JP2011505471A5 - - Google Patents
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- Publication number
- JP2011505471A5 JP2011505471A5 JP2010536136A JP2010536136A JP2011505471A5 JP 2011505471 A5 JP2011505471 A5 JP 2011505471A5 JP 2010536136 A JP2010536136 A JP 2010536136A JP 2010536136 A JP2010536136 A JP 2010536136A JP 2011505471 A5 JP2011505471 A5 JP 2011505471A5
- Authority
- JP
- Japan
- Prior art keywords
- foam
- forming composition
- containing compound
- active hydrogen
- effective amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 claims description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 239000006260 foam Substances 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- 239000011495 polyisocyanurate Substances 0.000 claims description 5
- 229920000582 polyisocyanurate Polymers 0.000 claims description 5
- 229920002635 polyurethane Polymers 0.000 claims description 5
- 239000004814 polyurethane Substances 0.000 claims description 5
- 229920001228 polyisocyanate Polymers 0.000 claims description 4
- 239000005056 polyisocyanate Substances 0.000 claims description 4
- 229920005862 polyol Polymers 0.000 claims description 4
- 150000003077 polyols Chemical class 0.000 claims description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- NLOLSXYRJFEOTA-UPHRSURJSA-N (z)-1,1,1,4,4,4-hexafluorobut-2-ene Chemical compound FC(F)(F)\C=C/C(F)(F)F NLOLSXYRJFEOTA-UPHRSURJSA-N 0.000 claims description 2
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US99092907P | 2007-11-29 | 2007-11-29 | |
| PCT/US2008/084727 WO2009073487A1 (en) | 2007-11-29 | 2008-11-25 | Compositions and use of cis-1,1,1,4,4,4-hexafluoro-2-butene foam-forming composition in the preparation of polyisocyanate-based foams |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014236317A Division JP6255332B2 (ja) | 2007-11-29 | 2014-11-21 | 組成物、およびポリイソシアネートベースの発泡体の製造におけるシス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテン発泡体形成組成物の使用 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2011505471A JP2011505471A (ja) | 2011-02-24 |
| JP2011505471A5 true JP2011505471A5 (enExample) | 2012-01-12 |
Family
ID=40568342
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010536136A Pending JP2011505471A (ja) | 2007-11-29 | 2008-11-25 | 組成物、およびポリイソシアネートベースの発泡体の製造におけるシス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテン発泡体形成組成物の使用 |
| JP2014236317A Active JP6255332B2 (ja) | 2007-11-29 | 2014-11-21 | 組成物、およびポリイソシアネートベースの発泡体の製造におけるシス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテン発泡体形成組成物の使用 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014236317A Active JP6255332B2 (ja) | 2007-11-29 | 2014-11-21 | 組成物、およびポリイソシアネートベースの発泡体の製造におけるシス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテン発泡体形成組成物の使用 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US8299137B2 (enExample) |
| EP (1) | EP2215154B1 (enExample) |
| JP (2) | JP2011505471A (enExample) |
| KR (1) | KR20100105636A (enExample) |
| CN (1) | CN101878253B (enExample) |
| AR (1) | AR071444A1 (enExample) |
| AU (1) | AU2008331468B2 (enExample) |
| BR (1) | BRPI0819059B1 (enExample) |
| CA (1) | CA2705271C (enExample) |
