JP6025284B2 - 蓄電装置用の電極及び蓄電装置 - Google Patents
蓄電装置用の電極及び蓄電装置 Download PDFInfo
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- JP6025284B2 JP6025284B2 JP2012175773A JP2012175773A JP6025284B2 JP 6025284 B2 JP6025284 B2 JP 6025284B2 JP 2012175773 A JP2012175773 A JP 2012175773A JP 2012175773 A JP2012175773 A JP 2012175773A JP 6025284 B2 JP6025284 B2 JP 6025284B2
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Classifications
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/04—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of carbon-silicon compounds, carbon or silicon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/134—Electrodes based on metals, Si or alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1393—Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1395—Processes of manufacture of electrodes based on metals, Si or alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/386—Silicon or alloys based on silicon
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/626—Metals
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Cell Electrode Carriers And Collectors (AREA)
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| JP2012175773A JP6025284B2 (ja) | 2011-08-19 | 2012-08-08 | 蓄電装置用の電極及び蓄電装置 |
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| JP3127043B2 (ja) | 1992-06-17 | 2001-01-22 | 株式会社マック・サイエンス | 熱重量検出装置 |
| CN102307817B (zh) * | 2008-09-18 | 2015-02-25 | 尼奥齐姆国际有限公司 | 处理有机物质以产生生物气体的厌氧方法 |
| WO2013027561A1 (en) | 2011-08-19 | 2013-02-28 | Semiconductor Energy Laboratory Co., Ltd. | Method for manufacturing graphene-coated object, negative electrode of secondary battery including graphene-coated object, and secondary battery including the negative electrode |
| JP6034621B2 (ja) * | 2011-09-02 | 2016-11-30 | 株式会社半導体エネルギー研究所 | 蓄電装置の電極および蓄電装置 |
| JP6050106B2 (ja) | 2011-12-21 | 2016-12-21 | 株式会社半導体エネルギー研究所 | 非水二次電池用シリコン負極の製造方法 |
| US8519450B1 (en) * | 2012-08-17 | 2013-08-27 | International Business Machines Corporation | Graphene-based non-volatile memory |
| JP2015082374A (ja) * | 2013-10-22 | 2015-04-27 | 株式会社半導体エネルギー研究所 | 電極の作製方法、二次電池の電極、及びそれを用いた二次電池 |
| WO2016030811A1 (en) | 2014-08-27 | 2016-03-03 | Semiconductor Energy Laboratory Co., Ltd. | Storage battery electrode, manufacturing method thereof, storage battery, electronic device, and graphene |
| WO2016160703A1 (en) | 2015-03-27 | 2016-10-06 | Harrup Mason K | All-inorganic solvents for electrolytes |
| WO2016178117A1 (en) | 2015-05-06 | 2016-11-10 | Semiconductor Energy Laboratory Co., Ltd. | Secondary battery and electronic device |
| JP6840476B2 (ja) | 2015-07-16 | 2021-03-10 | 株式会社半導体エネルギー研究所 | 蓄電装置の作製方法 |
| JP2017045726A (ja) | 2015-08-27 | 2017-03-02 | 株式会社半導体エネルギー研究所 | 電極、及びその製造方法、蓄電池、並びに電子機器 |
| DE112017007748B3 (de) | 2016-07-05 | 2022-07-28 | Semiconductor Energy Laboratory Co., Ltd. | Lithiumionen-Sekundärbatterie |
| US12308421B2 (en) | 2016-09-12 | 2025-05-20 | Semiconductor Energy Laboratory Co., Ltd. | Electrode and power storage device comprising graphene compound |
| US10707531B1 (en) | 2016-09-27 | 2020-07-07 | New Dominion Enterprises Inc. | All-inorganic solvents for electrolytes |
| CN116387602A (zh) | 2016-10-12 | 2023-07-04 | 株式会社半导体能源研究所 | 正极活性物质粒子以及正极活性物质粒子的制造方法 |
| US11489151B2 (en) | 2017-05-12 | 2022-11-01 | Semiconductor Energy Laboratory Co., Ltd. | Positive electrode active material particle |
