JP6255332B2 - 組成物、およびポリイソシアネートベースの発泡体の製造におけるシス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテン発泡体形成組成物の使用 - Google Patents
組成物、およびポリイソシアネートベースの発泡体の製造におけるシス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテン発泡体形成組成物の使用 Download PDFInfo
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- JP6255332B2 JP6255332B2 JP2014236317A JP2014236317A JP6255332B2 JP 6255332 B2 JP6255332 B2 JP 6255332B2 JP 2014236317 A JP2014236317 A JP 2014236317A JP 2014236317 A JP2014236317 A JP 2014236317A JP 6255332 B2 JP6255332 B2 JP 6255332B2
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- 239000000203 mixture Substances 0.000 title claims description 48
- 239000006260 foam Substances 0.000 title claims description 39
- 229920001228 polyisocyanate Polymers 0.000 title claims description 37
- 239000005056 polyisocyanate Substances 0.000 title claims description 37
- NLOLSXYRJFEOTA-UPHRSURJSA-N (z)-1,1,1,4,4,4-hexafluorobut-2-ene Chemical compound FC(F)(F)\C=C/C(F)(F)F NLOLSXYRJFEOTA-UPHRSURJSA-N 0.000 title claims description 26
- 238000004519 manufacturing process Methods 0.000 title description 11
- 229920005862 polyol Polymers 0.000 claims description 66
- 150000003077 polyols Chemical class 0.000 claims description 66
- 150000001875 compounds Chemical class 0.000 claims description 35
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 28
- 229910052739 hydrogen Inorganic materials 0.000 claims description 28
- 239000001257 hydrogen Substances 0.000 claims description 28
- 229920002635 polyurethane Polymers 0.000 claims description 19
- 239000004814 polyurethane Substances 0.000 claims description 19
- 229920000642 polymer Polymers 0.000 claims description 16
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 15
- 229920000570 polyether Polymers 0.000 claims description 15
- 239000011495 polyisocyanurate Substances 0.000 claims description 14
- 229920000582 polyisocyanurate Polymers 0.000 claims description 14
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 230000000694 effects Effects 0.000 claims description 2
- 239000004604 Blowing Agent Substances 0.000 description 13
- 229920005830 Polyurethane Foam Polymers 0.000 description 13
- 239000011496 polyurethane foam Substances 0.000 description 13
- -1 polyethylene terephthalate Polymers 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 11
- 238000009413 insulation Methods 0.000 description 10
- 239000004094 surface-active agent Substances 0.000 description 9
- 238000005187 foaming Methods 0.000 description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 8
- 229920005906 polyester polyol Polymers 0.000 description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 4
- 230000006378 damage Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000010792 warming Methods 0.000 description 3
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 description 2
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- 229920013701 VORANOL™ Polymers 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical group FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 description 2