| ES (1) | ES2661884T3 (enExample) |
| MX (1) | MX2010005757A (enExample) |
| WO (1) | WO2009073487A1 (enExample) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070098646A1 (en) | 2005-11-01 | 2007-05-03 | Nappa Mario J | Aerosol propellants comprising unsaturated fluorocarbons |
| MY145459A (en) | 2005-11-01 | 2012-02-15 | Du Pont | Solvent compositions comprising unsaturated fluorinated hydrocarbons |
| JP5624882B2 (ja) | 2007-04-27 | 2014-11-12 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | Z−1,1,1,4,4,4−ヘキサフルオロ−2−ブテンの共沸および共沸様組成物 |
| BR122018074416B1 (pt) | 2007-06-12 | 2019-03-19 | E. I. Du Pont De Nemours And Company | Composição e processo para produzir refrigeração |
| EP2170980B1 (en) * | 2007-07-20 | 2013-08-21 | E. I. du Pont de Nemours and Company | Compositions and use of cis-1,1,1,4,4,4-hexafluoro-2-butene foam-forming composition in the preparation of polyisocyanate-based foams |
| KR101527244B1 (ko) | 2007-09-06 | 2015-06-08 | 이 아이 듀폰 디 네모아 앤드 캄파니 | E-1,1,1,4,4,5,5,5-옥타플루오로-2-펜텐의 공비 및 공비-유사 조성물 |
| WO2009073487A1 (en) | 2007-11-29 | 2009-06-11 | E. I. Du Pont De Nemours And Company | Compositions and use of cis-1,1,1,4,4,4-hexafluoro-2-butene foam-forming composition in the preparation of polyisocyanate-based foams |
| ES2553269T3 (es) | 2007-12-19 | 2015-12-07 | E. I. Du Pont De Nemours And Company | Composiciones formadoras de espuma que contienen una mezcla azeotrópica o similar a un azeótropo que contiene cis-1,1,1,4,4,4-hexafluoro-2-buteno y ciclopentano y sus usos en la preparación de espumas basadas en poliisocianato |
| EP2393862B1 (en) * | 2009-02-03 | 2018-08-15 | The Chemours Company FC, LLC | Foam-forming compositions containing mixtures of cis-1,1,1,4,4,4-hexafluoro-2-butene and 1,1,1,3,3-pentafluoropropane and their uses in the preparation of polyisocyanate-based foams |
| US8481605B2 (en) * | 2009-05-21 | 2013-07-09 | Huntsman International Llc | Rigid polyurethane foam and system and method for making the same |
| DE102009028061A1 (de) | 2009-07-29 | 2011-02-10 | Evonik Goldschmidt Gmbh | Verfahren zur Herstellung von Polyurethanschaum |
| US8821749B2 (en) | 2010-04-26 | 2014-09-02 | E I Du Pont De Nemours And Company | Azeotrope-like compositions of E-1,1,1,4,4,4-hexafluoro-2-butene and 1-chloro-3,3,3-trifluoropropene |
| US20110269860A1 (en) * | 2010-04-28 | 2011-11-03 | E.I. Du Pont De Nemours And Company | Foam expansion agent compositions containing hydrohaloolefin butene and water and their uses in the preparation of polyurethane and polyisocyanurate polymer foams |
| US20120046372A1 (en) * | 2010-08-18 | 2012-02-23 | Honeywell International Inc. | Blowing agents, foamable compositions and foams |
| US9051442B2 (en) * | 2011-02-21 | 2015-06-09 | Honeywell International Inc. | Polyurethane foam premixes containing halogenated olefin blowing agents and foams made from same |
| US9556303B2 (en) * | 2011-02-21 | 2017-01-31 | Honeywell International Inc. | Catalysts for polyurethane foam polyol premixes containing halogenated olefin blowing agents |
