JP6607861B2 - 架橋組成物及びその形成方法 - Google Patents
架橋組成物及びその形成方法 Download PDFInfo
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- JP6607861B2 JP6607861B2 JP2016552216A JP2016552216A JP6607861B2 JP 6607861 B2 JP6607861 B2 JP 6607861B2 JP 2016552216 A JP2016552216 A JP 2016552216A JP 2016552216 A JP2016552216 A JP 2016552216A JP 6607861 B2 JP6607861 B2 JP 6607861B2
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- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- JRBJSXQPQWSCCF-UHFFFAOYSA-N 3,3'-Dimethoxybenzidine Chemical compound C1=C(N)C(OC)=CC(C=2C=C(OC)C(N)=CC=2)=C1 JRBJSXQPQWSCCF-UHFFFAOYSA-N 0.000 description 1
- LJGHYPLBDBRCRZ-UHFFFAOYSA-N 3-(3-aminophenyl)sulfonylaniline Chemical compound NC1=CC=CC(S(=O)(=O)C=2C=C(N)C=CC=2)=C1 LJGHYPLBDBRCRZ-UHFFFAOYSA-N 0.000 description 1
- ZBMISJGHVWNWTE-UHFFFAOYSA-N 3-(4-aminophenoxy)aniline Chemical compound C1=CC(N)=CC=C1OC1=CC=CC(N)=C1 ZBMISJGHVWNWTE-UHFFFAOYSA-N 0.000 description 1
- YEBSYMIZFYCPRG-UHFFFAOYSA-N 3-(oxomethylidene)penta-1,4-diene-1,5-dione Chemical compound O=C=CC(=C=O)C=C=O YEBSYMIZFYCPRG-UHFFFAOYSA-N 0.000 description 1
- WCXGOVYROJJXHA-UHFFFAOYSA-N 3-[4-[4-(3-aminophenoxy)phenyl]sulfonylphenoxy]aniline Chemical compound NC1=CC=CC(OC=2C=CC(=CC=2)S(=O)(=O)C=2C=CC(OC=3C=C(N)C=CC=3)=CC=2)=C1 WCXGOVYROJJXHA-UHFFFAOYSA-N 0.000 description 1
- QRCRYGXAOIFJGN-UHFFFAOYSA-N 3-ethenyloxolane-2,5-dione Chemical compound C=CC1CC(=O)OC1=O QRCRYGXAOIFJGN-UHFFFAOYSA-N 0.000 description 1
- ICNFHJVPAJKPHW-UHFFFAOYSA-N 4,4'-Thiodianiline Chemical compound C1=CC(N)=CC=C1SC1=CC=C(N)C=C1 ICNFHJVPAJKPHW-UHFFFAOYSA-N 0.000 description 1
- KOGSPLLRMRSADR-UHFFFAOYSA-N 4-(2-aminopropan-2-yl)-1-methylcyclohexan-1-amine Chemical compound CC(C)(N)C1CCC(C)(N)CC1 KOGSPLLRMRSADR-UHFFFAOYSA-N 0.000 description 1
- BFWYZZPDZZGSLJ-UHFFFAOYSA-N 4-(aminomethyl)aniline Chemical compound NCC1=CC=C(N)C=C1 BFWYZZPDZZGSLJ-UHFFFAOYSA-N 0.000 description 1
- DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 description 1
- BEKFRNOZJSYWKZ-UHFFFAOYSA-N 4-[2-(4-aminophenyl)-1,1,1,3,3,3-hexafluoropropan-2-yl]aniline Chemical compound C1=CC(N)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(N)C=C1 BEKFRNOZJSYWKZ-UHFFFAOYSA-N 0.000 description 1
- ZYEDGEXYGKWJPB-UHFFFAOYSA-N 4-[2-(4-aminophenyl)propan-2-yl]aniline Chemical compound C=1C=C(N)C=CC=1C(C)(C)C1=CC=C(N)C=C1 ZYEDGEXYGKWJPB-UHFFFAOYSA-N 0.000 description 1
