JP6328046B2 - リッチバーン排ガスからのアンモニア排出を減少させるための触媒 - Google Patents

リッチバーン排ガスからのアンモニア排出を減少させるための触媒 Download PDF

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JP6328046B2
JP6328046B2 JP2014503653A JP2014503653A JP6328046B2 JP 6328046 B2 JP6328046 B2 JP 6328046B2 JP 2014503653 A JP2014503653 A JP 2014503653A JP 2014503653 A JP2014503653 A JP 2014503653A JP 6328046 B2 JP6328046 B2 JP 6328046B2
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catalyst
molecular sieve
catalyst layer
gas
exhaust gas
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JP2014515701A5 (enExample
JP2014515701A (ja
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ジョーゼフ エム． フェデイコ，
ジョーゼフ エム． フェデイコ，
ハイ−イン チェン，
ハイ−イン チェン，
アーサー ジェイ． ライニング，
アーサー ジェイ． ライニング，
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Johnson Matthey PLC
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Johnson Matthey PLC
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/54—Nitrogen compounds
    • B01D53/58—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9436—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9459—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts
    • B01D53/9477—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts with catalysts positioned on separate bricks, e.g. exhaust systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/072—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/076—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B01J29/763—CHA-type, e.g. Chabazite, LZ-218
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0244—Coatings comprising several layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0246—Coatings comprising a zeolite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1021—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/90—Physical characteristics of catalysts
    • B01D2255/902—Multilayered catalyst
    • B01D2255/9022—Two layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
    • B01D53/945—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Catalysts (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
JP2014503653A 2011-04-08 2012-01-23 リッチバーン排ガスからのアンモニア排出を減少させるための触媒 Active JP6328046B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/083,154 US8101146B2 (en) 2011-04-08 2011-04-08 Catalysts for the reduction of ammonia emission from rich-burn exhaust
US13/083,154 2011-04-08
PCT/US2012/022191 WO2012138405A1 (en) 2011-04-08 2012-01-23 Catalysts for the reduction of ammonia emission from rich-burn exhaust

Related Child Applications (1)

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JP2016190011A Division JP6797625B2 (ja) 2011-04-08 2016-09-28 リッチバーン排ガスからのアンモニア排出を減少させるための触媒

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JP2014515701A JP2014515701A (ja) 2014-07-03
JP2014515701A5 JP2014515701A5 (enExample) 2015-03-12
JP6328046B2 true JP6328046B2 (ja) 2018-05-23

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JP2014503653A Active JP6328046B2 (ja) 2011-04-08 2012-01-23 リッチバーン排ガスからのアンモニア排出を減少させるための触媒
JP2016190011A Active JP6797625B2 (ja) 2011-04-08 2016-09-28 リッチバーン排ガスからのアンモニア排出を減少させるための触媒

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US (2) US8101146B2 (enExample)
EP (1) EP2694193A1 (enExample)
JP (2) JP6328046B2 (enExample)
KR (2) KR102047049B1 (enExample)
CN (2) CN108380207A (enExample)
BR (1) BR112013025988A2 (enExample)
RU (1) RU2593293C2 (enExample)
WO (1) WO2012138405A1 (enExample)

Families Citing this family (135)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AR065501A1 (es) * 2007-02-27 2009-06-10 Basf Catalysts Llc Catalizadores de zeolita cha de cobre
US7998423B2 (en) 2007-02-27 2011-08-16 Basf Corporation SCR on low thermal mass filter substrates
US20090196812A1 (en) 2008-01-31 2009-08-06 Basf Catalysts Llc Catalysts, Systems and Methods Utilizing Non-Zeolitic Metal-Containing Molecular Sieves Having the CHA Crystal Structure
EP2268897B1 (en) 2008-03-28 2020-11-11 Exxonmobil Upstream Research Company Low emission power generation and hydrocarbon recovery system and method
AU2009228062B2 (en) 2008-03-28 2014-01-16 Exxonmobil Upstream Research Company Low emission power generation and hydrocarbon recovery systems and methods
US9222671B2 (en) 2008-10-14 2015-12-29 Exxonmobil Upstream Research Company Methods and systems for controlling the products of combustion
AU2010318595C1 (en) 2009-11-12 2016-10-06 Exxonmobil Upstream Research Company Low emission power generation and hydrocarbon recovery systems and methods
US8293199B2 (en) * 2009-12-18 2012-10-23 Basf Corporation Process for preparation of copper containing molecular sieves with the CHA structure, catalysts, systems and methods
US8293198B2 (en) * 2009-12-18 2012-10-23 Basf Corporation Process of direct copper exchange into Na+-form of chabazite molecular sieve, and catalysts, systems and methods
KR101294098B1 (ko) * 2010-03-11 2013-08-08 존슨 맛쎄이 퍼블릭 리미티드 컴파니 ＮＯｘ의 선택적 촉매 환원을 위한 무질서 분자체 지지체
CA2801499C (en) 2010-07-02 2017-01-03 Exxonmobil Upstream Research Company Low emission power generation systems and methods
MX352291B (es) 2010-07-02 2017-11-16 Exxonmobil Upstream Res Company Star Sistemas y métodos de generación de potencia de triple ciclo de baja emisión.
