JP6004939B2 - ハロゲン化オレフィン発泡剤を含むフォーム及び発泡性組成物 - Google Patents
ハロゲン化オレフィン発泡剤を含むフォーム及び発泡性組成物 Download PDFInfo
- Publication number
- JP6004939B2 JP6004939B2 JP2012524735A JP2012524735A JP6004939B2 JP 6004939 B2 JP6004939 B2 JP 6004939B2 JP 2012524735 A JP2012524735 A JP 2012524735A JP 2012524735 A JP2012524735 A JP 2012524735A JP 6004939 B2 JP6004939 B2 JP 6004939B2
- Authority
- JP
- Japan
- Prior art keywords
- blowing agent
- polyol
- amine
- foam
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1808—Catalysts containing secondary or tertiary amines or salts thereof having alkylene polyamine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1816—Catalysts containing secondary or tertiary amines or salts thereof having carbocyclic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2101/00—Manufacture of cellular products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2115/00—Oligomerisation
- C08G2115/02—Oligomerisation to isocyanurate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
- C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US23283609P | 2009-08-11 | 2009-08-11 | |
| US61/232,836 | 2009-08-11 | ||
| US12/847,381 US9695267B2 (en) | 2009-08-11 | 2010-07-30 | Foams and foamable compositions containing halogenated olefin blowing agents |
| US12/847,381 | 2010-07-30 | ||
| PCT/US2010/044064 WO2011019528A2 (en) | 2009-08-11 | 2010-08-02 | Foams and foamable compositions containing halogenated olefin blowing agents |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014130250A Division JP2014205845A (ja) | 2009-08-11 | 2014-06-25 | ハロゲン化オレフィン発泡剤を含むフォーム及び発泡性組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2013501844A JP2013501844A (ja) | 2013-01-17 |
| JP6004939B2 true JP6004939B2 (ja) | 2016-10-12 |
Family
ID=43586743
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012524735A Expired - Fee Related JP6004939B2 (ja) | 2009-08-11 | 2010-08-02 | ハロゲン化オレフィン発泡剤を含むフォーム及び発泡性組成物 |
| JP2014130250A Ceased JP2014205845A (ja) | 2009-08-11 | 2014-06-25 | ハロゲン化オレフィン発泡剤を含むフォーム及び発泡性組成物 |
| JP2016196404A Withdrawn JP2017039942A (ja) | 2009-08-11 | 2016-10-04 | ハロゲン化オレフィン発泡剤を含むフォーム及び発泡性組成物 |
| JP2019072070A Pending JP2019131822A (ja) | 2009-08-11 | 2019-04-04 | ハロゲン化オレフィン発泡剤を含むフォーム及び発泡性組成物 |
Family Applications After (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014130250A Ceased JP2014205845A (ja) | 2009-08-11 | 2014-06-25 | ハロゲン化オレフィン発泡剤を含むフォーム及び発泡性組成物 |
| JP2016196404A Withdrawn JP2017039942A (ja) | 2009-08-11 | 2016-10-04 | ハロゲン化オレフィン発泡剤を含むフォーム及び発泡性組成物 |
| JP2019072070A Pending JP2019131822A (ja) | 2009-08-11 | 2019-04-04 | ハロゲン化オレフィン発泡剤を含むフォーム及び発泡性組成物 |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US9695267B2 (enExample) |
| EP (1) | EP2464684B1 (enExample) |
| JP (4) | JP6004939B2 (enExample) |
| CN (2) | CN107022103B (enExample) |
| BR (1) | BR112012003038A2 (enExample) |
| CA (1) | CA2770673A1 (enExample) |
| ES (1) | ES2795021T3 (enExample) |
| IN (1) | IN2012DN01280A (enExample) |
| MX (1) | MX2012001820A (enExample) |
| PL (1) | PL2464684T3 (enExample) |
| WO (1) | WO2011019528A2 (enExample) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2773366C (en) * | 2009-09-09 | 2018-03-06 | Arkema Inc. | Improved polyurethane foaming processes and foam properties using halogenated olefin blowing agent |