- KMKWGXGSGPYISJ-UHFFFAOYSA-N 4-[4-[2-[4-(4-aminophenoxy)phenyl]propan-2-yl]phenoxy]aniline Chemical compound C=1C=C(OC=2C=CC(N)=CC=2)C=CC=1C(C)(C)C(C=C1)=CC=C1OC1=CC=C(N)C=C1 KMKWGXGSGPYISJ-UHFFFAOYSA-N 0.000 description 1
- NVKGJHAQGWCWDI-UHFFFAOYSA-N 4-[4-amino-2-(trifluoromethyl)phenyl]-3-(trifluoromethyl)aniline Chemical group FC(F)(F)C1=CC(N)=CC=C1C1=CC=C(N)C=C1C(F)(F)F NVKGJHAQGWCWDI-UHFFFAOYSA-N 0.000 description 1
- KIFDSGGWDIVQGN-UHFFFAOYSA-N 4-[9-(4-aminophenyl)fluoren-9-yl]aniline Chemical compound C1=CC(N)=CC=C1C1(C=2C=CC(N)=CC=2)C2=CC=CC=C2C2=CC=CC=C21 KIFDSGGWDIVQGN-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- QPBMSSPJMNKDIM-UHFFFAOYSA-N NC1=CC=C(OC2=CC=C(C=C2)S(=O)(=O)C2=CC=C(C=C2)OC2=CC=C(C=C2)N)C=C1.NC1=C(C=C(C=C1)C1(C2=CC=CC=C2C=2C=CC=CC12)C1=CC(=C(C=C1)N)C)C Chemical compound NC1=CC=C(OC2=CC=C(C=C2)S(=O)(=O)C2=CC=C(C=C2)OC2=CC=C(C=C2)N)C=C1.NC1=C(C=C(C=C1)C1(C2=CC=CC=C2C=2C=CC=CC12)C1=CC(=C(C=C1)N)C)C QPBMSSPJMNKDIM-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000005700 Putrescine Substances 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005844 Thymol Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- GKXVJHDEWHKBFH-UHFFFAOYSA-N [2-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC=C1CN GKXVJHDEWHKBFH-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- IMUDHTPIFIBORV-UHFFFAOYSA-N aminoethylpiperazine Chemical compound NCCN1CCNCC1 IMUDHTPIFIBORV-UHFFFAOYSA-N 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 150000004984 aromatic diamines Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- NHOWLEZFTHYCTP-UHFFFAOYSA-N benzylhydrazine Chemical compound NNCC1=CC=CC=C1 NHOWLEZFTHYCTP-UHFFFAOYSA-N 0.000 description 1
- ZLSMCQSGRWNEGX-UHFFFAOYSA-N bis(4-aminophenyl)methanone Chemical class C1=CC(N)=CC=C1C(=O)C1=CC=C(N)C=C1 ZLSMCQSGRWNEGX-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- RECUKUPTGUEGMW-UHFFFAOYSA-N carvacrol Chemical compound CC(C)C1=CC=C(C)C(O)=C1 RECUKUPTGUEGMW-UHFFFAOYSA-N 0.000 description 1
- HHTWOMMSBMNRKP-UHFFFAOYSA-N carvacrol Natural products CC(=C)C1=CC=C(C)C(O)=C1 HHTWOMMSBMNRKP-UHFFFAOYSA-N 0.000 description 1
- 235000007746 carvacrol Nutrition 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 125000003636 chemical group Chemical group 0.000 description 1