WO2012003078A1 (en) 2010-07-02 2012-01-05 Exxonmobil Upstream Research Company Stoichiometric combustion with exhaust gas recirculation and direct contact cooler
JP5906555B2 (ja) 2010-07-02 2016-04-20 エクソンモービル アップストリーム リサーチ カンパニー 排ガス再循環方式によるリッチエアの化学量論的燃焼
TWI593872B (zh) 2011-03-22 2017-08-01 艾克頌美孚上游研究公司 整合系統及產生動力之方法
TWI564474B (zh) 2011-03-22 2017-01-01 艾克頌美孚上游研究公司 於渦輪系統中控制化學計量燃燒的整合系統和使用彼之產生動力的方法
TWI563166B (en) 2011-03-22 2016-12-21 Exxonmobil Upstream Res Co Integrated generation systems and methods for generating power
TWI563165B (en) 2011-03-22 2016-12-21 Exxonmobil Upstream Res Co Power generation system and method for generating power
US9242239B2 (en) * 2011-04-08 2016-01-26 Johnson Matthey Public Limited Company Catalysts for the reduction of ammonia emission from rich-burn exhaust
GB2492175B (en) * 2011-06-21 2018-06-27 Johnson Matthey Plc Exhaust system for internal combustion engine comprising catalysed filter substrate
US9810050B2 (en) 2011-12-20 2017-11-07 Exxonmobil Upstream Research Company Enhanced coal-bed methane production
US9353682B2 (en) 2012-04-12 2016-05-31 General Electric Company Methods, systems and apparatus relating to combustion turbine power plants with exhaust gas recirculation
US9784185B2 (en) 2012-04-26 2017-10-10 General Electric Company System and method for cooling a gas turbine with an exhaust gas provided by the gas turbine
US10273880B2 (en) 2012-04-26 2019-04-30 General Electric Company System and method of recirculating exhaust gas for use in a plurality of flow paths in a gas turbine engine
KR20150023543A (ko) 2012-06-01 2015-03-05 존슨 맛쎄이 퍼블릭 리미티드 컴파니 바나데이트를 포함하는 선택적 촉매 환원 벽유동형 필터
US9869279B2 (en) 2012-11-02 2018-01-16 General Electric Company System and method for a multi-wall turbine combustor
US9803865B2 (en) 2012-12-28 2017-10-31 General Electric Company System and method for a turbine combustor
US9631815B2 (en) 2012-12-28 2017-04-25 General Electric Company System and method for a turbine combustor
US9599070B2 (en) 2012-11-02 2017-03-21 General Electric Company System and method for oxidant compression in a stoichiometric exhaust gas recirculation gas turbine system
US10215412B2 (en) 2012-11-02 2019-02-26 General Electric Company System and method for load control with diffusion combustion in a stoichiometric exhaust gas recirculation gas turbine system
US9574496B2 (en) 2012-12-28 2017-02-21 General Electric Company System and method for a turbine combustor
US10107495B2 (en) 2012-11-02 2018-10-23 General Electric Company Gas turbine combustor control system for stoichiometric combustion in the presence of a diluent
US9708977B2 (en) 2012-12-28 2017-07-18 General Electric Company System and method for reheat in gas turbine with exhaust gas recirculation
US10161312B2 (en) 2012-11-02 2018-12-25 General Electric Company System and method for diffusion combustion with fuel-diluent mixing in a stoichiometric exhaust gas recirculation gas turbine system
US9611756B2 (en) 2012-11-02 2017-04-04 General Electric Company System and method for protecting components in a gas turbine engine with exhaust gas recirculation
GB201221025D0 (en) * 2012-11-22 2013-01-09 Johnson Matthey Plc Zoned catalysed substrate monolith
US8992869B2 (en) 2012-12-20 2015-03-31 Caterpillar Inc. Ammonia oxidation catalyst system
US10208677B2 (en) 2012-12-31 2019-02-19 General Electric Company Gas turbine load control system
US9581081B2 (en) 2013-01-13 2017-02-28 General Electric Company System and method for protecting components in a gas turbine engine with exhaust gas recirculation