| US20120046372A1 (en) * | 2010-08-18 | 2012-02-23 | Honeywell International Inc. | Blowing agents, foamable compositions and foams |
| MX350753B (es) * | 2011-02-21 | 2017-09-18 | Honeywell Int Inc | Premezclas de espumas de poliuretano que contienen agentes de soplado olefinicos halogenados y espumas fabricadas a partir de estas. |
| US9556303B2 (en) * | 2011-02-21 | 2017-01-31 | Honeywell International Inc. | Catalysts for polyurethane foam polyol premixes containing halogenated olefin blowing agents |
| US20120313035A1 (en) * | 2011-06-08 | 2012-12-13 | Honeywell International Inc. | Polyurethane foam premixes containing halogenated olefin blowing agents and foams made from same |
| US20140171527A1 (en) * | 2011-02-21 | 2014-06-19 | Honeywell International Inc. | Polyurethane foam premixes containing halogenated olefin blowing agents and foams made from same |
| CN106046411B (zh) * | 2011-04-15 | 2019-02-26 | 阿科玛股份有限公司 | 包含卤代烯烃发泡剂的聚氨酯多元醇共混物的改善的稳定性 |
| CN103547552B (zh) * | 2011-05-19 | 2017-02-08 | 阿科玛股份有限公司 | 氯三氟丙烯的不可燃氯组合物 |
| ES2529170T1 (es) * | 2011-07-28 | 2015-02-17 | Honeywell International Inc. | Espumas y artículos resistentes a la llama obtenidos de espumas que contienen 1-cloro-3,3,3-trifluoropropeno (1233zd) |
| AU2012292108B2 (en) * | 2011-08-01 | 2015-11-26 | Basf Se | HFO-/water-blown rigid-foam systems |
| EP2788415A4 (en) * | 2011-12-09 | 2015-08-12 | Honeywell Int Inc | FOAM AND ITEMS MANUFACTURED FROM IT WITH HCFO OR HFO BLADDER |
| CN103509168B (zh) * | 2012-06-15 | 2018-04-27 | 科思创聚合物(中国)有限公司 | 微孔聚氨酯的组合物、制备方法及其应用 |
| WO2014015315A1 (en) * | 2012-07-19 | 2014-01-23 | Honeywell International Inc. | Blowing agents for extruded polystyrene foam and extruded polystyrene foam and methods of foaming |
| US9522973B2 (en) * | 2012-10-02 | 2016-12-20 | Covestro Llc | Polyurethane and polyisocyanurate rigid foams for roofing insulation |
| EP2964693A4 (en) * | 2013-03-06 | 2016-10-05 | Honeywell Int Inc | STABLE STABLE COMPOUNDS OF 1,1,1,4,4,4-HEXAFLUOR-2-BUTENE |
| BR112015023773A2 (pt) | 2013-03-15 | 2017-07-18 | Owens Corning Intellectual Capital Llc | suporte no processamento para uso na manufatura de espuma de poliestireno extrudado usando agentes de sopro potencial de aquecimento global |
| ES2869388T3 (es) * | 2014-03-20 | 2021-10-25 | Dow Global Technologies Llc | Mezclas formuladas reactivas con isocianato que incluyen agente de expansión a base de olefina |
| CN106661260A (zh) * | 2014-07-16 | 2017-05-10 | 欧文斯科宁知识产权资产有限公司 | 用于采用低全球变暖潜力的发泡剂制造泡沫体的非‑voc加工助剂 |
| JP6626674B2 (ja) | 2014-10-08 | 2019-12-25 | 積水ソフランウイズ株式会社 | 硬質ポリウレタンフォーム用ポリオール組成物、及び硬質ポリウレタンフォームの製造方法 |
| US10894857B2 (en) | 2015-03-13 | 2021-01-19 | Basf Se | Method of forming a polyurethane foam article |
| CN107922575B (zh) * | 2015-06-18 | 2021-08-17 | 巴斯夫欧洲公司 | 生产硬质聚氨酯泡沫的方法 |
| CN109153762B (zh) * | 2016-05-17 | 2021-04-02 | 东曹株式会社 | 用于制造卤代烯烃发泡聚氨酯的胺催化剂组合物 |
| JP6903427B2 (ja) * | 2016-12-20 | 2021-07-14 | 日清紡ケミカル株式会社 | 2液型プレミックス組成物、裏込め注入用硬質ポリイソシアヌレートフォーム及び裏込め注入工法 |
| WO2019055441A1 (en) * | 2017-09-14 | 2019-03-21 | Huntsman International Llc | POLYURETHANE ISOLATION FOAM COMPOSITION COMPRISING HALOGENATED OLEFINS AND TERTIARY AMINE COMPOUND |
| WO2019088035A1 (ja) * | 2017-11-01 | 2019-05-09 | Agc株式会社 | 硬質発泡合成樹脂の製造方法 |
| CN112368315B (zh) * | 2018-06-27 | 2023-07-04 | 巴斯夫欧洲公司 | 制备硬质聚氨酯泡沫的方法及其作为绝热材料的用途 |