- 239000007806 chemical reaction intermediate Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- SWBRHWCHTZBDMX-UHFFFAOYSA-N cyclohexane;methane Chemical compound C.C1CCCCC1 SWBRHWCHTZBDMX-UHFFFAOYSA-N 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
- PONXTPCRRASWKW-KBPBESRZSA-N diphenylethylenediamine Chemical compound C1([C@H](N)[C@@H](N)C=2C=CC=CC=2)=CC=CC=C1 PONXTPCRRASWKW-KBPBESRZSA-N 0.000 description 1
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000019256 formaldehyde Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- SXCBDZAEHILGLM-UHFFFAOYSA-N heptane-1,7-diol Chemical compound OCCCCCCCO SXCBDZAEHILGLM-UHFFFAOYSA-N 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- FHKSXSQHXQEMOK-UHFFFAOYSA-N hexane-1,2-diol Chemical compound CCCCC(O)CO FHKSXSQHXQEMOK-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 125000001905 inorganic group Chemical group 0.000 description 1
- WYXXLXHHWYNKJF-UHFFFAOYSA-N isocarvacrol Natural products CC(C)C1=CC=C(O)C(C)=C1 WYXXLXHHWYNKJF-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 125000005647 linker group Chemical group 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- QHJABUZHRJTCAR-UHFFFAOYSA-N n'-methylpropane-1,3-diamine Chemical compound CNCCCN QHJABUZHRJTCAR-UHFFFAOYSA-N 0.000 description 1
- OHQOKJPHNPUMLN-UHFFFAOYSA-N n,n'-diphenylmethanediamine Chemical class C=1C=CC=CC=1NCNC1=CC=CC=C1 OHQOKJPHNPUMLN-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Chemical class CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920006295 polythiol Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 125000006308 propyl amino group Chemical group 0.000 description 1
- YLQLIQIAXYRMDL-UHFFFAOYSA-N propylheptyl alcohol Chemical compound CCCCCC(CO)CCC YLQLIQIAXYRMDL-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- VHNQIURBCCNWDN-UHFFFAOYSA-N pyridine-2,6-diamine Chemical compound NC1=CC=CC(N)=N1 VHNQIURBCCNWDN-UHFFFAOYSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229940024463 silicone emollient and protective product Drugs 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 229940063673 spermidine Drugs 0.000 description 1
- 229940063675 spermine Drugs 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Chemical group 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
- C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