US9512759B2 (en) 2013-02-06 2016-12-06 General Electric Company System and method for catalyst heat utilization for gas turbine with exhaust gas recirculation
US9938861B2 (en) 2013-02-21 2018-04-10 Exxonmobil Upstream Research Company Fuel combusting method
TW201502356A (zh) 2013-02-21 2015-01-16 Exxonmobil Upstream Res Co 氣渦輪機排氣中氧之減少
RU2637609C2 (ru) 2013-02-28 2017-12-05 Эксонмобил Апстрим Рисерч Компани Система и способ для камеры сгорания турбины
TW201500635A (zh) 2013-03-08 2015-01-01 Exxonmobil Upstream Res Co 處理廢氣以供用於提高油回收
US20140250945A1 (en) 2013-03-08 2014-09-11 Richard A. Huntington Carbon Dioxide Recovery
JP6143895B2 (ja) 2013-03-08 2017-06-07 エクソンモービル アップストリーム リサーチ カンパニー 発電及びメタンハイドレートからのメタン回収
US9618261B2 (en) 2013-03-08 2017-04-11 Exxonmobil Upstream Research Company Power generation and LNG production
CN104703694B (zh) * 2013-03-15 2018-12-21 庄信万丰股份有限公司 用于处理废气的催化剂
US9687785B2 (en) * 2013-05-31 2017-06-27 Johnson Matthey Public Limited Company Catalyzed filter for treating exhaust gas
CN109736921B (zh) * 2013-05-31 2024-07-26 庄信万丰股份有限公司 用于处理废气的经催化的过滤器
US9835089B2 (en) 2013-06-28 2017-12-05 General Electric Company System and method for a fuel nozzle
US9617914B2 (en) 2013-06-28 2017-04-11 General Electric Company Systems and methods for monitoring gas turbine systems having exhaust gas recirculation
TWI654368B (zh) 2013-06-28 2019-03-21 美商艾克頌美孚上游研究公司 用於控制在廢氣再循環氣渦輪機系統中的廢氣流之系統、方法與媒體
US9631542B2 (en) 2013-06-28 2017-04-25 General Electric Company System and method for exhausting combustion gases from gas turbine engines
US9057301B2 (en) * 2013-07-02 2015-06-16 General Electric Company Emissions control in stationary rich burn engines
JP6278561B2 (ja) * 2013-07-10 2018-02-14 国立大学法人広島大学 結晶性アルミノシリケート及びその製造方法
US9903588B2 (en) 2013-07-30 2018-02-27 General Electric Company System and method for barrier in passage of combustor of gas turbine engine with exhaust gas recirculation
US9587510B2 (en) 2013-07-30 2017-03-07 General Electric Company System and method for a gas turbine engine sensor
US9951658B2 (en) 2013-07-31 2018-04-24 General Electric Company System and method for an oxidant heating system
US9752458B2 (en) 2013-12-04 2017-09-05 General Electric Company System and method for a gas turbine engine
US10030588B2 (en) 2013-12-04 2018-07-24 General Electric Company Gas turbine combustor diagnostic system and method
US9878309B2 (en) * 2013-12-06 2018-01-30 Danmarks Tekniske Universitet Catalyst for ammonia oxidation
US10227920B2 (en) 2014-01-15 2019-03-12 General Electric Company Gas turbine oxidant separation system
US9915200B2 (en) 2014-01-21 2018-03-13 General Electric Company System and method for controlling the combustion process in a gas turbine operating with exhaust gas recirculation
US9863267B2 (en) 2014-01-21 2018-01-09 General Electric Company System and method of control for a gas turbine engine
US10079564B2 (en) 2014-01-27 2018-09-18 General Electric Company System and method for a stoichiometric exhaust gas recirculation gas turbine system
US9149768B1 (en) * 2014-03-27 2015-10-06 General Electric Company Emission control in rich burn natural gas engines
US9267412B2 (en) * 2014-04-15 2016-02-23 General Electric Company Exhaust aftertreatement system with catalytic deactivation monitoring
US9757718B2 (en) 2014-05-09 2017-09-12 Johnson Matthey Public Limited Company Ammonia slip catalyst having platinum impregnated on high porosity substrates
GB2530129B (en) * 2014-05-16 2016-10-26 Johnson Matthey Plc Catalytic article for treating exhaust gas
