IN2012DN01280A - - Google Patents
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- Publication number
- IN2012DN01280A IN2012DN01280A IN1280DEN2012A IN2012DN01280A IN 2012DN01280 A IN2012DN01280 A IN 2012DN01280A IN 1280DEN2012 A IN1280DEN2012 A IN 1280DEN2012A IN 2012DN01280 A IN2012DN01280 A IN 2012DN01280A
- Authority
- IN
- India
- Prior art keywords
- foams
- methods
- surfactant
- long
- preparation
- Prior art date
Links
- 239000006260 foam Substances 0.000 abstract 7
- 238000000034 method Methods 0.000 abstract 4
- 230000007774 longterm Effects 0.000 abstract 3
- 239000004094 surface-active agent Substances 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000000354 decomposition reaction Methods 0.000 abstract 2
- 229920000582 polyisocyanurate Polymers 0.000 abstract 2
- 239000011495 polyisocyanurate Substances 0.000 abstract 2
- 229920005862 polyol Polymers 0.000 abstract 2
- 150000003077 polyols Chemical class 0.000 abstract 2
- 229920002635 polyurethane Polymers 0.000 abstract 2
- 239000004814 polyurethane Substances 0.000 abstract 2
- 238000002360 preparation method Methods 0.000 abstract 2
- 239000004604 Blowing Agent Substances 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 230000001939 inductive effect Effects 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920001296 polysiloxane Polymers 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1808—Catalysts containing secondary or tertiary amines or salts thereof having alkylene polyamine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1816—Catalysts containing secondary or tertiary amines or salts thereof having carbocyclic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2101/00—Manufacture of cellular products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2115/00—Oligomerisation
- C08G2115/02—Oligomerisation to isocyanurate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
- C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US23283609P | 2009-08-11 | 2009-08-11 | |
| US12/847,381 US9695267B2 (en) | 2009-08-11 | 2010-07-30 | Foams and foamable compositions containing halogenated olefin blowing agents |
| PCT/US2010/044064 WO2011019528A2 (en) | 2009-08-11 | 2010-08-02 | Foams and foamable compositions containing halogenated olefin blowing agents |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| IN2012DN01280A true IN2012DN01280A (enExample) | 2015-05-15 |
Family
ID=43586743
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IN1280DEN2012 IN2012DN01280A (enExample) | 2009-08-11 | 2010-08-02 |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US9695267B2 (enExample) |
| EP (1) | EP2464684B1 (enExample) |
| JP (4) | JP6004939B2 (enExample) |
| CN (2) | CN107022103B (enExample) |
| BR (1) | BR112012003038A2 (enExample) |
| CA (1) | CA2770673A1 (enExample) |
| ES (1) | ES2795021T3 (enExample) |
| IN (1) | IN2012DN01280A (enExample) |
| MX (1) | MX2012001820A (enExample) |
| PL (1) | PL2464684T3 (enExample) |
| WO (1) | WO2011019528A2 (enExample) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112012005374A2 (pt) * | 2009-09-09 | 2016-03-29 | Arkema Inc | processos de melhoramento de espuma de poliuretano e propriedades da espuma utilizando agentes de insuflação de olefinas halogenadas |
| US20120046372A1 (en) * | 2010-08-18 | 2012-02-23 | Honeywell International Inc. | Blowing agents, foamable compositions and foams |
| US9556303B2 (en) * | 2011-02-21 | 2017-01-31 | Honeywell International Inc. | Catalysts for polyurethane foam polyol premixes containing halogenated olefin blowing agents |