| WO2020035382A1 (en) * | 2018-08-16 | 2020-02-20 | Basf Se | A polyisocyanate composition, a polyurethane foam obtained therefrom and use thereof |
| CN112566955B (zh) * | 2018-08-16 | 2023-04-14 | 巴斯夫欧洲公司 | 环境友好驱动的聚氨酯喷涂泡沫体系 |
| US11578165B2 (en) | 2019-01-21 | 2023-02-14 | Talaco Holdings, LLC | Methods of making foams exhibiting desired properties from aromatic polyester polyether polyols derived from polyethylene terephthalates and foams made therefrom |
| CN114829441A (zh) * | 2019-12-17 | 2022-07-29 | 巴斯夫欧洲公司 | 制备绝热制品的弹性的发泡方法 |
| JP7445290B2 (ja) * | 2020-01-31 | 2024-03-07 | アップコン株式会社 | ビバリウム装飾品 |
| KR102160534B1 (ko) * | 2020-02-07 | 2020-09-28 | 최규술 | 준불연 폴리우레탄 폼블록 및 그 제조방법 |
| PL4157910T3 (pl) * | 2020-06-02 | 2025-05-12 | Huntsman International Llc | Zastosowanie związków epoksydowych jako środków usuwających dwutlenek węgla w piankach zawierających pir w celu uzyskania lepszych właściwości izolacji cieplnej |
| US11655328B2 (en) | 2020-09-02 | 2023-05-23 | Ventrex Systems, LLC | Dimensionally stable closed-cell and rigid foams produced with methylal blowing agent |
| JP7568523B2 (ja) * | 2021-01-20 | 2024-10-16 | 株式会社ジェイエスピー | ポリスチレン系樹脂押出発泡板の製造方法 |
| US11753516B2 (en) | 2021-10-08 | 2023-09-12 | Covestro Llc | HFO-containing compositions and methods of producing foams |
| JP2025502041A (ja) * | 2022-01-13 | 2025-01-24 | ハネウェル・インターナショナル・インコーポレーテッド | 改善された特性を有する低密度熱硬化性発泡体 |
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| US3277138A (en) * | 1966-10-04 | Method for the chlorination of aromatic isocyanates | ||
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| BE536296A (enExample) | 1954-03-22 | |||
| IT535373A (enExample) | 1954-06-10 | |||
| US2846458A (en) | 1956-05-23 | 1958-08-05 | Dow Corning | Organosiloxane ethers |
| US3454606A (en) * | 1963-11-14 | 1969-07-08 | Union Carbide Corp | Isocyanatophenylsulfonyl isocyanates |
| US3124605A (en) * | 1963-12-05 | 1964-03-10 | Biuret polyisocyanates | |
| DE1202785B (de) * | 1964-07-21 | 1965-10-14 | Scholven Chemie Ag | Verfahren zur Herstellung von 1-Isocyanato-3-(isocyanatomethyl)-3, 5, 5-trimethylcyclohexan |
| US3394164A (en) * | 1965-10-24 | 1968-07-23 | Upjohn Co | Stabilized methylenebis-(phenyl isocyanate) compositions |
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| US4868224A (en) * | 1988-10-21 | 1989-09-19 | Mobay Corporation | Process for the production of molded products using internal mold release agents |
| US5300531A (en) * | 1992-12-30 | 1994-04-05 | The Dow Chemical Company | Plastic skin cladded polyurethanes having improved surface appearance |
| US5308881A (en) * | 1993-10-25 | 1994-05-03 | The Celotex Corporation | Surfactant for polyisocyanurate foams made with alternative blowing agents |
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| KR100188298B1 (ko) * | 1995-01-30 | 1999-06-01 | 모리시따요오이찌 | 단열발포체 및 그 제조방법 |
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| JP3804289B2 (ja) * | 1998-09-22 | 2006-08-02 | ダイキン工業株式会社 | 1,1,1,3,3−ペンタフルオロプロパン及び/又は1−クロロ−3,3,3−トリフルオロプロペンの製造方法 |
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| US7279451B2 (en) * | 2002-10-25 | 2007-10-09 | Honeywell International Inc. | Compositions containing fluorine substituted olefins |