| US20140171527A1 (en) * | 2011-02-21 | 2014-06-19 | Honeywell International Inc. | Polyurethane foam premixes containing halogenated olefin blowing agents and foams made from same |
| JP2014506947A (ja) * | 2011-02-21 | 2014-03-20 | ハネウェル・インターナショナル・インコーポレーテッド | ハロゲン化オレフィン発泡剤を含むポリウレタンフォームプレミックス及びそれから製造されるフォーム |
| US20120313035A1 (en) * | 2011-06-08 | 2012-12-13 | Honeywell International Inc. | Polyurethane foam premixes containing halogenated olefin blowing agents and foams made from same |
| WO2012162684A2 (en) | 2011-05-25 | 2012-11-29 | E. I. Du Pont De Nemours And Company | Closed-cell tannin-based foams without formaldehyde |
| US9260579B2 (en) | 2011-05-25 | 2016-02-16 | E I Du Pont De Nemours And Company | Mixed tannin-phenolic foams |
| EP2714786B1 (en) * | 2011-05-25 | 2015-10-28 | E. I. du Pont de Nemours and Company | Phenolic foams with blowing agent 1, 1, 1, 4, 4, 4-hexafluoro - 2 - butene |
| DK2739676T4 (da) * | 2011-08-01 | 2024-11-11 | Basf Se | Hfo/vanddrevne systemer af hårdt skum |
| US9896558B2 (en) | 2011-08-01 | 2018-02-20 | Basf Se | HFO/water-blown rigid foam systems |
| US9481790B2 (en) * | 2012-10-08 | 2016-11-01 | Icp Adhesives And Sealants, Inc. | Marine foam |
| JP2016516106A (ja) * | 2013-03-06 | 2016-06-02 | ハネウェル・インターナショナル・インコーポレーテッド | 1,1,1,4,4,4−ヘキサフルオロ−2−ブテンを含む保存安定性発泡性組成物 |
| US20150210818A1 (en) * | 2014-01-27 | 2015-07-30 | E I Du Pont De Nemours And Company | Cryogenic insulation foam |
| WO2016201293A1 (en) * | 2015-06-12 | 2016-12-15 | Icp Adhesives And Sealants, Inc. | Marine foam |
| CN109104864B (zh) * | 2016-03-29 | 2021-04-23 | 陶氏环球技术有限责任公司 | 半刚性聚氨酯泡沫及其制造方法 |
| US10131758B2 (en) * | 2016-07-25 | 2018-11-20 | Accella Polyurethane Systems, Llc | Polyurethane foam-forming compositions, methods of making low density foams using such compositions, and foams formed therefrom |
| CA3051166A1 (en) * | 2017-01-31 | 2018-08-09 | Basf Se | Hfo containing pu formulation |
| CA2963751A1 (en) * | 2017-02-13 | 2018-08-13 | Honeywell International Inc. | Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene |
| CN108727551A (zh) * | 2017-04-19 | 2018-11-02 | 科思创德国股份有限公司 | 一种硬质聚氨酯泡沫及其制备方法与应用 |
| CN108359121B (zh) | 2017-12-14 | 2019-03-15 | 浙江衢化氟化学有限公司 | 一种共沸和类共沸组合物 |
| WO2021076435A1 (en) | 2019-10-15 | 2021-04-22 | Icp Construction, Inc. | Sprayable marine foam |
| US11732081B2 (en) | 2021-06-08 | 2023-08-22 | Covestro Llc | HCFO-containing isocyanate-reactive compositions, related foam-forming compositions and flame retardant PUR-PIR foams |
| US12098545B2 (en) | 2021-06-29 | 2024-09-24 | Covestro Llc | HFO-containing isocyanate-reactive compositions, related polyurethane foam-forming compositions, and spray-applied polyurethane foams |
| US11905707B2 (en) | 2021-06-29 | 2024-02-20 | Covestro Llc | Foam wall structures and methods for their manufacture |
| US11767394B2 (en) | 2021-12-09 | 2023-09-26 | Covestro Llc | HCFO-containing polyurethane foam-forming compositions, related foams and methods for their production |
| US11767407B1 (en) | 2022-04-21 | 2023-09-26 | Covestro Llc | HCFO-containing polyurethane foam-forming compositions, related foams and methods for their production |