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920006389 polyphenyl polymer Polymers 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000005720 sucrose Substances 0.000 description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
- NLOLSXYRJFEOTA-OWOJBTEDSA-N (e)-1,1,1,4,4,4-hexafluorobut-2-ene Chemical compound FC(F)(F)\C=C\C(F)(F)F NLOLSXYRJFEOTA-OWOJBTEDSA-N 0.000 description 1
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
- CDMDQYCEEKCBGR-UHFFFAOYSA-N 1,4-diisocyanatocyclohexane Chemical compound O=C=NC1CCC(N=C=O)CC1 CDMDQYCEEKCBGR-UHFFFAOYSA-N 0.000 description 1
- SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 description 1
- VZDIRINETBAVAV-UHFFFAOYSA-N 2,4-diisocyanato-1-methylcyclohexane Chemical compound CC1CCC(N=C=O)CC1N=C=O VZDIRINETBAVAV-UHFFFAOYSA-N 0.000 description 1
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000005529 alkyleneoxy group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 150000003961 organosilicon compounds Chemical class 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000013500 performance material Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 238000005829 trimerization reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/487—Polyethers containing cyclic groups
- C08G18/4883—Polyethers containing cyclic groups containing cyclic groups having at least one oxygen atom in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C19/00—Acyclic saturated compounds containing halogen atoms
- C07C19/08—Acyclic saturated compounds containing halogen atoms containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Description
ブテンの使用を開示している。
られる。従来装置とは、フルオロトリクロロメタン(CCl3F、CFC−11)などの、従来のイソシアネートベースの発泡体発泡剤が用いられる、イソシアネートベースの発泡体の製造に従来用いられた装置、設備、および手順を意味する。かかる従来装置は、H.Bodenらによって、G.Oerter編Polyurethane Handbook,Hanser Publishers,New York,1985年の第4章;SPI 34th Annual Technical/Marketing Conference,1992年10月21日−10月24日,New Orleans,LouisianaからのPolyurethanes92に発表された“Fine Celled CFC−Free Rigid Foam−New Machinery with Low Boiling Blowing Agents”という表題のH.Grunbauerらによる論文;およびProceedings of the SPI/ISOPAからPolyurethanes World Congress 1991,1991年9月24−26日,Acropolis,Nice,Franceで発表された“Soluble or Insoluble Alternative Blowing Agents? Processing Technologies for Both Alternatives,Presented by the Equipment Manufacturer”という表題のM.Tavernaらによる論文に議論されている。これらの開示は、参照により本明細書によって援用される。
9641−1206)から購入したスクロース/グリセリン開始ポリエーテルポリオール(Voranol 360)である。ポリオールBは25℃で3,600センチポアズの粘度を有する。ポリオールB中のヒドロキシル基の含有率は、ポリオールBの1グラム当たり360mgKOHに等しい。
相溶性試験
ポリオール−発泡剤(シス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテン)相溶性試験は、Aerotech Labによって製造された3オンスのエアゾール密封ガラス容器中で行った。50グラムのポリオールをガラス容器に装填した。ガラス容器を次に大気圧下に室温で密封した。シス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテンをポリオールへ加える前に、50グラムのポリオールを含有するガラス容器を25±2℃で15分間保ち、無色透明な外観について目視により確認した。シス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテンを次に、2.5(ポリオールの重量を基準として5重量%)グラム増分でガラス容器に注入した。各注入後に、容器を15分間振盪して完全な混合を確実にした。容器を次に25±2℃で15分間保ち、分離および/またはエマルジョンについて目視により検査した。安定なエマルジョンまたは分離を観察するか、または合計30グラム(ポリオールの重量を基準として60重量%)のシス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテンを加えるまで上記の工程を繰り返した。
。ポリオールAはシス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテンと低い相溶性を有し、合計12.5グラム(ポリオールの重量を基準として25重量%)のシス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテンを注入した後に安定なエマルジョンを示した。ポリオールCはまた、シス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテンと低い相溶性を有し、合計2.5グラム(ポリオールの重量を基準として5重量%)のシス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテンを注入した後に発泡剤から相分離を示した。