| US20140171527A1 (en) * | 2011-02-21 | 2014-06-19 | Honeywell International Inc. | Polyurethane foam premixes containing halogenated olefin blowing agents and foams made from same |
| JP2014506947A (ja) * | 2011-02-21 | 2014-03-20 | ハネウェル・インターナショナル・インコーポレーテッド | ハロゲン化オレフィン発泡剤を含むポリウレタンフォームプレミックス及びそれから製造されるフォーム |
| US20120313035A1 (en) * | 2011-06-08 | 2012-12-13 | Honeywell International Inc. | Polyurethane foam premixes containing halogenated olefin blowing agents and foams made from same |
| MX348762B (es) * | 2011-04-15 | 2017-06-28 | Arkema Inc | Estabilidad mejorada de mezclas de polioles poliuretánicos que contienen un agente de soplado olefínico halogenado. |
| KR101951618B1 (ko) * | 2011-05-19 | 2019-02-25 | 알케마 인코포레이티드 | 클로로-트리플루오로프로펜의 불연성 조성물 |
| EP2737006A4 (en) * | 2011-07-28 | 2015-11-04 | Honeywell Int Inc | FOAMS AND FLAME-RESISTANT ARTICLES OF FOAMING WITH 1-CHLORO-3,3,3-TRIFLUORPROPENE (1233ZD) |
| DK2739676T4 (da) * | 2011-08-01 | 2024-11-11 | Basf Se | Hfo/vanddrevne systemer af hårdt skum |
| JP2015500362A (ja) * | 2011-12-09 | 2015-01-05 | ハネウェル・インターナショナル・インコーポレーテッド | 発泡体、およびｈｃｆｏまたはｈｆｏ発泡剤を含む発泡体から作られる物品 |
| CN103509168B (zh) * | 2012-06-15 | 2018-04-27 | 科思创聚合物（中国）有限公司 | 微孔聚氨酯的组合物、制备方法及其应用 |
| PT3312222T (pt) * | 2012-07-19 | 2023-03-20 | Honeywell Int Inc | Agentes de expansão para espuma de poliestireno extrudido e espuma de poliestireno extrudido |
| US9522973B2 (en) * | 2012-10-02 | 2016-12-20 | Covestro Llc | Polyurethane and polyisocyanurate rigid foams for roofing insulation |
| JP2016516106A (ja) * | 2013-03-06 | 2016-06-02 | ハネウェル・インターナショナル・インコーポレーテッド | １，１，１，４，４，４−ヘキサフルオロ−２−ブテンを含む保存安定性発泡性組成物 |
| DK3495407T3 (da) | 2013-03-15 | 2024-03-04 | Owens Corning Intellectual Capital Llc | Forarbejdsningshjælpemidler til anvendelse til fremstilling af ekstruderede polystyrenskum ved anvendelse af opskumningsmidler med lavt potentiale for global opvarmning |
| EP3119824B1 (en) | 2014-03-20 | 2021-04-28 | Dow Global Technologies LLC | Formulated isocyanate-reactive blends including olefin based blowing agent |
| FI3169723T3 (fi) * | 2014-07-16 | 2024-05-06 | Owens Corning Intellectual Capital Llc | VOC-vapaita valmistuksen apuaineita käytettäväksi vaahtojen valmistamisessa käyttämällä alhaisen lämmityspotentiaalin omaavia paisuteaineita |
| JP6626674B2 (ja) | 2014-10-08 | 2019-12-25 | 積水ソフランウイズ株式会社 | 硬質ポリウレタンフォーム用ポリオール組成物、及び硬質ポリウレタンフォームの製造方法 |
| CA2979277C (en) | 2015-03-13 | 2023-09-12 | Basf Se | Method of forming a polyurethane foam article |
| WO2016202912A1 (de) * | 2015-06-18 | 2016-12-22 | Basf Se | Verfahren zur herstellung von polyurethan-hartschaumstoffen |
| WO2017199931A1 (ja) * | 2016-05-17 | 2017-11-23 | 東ソー株式会社 | ハロアルケン発泡ポリウレタン製造用のアミン触媒組成物 |
| JP6903427B2 (ja) * | 2016-12-20 | 2021-07-14 | 日清紡ケミカル株式会社 | ２液型プレミックス組成物、裏込め注入用硬質ポリイソシアヌレートフォーム及び裏込め注入工法 |
| US11649315B2 (en) * | 2017-09-14 | 2023-05-16 | Huntsman International Llc | Polyurethane insulation foam composition comprising halogenated olefins and a tertiary amine compound |
| CN111263780B (zh) * | 2017-11-01 | 2022-04-05 | Ａｇｃ株式会社 | 硬质发泡合成树脂的制造方法 |
| CN112368315B (zh) * | 2018-06-27 | 2023-07-04 | 巴斯夫欧洲公司 | 制备硬质聚氨酯泡沫的方法及其作为绝热材料的用途 |
| CA3109540A1 (en) * | 2018-08-16 | 2020-02-20 | Basf Se | Environmentally friendly driven polyurethane spray foam systems |
| CN112638977B (zh) * | 2018-08-16 | 2024-03-19 | 巴斯夫欧洲公司 | 多异氰酸酯组合物、由其获得的聚氨酯泡沫及其用途 |
| US11578165B2 (en) | 2019-01-21 | 2023-02-14 | Talaco Holdings, LLC | Methods of making foams exhibiting desired properties from aromatic polyester polyether polyols derived from polyethylene terephthalates and foams made therefrom |