| US11827735B1 (en) | 2022-09-01 | 2023-11-28 | Covestro Llc | HFO-containing isocyanate-reactive compositions, related foam-forming compositions and flame retardant PUR-PIR foams |
Family Cites Families (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL121693C (enExample) * | 1959-05-22 | |||
| DE1122697B (de) | 1960-05-06 | 1962-01-25 | Bayer Ag | Verfahren zur Herstellung von Schaumstoffen auf Isocyanatbasis |
| US3884828A (en) * | 1970-10-15 | 1975-05-20 | Dow Corning | Propellants and refrigerants based on trifluoropropene |
| US3723318A (en) * | 1971-11-26 | 1973-03-27 | Dow Corning | Propellants and refrigerants based on trifluoropropene |
| FR2280360A1 (fr) | 1974-08-02 | 1976-02-27 | Sogeras | Composition cosmetologique oxygenante |
| NL179914C (nl) * | 1975-11-04 | 1986-12-01 | Dow Chemical Co | Werkwijze voor het door extrusie vervaardigen van een schuimvoorwerp uit een thermoplastische alkenyl-aromatische kunsthars. |
| US4394491A (en) * | 1980-10-08 | 1983-07-19 | The Dow Chemical Company | Addition polymerizable adduct of a polymeric monoahl and an unsaturated isocyanate |
| FR2523956A1 (fr) * | 1982-03-26 | 1983-09-30 | Ugine Kuhlmann | Bis-(perfluoroalkyl)-1,2-ethenes ramifies, leur preparation et leur utilisation comme transporteurs d'oxygene convertisseur electromecanique |
| GB8516826D0 (en) * | 1985-07-03 | 1985-08-07 | Dow Chemical Nederland | Precursor compositions of nitrogen-containing polyols |
| US4704410A (en) * | 1986-06-30 | 1987-11-03 | The Dow Chemical Company | Molded rigid polyurethane foams prepared from aminoalkylpiperazine-initiated polyols |
| DE3818692A1 (de) * | 1988-06-01 | 1989-12-07 | Bayer Ag | Verwendung von 1,1,1,4,4,4-hexafluorbutan als treib- und daemmgas fuer die herstellung von kunststoff-schaumstoffen |
| EP0350316B1 (en) | 1988-07-08 | 1997-05-02 | Rhone-Poulenc Chimie | Cleaning and drying of electronic assemblies |
| US4945119A (en) | 1989-05-10 | 1990-07-31 | The Dow Chemical Company | Foaming system for rigid urethane and isocyanurate foams |
| US5037572A (en) * | 1990-10-03 | 1991-08-06 | E. I. Du Pont De Nemours And Company | Ternary azeotropic compositions of n-perfluorobutylethylene and trans-1,2-dichloroethylene with methanol or ethanol or isopropanol |
| US5204159A (en) * | 1991-03-29 | 1993-04-20 | Tan Domingo K L | Deformable, slip-free, anti-skid pads for snow and ice |
| US5164419A (en) * | 1991-05-20 | 1992-11-17 | E. I. Du Pont De Nemours And Company | Blowing agent and process for preparing polyurethane foam |
| JPH0585966A (ja) | 1991-09-25 | 1993-04-06 | Daikin Ind Ltd | 冷 媒 |
| JPH05179043A (ja) | 1991-11-18 | 1993-07-20 | Daikin Ind Ltd | フルオロブテンからなる発泡剤およびプラスチック発泡体の製造方法 |
| US5332761A (en) * | 1992-06-09 | 1994-07-26 | The Dow Chemical Company | Flexible bimodal foam structures |
| DE4305163A1 (de) * | 1993-02-19 | 1994-08-25 | Bayer Ag | Verfahren zur Herstellung von Hexafluorbuten |
| US5494601A (en) | 1993-04-01 | 1996-02-27 | Minnesota Mining And Manufacturing Company | Azeotropic compositions |