US10047633B2 (en) 2014-05-16 2018-08-14 General Electric Company Bearing housing
CN106714968B (zh) * 2014-05-27 2019-09-06 丹麦技术大学 用于在含氢气的气体中选择性地氧化氨的催化剂、方法以及装置的应用
US10252217B2 (en) * 2014-06-05 2019-04-09 Basf Corporation Catalytic articles containing platinum group metals and non-platinum group metals and methods of making and using same
US10655542B2 (en) 2014-06-30 2020-05-19 General Electric Company Method and system for startup of gas turbine system drive trains with exhaust gas recirculation
US9885290B2 (en) 2014-06-30 2018-02-06 General Electric Company Erosion suppression system and method in an exhaust gas recirculation gas turbine system
US10060359B2 (en) 2014-06-30 2018-08-28 General Electric Company Method and system for combustion control for gas turbine system with exhaust gas recirculation
WO2016004151A1 (en) * 2014-07-02 2016-01-07 Johnson Matthey Public Limited Company Perovskite with an ovlerlayer scr component as an ammonia oxidation catalyst and a system for exhaust emission control on diesel engines
WO2016060668A1 (en) * 2014-10-16 2016-04-21 Cummins Emission Solutions, Inc. Aftertreatment systems for dual-fuel engines
US10179329B2 (en) * 2014-11-19 2019-01-15 Johnson Matthey Public Limited Company Combining SCR with PNA for low temperature emission control
US9347358B1 (en) * 2014-11-26 2016-05-24 General Electric Company Silencer for mid-bed air injection mixing
US9819292B2 (en) 2014-12-31 2017-11-14 General Electric Company Systems and methods to respond to grid overfrequency events for a stoichiometric exhaust recirculation gas turbine
US9869247B2 (en) 2014-12-31 2018-01-16 General Electric Company Systems and methods of estimating a combustion equivalence ratio in a gas turbine with exhaust gas recirculation
US10788212B2 (en) 2015-01-12 2020-09-29 General Electric Company System and method for an oxidant passageway in a gas turbine system with exhaust gas recirculation
US10253690B2 (en) 2015-02-04 2019-04-09 General Electric Company Turbine system with exhaust gas recirculation, separation and extraction
US10316746B2 (en) 2015-02-04 2019-06-11 General Electric Company Turbine system with exhaust gas recirculation, separation and extraction
US10094566B2 (en) 2015-02-04 2018-10-09 General Electric Company Systems and methods for high volumetric oxidant flow in gas turbine engine with exhaust gas recirculation
US10267270B2 (en) 2015-02-06 2019-04-23 General Electric Company Systems and methods for carbon black production with a gas turbine engine having exhaust gas recirculation
MY193820A (en) * 2015-02-27 2022-10-27 Basf Corp Exhaust gas treatment system
US10145269B2 (en) 2015-03-04 2018-12-04 General Electric Company System and method for cooling discharge flow
US10480792B2 (en) 2015-03-06 2019-11-19 General Electric Company Fuel staging in a gas turbine engine
US20160273437A1 (en) * 2015-03-17 2016-09-22 General Electric Company Systems and methods for monitoring the health of a mid-bed oxidant injection system
JP6292159B2 (ja) * 2015-04-13 2018-03-14 トヨタ自動車株式会社 排ガス浄化用触媒
JP6830451B2 (ja) * 2015-06-18 2021-02-17 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーＪｏｈｎｓｏｎ Ｍａｔｔｈｅｙ Ｐｕｂｌｉｃ Ｌｉｍｉｔｅｄ Ｃｏｍｐａｎｙ Ｎｈ３過剰負荷耐性ｓｃｒ触媒
US9937489B2 (en) * 2015-06-18 2018-04-10 Johnson Matthey Public Limited Company Exhaust system without a DOC having an ASC acting as a DOC in a system with an SCR catalyst before the ASC
CN105214723B (zh) * 2015-07-23 2018-05-04 清华大学苏州汽车研究院（吴江） 含铜的氨氧化催化剂及其制备方法
MX2018002701A (es) 2015-09-04 2018-04-13 Basf Se Sistemas integrados de scr y catalizadores de oxidacion de amoniaco.