| BR112022009472A2 (pt) * | 2019-12-17 | 2022-07-26 | Basf Se | Processo descontínuo para a produção de uma série de pelo menos dois artigos contendo espuma de poliuretano termicamente isolante, processos implementado por computador, unidade de produção e meio legível por computador |
| JP7445290B2 (ja) * | 2020-01-31 | 2024-03-07 | アップコン株式会社 | ビバリウム装飾品 |
| KR102160534B1 (ko) * | 2020-02-07 | 2020-09-28 | 최규술 | 준불연 폴리우레탄 폼블록 및 그 제조방법 |
| CA3184900A1 (en) * | 2020-06-02 | 2021-12-09 | Huntsman International Llc | Use of epoxy compounds as carbon dioxide scavengers in pir comprising foams for superior thermal insulation properties |
| US11655328B2 (en) | 2020-09-02 | 2023-05-23 | Ventrex Systems, LLC | Dimensionally stable closed-cell and rigid foams produced with methylal blowing agent |
| JP7568523B2 (ja) * | 2021-01-20 | 2024-10-16 | 株式会社ジェイエスピー | ポリスチレン系樹脂押出発泡板の製造方法 |
| US11753516B2 (en) | 2021-10-08 | 2023-09-12 | Covestro Llc | HFO-containing compositions and methods of producing foams |
| JP2025502041A (ja) * | 2022-01-13 | 2025-01-24 | ハネウェル・インターナショナル・インコーポレーテッド | 改善された特性を有する低密度熱硬化性発泡体 |
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|---|---|---|---|---|
| US3277138A (en) | 1966-10-04 | Method for the chlorination of aromatic isocyanates | ||
| US3001973A (en) | 1953-05-23 | 1961-09-26 | Bayer Ag | Production of cross-linked plastics |
| BE536296A (enExample) | 1954-03-22 | |||
| IT535373A (enExample) | 1954-06-10 | |||
| US2846458A (en) | 1956-05-23 | 1958-08-05 | Dow Corning | Organosiloxane ethers |
| US3454606A (en) | 1963-11-14 | 1969-07-08 | Union Carbide Corp | Isocyanatophenylsulfonyl isocyanates |
| US3124605A (en) | 1963-12-05 | 1964-03-10 | Biuret polyisocyanates | |
| DE1202785B (de) | 1964-07-21 | 1965-10-14 | Scholven Chemie Ag | Verfahren zur Herstellung von 1-Isocyanato-3-(isocyanatomethyl)-3, 5, 5-trimethylcyclohexan |
| US3394164A (en) | 1965-10-24 | 1968-07-23 | Upjohn Co | Stabilized methylenebis-(phenyl isocyanate) compositions |
| US3492330A (en) | 1965-12-09 | 1970-01-27 | Union Carbide Corp | Norbornane diisocyanates |
| US4147847A (en) | 1973-11-14 | 1979-04-03 | Dow Corning Corporation | Method of preparing flexible flame retardant polyether based one-shot polyurethane foams and compositions therefore |
| US4426461A (en) | 1982-07-14 | 1984-01-17 | Thermocell Development, Ltd. | Modified polyisocyanurate foam and method of preparation |
| US4868224A (en) | 1988-10-21 | 1989-09-19 | Mobay Corporation | Process for the production of molded products using internal mold release agents |
| US5300531A (en) | 1992-12-30 | 1994-04-05 | The Dow Chemical Company | Plastic skin cladded polyurethanes having improved surface appearance |
| US5308881A (en) * | 1993-10-25 | 1994-05-03 | The Celotex Corporation | Surfactant for polyisocyanurate foams made with alternative blowing agents |
| US5762822A (en) | 1994-12-29 | 1998-06-09 | Basf Corporation | Dimensionally stable closed cell rigid polyisocyanate based foam prepared from a froth foaming mixture |
| KR100188298B1 (ko) * | 1995-01-30 | 1999-06-01 | 모리시따요오이찌 | 단열발포체 및 그 제조방법 |
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| JP3804289B2 (ja) | 1998-09-22 | 2006-08-02 | ダイキン工業株式会社 | １，１，１，３，３−ペンタフルオロプロパン及び／又は１−クロロ−３，３，３−トリフルオロプロペンの製造方法 |
| US6395796B1 (en) | 1999-01-05 | 2002-05-28 | Crompton Corporation | Process for preparing polyurethane foam |
| DE10025932A1 (de) * | 2000-05-26 | 2001-12-06 | Freudenberg Carl Fa | Polyurethan-Formkörper |
