CA2879930C - Isocyanate reactive composition and methods to reduce aldehydes emitted from polyurethanes - Google Patents

Isocyanate reactive composition and methods to reduce aldehydes emitted from polyurethanes Download PDF

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Publication number
CA2879930C
CA2879930C CA2879930A CA2879930A CA2879930C CA 2879930 C CA2879930 C CA 2879930C CA 2879930 A CA2879930 A CA 2879930A CA 2879930 A CA2879930 A CA 2879930A CA 2879930 C CA2879930 C CA 2879930C
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Prior art keywords
amine components
circle
composition
nitrogen atoms
amine
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CA2879930A
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English (en)
French (fr)
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CA2879930A1 (en
Inventor
Geert Lodewijk Dries
Robert Allison Grigsby, Jr.
Ernest Lee Rister, Jr.
Eugene P. Wiltz, Jr.
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Huntsman Petrochemical LLC
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Huntsman Petrochemical LLC
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Publication of CA2879930A1 publication Critical patent/CA2879930A1/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/485—Polyethers containing oxyethylene units and other oxyalkylene units containing mixed oxyethylene-oxypropylene or oxyethylene-higher oxyalkylene end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/14—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/302—Water
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C08G18/3228—Polyamines acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
    • C08G18/6685—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3225 or polyamines of C08G18/38
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0058—≥50 and <150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CA2879930A 2012-08-16 2013-07-10 Isocyanate reactive composition and methods to reduce aldehydes emitted from polyurethanes Active CA2879930C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201261683957P 2012-08-16 2012-08-16
US61/683,957 2012-08-16
EP12181977.5A EP2703421A1 (en) 2012-08-28 2012-08-28 A composition for making foams with reduced aldehyde emission
EP12181977.5 2012-08-28
PCT/EP2013/064519 WO2014026802A1 (en) 2012-08-16 2013-07-10 A composition

Publications (2)

Publication Number Publication Date
CA2879930A1 CA2879930A1 (en) 2014-02-20
CA2879930C true CA2879930C (en) 2020-03-10

Family

ID=46832229

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2879930A Active CA2879930C (en) 2012-08-16 2013-07-10 Isocyanate reactive composition and methods to reduce aldehydes emitted from polyurethanes

Country Status (10)

Country Link
US (3) US10308754B2 (enExample)
EP (2) EP2703421A1 (enExample)
JP (4) JP6291494B2 (enExample)
KR (1) KR102027988B1 (enExample)
CN (1) CN104797617B (enExample)
CA (1) CA2879930C (enExample)
IN (1) IN2015DN00650A (enExample)
MX (1) MX346638B (enExample)
PL (1) PL2885330T3 (enExample)
WO (1) WO2014026802A1 (enExample)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016005479A1 (en) * 2014-07-10 2016-01-14 Huntsman Petrochemical Llc A composition to reduce the amount of aldehydes emitted from polyurethane foams
KR101692970B1 (ko) * 2014-12-12 2017-01-06 주식회사 태성환경연구소 알데히드 저감용 액상제거제 함유 폴리우레탄폼 및 이의 제조방법
US20180086872A1 (en) * 2015-04-17 2018-03-29 Basf Se Polyurethanes with reduced aldehyde emission
EP3303430B1 (de) * 2015-05-28 2019-04-03 Basf Se Polyurethane mit reduzierter aldehydemission
JP6657267B2 (ja) * 2015-06-16 2020-03-04 エボニック オペレーションズ ゲーエムベーハー ポリウレタンフォーム用のアルデヒド捕捉剤
US10696777B2 (en) 2015-06-16 2020-06-30 Evonik Operations Gmbh Aldehyde scavengers mixtures for polyurethane foams
CN116675827A (zh) 2015-09-28 2023-09-01 美利肯公司 用于制备聚氨酯聚合物的方法
CA3010864C (en) * 2016-02-05 2024-01-16 Huntsman International Llc Method for the reduction of aldehyde emission in polyurethane foam
JP6780961B2 (ja) * 2016-06-14 2020-11-04 株式会社ブリヂストン ポリウレタン用アルデヒド捕捉剤、ポリウレタン、及びポリウレタンの製造方法
KR20190115055A (ko) * 2017-02-16 2019-10-10 다우 글로벌 테크놀로지스 엘엘씨 감소된 알데히드 배출물을 갖는 폴리우레탄 폼
WO2018234348A1 (en) 2017-06-21 2018-12-27 Huntsman International Llc Formulation for reduction of formaldehyde emission in pu foam
CA3088822A1 (en) 2017-12-18 2019-06-27 Huntsman International Llc Method for reduction of aldehyde emission in polyurethane comprising materials
CN110467808A (zh) * 2018-05-11 2019-11-19 襄阳亚克化学有限公司 用于聚氨酯泡沫的除醛阻燃剂及其制备方法
WO2020024231A1 (en) * 2018-08-02 2020-02-06 Dow Global Technologies Llc Methods for reducing aldehyde emissions in polyurethane foams
JP7135557B2 (ja) * 2018-08-07 2022-09-13 東ソー株式会社 ポリウレア樹脂製造用硬化剤組成物及びそれを用いたポリウレア樹脂の製造方法
CN110128614B (zh) * 2019-04-12 2021-06-11 浙江华峰合成树脂有限公司 高剥离发泡层用无溶剂聚氨酯树脂及其制备方法和应用
WO2021021098A1 (en) * 2019-07-29 2021-02-04 Huntsman Petrochemical Llc A polyurethane composition with reduced aldehyde emission
JP2022022758A (ja) * 2020-07-06 2022-02-07 東ソー株式会社 ポリウレタンフォーム製造用のアミン触媒組成物及びその用途
JPWO2023195269A1 (enExample) 2022-04-06 2023-10-12
CN119855854A (zh) 2022-09-08 2025-04-18 三菱瓦斯化学株式会社 发泡树脂形成性组合物、聚脲系树脂发泡体和聚脲系树脂发泡体的制造方法

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DE102009047846A1 (de) * 2009-09-30 2011-03-31 Bayer Materialscience Ag Verfahren zur Erniedrigung von Emissionen eines Polyurethanschaumstoffes
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WO2016005479A1 (en) * 2014-07-10 2016-01-14 Huntsman Petrochemical Llc A composition to reduce the amount of aldehydes emitted from polyurethane foams

Also Published As

Publication number Publication date
MX2015001877A (es) 2015-05-07
JP6291494B2 (ja) 2018-03-14
US20210347932A1 (en) 2021-11-11
JP6324450B2 (ja) 2018-05-16
CA2879930A1 (en) 2014-02-20
US11680130B2 (en) 2023-06-20
US10308754B2 (en) 2019-06-04
JP2015526558A (ja) 2015-09-10
JP6564479B2 (ja) 2019-08-21
EP2885330A1 (en) 2015-06-24
KR102027988B1 (ko) 2019-10-02
JP2018119148A (ja) 2018-08-02
KR20150043414A (ko) 2015-04-22
IN2015DN00650A (enExample) 2015-06-26
WO2014026802A1 (en) 2014-02-20
EP2703421A1 (en) 2014-03-05
JP6807994B2 (ja) 2021-01-06
CN104797617B (zh) 2017-06-23
PL2885330T3 (pl) 2017-09-29
US20190263958A1 (en) 2019-08-29
CN104797617A (zh) 2015-07-22
MX346638B (es) 2017-03-27
EP2885330B1 (en) 2016-04-27
US20150191564A1 (en) 2015-07-09
JP2019206712A (ja) 2019-12-05
JP2017014516A (ja) 2017-01-19
US11053338B2 (en) 2021-07-06

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