JP6106952B2 - 放射性物質吸着材、並びにそれを用いた吸着容器、吸着塔、及び水処理装置 - Google Patents

放射性物質吸着材、並びにそれを用いた吸着容器、吸着塔、及び水処理装置 Download PDF

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Publication number
JP6106952B2
JP6106952B2 JP2012122215A JP2012122215A JP6106952B2 JP 6106952 B2 JP6106952 B2 JP 6106952B2 JP 2012122215 A JP2012122215 A JP 2012122215A JP 2012122215 A JP2012122215 A JP 2012122215A JP 6106952 B2 JP6106952 B2 JP 6106952B2
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Prior art keywords
titanate
adsorption
water
radioactive
adsorbent
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JP2012122215A
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English (en)
Japanese (ja)
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JP2013246145A (ja
Inventor
森　浩一
浩一 森
伸樹 糸井
伸樹 糸井
久実子 葉利
久実子 葉利
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Otsuka Chemical Co Ltd
Kurita Water Industries Ltd
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Otsuka Chemical Co Ltd
Kurita Water Industries Ltd
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Priority to JP2012122215A priority Critical patent/JP6106952B2/ja
Application filed by Otsuka Chemical Co Ltd, Kurita Water Industries Ltd filed Critical Otsuka Chemical Co Ltd
Priority to US14/403,009 priority patent/US20150306594A1/en
Priority to PCT/JP2013/064028 priority patent/WO2013179940A1/fr
Priority to CN201380028418.7A priority patent/CN104412329B/zh
Priority to EP13796716.2A priority patent/EP2860735B1/fr
Priority to RU2014152675A priority patent/RU2629961C2/ru
Priority to TW102118651A priority patent/TWI619549B/zh
Publication of JP2013246145A publication Critical patent/JP2013246145A/ja
Priority to US15/094,487 priority patent/US20160314864A1/en
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    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/02—Treating gases
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04—Treating liquids
    • G21F9/06—Processing
    • G21F9/12—Processing by absorption; by adsorption; by ion-exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0211—Compounds of Ti, Zr, Hf
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/12—Naturally occurring clays or bleaching earth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28016—Particle form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3007—Moulding, shaping or extruding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3042—Use of binding agents; addition of materials ameliorating the mechanical properties of the produced sorbent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/10—Oxides or hydroxides
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04—Treating liquids
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/006—Radioactive compounds

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • General Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Thermal Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
JP2012122215A 2012-05-29 2012-05-29 放射性物質吸着材、並びにそれを用いた吸着容器、吸着塔、及び水処理装置 Active JP6106952B2 (ja)

Priority Applications (8)

Application Number Priority Date Filing Date Title
JP2012122215A JP6106952B2 (ja) 2012-05-29 2012-05-29 放射性物質吸着材、並びにそれを用いた吸着容器、吸着塔、及び水処理装置
PCT/JP2013/064028 WO2013179940A1 (fr) 2012-05-29 2013-05-21 Adsorbant de matière radioactive, cuve d'adsorption, tour d'adsorption et dispositif de traitement des eaux
CN201380028418.7A CN104412329B (zh) 2012-05-29 2013-05-21 放射性物质吸附材料、吸附容器、吸附塔、及水处理装置
EP13796716.2A EP2860735B1 (fr) 2012-05-29 2013-05-21 Adsorbant de matière radioactive, cuve d'adsorption, tour d'adsorption et dispositif de traitement des eaux
US14/403,009 US20150306594A1 (en) 2012-05-29 2013-05-21 Radioactive material adsorbent, adsorption vessel, adsorption tower, and water treatment device
RU2014152675A RU2629961C2 (ru) 2012-05-29 2013-05-21 Адсорбент радиоактивного материала, адсорбционный сосуд, адсорбционная колонна и устройство для обработки воды
TW102118651A TWI619549B (zh) 2012-05-29 2013-05-27 Radioactive material adsorbing material, adsorption container, adsorption tower, and water treatment device
US15/094,487 US20160314864A1 (en) 2012-05-29 2016-04-08 Method for adsorbilng radioactive material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2012122215A JP6106952B2 (ja) 2012-05-29 2012-05-29 放射性物質吸着材、並びにそれを用いた吸着容器、吸着塔、及び水処理装置

Publications (2)

Publication Number Publication Date
JP2013246145A JP2013246145A (ja) 2013-12-09
JP6106952B2 true JP6106952B2 (ja) 2017-04-05

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JP2012122215A Active JP6106952B2 (ja) 2012-05-29 2012-05-29 放射性物質吸着材、並びにそれを用いた吸着容器、吸着塔、及び水処理装置

Country Status (7)