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| KR20070053708A (ko) * | 2004-08-04 | 2007-05-25 | 포움 서플라이즈 인코포레이션 | 폴리우레탄 폼에서의 반응도 변동 및 촉매 분해 |
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| TWI626262B (zh) | 2005-06-24 | 2018-06-11 | 哈尼威爾國際公司 | 發泡體及其產品 |
| TWI645031B (zh) * | 2005-06-24 | 2018-12-21 | 哈尼威爾國際公司 | 含有經氟取代之烯烴之組合物及其用途 |
| MY145459A (en) | 2005-11-01 | 2012-02-15 | Du Pont | Solvent compositions comprising unsaturated fluorinated hydrocarbons |
| EP1943299A2 (en) * | 2005-11-01 | 2008-07-16 | E.I.Du pont de nemours and company | Methods for making foams using blowing agents comprising unsaturated fluorocarbons |
| CN101646722A (zh) * | 2007-03-29 | 2010-02-10 | 阿科玛股份有限公司 | 氢氯氟烯烃的发泡剂组合物 |
| WO2008121783A1 (en) * | 2007-03-29 | 2008-10-09 | Arkema Inc. | Blowing agent composition of hydrochlorofluoroolefin |
| US9550854B2 (en) * | 2007-10-12 | 2017-01-24 | Honeywell International Inc. | Amine catalysts for polyurethane foams |
| US9453115B2 (en) * | 2007-10-12 | 2016-09-27 | Honeywell International Inc. | Stabilization of polyurethane foam polyol premixes containing halogenated olefin blowing agents |
| US20090099273A1 (en) * | 2007-10-12 | 2009-04-16 | Williams David J | Non-silicone surfactants for polyurethane or polyisocyanurate foam containing halogenated olefins as blowing agents |
| US20090124719A1 (en) | 2007-11-08 | 2009-05-14 | E. I. Dupont De Nemours And Company | Polyurethane foams from polytrimethylene ether glycol |
| DE102009028061A1 (de) * | 2009-07-29 | 2011-02-10 | Evonik Goldschmidt Gmbh | Verfahren zur Herstellung von Polyurethanschaum |
-
2010
- 2010-07-30 US US12/847,381 patent/US9695267B2/en active Active
- 2010-08-02 MX MX2012001820A patent/MX2012001820A/es unknown
- 2010-08-02 ES ES10808524T patent/ES2795021T3/es active Active
- 2010-08-02 CN CN201610882776.XA patent/CN107022103B/zh active Active
- 2010-08-02 WO PCT/US2010/044064 patent/WO2011019528A2/en not_active Ceased
- 2010-08-02 CN CN201080045617.5A patent/CN102575045B/zh active Active
- 2010-08-02 PL PL10808524T patent/PL2464684T3/pl unknown
- 2010-08-02 CA CA2770673A patent/CA2770673A1/en not_active Abandoned
- 2010-08-02 EP EP10808524.2A patent/EP2464684B1/en active Active
- 2010-08-02 BR BR112012003038A patent/BR112012003038A2/pt not_active Application Discontinuation
- 2010-08-02 IN IN1280DEN2012 patent/IN2012DN01280A/en unknown
- 2010-08-02 JP JP2012524735A patent/JP6004939B2/ja not_active Expired - Fee Related
-
2014
- 2014-06-25 JP JP2014130250A patent/JP2014205845A/ja not_active Ceased
-
2016
- 2016-10-04 JP JP2016196404A patent/JP2017039942A/ja not_active Withdrawn
-
2017
- 2017-06-30 US US15/639,455 patent/US20180016379A1/en not_active Abandoned
-
2019
- 2019-04-04 JP JP2019072070A patent/JP2019131822A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JP2014205845A (ja) | 2014-10-30 |
| EP2464684A2 (en) | 2012-06-20 |
| CN107022103B (zh) | 2020-11-27 |
| CN102575045B (zh) | 2016-11-09 |
| US9695267B2 (en) | 2017-07-04 |
| PL2464684T3 (pl) | 2020-09-07 |
| WO2011019528A2 (en) | 2011-02-17 |
| US20180016379A1 (en) | 2018-01-18 |
| JP6004939B2 (ja) | 2016-10-12 |
| MX2012001820A (es) | 2012-06-01 |
| EP2464684B1 (en) | 2020-04-22 |
| CN107022103A (zh) | 2017-08-08 |
| CA2770673A1 (en) | 2011-02-17 |
| JP2019131822A (ja) | 2019-08-08 |
| JP2013501844A (ja) | 2013-01-17 |
| JP2017039942A (ja) | 2017-02-23 |
| ES2795021T3 (es) | 2020-11-20 |
| EP2464684A4 (en) | 2014-05-14 |
| CN102575045A (zh) | 2012-07-11 |
| BR112012003038A2 (pt) | 2016-04-19 |
| US20110039964A1 (en) | 2011-02-17 |
| WO2011019528A3 (en) | 2011-06-09 |
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