BR112018072056A2 (pt) * 2016-04-29 2019-02-12 Johnson Matthey Public Limited Company sistema de escape para um motor de combustão interna, substrato monolítico de fluxo de parede catalítica, métodos para fabricar um substrato monolítico catalisado e para tratar gases de escape de um motor de combustão interna, motor de ignição por compressão, e, veículo
GB201614677D0 (en) * 2016-08-30 2016-10-12 Johnson Matthey Plc Oxidation catalyst for a diesel engine exhaust
CA3041422A1 (en) 2016-10-24 2018-05-03 Basf Corporation Integrated scr catalyst and lnt for nox abatement
EP3323785A1 (en) * 2016-11-18 2018-05-23 Umicore AG & Co. KG Crystalline zeolites with eri/cha intergrowth framework type
US10500571B2 (en) * 2017-03-29 2019-12-10 Johnson Matthey Public Limited Company ASC with platinum group metal in multiple layers
JP6601449B2 (ja) * 2017-04-04 2019-11-06 トヨタ自動車株式会社 内燃機関の排気浄化装置
WO2018224651A2 (en) 2017-06-09 2018-12-13 Basf Se Catalytic article and exhaust gas treatment systems
KR102698126B1 (ko) 2017-06-09 2024-08-27 바스프 코포레이션 촉매 물품 및 배기가스 처리 시스템
CN111315482B (zh) * 2017-09-07 2024-01-23 巴斯夫公司 具有减少的骨架外铝的沸石
JP2020536727A (ja) 2017-10-12 2020-12-17 ビーエーエスエフ コーポレーション ＮＯｘ吸収体およびＳＣＲ触媒の組み合わせ
CN109701618B (zh) * 2017-10-26 2021-08-03 中国石油化工股份有限公司 Aei复合分子筛及其合成方法
KR102659805B1 (ko) * 2017-11-10 2024-04-23 바스프 코포레이션 암모니아 산화가 감소된 촉매화된 매연 필터
JP7451402B2 (ja) 2017-12-08 2024-03-18 ジョンソン マッセイ （シャンハイ） ケミカルズ リミテッド ガソリンエンジンからの排気ガス処理のための新規多領域ｔｗｃ
US11642658B2 (en) 2018-07-27 2023-05-09 Johnson Matthey Public Limited Company PGM nanoparticles TWC catalysts for gasoline exhaust gas applications
CN109289906B (zh) * 2018-09-26 2020-09-25 中国科学院生态环境研究中心 一种氨气净化催化剂及其制备方法和用途
CN111001434B (zh) * 2018-10-08 2021-03-16 中自环保科技股份有限公司 一种当量燃烧天然气车集成催化剂体系及其制备方法
CN109225316B (zh) * 2018-10-08 2020-03-31 中自环保科技股份有限公司 一种尾气处理催化剂及其制备方法和用途
US10914217B2 (en) * 2019-01-31 2021-02-09 Hyundai Motor Company Ammonia production catalyst and after treatment system
RU2699228C1 (ru) * 2019-05-20 2019-09-04 Алексей Юрьевич Кочетков Гетерогенный катализатор окисления неорганических и/или органических соединений
US11167272B2 (en) 2019-07-15 2021-11-09 Ford Global Technologies, Llc Exhaust treatment system including nickel-containing catalyst
CN111068764B (zh) * 2019-11-29 2023-04-28 天津大学 用于柴油车尾气的nh3-sco催化剂及其制备方法
CN110961144A (zh) * 2019-12-14 2020-04-07 中触媒新材料股份有限公司 一种具有cha/lev拓扑结构共生复合分子筛及其制备方法和scr应用
CN111068512B (zh) * 2019-12-26 2021-06-18 南京工大环境科技有限公司 一种降低尾气氨排放的集成式催化转化系统及其方法
CN111022160A (zh) * 2019-12-31 2020-04-17 广西玉柴机器股份有限公司 一种燃气发动机的催化器结构
JP2023540136A (ja) 2020-09-08 2023-09-21 ビーエーエスエフ コーポレーション 排気ガス水素濃縮を介した触媒の性能強化
IT202100007202A1 (it) * 2021-03-24 2022-09-24 Fpt Ind Spa Sistema di propulsione per veicoli pesanti comprendente un sistema di post trattamento di gas esausti
WO2023272317A1 (en) * 2021-06-30 2023-01-05 Innio Jenbacher Gmbh & Co Og An internal combustion engine and a method for operating an internal combustion engine
