JP6291494B2 - 組成物 - Google Patents

組成物 Download PDF

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Publication number
JP6291494B2
JP6291494B2 JP2015526912A JP2015526912A JP6291494B2 JP 6291494 B2 JP6291494 B2 JP 6291494B2 JP 2015526912 A JP2015526912 A JP 2015526912A JP 2015526912 A JP2015526912 A JP 2015526912A JP 6291494 B2 JP6291494 B2 JP 6291494B2
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JP
Japan
Prior art keywords
amine
component
isocyanate
foam
groups
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2015526912A
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English (en)
Japanese (ja)
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JP2015526558A (ja
Inventor
ドリース，ゲールト・ロデウェイク
グリグスビー，ロバート・アリソン，ジュニア
リスター，アーネスト・リー，ジュニア
ウィルツ，ユージーン・ピー，ジュニア
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Huntsman Petrochemical LLC
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Huntsman Petrochemical LLC
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Filing date
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Publication of JP2015526558A publication Critical patent/JP2015526558A/ja
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Publication of JP6291494B2 publication Critical patent/JP6291494B2/ja
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/485—Polyethers containing oxyethylene units and other oxyalkylene units containing mixed oxyethylene-oxypropylene or oxyethylene-higher oxyalkylene end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/14—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/302—Water
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C08G18/3228—Polyamines acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
    • C08G18/6685—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3225 or polyamines of C08G18/38
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0058—≥50 and <150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
JP2015526912A 2012-08-16 2013-07-10 組成物 Active JP6291494B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201261683957P 2012-08-16 2012-08-16
US61/683,957 2012-08-16
EP12181977.5A EP2703421A1 (en) 2012-08-28 2012-08-28 A composition for making foams with reduced aldehyde emission
EP12181977.5 2012-08-28
PCT/EP2013/064519 WO2014026802A1 (en) 2012-08-16 2013-07-10 A composition

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2016159452A Division JP6324450B2 (ja) 2012-08-16 2016-08-16 組成物

Publications (2)

Publication Number Publication Date
JP2015526558A JP2015526558A (ja) 2015-09-10
JP6291494B2 true JP6291494B2 (ja) 2018-03-14

Family

ID=46832229

Family Applications (4)

Application Number Title Priority Date Filing Date
JP2015526912A Active JP6291494B2 (ja) 2012-08-16 2013-07-10 組成物
JP2016159452A Active JP6324450B2 (ja) 2012-08-16 2016-08-16 組成物
JP2018025773A Active JP6564479B2 (ja) 2012-08-16 2018-02-16 組成物
JP2019136952A Active JP6807994B2 (ja) 2012-08-16 2019-07-25 組成物

Family Applications After (3)

Application Number Title Priority Date Filing Date
JP2016159452A Active JP6324450B2 (ja) 2012-08-16 2016-08-16 組成物
JP2018025773A Active JP6564479B2 (ja) 2012-08-16 2018-02-16 組成物
JP2019136952A Active JP6807994B2 (ja) 2012-08-16 2019-07-25 組成物

Country Status (10)

