel Substances 0.000 description 10
- 230000006698 induction Effects 0.000 description 10
- 238000004140 cleaning Methods 0.000 description 9
- 238000003860 storage Methods 0.000 description 9
- 229910045601 alloy Inorganic materials 0.000 description 8
- 239000000956 alloy Substances 0.000 description 8
- 230000007423 decrease Effects 0.000 description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- 238000005868 electrolysis reaction Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000011244 liquid electrolyte Substances 0.000 description 6
- 239000012528 membrane Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 5
- 229910001092 metal group alloy Inorganic materials 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- 230000033228 biological regulation Effects 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000001419 dependent effect Effects 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 230000005672 electromagnetic field Effects 0.000 description 3
- 238000004146 energy storage Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 229910001338 liquidmetal Inorganic materials 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000011144 upstream manufacturing Methods 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- DNEHKUCSURWDGO-UHFFFAOYSA-N aluminum sodium Chemical compound [Na].[Al] DNEHKUCSURWDGO-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000003487 electrochemical reaction Methods 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 229910000528 Na alloy Inorganic materials 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229910052789 astatine Inorganic materials 0.000 description 1
- RYXHOMYVWAEKHL-UHFFFAOYSA-N astatine atom Chemical compound [At] RYXHOMYVWAEKHL-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 238000007084 catalytic combustion reaction Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012777 electrically insulating material Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000003385 sodium Chemical class 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- H01M4/463—Aluminium based
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Description
Claims (19)
- ナトリウム母材(53)の中にアルミニウム合金の粒子(54)を含むアノード本体(12)を備える
アルミニウム空気電池のためのアノード。 - 前記アノード本体(12)における粒子(54)の割合は、40重量%から80重量%までの範囲にある
ことを特徴とする請求項1のアノード。 - 前記アノード本体(12)における粒子(54)の割合は、60重量%から70重量%までの範囲にある
ことを特徴とする請求項2のアノード。 - 前記アルミニウム合金はジルコニウムを含む
ことを特徴とする請求項1〜3のいずれか1項のアノード。 - 前記アルミニウム合金は、0.01重量%から1.00重量%までのジルコニウムを含む
ことを特徴とする請求項4のアノード。 - 前記アルミニウム合金は、0.05重量%から0.80重量%までのジルコニウムを含む
ことを特徴とする請求項5のアノード。 - ナトリウム母材(53)の中にアルミニウム合金の粒子(54)を含む固形物の、空気電池(1)のアノード(11)のアノード本体(12)としての
使用法。 - アルミニウム空気電池(1)のためのアノード(11)を製造する方法であって、
アルミニウム合金を有する粒子状の物質がナトリウム溶融物に投入され、
前記ナトリウム溶融物を有する前記アノード(11)のアノード本体(12)が、投入された粒子状の物質とともに鋳造される
方法。 - フッ素、塩素、臭素及びヨウ素のうちの少なくとも1つの化合物と少なくとも1つの界面活性剤とを含む酸の水溶液又はアルカリの水溶液から成る、
アルミニウム空気電池(1)のための電解液。 - 前記酸又はアルカリは、水において10重量%から40重量%までの割合を有する
ことを特徴とする請求項9の電解液。 - 前記化合物は、前記酸又はアルカリにおいて0.1重量%から4.0重量%までの割合を有する
ことを特徴とする請求項9又は10の電解液。 - 前記化合物は、前記酸又はアルカリにおいて0.5重量%から2.0重量%までの割合を有する
ことを特徴とする請求項11の電解液。 - 前記化合物は、フッ化物である
ことを特徴とする請求項9〜12のいずれか1項の電解液。 - 前記化合物は、五フッ化カリウムアルミニウムである
ことを特徴とする請求項13の電解液。 - 前記界面活性剤は、前記酸又はアルカリにおいて0.1重量%から2.0重量%までの割合を有する
ことを特徴とする請求項9〜14のいずれか1項の電解液。 - 前記界面活性剤は、前記酸又はアルカリにおいて0.2重量%から1.0重量%までの割合を有する
ことを特徴とする請求項15の電解液。 - 前記界面活性剤は、ラウリル硫酸ナトリウムである
ことを特徴とする請求項9〜16のいずれか1項の電解液。 - フッ素、塩素、臭素及びヨウ素のうちの少なくとも1つの化合物と少なくとも1つの界面活性剤とを含む酸の水溶液又はアルカリの水溶液から成る混合物の、アルミニウム空気電池(1)の電解液としての
使用法。 - カソード(7)と、
アノード(11)と、
前記カソード(7)と前記アノード(11)との間に配置された電解液とを有し、
前記アノード(11)は請求項1〜6のいずれか1項のアノードとして構成され、及び/又は、前記電解液は請求項9〜17のいずれか1項の電解液として構成される
空気電池、好ましくはアルミニウム空気電池。
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DE102014208047.9A DE102014208047A1 (de) | 2014-04-29 | 2014-04-29 | Anode und Elektrolyt für eine Metall-Luft-Batterie |
DE102014208047.9 | 2014-04-29 | ||
PCT/EP2015/057742 WO2015165707A1 (de) | 2014-04-29 | 2015-04-09 | Anode und elektrolyt für eine metall-luft-batterie |
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JP2017517100A JP2017517100A (ja) | 2017-06-22 |
JP6637441B2 true JP6637441B2 (ja) | 2020-01-29 |
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US (1) | US10326187B2 (ja) |
EP (1) | EP3138151B1 (ja) |
JP (1) | JP6637441B2 (ja) |
KR (1) | KR20160146995A (ja) |
CN (1) | CN106471648B (ja) |
DE (1) | DE102014208047A1 (ja) |
IL (1) | IL248409A0 (ja) |
WO (1) | WO2015165707A1 (ja) |
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2015
- 2015-04-09 JP JP2016565248A patent/JP6637441B2/ja not_active Expired - Fee Related
- 2015-04-09 US US15/307,808 patent/US10326187B2/en not_active Expired - Fee Related
- 2015-04-09 EP EP15716479.9A patent/EP3138151B1/de not_active Not-in-force
- 2015-04-09 WO PCT/EP2015/057742 patent/WO2015165707A1/de active Application Filing
- 2015-04-09 CN CN201580033481.9A patent/CN106471648B/zh not_active Expired - Fee Related
- 2015-04-09 KR KR1020167033103A patent/KR20160146995A/ko unknown
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EP3138151B1 (de) | 2018-10-03 |
US20170047626A1 (en) | 2017-02-16 |
DE102014208047A1 (de) | 2015-10-29 |
US10326187B2 (en) | 2019-06-18 |
CN106471648B (zh) | 2020-02-14 |
KR20160146995A (ko) | 2016-12-21 |
JP2017517100A (ja) | 2017-06-22 |
WO2015165707A1 (de) | 2015-11-05 |
CN106471648A (zh) | 2017-03-01 |
IL248409A0 (en) | 2016-11-30 |
EP3138151A1 (de) | 2017-03-08 |
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