Country Link
US (2) US20150306594A1 (fr)
EP (1) EP2860735B1 (fr)
JP (1) JP6106952B2 (fr)
CN (1) CN104412329B (fr)
RU (1) RU2629961C2 (fr)
TW (1) TWI619549B (fr)
WO (1) WO2013179940A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2681972C2 (ru) * 2014-09-22 2019-03-14 ФОРД ГЛОУБАЛ ТЕКНОЛОДЖИЗ, ЭлЭлСи Устройство транспортного средства, устройство и способ управления системой нагрева, вентиляции и кондиционирования воздуха

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6197482B2 (ja) * 2013-08-26 2017-09-20 栗田工業株式会社 ストロンチウム吸着剤の製造方法
JP6263066B2 (ja) * 2014-03-27 2018-01-17 株式会社クボタ 複合チタネートイオン交換体
CN104475008B (zh) * 2014-12-19 2017-02-01 北京林业大学 一种高温co2吸附材料及其在吸附增强型产氢反应中的应用方法
JP6407087B2 (ja) * 2015-03-31 2018-10-17 株式会社クボタ 複合イオン交換体並びにそれを備えたイオン吸着装置及び水処理システム
JP6928928B2 (ja) * 2016-12-15 2021-09-01 東洋紡株式会社 放射性物質除去フィルタ、それを用いる放射性物質除去フィルタユニット及び放射性物質の除去方法
JP7086524B2 (ja) 2017-03-08 2022-06-20 株式会社荏原製作所 アルカリ土類金属イオン吸着剤及びその製造方法並びにアルカリ土類金属イオン含有液処理装置
JP6470354B2 (ja) * 2017-07-05 2019-02-13 株式会社荏原製作所 シリコチタネート成形体及びその製造方法、シリコチタネート成形体を含むセシウム又はストロンチウムの吸着剤、及び当該吸着剤を用いる放射性廃液の除染方法

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US1697929A (en) * 1925-06-02 1929-01-08 Titanium Pigment Co Inc Alkali-metal titanate and method of making same
US3328117A (en) * 1963-05-10 1967-06-27 Du Pont Process for producing fibrous alkali metal titanates
JPS56100637A (en) * 1980-01-16 1981-08-12 Natl Inst For Res In Inorg Mater Ion exchange material of cesium in aqueous solution and fixing method for cesium
US4373037A (en) * 1981-05-29 1983-02-08 Engelhard Corporation Asbestos-free friction material incorporating attapulgite clay
FI821535L (fi) * 1982-04-30 1983-10-31 Jukka Kalevi Lehto Foerfarande foer framstaellning av titanater
US4432893A (en) * 1982-05-19 1984-02-21 The United States Of America As Represented By The Department Of Energy Precipitation-adsorption process for the decontamination of nuclear waste supernates
JPH0915389A (ja) * 1995-06-27 1997-01-17 Japan Atom Energy Res Inst 放射性核種の吸着材及びその製造方法及び放射性廃棄物の減容処理方法
WO1997014652A1 (fr) * 1995-10-20 1997-04-24 Alliedsignal Inc. Titanate de sodium en couches, partiellement cristallin
FI956222A0 (fi) * 1995-12-22 1995-12-22 Ivo International Oy Framstaellning av granulaera titanatjonbytare
US5989434A (en) * 1997-10-31 1999-11-23 3M Innovative Properties Company Method for removing metal ions from solution with titanate sorbents
JP2001133594A (ja) * 1999-11-05 2001-05-18 Jgc Corp 原子炉冷却水からの放射性核種の除去方法
ES2682283T3 (es) * 2007-04-04 2018-09-19 Otsuka Chemical Co., Ltd. Titanato de potasio, procedimiento de producción del mismo, materiales de fricción y composiciones de resina
EP2243547A1 (fr) * 2009-04-20 2010-10-27 Fortum OYJ Nouveau sorbant, son procédé de fabrication et son utilisation
CN202058473U (zh) * 2011-03-16 2011-11-30 中科华核电技术研究院有限公司 一种放射性废物处理装置
CN102347089B (zh) * 2011-10-28 2013-10-23 衡阳师范学院 核电站安全壳内放射性核素吸附沉淀的方法及装置

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2681972C2 (ru) * 2014-09-22 2019-03-14 ФОРД ГЛОУБАЛ ТЕКНОЛОДЖИЗ, ЭлЭлСи Устройство транспортного средства, устройство и способ управления системой нагрева, вентиляции и кондиционирования воздуха

Also Published As

Publication number Publication date
TW201408366A (zh) 2014-03-01
US20150306594A1 (en) 2015-10-29
RU2014152675A (ru) 2016-07-20
EP2860735A4 (fr) 2016-02-24
JP2013246145A (ja) 2013-12-09
CN104412329B (zh) 2017-10-13
RU2629961C2 (ru) 2017-09-05
EP2860735A1 (fr) 2015-04-15
EP2860735B1 (fr) 2017-06-28
US20160314864A1 (en) 2016-10-27
TWI619549B (zh) 2018-04-01
CN104412329A (zh) 2015-03-11
WO2013179940A1 (fr) 2013-12-05

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