Country Link
US (3) US10308754B2 (enExample)
EP (2) EP2703421A1 (enExample)
JP (4) JP6291494B2 (enExample)
KR (1) KR102027988B1 (enExample)
CN (1) CN104797617B (enExample)
CA (1) CA2879930C (enExample)
IN (1) IN2015DN00650A (enExample)
MX (1) MX346638B (enExample)
PL (1) PL2885330T3 (enExample)
WO (1) WO2014026802A1 (enExample)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016005479A1 (en) * 2014-07-10 2016-01-14 Huntsman Petrochemical Llc A composition to reduce the amount of aldehydes emitted from polyurethane foams
KR101692970B1 (ko) * 2014-12-12 2017-01-06 주식회사 태성환경연구소 알데히드 저감용 액상제거제 함유 폴리우레탄폼 및 이의 제조방법
US20180086872A1 (en) * 2015-04-17 2018-03-29 Basf Se Polyurethanes with reduced aldehyde emission
EP3303430B1 (de) * 2015-05-28 2019-04-03 Basf Se Polyurethane mit reduzierter aldehydemission
JP6657267B2 (ja) * 2015-06-16 2020-03-04 エボニック オペレーションズ ゲーエムベーハー ポリウレタンフォーム用のアルデヒド捕捉剤
US10696777B2 (en) 2015-06-16 2020-06-30 Evonik Operations Gmbh Aldehyde scavengers mixtures for polyurethane foams
CN116675827A (zh) 2015-09-28 2023-09-01 美利肯公司 用于制备聚氨酯聚合物的方法
CA3010864C (en) * 2016-02-05 2024-01-16 Huntsman International Llc Method for the reduction of aldehyde emission in polyurethane foam
JP6780961B2 (ja) * 2016-06-14 2020-11-04 株式会社ブリヂストン ポリウレタン用アルデヒド捕捉剤、ポリウレタン、及びポリウレタンの製造方法
KR20190115055A (ko) * 2017-02-16 2019-10-10 다우 글로벌 테크놀로지스 엘엘씨 감소된 알데히드 배출물을 갖는 폴리우레탄 폼
WO2018234348A1 (en) 2017-06-21 2018-12-27 Huntsman International Llc Formulation for reduction of formaldehyde emission in pu foam
CA3088822A1 (en) 2017-12-18 2019-06-27 Huntsman International Llc Method for reduction of aldehyde emission in polyurethane comprising materials
CN110467808A (zh) * 2018-05-11 2019-11-19 襄阳亚克化学有限公司 用于聚氨酯泡沫的除醛阻燃剂及其制备方法
WO2020024231A1 (en) * 2018-08-02 2020-02-06 Dow Global Technologies Llc Methods for reducing aldehyde emissions in polyurethane foams
JP7135557B2 (ja) * 2018-08-07 2022-09-13 東ソー株式会社 ポリウレア樹脂製造用硬化剤組成物及びそれを用いたポリウレア樹脂の製造方法
CN110128614B (zh) * 2019-04-12 2021-06-11 浙江华峰合成树脂有限公司 高剥离发泡层用无溶剂聚氨酯树脂及其制备方法和应用
WO2021021098A1 (en) * 2019-07-29 2021-02-04 Huntsman Petrochemical Llc A polyurethane composition with reduced aldehyde emission
JP2022022758A (ja) * 2020-07-06 2022-02-07 東ソー株式会社 ポリウレタンフォーム製造用のアミン触媒組成物及びその用途
JPWO2023195269A1 (enExample) 2022-04-06 2023-10-12
CN119855854A (zh) 2022-09-08 2025-04-18 三菱瓦斯化学株式会社 发泡树脂形成性组合物、聚脲系树脂发泡体和聚脲系树脂发泡体的制造方法

