RU2014152675A - Адсорбент радиоактивного материала, адсорбционный сосуд, адсорбционная колонна и устройство для обработки воды - Google Patents
Адсорбент радиоактивного материала, адсорбционный сосуд, адсорбционная колонна и устройство для обработки воды Download PDFInfo
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- RU2014152675A RU2014152675A RU2014152675A RU2014152675A RU2014152675A RU 2014152675 A RU2014152675 A RU 2014152675A RU 2014152675 A RU2014152675 A RU 2014152675A RU 2014152675 A RU2014152675 A RU 2014152675A RU 2014152675 A RU2014152675 A RU 2014152675A
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- Russia
- Prior art keywords
- radioactive material
- adsorbent
- material according
- titanate
- adsorption
- Prior art date
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- 239000012857 radioactive material Substances 0.000 title claims abstract 25
- 239000003463 adsorbent Substances 0.000 title claims abstract 23
- 238000001179 sorption measurement Methods 0.000 title claims abstract 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract 8
- 239000002245 particle Substances 0.000 claims abstract 8
- 239000011230 binding agent Substances 0.000 claims abstract 4
- 239000002734 clay mineral Substances 0.000 claims abstract 4
- 239000000126 substance Substances 0.000 claims abstract 4
- 229960000892 attapulgite Drugs 0.000 claims abstract 2
- 150000001768 cations Chemical class 0.000 claims abstract 2
- 230000001788 irregular Effects 0.000 claims abstract 2
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract 2
- 230000002285 radioactive effect Effects 0.000 claims abstract 2
- 229910052712 strontium Inorganic materials 0.000 claims abstract 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims abstract 2
Classifications
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- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/02—Treating gases
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/06—Processing
- G21F9/12—Processing by absorption; by adsorption; by ion-exchange
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
- B01D15/08—Selective adsorption, e.g. chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0211—Compounds of Ti, Zr, Hf
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/041—Oxides or hydroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/12—Naturally occurring clays or bleaching earth
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
- B01J20/28004—Sorbent size or size distribution, e.g. particle size
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28016—Particle form
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3007—Moulding, shaping or extruding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3042—Use of binding agents; addition of materials ameliorating the mechanical properties of the produced sorbent
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/10—Oxides or hydroxides
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/006—Radioactive compounds
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- High Energy & Nuclear Physics (AREA)
- General Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Thermal Sciences (AREA)
- Dispersion Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
1. Адсорбент радиоактивного материала, содержащий титанат, представленный химической формулой MTiO(M: одновалентный катион).2. Адсорбент радиоактивного материала по п. 1, в котором титанат имеет средний диаметр частиц 1-150 мкм.3. Адсорбент радиоактивного материала по п. 1 или 2, в котором химическая формула представлена KTiO.4. Адсорбент радиоактивного материала по п. 3, в котором титанат имеет форму, в которой множество выступов простираются в нерегулярных направлениях.5. Адсорбент радиоактивного материала по п. 1 или 2, в котором радиоактивный материал представляет собой радиоактивный стронций.6. Адсорбент радиоактивного материала по п. 1, в котором титанат формуют в частицы, имеющие диаметр частиц в диапазоне 150-3000 мкм путем использования связующего.7. Адсорбент радиоактивного материала по п. 6, в котором связующее представляет собой глинистый минерал.8. Адсорбент радиоактивного материала по п. 7, в котором глинистый минерал представляет собой аттапульгит.9. Адсорбент радиоактивного материала по любому из пп. 6-8, в котором формованные частицы обжигают при температуре, варьирующейся от 500°C до 900°C.10. Адсорбционный сосуд, наполненный адсорбентом радиоактивного материала по любому из пп. 1-9.11. Адсорбционная колонна, наполненная адсорбентом радиоактивного материала по любому из пп. 1-9.12. Устройство для обработки воды, включающее в себя адсорбционный сосуд по п. 10 или адсорбционную колонну по п. 11.
Claims (12)
1. Адсорбент радиоактивного материала, содержащий титанат, представленный химической формулой M2Ti2O5 (M: одновалентный катион).