| US5578137A (en) * | 1993-08-31 | 1996-11-26 | E. I. Du Pont De Nemours And Company | Azeotropic or azeotrope-like compositions including 1,1,1,2,3,4,4,5,5,5-decafluoropentane |
| US5539008A (en) * | 1993-12-29 | 1996-07-23 | Minnesota Mining And Manufacturing Company | Foamable composition containing unsaturated perfluorochemical blowing agent |
| US5977271A (en) | 1994-09-02 | 1999-11-02 | The Dow Chemical Company | Process for preparing thermoset interpolymers and foams |
| FR2731436B1 (fr) | 1995-03-09 | 1997-04-30 | Atochem Elf Sa | Utilisation d'hydrofluoroalcenes comme agents de nettoyage, et compositions utilisables a cet effet |
| US5900185A (en) * | 1996-09-27 | 1999-05-04 | University Of New Mexico | Tropodegradable bromine-containing halocarbon additives to decrease flammability of refrigerants, foam blowing agents, solvents, aerosol propellants, and sterilants |
| US6071580A (en) * | 1997-06-11 | 2000-06-06 | The Dow Chemical Company | Absorbent, extruded thermoplastic foams |
| SK170899A3 (en) * | 1997-06-13 | 2000-06-12 | Huntsman Ici Chemicals Llc The | Isocyanate compositions for blown polyurethane foams |
| US5908822A (en) * | 1997-10-28 | 1999-06-01 | E. I. Du Pont De Nemours And Company | Compositions and processes for drying substrates |
| US5977217A (en) * | 1998-04-07 | 1999-11-02 | Kirker Enterprises, Inc. | Quick drying nail enamel composition |
| US6610250B1 (en) * | 1999-08-23 | 2003-08-26 | 3M Innovative Properties Company | Apparatus using halogenated organic fluids for heat transfer in low temperature processes requiring sterilization and methods therefor |
| ATE307161T1 (de) * | 2000-10-24 | 2005-11-15 | Dow Global Technologies Inc | Herstellungverfahren für multimodalen thermoplastischen polymerschaum |
| DE10055084A1 (de) * | 2000-11-07 | 2002-06-13 | Basf Ag | Flexible, offenzellige, mikrozelluläre Polymerschäume |
| CN106634852A (zh) * | 2002-10-25 | 2017-05-10 | 霍尼韦尔国际公司 | 含有氟取代烯烃的组合物 |
| US7279451B2 (en) | 2002-10-25 | 2007-10-09 | Honeywell International Inc. | Compositions containing fluorine substituted olefins |
| US20050148677A1 (en) * | 2003-12-30 | 2005-07-07 | Elsken Kevin J. | Low K-factor rigid foam systems |
| US6969701B2 (en) * | 2004-04-16 | 2005-11-29 | Honeywell International Inc. | Azeotrope-like compositions of tetrafluoropropene and trifluoroiodomethane |
| CA2563544A1 (en) | 2004-04-19 | 2005-10-27 | Centre National De La Recherche Scientifique (C.N.R.S.) | Lung surfactant supplements |
| CN103462894A (zh) | 2005-03-16 | 2013-12-25 | 霍尼韦尔国际公司 | 药物递送制剂、装置和方法 |
| US20070077488A1 (en) * | 2005-10-04 | 2007-04-05 | Kaimin Chen | Power capability of a cathode |
| MY145459A (en) * | 2005-11-01 | 2012-02-15 | Du Pont | Solvent compositions comprising unsaturated fluorinated hydrocarbons |
| US20070098646A1 (en) | 2005-11-01 | 2007-05-03 | Nappa Mario J | Aerosol propellants comprising unsaturated fluorocarbons |
| EP1943299A2 (en) * | 2005-11-01 | 2008-07-16 | E.I.Du pont de nemours and company | Methods for making foams using blowing agents comprising unsaturated fluorocarbons |
| US7708903B2 (en) * | 2005-11-01 | 2010-05-04 | E.I. Du Pont De Nemours And Company | Compositions comprising fluoroolefins and uses thereof |