高度に相溶性のポリエーテルポリオール(ポリオールB)から製造されるポリウレタンフォーム
ポリオールB、界面活性剤、触媒、水およびシス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテンを手動によりプレミックスし、次にポリイソシアネートと混合した。生じた混合物を8インチ×8インチ×2.5インチの紙箱に注ぎ込み、ポリウレタンフォームを形成した。発泡体の調合物および特性を下の表1および2に示す。
低い相溶性のポリエーテルポリオール(ポリオールC)を含有する発泡体形成組成物から製造されるポリウレタンフォーム
ポリオールCを使用して実施例2に記載されるのと同じ方法でポリウレタンフォームを製造した。ポリウレタン調合物および特性を下の表3および4に示す。シス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテンと低い相溶性のポリオール(ポリオールC)とを含む発泡体形成組成物を使用することによって、発泡体のR値は、実施例2の6.9
から7.2に改善された。
高度に相溶性のポリオールBから製造されるポリウレタンフォームを改善するための発泡体形成組成物の使用
低い相溶性のポリエステルポリオール(ポリオールA)およびポリエーテルポリオール(ポリオールC)を、実施例2に記載されるような高度に相溶性のポリオールBを含有する調合物に添加した。実施例2の発泡体形成組成物への低い相溶性のポリオールAおよびCの組み入れは、R値を実施例2の6.9から7.4に改善した。ポリウレタン調合物および特性を下の表5および6に示す。
低い相溶性のポリオールAおよびCを含有する発泡体形成組成物を使用して製造されるポリウレタンフォーム
低い相溶性のポリエーテルポリオール(ポリオールC)および低い相溶性のポリエステルポリオール(ポリオールA)を使用して実施例2に記載されるのと同じ方法でポリウレタンフォームを製造した。ポリウレタン調合物および特性を下の表7および8に示す。発泡体形成組成物は、高度に相溶性のポリエーテルポリオール(ポリオールB)を使用して製造された発泡体のR値6.9と比較して、7.8のポリウレタンフォームを生成した。
1.シス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテンと2個以上の活性水素を有する低い相溶性の活性水素含有化合物とを含む発泡体形成組成物であって、2個以上の活性水素を有する前記低い相溶性の活性水素含有化合物がポリエーテルポリオールである組成物。
2.2個以上の活性水素を有する高度に相溶性の活性水素含有化合物をさらに含む上記1に記載の発泡体形成組成物。
3.高度に相溶性の活性水素含有化合物がポリオールである上記2に記載の発泡体形成組成物。
4.高度に相溶性の活性水素含有化合物がポリエーテルポリオールである上記3に記載の発泡体形成組成物。
5.有効量の上記1に記載の発泡体形成組成物と、好適なポリイソシアネートとの反応から製造された独立気泡ポリウレタンまたはポリイソシアヌレートポリマー発泡体。
6.ポリマー発泡体が6.5フィート2−時間−°F/BTU−インチより大きい初期R
値を有する上記5に記載の独立気泡ポリウレタンまたはポリイソシアヌレートポリマー発泡体。
7.有効量の上記1に記載の発泡体形成組成物と、好適なポリイソシアネートとを反応させる工程を含む独立気泡ポリウレタンまたはポリイソシアヌレートポリマー発泡体の製造方法。
Claims (6)
- シス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテン、2個以上の活性水素を有する低い相溶性の活性水素含有化合物および2個以上の活性水素を有する高度に相溶性の活性水素含有化合物を含む発泡体形成組成物であって、2個以上の活性水素を有する前記低い相溶性の活性水素含有化合物がポリエーテルポリオールであり、「低い相溶性」は、大気圧下の室温で測定された場合にそれへのシス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテンの溶解度が25重量%を超えない活性水素含有化合物を意味し、「高度に相溶性」は、大気圧下の室温で測定された場合にそれへのシス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテンの溶解度が40重量%超である活性水素含有化合物を意味する、組成物。
- 高度に相溶性の活性水素含有化合物がポリオールである請求項1に記載の発泡体形成組成物。
- 高度に相溶性の活性水素含有化合物がポリエーテルポリオールである請求項2に記載の発泡体形成組成物。
- 有効量の請求項1に記載の発泡体形成組成物と、好適なポリイソシアネートとの反応から製造された独立気泡ポリウレタンまたはポリイソシアヌレートポリマー発泡体。
- ポリマー発泡体が6.5フィート2−時間−°F/BTU−インチより大きい初期R値を有する請求項4に記載の独立気泡ポリウレタンまたはポリイソシアヌレートポリマー発泡体。
- 有効量の請求項1に記載の発泡体形成組成物と、好適なポリイソシアネートとを反応させる工程を含む独立気泡ポリウレタンまたはポリイソシアヌレートポリマー発泡体の製造方法。
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EP2215154B1 (en) | 2017-12-20 |
EP2215154A1 (en) | 2010-08-11 |
CN101878253A (zh) | 2010-11-03 |
AU2008331468A1 (en) | 2009-06-11 |
US20100280141A1 (en) | 2010-11-04 |
AU2008331468B2 (en) | 2015-02-05 |
WO2009073487A1 (en) | 2009-06-11 |
CA2705271A1 (en) | 2009-06-11 |
JP2011505471A (ja) | 2011-02-24 |
AR071444A1 (es) | 2010-06-23 |
ES2661884T3 (es) | 2018-04-04 |
CN101878253B (zh) | 2013-05-29 |
MX2010005757A (es) | 2010-06-09 |
US8299137B2 (en) | 2012-10-30 |
BRPI0819059A2 (pt) | 2015-05-05 |
KR20100105636A (ko) | 2010-09-29 |
CA2705271C (en) | 2016-04-05 |
JP2015071780A (ja) | 2015-04-16 |
BRPI0819059B1 (pt) | 2019-05-21 |
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