2. Адсорбент радиоактивного материала по п. 1, в котором титанат имеет средний диаметр частиц 1-150 мкм.
3. Адсорбент радиоактивного материала по п. 1 или 2, в котором химическая формула представлена K2Ti2O5.
4. Адсорбент радиоактивного материала по п. 3, в котором титанат имеет форму, в которой множество выступов простираются в нерегулярных направлениях.
5. Адсорбент радиоактивного материала по п. 1 или 2, в котором радиоактивный материал представляет собой радиоактивный стронций.
6. Адсорбент радиоактивного материала по п. 1, в котором титанат формуют в частицы, имеющие диаметр частиц в диапазоне 150-3000 мкм путем использования связующего.
7. Адсорбент радиоактивного материала по п. 6, в котором связующее представляет собой глинистый минерал.
8. Адсорбент радиоактивного материала по п. 7, в котором глинистый минерал представляет собой аттапульгит.
9. Адсорбент радиоактивного материала по любому из пп. 6-8, в котором формованные частицы обжигают при температуре, варьирующейся от 500°C до 900°C.
10. Адсорбционный сосуд, наполненный адсорбентом радиоактивного материала по любому из пп. 1-9.
11. Адсорбционная колонна, наполненная адсорбентом радиоактивного материала по любому из пп. 1-9.
12. Устройство для обработки воды, включающее в себя адсорбционный сосуд по п. 10 или адсорбционную колонну по п. 11.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2012-122215 | 2012-05-29 | ||
JP2012122215A JP6106952B2 (ja) | 2012-05-29 | 2012-05-29 | 放射性物質吸着材、並びにそれを用いた吸着容器、吸着塔、及び水処理装置 |
PCT/JP2013/064028 WO2013179940A1 (ja) | 2012-05-29 | 2013-05-21 | 放射性物質吸着材、吸着容器、吸着塔、及び水処理装置 |
Publications (2)
Publication Number | Publication Date |
---|---|
RU2014152675A true RU2014152675A (ru) | 2016-07-20 |
RU2629961C2 RU2629961C2 (ru) | 2017-09-05 |
Family
ID=49673142
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU2014152675A RU2629961C2 (ru) | 2012-05-29 | 2013-05-21 | Адсорбент радиоактивного материала, адсорбционный сосуд, адсорбционная колонна и устройство для обработки воды |
Country Status (7)
Country | Link |
---|---|
US (2) | US20150306594A1 (ru) |
EP (1) | EP2860735B1 (ru) |
JP (1) | JP6106952B2 (ru) |
CN (1) | CN104412329B (ru) |
RU (1) | RU2629961C2 (ru) |
TW (1) | TWI619549B (ru) |
WO (1) | WO2013179940A1 (ru) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6197482B2 (ja) * | 2013-08-26 | 2017-09-20 | 栗田工業株式会社 | ストロンチウム吸着剤の製造方法 |
JP6263066B2 (ja) * | 2014-03-27 | 2018-01-17 | 株式会社クボタ | 複合チタネートイオン交換体 |
US9862247B2 (en) * | 2014-09-22 | 2018-01-09 | Ford Global Technologies, Llc | Directional climate control system with infrared targeting |
CN104475008B (zh) * | 2014-12-19 | 2017-02-01 | 北京林业大学 | 一种高温co2吸附材料及其在吸附增强型产氢反应中的应用方法 |
JP6407087B2 (ja) * | 2015-03-31 | 2018-10-17 | 株式会社クボタ | 複合イオン交換体並びにそれを備えたイオン吸着装置及び水処理システム |
JP6928928B2 (ja) * | 2016-12-15 | 2021-09-01 | 東洋紡株式会社 | 放射性物質除去フィルタ、それを用いる放射性物質除去フィルタユニット及び放射性物質の除去方法 |
JP7086524B2 (ja) | 2017-03-08 | 2022-06-20 | 株式会社荏原製作所 | アルカリ土類金属イオン吸着剤及びその製造方法並びにアルカリ土類金属イオン含有液処理装置 |