| CN117038957A (zh) | 2017-05-19 | 2023-11-10 | 株式会社半导体能源研究所 | 锂离子二次电池 |
| CN118335885A (zh) | 2017-06-26 | 2024-07-12 | 株式会社半导体能源研究所 | 正极活性物质的制造方法及二次电池 |
| CN110843594A (zh) * | 2019-12-05 | 2020-02-28 | 广东奥美格传导科技股份有限公司 | 交直流一体充电桩的充电控制系统 |
| WO2021222860A1 (en) * | 2020-05-01 | 2021-11-04 | Neutron Holdings, Inc. Dba Lime | Flexible connector mechanism for light electric vehicles |
Family Cites Families (95)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4628015A (en) | 1984-09-20 | 1986-12-09 | Kanebo, Ltd. | Insoluble and infusible substrate with a polyacene-type skeletal structure, and its applications for electrical conductor and organic cell |
| JPH0660870A (ja) | 1992-08-05 | 1994-03-04 | Toshiba Battery Co Ltd | 乾電池の製造法 |
| JP4393610B2 (ja) | 1999-01-26 | 2010-01-06 | 日本コークス工業株式会社 | リチウム二次電池用負極材料、リチウム二次電池、及び同二次電池の充電方法 |
| WO2001029913A1 (fr) | 1999-10-22 | 2001-04-26 | Sanyo Electric Co., Ltd. | Procede de production d'un materiau destine a une electrode de pile au lithium |
| CN1189958C (zh) | 1999-10-22 | 2005-02-16 | 三洋电机株式会社 | 可充电锂电池电极的制造方法 |
| CA2388013A1 (en) | 1999-10-22 | 2001-04-26 | Sanyo Electric Co., Ltd. | A rechargeable lithium battery and an electrode therefor |
| WO2001031723A1 (en) | 1999-10-22 | 2001-05-03 | Sanyo Electric Co., Ltd. | Electrode for lithium secondary cell and lithium secondary cell |
| AU7950700A (en) | 1999-10-22 | 2001-05-08 | Sanyo Electric Co., Ltd. | Electrode for lithium cell and lithium secondary cell |
| JP2002083594A (ja) | 1999-10-22 | 2002-03-22 | Sanyo Electric Co Ltd | リチウム電池用電極並びにこれを用いたリチウム電池及びリチウム二次電池 |
| KR100520872B1 (ko) | 1999-10-22 | 2005-10-12 | 산요덴키가부시키가이샤 | 리튬 전지용 전극 및 리튬 2차전지 |
| JP2001210315A (ja) | 2000-01-25 | 2001-08-03 | Sanyo Electric Co Ltd | リチウム二次電池用電極及びこれを用いたリチウム二次電池 |
| DE10003509A1 (de) | 2000-01-27 | 2001-08-02 | Basf Ag | Verfahren zur Herstellung schlagzäher Kunststoffe |
| JP2002063894A (ja) | 2000-08-22 | 2002-02-28 | Sharp Corp | 炭素材料膜の作製方法及び該炭素材料膜を用いた非水電解質二次電池 |
| JP2004259475A (ja) | 2003-02-24 | 2004-09-16 | Osaka Gas Co Ltd | リチウム二次電池用負極材とその製造方法、及びそれを用いたリチウム二次電池 |
| US7939218B2 (en) | 2004-12-09 | 2011-05-10 | Nanosys, Inc. | Nanowire structures comprising carbon |
| US8278011B2 (en) | 2004-12-09 | 2012-10-02 | Nanosys, Inc. | Nanostructured catalyst supports |
| CN102593466A (zh) | 2004-12-09 | 2012-07-18 | 奈米系统股份有限公司 | 用于燃料电池的基于纳米线的膜电极组件 |
| US7842432B2 (en) | 2004-12-09 | 2010-11-30 | Nanosys, Inc. | Nanowire structures comprising carbon |
| JP3850427B2 (ja) | 2005-03-22 | 2006-11-29 | 株式会社物産ナノテク研究所 | 炭素繊維結合体およびこれを用いた複合材料 |
| US8003257B2 (en) | 2005-07-04 | 2011-08-23 | Showa Denko K.K. | Method for producing anode for lithium secondary battery and anode composition, and lithium secondary battery |
| WO2008048295A2 (en) | 2005-11-18 | 2008-04-24 | Northwestern University | Stable dispersions of polymer-coated graphitic nanoplatelets |
| WO2007061945A2 (en) | 2005-11-21 | 2007-05-31 | Nanosys, Inc. | Nanowire structures comprising carbon |
| EP1995213A4 (en) * | 2006-03-13 | 2010-03-24 | Nikon Corp | METHOD OF PRODUCTION OF CARBON NANOPHONE AGGREGATES, CARBON NANOPHONIC UNITS, CATALYST LINE DISPERSION MEMBRANE, ELECTRONIC MIXTURES AND FIELD EMISSION INDICATORS |
| CN101454938A (zh) | 2006-06-02 | 2009-06-10 | 三菱化学株式会社 | 非水电解液以及非水电解质电池 |
| JP5272297B2 (ja) | 2006-10-17 | 2013-08-28 | 日産自動車株式会社 | 電池用電極 |