| US20070100010A1 (en) | 2005-11-01 | 2007-05-03 | Creazzo Joseph A | Blowing agents for forming foam comprising unsaturated fluorocarbons |
| US8287752B2 (en) * | 2005-11-01 | 2012-10-16 | E I Du Pont De Nemours And Company | Fire extinguishing and fire suppression compositions comprising unsaturated fluorocarbons |
| KR20080114757A (ko) * | 2006-02-28 | 2008-12-31 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 세정 분야를 위한 플루오르화 화합물을 포함하는 공비 조성물 |
| RU2006139128A (ru) | 2006-11-07 | 2008-05-20 | Е.И.Дюпон де Немур энд Компани (US) | Способ получения фторированных олефинов |
| US8618339B2 (en) * | 2007-04-26 | 2013-12-31 | E I Du Pont De Nemours And Company | High selectivity process to make dihydrofluoroalkenes |
| JP5624882B2 (ja) | 2007-04-27 | 2014-11-12 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | Z−1,1,1,4,4,4−ヘキサフルオロ−2−ブテンの共沸および共沸様組成物 |
| BR122018074416B1 (pt) | 2007-06-12 | 2019-03-19 | E. I. Du Pont De Nemours And Company | Composição e processo para produzir refrigeração |
| EP2170980B1 (en) | 2007-07-20 | 2013-08-21 | E. I. du Pont de Nemours and Company | Compositions and use of cis-1,1,1,4,4,4-hexafluoro-2-butene foam-forming composition in the preparation of polyisocyanate-based foams |
| KR20100063027A (ko) | 2007-07-20 | 2010-06-10 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 조성물 및 폴리아이소시아네이트계 폼의 제조에서 트랜스-1,1,1,4,4,4-헥사플루오로-2-부텐 폼-형성 조성물의 용도 |
| KR101527244B1 (ko) | 2007-09-06 | 2015-06-08 | 이 아이 듀폰 디 네모아 앤드 캄파니 | E-1,1,1,4,4,5,5,5-옥타플루오로-2-펜텐의 공비 및 공비-유사 조성물 |
| WO2009073487A1 (en) | 2007-11-29 | 2009-06-11 | E. I. Du Pont De Nemours And Company | Compositions and use of cis-1,1,1,4,4,4-hexafluoro-2-butene foam-forming composition in the preparation of polyisocyanate-based foams |
| ES2553269T3 (es) | 2007-12-19 | 2015-12-07 | E. I. Du Pont De Nemours And Company | Composiciones formadoras de espuma que contienen una mezcla azeotrópica o similar a un azeótropo que contiene cis-1,1,1,4,4,4-hexafluoro-2-buteno y ciclopentano y sus usos en la preparación de espumas basadas en poliisocianato |
-
2008
- 2008-11-25 WO PCT/US2008/084727 patent/WO2009073487A1/en not_active Ceased
- 2008-11-25 AU AU2008331468A patent/AU2008331468B2/en active Active
- 2008-11-25 CN CN2008801183125A patent/CN101878253B/zh active Active
- 2008-11-25 US US12/743,255 patent/US8299137B2/en active Active
- 2008-11-25 EP EP08855818.4A patent/EP2215154B1/en active Active
- 2008-11-25 BR BRPI0819059-3A patent/BRPI0819059B1/pt not_active IP Right Cessation
- 2008-11-25 KR KR1020107014298A patent/KR20100105636A/ko not_active Ceased
- 2008-11-25 CA CA2705271A patent/CA2705271C/en active Active
- 2008-11-25 MX MX2010005757A patent/MX2010005757A/es active IP Right Grant
- 2008-11-25 ES ES08855818.4T patent/ES2661884T3/es active Active
- 2008-11-25 JP JP2010536136A patent/JP2011505471A/ja active Pending
- 2008-11-28 AR ARP080105221A patent/AR071444A1/es not_active Application Discontinuation
-
2014
- 2014-11-21 JP JP2014236317A patent/JP6255332B2/ja active Active
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