CN115843275B (zh) * 2021-09-01 2024-02-06 宁波吉利罗佑发动机零部件有限公司 氨吸附催化剂及其制备方法和应用
EP4415880A1 (en) 2021-10-12 2024-08-21 Johnson Matthey (Shanghai) Chemicals Limited Novel zoned catalysts for cng engine exhaust gas treatments with improved ammonia emission control
CN216617683U (zh) * 2022-02-16 2022-05-27 烟台杰瑞石油装备技术有限公司 涡轮发动机进气冷却系统以及涡轮发动机设备
US11686236B1 (en) * 2022-02-18 2023-06-27 Saudi Arabian Oil Company Device for the reduction of ammonia and nitrogen oxides emissions
CN114575971B (zh) * 2022-03-01 2022-12-23 东风商用车有限公司 利用纯氨气的后处理系统及其方法
WO2023198569A1 (de) * 2022-04-11 2023-10-19 Umicore Ag & Co. Kg Ammoniaksperrkatalysator für stöchiometrische verbrennungsmotoren
DE102022126366A1 (de) 2022-10-11 2024-04-11 Ws Reformer Gmbh Verwendung eines Katalysators zur Entfernung von Ammoniak aus einem wasserstoffreichen Brenngas und Verfahren zur Entfernung von Ammoniak aus einem wasserstoffreichen Brenngas
EP4414052A1 (en) 2023-02-10 2024-08-14 Johnson Matthey Public Limited Company Scr catalyst article and systems for reducing n2o in exhaust gas
EP4414051A1 (en) 2023-02-10 2024-08-14 Johnson Matthey Public Limited Company System for treating exhaust gas from nitrogen-containing-fuel- or hydrogen-combustor
JP2024130360A (ja) 2023-03-14 2024-09-30 トヨタ自動車株式会社 エンジン制御装置
GB202402672D0 (en) 2024-02-26 2024-04-10 Johnson Matthey Plc Process and system
WO2025193679A1 (en) * 2024-03-12 2025-09-18 Basf Mobile Emissions Catalysts Llc Methods for synthesizing precious metal - base metal nanocrystal alloys in aqueous solutions

Family Cites Families (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10020170C1 (de) 2000-04-25 2001-09-06 Emitec Emissionstechnologie Verfahren zum Entfernen von Rußpartikeln aus einem Abgas und zugehöriges Auffangelement
JPS5386694A (en) * 1976-12-28 1978-07-31 Kurita Water Ind Ltd Ammonia oxidation catalyst
US5024981A (en) * 1989-04-20 1991-06-18 Engelhard Corporation Staged metal-promoted zeolite catalysts and method for catalytic reduction of nitrogen oxides using the same
US5168085A (en) * 1991-05-20 1992-12-01 Corning Incorporated Multi-stage twc system
JPH07328440A (ja) * 1994-06-14 1995-12-19 Ishikawajima Harima Heavy Ind Co Ltd アンモニア分解用触媒
JP3513536B2 (ja) * 1995-01-27 2004-03-31 トヨタ自動車株式会社 排気浄化方法及び排気浄化装置
US5783160A (en) 1995-01-27 1998-07-21 Toyota Jidosha Kabushiki Kaisha Method for purifying combustion exhaust gas
JP3499350B2 (ja) * 1995-12-08 2004-02-23 トヨタ自動車株式会社 内燃機関の排ガス浄化方法
FI107828B (fi) 1999-05-18 2001-10-15 Kemira Metalkat Oy Dieselmoottoreiden pakokaasujen puhdistusjärjestelmä ja menetelmä dieselmoottoreiden pakokaasujen puhdistamiseksi
US7481983B2 (en) 2004-08-23 2009-01-27 Basf Catalysts Llc Zone coated catalyst to simultaneously reduce NOx and unreacted ammonia
JP2007021482A (ja) * 2005-06-14 2007-02-01 Sumiko Eco-Engineering Co Ltd アンモニア分解触媒及びアンモニア処理方法