| JP5153189B2 (ja) | 2007-03-30 | 2013-02-27 | 三井造船株式会社 | リチウムイオン二次電池正極材料の製造方法 |
| KR100923304B1 (ko) | 2007-10-29 | 2009-10-23 | 삼성전자주식회사 | 그라펜 시트 및 그의 제조방법 |
| US7745047B2 (en) | 2007-11-05 | 2010-06-29 | Nanotek Instruments, Inc. | Nano graphene platelet-base composite anode compositions for lithium ion batteries |
| JP5377946B2 (ja) | 2007-12-25 | 2013-12-25 | 花王株式会社 | リチウム電池正極用複合材料 |
| US8426064B2 (en) | 2007-12-25 | 2013-04-23 | Kao Corporation | Composite material for positive electrode of lithium battery |
| WO2009137241A2 (en) | 2008-04-14 | 2009-11-12 | Bandgap Engineering, Inc. | Process for fabricating nanowire arrays |
| WO2009127901A1 (en) | 2008-04-14 | 2009-10-22 | High Power Lithium S.A. | Lithium metal phosphate/carbon nanocomposites as cathode active materials for secondary lithium batteries |
| US8936874B2 (en) * | 2008-06-04 | 2015-01-20 | Nanotek Instruments, Inc. | Conductive nanocomposite-based electrodes for lithium batteries |
| US8450014B2 (en) | 2008-07-28 | 2013-05-28 | Battelle Memorial Institute | Lithium ion batteries with titania/graphene anodes |
| US8257867B2 (en) | 2008-07-28 | 2012-09-04 | Battelle Memorial Institute | Nanocomposite of graphene and metal oxide materials |
| US9190667B2 (en) | 2008-07-28 | 2015-11-17 | Nanotek Instruments, Inc. | Graphene nanocomposites for electrochemical cell electrodes |
| JP5196555B2 (ja) | 2008-08-06 | 2013-05-15 | 独立行政法人産業技術総合研究所 | 電極材料前駆体の製造方法及び得られた電極材料前駆体を用いる電極材料の製造方法 |
| US8821763B2 (en) | 2008-09-30 | 2014-09-02 | Tdk Corporation | Active material and method of manufacturing active material |
| JP2010129332A (ja) | 2008-11-27 | 2010-06-10 | Toyota Motor Corp | 非水電解質二次電池 |
| US8580432B2 (en) | 2008-12-04 | 2013-11-12 | Nanotek Instruments, Inc. | Nano graphene reinforced nanocomposite particles for lithium battery electrodes |
| US9093693B2 (en) | 2009-01-13 | 2015-07-28 | Samsung Electronics Co., Ltd. | Process for producing nano graphene reinforced composite particles for lithium battery electrodes |
| EP2237346B1 (en) | 2009-04-01 | 2017-08-09 | The Swatch Group Research and Development Ltd. | Electrically conductive nanocomposite material comprising sacrificial nanoparticles and open porous nanocomposites produced thereof |
| EP2228855B1 (en) | 2009-03-12 | 2014-02-26 | Belenos Clean Power Holding AG | Open porous electrically conductive nanocomposite material |
| JP2010262752A (ja) * | 2009-04-30 | 2010-11-18 | Furukawa Electric Co Ltd:The | リチウムイオン二次電池用の負極、それを用いたリチウムイオン二次電池、リチウムイオン二次電池用の負極の製造方法 |
| US20140370380A9 (en) | 2009-05-07 | 2014-12-18 | Yi Cui | Core-shell high capacity nanowires for battery electrodes |
| US20100285358A1 (en) | 2009-05-07 | 2010-11-11 | Amprius, Inc. | Electrode Including Nanostructures for Rechargeable Cells |
| US20100291438A1 (en) | 2009-05-15 | 2010-11-18 | PDC Energy, LLC | Electrode material, lithium-ion battery and method thereof |
| US8450012B2 (en) | 2009-05-27 | 2013-05-28 | Amprius, Inc. | Interconnected hollow nanostructures containing high capacity active materials for use in rechargeable batteries |
| US20100330419A1 (en) | 2009-06-02 | 2010-12-30 | Yi Cui | Electrospinning to fabricate battery electrodes |
| JP5369031B2 (ja) | 2009-08-11 | 2013-12-18 | 積水化学工業株式会社 | 炭素材料、電極材料及びリチウムイオン二次電池負極材料 |
| JP2011048992A (ja) | 2009-08-26 | 2011-03-10 | Sekisui Chem Co Ltd | 炭素材料、電極材料及びリチウムイオン二次電池負極材料 |