JP6470354B2 (ja) | 2017-07-05 | 2019-02-13 | 株式会社荏原製作所 | シリコチタネート成形体及びその製造方法、シリコチタネート成形体を含むセシウム又はストロンチウムの吸着剤、及び当該吸着剤を用いる放射性廃液の除染方法 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1697929A (en) * | 1925-06-02 | 1929-01-08 | Titanium Pigment Co Inc | Alkali-metal titanate and method of making same |
US3328117A (en) * | 1963-05-10 | 1967-06-27 | Du Pont | Process for producing fibrous alkali metal titanates |
JPS56100637A (en) * | 1980-01-16 | 1981-08-12 | Natl Inst For Res In Inorg Mater | Ion exchange material of cesium in aqueous solution and fixing method for cesium |
US4373037A (en) * | 1981-05-29 | 1983-02-08 | Engelhard Corporation | Asbestos-free friction material incorporating attapulgite clay |
FI821535L (fi) * | 1982-04-30 | 1983-10-31 | Jukka Kalevi Lehto | Foerfarande foer framstaellning av titanater |
US4432893A (en) * | 1982-05-19 | 1984-02-21 | The United States Of America As Represented By The Department Of Energy | Precipitation-adsorption process for the decontamination of nuclear waste supernates |
JPH0915389A (ja) * | 1995-06-27 | 1997-01-17 | Japan Atom Energy Res Inst | 放射性核種の吸着材及びその製造方法及び放射性廃棄物の減容処理方法 |
WO1997014652A1 (en) * | 1995-10-20 | 1997-04-24 | Alliedsignal Inc. | Partially crystalline layered sodium titanate |
FI956222A0 (fi) * | 1995-12-22 | 1995-12-22 | Ivo International Oy | Framstaellning av granulaera titanatjonbytare |
US5989434A (en) * | 1997-10-31 | 1999-11-23 | 3M Innovative Properties Company | Method for removing metal ions from solution with titanate sorbents |
JP2001133594A (ja) * | 1999-11-05 | 2001-05-18 | Jgc Corp | 原子炉冷却水からの放射性核種の除去方法 |
KR101428833B1 (ko) * | 2007-04-04 | 2014-08-08 | 오츠카 가가쿠 가부시키가이샤 | 티탄산칼륨, 그의 제조 방법, 마찰재 및 수지 조성물 |
EP2243547A1 (en) * | 2009-04-20 | 2010-10-27 | Fortum OYJ | Novel sorbent, method of producing the same and the use thereof |
CN202058473U (zh) * | 2011-03-16 | 2011-11-30 | 中科华核电技术研究院有限公司 | 一种放射性废物处理装置 |
CN102347089B (zh) * | 2011-10-28 | 2013-10-23 | 衡阳师范学院 | 核电站安全壳内放射性核素吸附沉淀的方法及装置 |
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2012
- 2012-05-29 JP JP2012122215A patent/JP6106952B2/ja active Active
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2013
- 2013-05-21 WO PCT/JP2013/064028 patent/WO2013179940A1/ja active Application Filing
- 2013-05-21 US US14/403,009 patent/US20150306594A1/en not_active Abandoned
- 2013-05-21 EP EP13796716.2A patent/EP2860735B1/en active Active
- 2013-05-21 RU RU2014152675A patent/RU2629961C2/ru active
- 2013-05-21 CN CN201380028418.7A patent/CN104412329B/zh active Active
- 2013-05-27 TW TW102118651A patent/TWI619549B/zh active
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2016
- 2016-04-08 US US15/094,487 patent/US20160314864A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
JP2013246145A (ja) | 2013-12-09 |
EP2860735B1 (en) | 2017-06-28 |
US20160314864A1 (en) | 2016-10-27 |
CN104412329A (zh) | 2015-03-11 |
JP6106952B2 (ja) | 2017-04-05 |
WO2013179940A1 (ja) | 2013-12-05 |
TWI619549B (zh) | 2018-04-01 |
EP2860735A4 (en) | 2016-02-24 |
EP2860735A1 (en) | 2015-04-15 |
US20150306594A1 (en) | 2015-10-29 |
TW201408366A (zh) | 2014-03-01 |
CN104412329B (zh) | 2017-10-13 |
RU2629961C2 (ru) | 2017-09-05 |
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