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5080969A (enExample) * 1973-11-21 1975-07-01
US5700846A (en) 1994-06-15 1997-12-23 Huntsman Petrochemical Corporation Polyurea foam made from a partially aminated polyether polyamine
AT406053B (de) 1997-09-10 2000-02-25 Petruzalek Ges M B H Verwendung von biologisch abbaubaren, geschäumten polymeren als verpackungsmaterialien
JPH11279254A (ja) * 1998-03-27 1999-10-12 Toho Chem Ind Co Ltd 硬質ポリウレタンフォームの製造方法
JP3311307B2 (ja) * 1998-11-30 2002-08-05 花王株式会社 ポリウレタンフォームの製造法
ES2254360T3 (es) 2000-01-26 2006-06-16 Basf Aktiengesellschaft Espumas de poliuterano modificadas como absorbentes.
DE10003157B4 (de) 2000-01-26 2006-10-26 Basf Ag Verfahren zur Herstellung von funktionalisierten Polyurethanschaumstoffen
DE10006340A1 (de) 2000-02-12 2001-08-16 Basf Ag Verfahren zur Herstellung von Polyurethan-Schaumstoffen
DE10258046A1 (de) * 2002-12-11 2004-06-24 Basf Ag Verfahren zur Erniedrigung von Emissionen aus Polyurethanschaumstoffen
JP5080969B2 (ja) 2004-04-01 2012-11-21 チバ ホールディング インコーポレーテッド アルキル化されたｐａｎａ及びｄｐａ組成物
JP3959092B2 (ja) * 2004-12-27 2007-08-15 住化バイエルウレタン株式会社 ポリウレタン成形品およびその製造方法
JP4984449B2 (ja) * 2005-07-15 2012-07-25 東ソー株式会社 アルキル化ポリアルキレンポリアミン組成物、及びその製造方法
KR20090023574A (ko) 2006-04-20 2009-03-05 트랜스포트 파마슈티컬스, 인코포레이티드 이온영동요법적 약물 전달을 위한 약제학적 제형
US8552078B2 (en) * 2006-10-17 2013-10-08 Air Products And Chemicals, Inc. Crosslinkers for improving stability of polyurethane foams
JP5655261B2 (ja) * 2007-02-27 2015-01-21 東ソー株式会社 軟質又は半硬質ポリウレタンフォーム製造用の触媒組成物、及びそれを用いた軟質及び半硬質ポリウレタンフォームの製造法
JP4944944B2 (ja) 2007-02-28 2012-06-06 Ｈｏｙａ株式会社 プラスチックレンズ原料液注入方法および注入装置、ならびにプラスチックレンズの製造方法
JP5178072B2 (ja) * 2007-07-12 2013-04-10 三井化学株式会社 接着剤、該接着剤を含む複合材料および複合材料の製造方法
WO2009114329A2 (en) * 2008-03-07 2009-09-17 Dow Global Technologies Inc. Polyurethanes having low levels of aldehyde emissions
US20110009512A1 (en) 2008-03-20 2011-01-13 Huntsman Petrochemical Llc Reduction of aldehydes in amines
CN102803325A (zh) * 2009-04-24 2012-11-28 东曹株式会社 用于制造聚氨酯泡沫的发泡性添加剂、以及使用该发泡性添加剂的硬质聚氨酯泡沫的制造方法
DE102009047846A1 (de) * 2009-09-30 2011-03-31 Bayer Materialscience Ag Verfahren zur Erniedrigung von Emissionen eines Polyurethanschaumstoffes
WO2011084865A1 (en) 2010-01-08 2011-07-14 Huntsman Petrochemical Llc Inhibition of amine oxidation
WO2016005479A1 (en) * 2014-07-10 2016-01-14 Huntsman Petrochemical Llc A composition to reduce the amount of aldehydes emitted from polyurethane foams

Also Published As

Publication number Publication date
MX2015001877A (es) 2015-05-07
US20210347932A1 (en) 2021-11-11
JP6324450B2 (ja) 2018-05-16
CA2879930A1 (en) 2014-02-20
US11680130B2 (en) 2023-06-20
US10308754B2 (en) 2019-06-04
JP2015526558A (ja) 2015-09-10
JP6564479B2 (ja) 2019-08-21
EP2885330A1 (en) 2015-06-24
KR102027988B1 (ko) 2019-10-02
JP2018119148A (ja) 2018-08-02
KR20150043414A (ko) 2015-04-22
CA2879930C (en) 2020-03-10
IN2015DN00650A (enExample) 2015-06-26
WO2014026802A1 (en) 2014-02-20
EP2703421A1 (en) 2014-03-05
JP6807994B2 (ja) 2021-01-06
CN104797617B (zh) 2017-06-23
PL2885330T3 (pl) 2017-09-29
US20190263958A1 (en) 2019-08-29
CN104797617A (zh) 2015-07-22
MX346638B (es) 2017-03-27
EP2885330B1 (en) 2016-04-27
US20150191564A1 (en) 2015-07-09
JP2019206712A (ja) 2019-12-05
JP2017014516A (ja) 2017-01-19
US11053338B2 (en) 2021-07-06

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