WO2007004774A1 (en) * 2005-07-06 2007-01-11 Heesung Catalysts Corporation An oxidation catalyst for nh3 and an apparatus for treating slipped or scrippedd nh3
KR100765413B1 (ko) 2005-07-06 2007-10-09 희성촉매 주식회사 암모니아 산화촉매 및 이를 이용한 슬립 암모니아 또는폐암모니아 처리장치
US20070149394A1 (en) 2005-12-22 2007-06-28 Foster Wheeler Energy Corporation Catalyst, a method of using a catalyst, and an arrangement including a catalyst, for controlling NO and/or CO emissions from a combustion system without using external reagent
CN101454065A (zh) * 2006-05-31 2009-06-10 尤米科尔股份公司及两合公司 降低柴油发动机废气中含氮污染气体的催化剂
US20080072578A1 (en) * 2006-09-21 2008-03-27 Kumar Sanath V Treatment Systems and Methods for Internal Combustion Engine Exhaust Streams
US8389432B2 (en) * 2006-09-25 2013-03-05 Umicore Ag & Co. Kg Structured automotive catalyst with improved thermal ageing stability
AR065501A1 (es) * 2007-02-27 2009-06-10 Basf Catalysts Llc Catalizadores de zeolita cha de cobre
RU2009135861A (ru) 2007-02-27 2011-04-10 Басф Каталистс Ллк (Us) Бифункциональные катализаторы для селективного окисления аммиака
DK3278863T3 (da) * 2007-04-26 2020-02-17 Johnson Matthey Plc Overgangsmetal/aei-zeolit-scr-katalysator
US7727499B2 (en) 2007-09-28 2010-06-01 Basf Catalysts Llc Ammonia oxidation catalyst for power utilities
US20090196812A1 (en) * 2008-01-31 2009-08-06 Basf Catalysts Llc Catalysts, Systems and Methods Utilizing Non-Zeolitic Metal-Containing Molecular Sieves Having the CHA Crystal Structure
DE102008008786A1 (de) * 2008-02-12 2009-08-13 Man Nutzfahrzeuge Aktiengesellschaft Vorrichtung zur Verminderung von Dibenzo-Dioxin- und Dibenzo-Furan-Emissionen aus übergangsmetallhaltigen Katalysatoren
US8393140B2 (en) 2008-05-02 2013-03-12 GM Global Technology Operations LLC Passive ammonia-selective catalytic reduction for NOx control in internal combustion engines
GB0812544D0 (en) 2008-07-09 2008-08-13 Johnson Matthey Plc Exhaust system for a lean burn IC engine
US10632423B2 (en) 2008-11-03 2020-04-28 Basf Corporation Bimetallic catalysts for selective ammonia oxidation
US8524185B2 (en) * 2008-11-03 2013-09-03 Basf Corporation Integrated SCR and AMOx catalyst systems
US8091342B2 (en) 2009-01-28 2012-01-10 GM Global Technology Operations LLC Technique for production of ammonia on demand in a three way catalyst for a passive selective catalytic reduction system
WO2010121257A1 (en) 2009-04-17 2010-10-21 Johnson Matthey Public Limited Company Small pore molecular sieve supported copper catalysts durable against lean/rich aging for the reduction of nitrogen oxides
JP5610513B2 (ja) * 2009-05-12 2014-10-22 一般財団法人電力中央研究所 乾式アンモニア分解処理方法及び乾式アンモニア分解処理装置及び発電設備
WO2011118777A1 (ja) * 2010-03-26 2011-09-29 株式会社 キャタラー 排ガス浄化システム
KR101481600B1 (ko) * 2013-05-02 2015-01-14 희성촉매 주식회사 선택적 촉매 환원 (scr) 시스템에서의 암모니아 산화촉매

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