| US8526167B2 (en) | 2009-09-03 | 2013-09-03 | Applied Materials, Inc. | Porous amorphous silicon-carbon nanotube composite based electrodes for battery applications |
| KR101736462B1 (ko) | 2009-09-21 | 2017-05-16 | 한화테크윈 주식회사 | 그래핀의 제조 방법 |
| US8778538B2 (en) | 2009-11-06 | 2014-07-15 | Northwestern University | Electrode material comprising graphene-composite materials in a graphite network |
| US9431649B2 (en) | 2009-11-23 | 2016-08-30 | Uchicago Argonne, Llc | Coated electroactive materials |
| US8652687B2 (en) | 2009-12-24 | 2014-02-18 | Nanotek Instruments, Inc. | Conductive graphene polymer binder for electrochemical cell electrodes |
| US20110183203A1 (en) | 2010-01-27 | 2011-07-28 | Molecular Nanosystems, Inc. | Polymer supported electrodes |
| US9172088B2 (en) | 2010-05-24 | 2015-10-27 | Amprius, Inc. | Multidimensional electrochemically active structures for battery electrodes |
| KR101906606B1 (ko) | 2010-03-03 | 2018-10-10 | 암프리우스, 인코포레이티드 | 활물질을 증착하기 위한 템플릿 전극 구조체 |
| US9780365B2 (en) | 2010-03-03 | 2017-10-03 | Amprius, Inc. | High-capacity electrodes with active material coatings on multilayered nanostructured templates |
| US20110227000A1 (en) | 2010-03-19 | 2011-09-22 | Ruoff Rodney S | Electrophoretic deposition and reduction of graphene oxide to make graphene film coatings and electrode structures |
| EP2550698A4 (en) | 2010-03-22 | 2015-04-08 | Amprius Inc | NETWORKING OF NANOSTRUCTURES FROM AN ELECTROCHEMICAL ACTIVE MATERIAL |
| WO2011136028A1 (en) | 2010-04-28 | 2011-11-03 | Semiconductor Energy Laboratory Co., Ltd. | Power storage device and method for manufacturing the same |
| WO2011149958A2 (en) | 2010-05-24 | 2011-12-01 | Amprius, Inc. | Multidimensional electrochemically active structures for battery electrodes |
| US20110294005A1 (en) | 2010-05-28 | 2011-12-01 | Semiconductor Energy Laboratory Co., Ltd. | Power storage device, electrode, and electric device |
| US8852294B2 (en) | 2010-05-28 | 2014-10-07 | Semiconductor Energy Laboratory Co., Ltd. | Power storage device and method for manufacturing the same |
| KR101838627B1 (ko) | 2010-05-28 | 2018-03-14 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 축전 장치 및 그 제작 방법 |
| WO2011152189A1 (en) | 2010-06-01 | 2011-12-08 | Semiconductor Energy Laboratory Co., Ltd. | Energy storage device and manufacturing method thereof |
| WO2011152190A1 (en) | 2010-06-02 | 2011-12-08 | Semiconductor Energy Laboratory Co., Ltd. | Power storage device and method for manufacturing the same |
| WO2011155397A1 (en) | 2010-06-11 | 2011-12-15 | Semiconductor Energy Laboratory Co., Ltd. | Power storage device |
| WO2012002136A1 (en) | 2010-06-30 | 2012-01-05 | Semiconductor Energy Laboratory Co., Ltd. | Manufacturing method of power storage device |
| US8846530B2 (en) | 2010-06-30 | 2014-09-30 | Semiconductor Energy Laboratory Co., Ltd. | Method for forming semiconductor region and method for manufacturing power storage device |
| US20120003383A1 (en) | 2010-06-30 | 2012-01-05 | Semiconductor Energy Laboratory Co., Ltd. | Manufacturing method of energy storage device |
| US20120015247A1 (en) | 2010-07-14 | 2012-01-19 | Semiconductor Energy Laboratory Co., Ltd. | Silicon crystal body and power storage device using the silicon crystal body |
| DE112011102750T5 (de) | 2010-08-19 | 2013-07-04 | Semiconductor Energy Laboratory Co., Ltd. | Elektrisches Gerät |