| US6844475B1 (en) * | 2003-08-08 | 2005-01-18 | Honeywell International Business Machines | Low temperature production of 1-chloro-3,3,3-trifluoropropene (HCFC-1233zd) |
| US9499729B2 (en) * | 2006-06-26 | 2016-11-22 | Honeywell International Inc. | Compositions and methods containing fluorine substituted olefins |
| CN1976885B (zh) * | 2004-04-29 | 2010-05-26 | 霍尼韦尔国际公司 | 1,3,3,3-四氟丙烯和2,3,3,3-四氟丙烯的合成方法 |
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| CN101356217A (zh) * | 2005-11-01 | 2009-01-28 | 纳幕尔杜邦公司 | 用于形成泡沫的包含不饱和氟碳化合物的发泡剂 |
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| EP2129709B2 (en) * | 2007-03-29 | 2021-05-12 | Arkema Inc. | Process for preparing thermosetting foams |
| CN104962070B (zh) * | 2007-03-29 | 2018-06-01 | 阿科玛股份有限公司 | 氢氯氟烯烃以及氢氟烯烃的发泡剂组合物 |
| US9550854B2 (en) * | 2007-10-12 | 2017-01-24 | Honeywell International Inc. | Amine catalysts for polyurethane foams |
| US9453115B2 (en) * | 2007-10-12 | 2016-09-27 | Honeywell International Inc. | Stabilization of polyurethane foam polyol premixes containing halogenated olefin blowing agents |
| US20090099273A1 (en) * | 2007-10-12 | 2009-04-16 | Williams David J | Non-silicone surfactants for polyurethane or polyisocyanurate foam containing halogenated olefins as blowing agents |
| US20090124719A1 (en) * | 2007-11-08 | 2009-05-14 | E. I. Dupont De Nemours And Company | Polyurethane foams from polytrimethylene ether glycol |
| DE102009028061A1 (de) * | 2009-07-29 | 2011-02-10 | Evonik Goldschmidt Gmbh | Verfahren zur Herstellung von Polyurethanschaum |
-
2010
- 2010-07-30 US US12/847,381 patent/US9695267B2/en active Active
- 2010-08-02 PL PL10808524T patent/PL2464684T3/pl unknown
- 2010-08-02 ES ES10808524T patent/ES2795021T3/es active Active
- 2010-08-02 CN CN201610882776.XA patent/CN107022103B/zh active Active
- 2010-08-02 IN IN1280DEN2012 patent/IN2012DN01280A/en unknown
- 2010-08-02 BR BR112012003038A patent/BR112012003038A2/pt not_active Application Discontinuation
- 2010-08-02 WO PCT/US2010/044064 patent/WO2011019528A2/en not_active Ceased
- 2010-08-02 MX MX2012001820A patent/MX2012001820A/es unknown
- 2010-08-02 CN CN201080045617.5A patent/CN102575045B/zh active Active
- 2010-08-02 CA CA2770673A patent/CA2770673A1/en not_active Abandoned
- 2010-08-02 JP JP2012524735A patent/JP6004939B2/ja not_active Expired - Fee Related
- 2010-08-02 EP EP10808524.2A patent/EP2464684B1/en active Active
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Also Published As
| Publication number | Publication date |
|---|---|
| US20110039964A1 (en) | 2011-02-17 |
| US20180016379A1 (en) | 2018-01-18 |
| US9695267B2 (en) | 2017-07-04 |
| EP2464684B1 (en) | 2020-04-22 |
| CN107022103B (zh) | 2020-11-27 |
| CN107022103A (zh) | 2017-08-08 |
| PL2464684T3 (pl) | 2020-09-07 |
| CN102575045A (zh) | 2012-07-11 |
| MX2012001820A (es) | 2012-06-01 |
| JP2019131822A (ja) | 2019-08-08 |
| CN102575045B (zh) | 2016-11-09 |
| WO2011019528A2 (en) | 2011-02-17 |
| JP2017039942A (ja) | 2017-02-23 |
| BR112012003038A2 (pt) | 2016-04-19 |
| EP2464684A4 (en) | 2014-05-14 |
| ES2795021T3 (es) | 2020-11-20 |
| EP2464684A2 (en) | 2012-06-20 |
| JP2014205845A (ja) | 2014-10-30 |
| IN2012DN01280A (enExample) | 2015-05-15 |
| JP2013501844A (ja) | 2013-01-17 |
| CA2770673A1 (en) | 2011-02-17 |
| WO2011019528A3 (en) | 2011-06-09 |
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