- C08G77/388—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
- C08L83/06—Polysiloxanes containing silicon bound to oxygen-containing groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/10—General cosmetic use
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- General Chemical & Material Sciences (AREA)
- Dermatology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Silicon Polymers (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
様々な実施形態において、上記シロキサン類のそれぞれは、それらの骨格のそれぞれにおけるシロキサン結合(Si−O−Si)から構成される。あるいは、上記シロキサン類のそれぞれは、1つ又は複数の二価基、例えば−CH2−結合基によって分離されたシロキサン結合を含むことができる。適切な二価基の更なる例には、ポリエーテル基、例えば−CH2CH2O−結合基(すなわちEO基)、−CH(CH3)CH2O−結合基(すなわちPO基)等が含まれる。異なる二価基の組合せが、それらの骨格のそれぞれにおいて存在してもよい。上記二価基のそれぞれは、1つだけでも、例えば2回、5回、10回、10回超等繰り返してもよい。いくつかの実施形態において、上記シロキサン類は、ポリエーテル基を含んでいない。
式中、R3は、二価の基である。一般に、R3は、ヒドロカルビレン、ヘテロヒドロカルビレン、又はオルガノヘテリレン基である。様々な実施形態において、R3は、(CH2)nであって、式中、nは、1〜30、1〜25、1〜20、1〜15、1〜10、1〜5、又は1〜3、あるいは中間の任意の数から選択される整数である。一般に、nは3である。
R5 3Si−O−[SiR1R4−O−]w[SiR1R2−O−]x[SiR1R4−O−]ySiR5 3(B)。
(CH3)3Si−O−[Si(CH3)2−O−]w[Si(Ch3)R2−O−]x[Si(CH3)R4−O−]ySi(CH3)3(B1)。
第一の実施形態
第二の実施形態
第三及び第四の実施形態
HO−[Z]d−[SiR8R10−O−]a[SiR8R9−O−]b[SiR8R10−O−]cSi−[Z]d−OH(C1);又は
R2N−[Z]d−[SiR8R10−O−]a[SiR8R9−O−]b[SiR8R10−O−]cSi−[Z]d−NR2(C2)。
−[Z]d−[SiR8R10−O−]a[SiR8R9−O−]b[SiR8R10−O−]cSi−[Z]d−(ii)。
(1)R2が結合する部位(複数可)に水素原子を有するオルガノハイドロジェンシロキサンを酸無粋物化合物と付加反応させて、上記シロキサンを形成すること、及び
(2)ステップ(1)で得られたシロキサンを、上記反応物と組み合わせることにより、開環反応させて、本組成物を形成すること。
実施例1:アリルコハク酸無水物官能性(ASA)シロキサン
実施例2:1−ヘキセンで仕上げるASAシロキサン
実施例3:1−ヘキサデセンで仕上げるASAシロキサン
第一の実施形態
実施例4:ASAシロキサン及びPEG
実施例5:ASAシロキサン及びジオール
実施例6:溶媒存在下でのASAソロキサン及びジオール
実施例7:ASAシロキサン及びPAG
実施例8:ASAシロキサン、モノオール、及びジオール
第二の実施形態
実施例9:ASAシロキサン及び1,8−ジアミノオクタン
実施例10:ASAシロキサン及びポリ(エチレングリコール)ジアミン
実施例11:ASAシロキサン及び1,5−ジアミノ−2−メチルペンタン
第三の実施形態
実施例12:ASAシロキサン及び水酸基末端シロキサン
実施例13:ASAシロキサン及び水酸基末端シロキサン
実施例14:ASAシロキサン及び水酸基末端シロキサン
実施例15:インデックス反応下/部分反応下での、ASAシロキサン及び水酸基末端シロキサン
第四の実施形態
実施例16:ASAシロキサン及びアミノプロピル−エンドブロックシロキサン
Claims (10)
- 架橋組成物であって、
少なくとも1つのペンダント酸無水物基を有する第一のシロキサンと、
少なくとも1つのペンダント酸無水物基を有する第二のシロキサンと、
前記第一のシロキサン及び前記第二のシロキサンの前記ペンダント酸無水物基と反応する2つの炭素原子に結合した水酸基を有するジオールである有機ポリオールと、の反応生成物を含む、架橋組成物。 - 架橋組成物であって、
少なくとも1つのペンダント酸無水物基を有する第一のシロキサンと、
少なくとも1つのペンダント酸無水物基を有する第二のシロキサンと、
i)前記第一のシロキサン及び前記第二のシロキサンの前記ペンダント酸無水物基と反応する2つの炭素原子に結合した水酸基を有するジオールである有機ポリオール、
ii)前記第一のシロキサン及び前記第二のシロキサンの前記ペンダント酸無水物基と反応する2つのアミン基を有するアミノ酸以外のジアミンである有機ポリアミン、