| US8691441B2 (en) | 2010-09-07 | 2014-04-08 | Nanotek Instruments, Inc. | Graphene-enhanced cathode materials for lithium batteries |
| US9012080B2 (en) | 2010-09-21 | 2015-04-21 | Semiconductor Energy Laboratory Co., Ltd. | Needle-like microstructure and device having needle-like microstructure |
| KR102083375B1 (ko) | 2010-10-08 | 2020-03-03 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 에너지 저장 장치용 양극 활물질의 제조 방법 및 에너지 저장 장치 |
| US20120088151A1 (en) | 2010-10-08 | 2012-04-12 | Semiconductor Energy Laboratory Co., Ltd. | Positive-electrode active material and power storage device |
| WO2012054767A2 (en) | 2010-10-22 | 2012-04-26 | Amprius Inc. | Battery electrode structures for high mass loadings of high capacity active materials |
| CN102064322B (zh) * | 2010-11-25 | 2013-02-27 | 深圳清研紫光科技有限公司 | 锂离子电池负极用的硅/石墨烯层状复合材料的制备方法 |
| KR101899374B1 (ko) | 2010-11-26 | 2018-09-17 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 반도체막, 반도체막의 형성 방법 및 축전 장치 |
| US9543577B2 (en) | 2010-12-16 | 2017-01-10 | Semiconductor Energy Laboratory Co., Ltd. | Active material, electrode including the active material and manufacturing method thereof, and secondary battery |
| WO2012132307A1 (en) | 2011-03-25 | 2012-10-04 | Semiconductor Energy Laboratory Co., Ltd. | Lithium-ion secondary battery |
| TWI643814B (zh) | 2011-06-03 | 2018-12-11 | 半導體能源研究所股份有限公司 | 單層和多層石墨烯,彼之製法,含彼之物件,以及含彼之電器裝置 |
| KR102650871B1 (ko) | 2011-06-03 | 2024-03-26 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 전극을 제조하기 위한 방법 |
| KR101978726B1 (ko) | 2011-06-03 | 2019-05-15 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 축전 장치 및 그 제작 방법 |
| KR20130007429A (ko) | 2011-06-24 | 2013-01-18 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 그래핀, 축전 장치 및 전기 기기 |
| US9218916B2 (en) | 2011-06-24 | 2015-12-22 | Semiconductor Energy Laboratory Co., Ltd. | Graphene, power storage device, and electric device |
| US20120328956A1 (en) | 2011-06-24 | 2012-12-27 | Semiconductor Energy Laboratory Co., Ltd. | Multilayer graphene and power storage device |
| WO2013006583A2 (en) | 2011-07-01 | 2013-01-10 | Amprius, Inc. | Template electrode structures with enhanced adhesion characteristics |
| US8814956B2 (en) | 2011-07-14 | 2014-08-26 | Semiconductor Energy Laboratory Co., Ltd. | Power storage device, electrode, and manufacturing method thereof |
| WO2013015229A1 (en) | 2011-07-22 | 2013-01-31 | Semiconductor Energy Laboratory Co., Ltd. | Graphite oxide, graphene oxide or graphene, electric device using the same and method of manufacturing the same, and electrodialysis apparatus |
| US8663841B2 (en) * | 2011-09-16 | 2014-03-04 | Semiconductor Energy Laboratory Co., Ltd. | Power storage device |
| JP6045260B2 (ja) * | 2011-09-16 | 2016-12-14 | 株式会社半導体エネルギー研究所 | 蓄電装置 |
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| JP6250765B2 (ja) | 2017-12-20 |
| US10050273B2 (en) | 2018-08-14 |
| JP2015213085A (ja) | 2015-11-26 |
| CN102956888B (zh) | 2016-12-21 |
| US20140170500A1 (en) | 2014-06-19 |
| JP2017004982A (ja) | 2017-01-05 |
| CN102956888A (zh) | 2013-03-06 |
| US20130043057A1 (en) | 2013-02-21 |
| JP2013062237A (ja) | 2013-04-04 |
| JP6001731B2 (ja) | 2016-10-05 |
| CN106848195B (zh) | 2020-04-28 |
| CN106848195A (zh) | 2017-06-13 |
| US8685569B2 (en) | 2014-04-01 |
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