iii)前記第一のシロキサン及び前記第二のシロキサンの前記ペンダント酸無水物基と反応する少なくとも2つの炭素原子に結合した水酸基を有する第三のシロキサン、
iv)前記第一のシロキサン及び前記第二のシロキサンの前記ペンダント酸無水物基と反応する少なくとも2つのアミン基を有する第四のシロキサン、又は
v)これらの組み合わせと、の反応生成物を含み、
前記第一のシロキサン及び前記第二のシロキサンのそれぞれが、少なくとも1つの[SiR1R2−O−]単位を有し、R1は、独立に選択される、置換又は非置換のヒドロカルビル基であり、R2は、下記一般式(A):
のペンダント無水物基であり;R3は、二価の基である、架橋組成物。 - i)前記有機ポリアミンが、2つの末端アミン基を有する、及び/又は
ii)前記第三のシロキサンが、2つの末端水酸基を有する、及び/又は
iii)前記第四のシロキサンが、2つの末端アミン基を有する、請求項2に記載の架橋組成物。 - 前記第一のシロキサン及び前記第二のシロキサンのそれぞれが、少なくとも1つの[SiR1R2−O−]単位を有し、R1は、独立に選択される、置換又は非置換のヒドロカルビル基であり、R2は、下記一般式(A):
のペンダント無水物基であり;R3は、二価の基である、請求項1に記載の架橋組成物。 - 前記第一のシロキサン及び前記第二のシロキサンのそれぞれが、個別に、下記一般式(B):
R5 3Si−O−[SiR1R4−O−]w[SiR1R2−O−]x[SiR1R4−O−]ySiR5 3 (B)
で示されるものであり;
R1及びR2のそれぞれは、上記定義のとおりのものであり、あるいは、各R1は、独立に選択されるアルキル基であり;R3は、ヒドロカルビレン又はオルガノヘテリレン基であり;R4は、置換又は非置換のヒドロカルビル基、又は(R6O)m基であり、式中、R6はアルキル基又はアリール基であり、かつmが1〜50から選択される整数であり;各R5は、独立に選択される、置換又は非置換のヒドロカルビル基であり;wは、0〜1,000から選択される整数であり;xは、1〜100から選択される整数であり;yは、0〜1,000から選択される整数であり;但しw及びyが同時に0になることはない、請求項4に記載の架橋組成物。 - 前記有機ポリオールが:
i)下記一般式を有し、HO−R7−OH;式中、R7は、ヒドロカルビレン又はオルガノヘテリレン基のうちの少なくとも1つを含む、請求項1〜5のいずれか一項に記載の架橋組成物。 - 前記有機ポリアミンが:
i)下記一般式を有し;RHN−R7−NHR、式中、各Rが、独立に水素原子(H)又はR1であり;R7が、ヒドロカルビレン又はオルガノヘテリレン基の少なくとも1つを含む:請求項2〜5のいずれか一項に記載の架橋組成物。 - 前記第三のシロキサンが、下記
一般式:
i)HO−[Z]d−[SiR8R10−O−]a[SiR8R9−O−]b[SiR8R10−O−]cSi−[Z]d−OH (C1);
又は
ii)RHN−[Z]d−[SiR8R10−O−]a[SiR8R9−O−]b[SiR8R10−O−]cSi−[Z]d−NHR (C2)
に示されるものであり;
式中、各Rが、独立に水素原子(H)又はR1であり;R8、R9、及びR10のそれぞれが、独立に選択される、置換又は非置換のヒドロカルビル基であり;各Zが、独立にヒドロカルビレン又はオルガノヘテリレン基のうちの少なくとも1つを有し;aが、0〜1,000から選択される整数であり;bが、1〜200から選択される整数であり;cが、0〜1,000から選択される整数であり;かつ各dが、独立に0又は1である、請求項2〜5のいずれか一項に記載の架橋組成物。 - 前記第三のシロキサンが、一般式:R* sSiO(4−s)/2の樹脂であり、式中、R*が、独立に選択される、置換ヒドロカルビル基、非置換ヒドロカルビル基、水酸基、又はアミン基であり、ただし、R * の少なくとも2つは水酸基で置換されたヒドロカルビル基であり、sが、2〜3である、請求項2〜5のいずれか一項に記載の架橋組成物。
- 下記一般式の架橋組成物であって;
式中、Xは、下記一般式(i)で示され;
W及びW*のそれぞれは、独立に酸素原子(O)又はN−Rであり、Rは、独立に水素原子(H)又はR1であり;各Yは、2つの炭素原子に結合した水酸基を有するジオールである有機ポリオール由来の二価基、又は2つのアミン基を有するアミノ酸以外のジアミンである有機ポリアミン由来の二価基であり;R1、R11、R4、R14、R5、及びR15のそれぞれは、独立に選択される、置換又は非置換のヒドロカルビル基であり;R3及びR13のそれぞれは、独立に選択される、二価基であり;w及びwwのそれぞれは、0〜1,000から独立に選択される整数であり;x及びxxのそれぞれは、1〜100から独立に選択される整数であり;y及びyyのそれぞれは、0〜1,000から独立に選択される整数であり;但しw及びyが同時に0になることはなく、ww及びyyが同時に0になることはない、架橋組成物。
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CN105531301A (zh) | 2016-04-27 |
EP3063208A1 (en) | 2016-09-07 |
US9714323B2 (en) | 2017-07-25 |
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