JP5969387B2 - ヒドロシリル化触媒 - Google Patents

ヒドロシリル化触媒 Download PDF

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Publication number
JP5969387B2
JP5969387B2 JP2012519754A JP2012519754A JP5969387B2 JP 5969387 B2 JP5969387 B2 JP 5969387B2 JP 2012519754 A JP2012519754 A JP 2012519754A JP 2012519754 A JP2012519754 A JP 2012519754A JP 5969387 B2 JP5969387 B2 JP 5969387B2
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Japan
Prior art keywords
group
alkyl
unsaturated
complex
substituted
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Expired - Fee Related
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JP2012519754A
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Japanese (ja)
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JP2012532885A5 (cg-RX-API-DMAC7.html
JP2012532885A (ja
Inventor
デリス，ヨハネス，ジー，ピー
チリク，ポール，ジェイ
トンデロー，アーロン，エム
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Cornell University
Momentive Performance Materials Inc
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Cornell University
Momentive Performance Materials Inc
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/0825—Preparations of compounds not comprising Si-Si or Si-cyano linkages
    • C07F7/0827—Syntheses with formation of a Si-C bond
    • C07F7/0829—Hydrosilylation reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/06—Cobalt compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0834—Compounds having one or more O-Si linkage
    • C07F7/0838—Compounds with one or more Si-O-Si sequences
    • C07F7/0872—Preparation and treatment thereof
    • C07F7/0876—Reactions involving the formation of bonds to a Si atom of a Si-O-Si sequence other than a bond of the Si-O-Si linkage
    • C07F7/0878—Si-C bond
    • C07F7/0879—Hydrosilylation reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/12—Organo silicon halides
    • C07F7/16—Preparation thereof from silicon and halogenated hydrocarbons direct synthesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Silicon Polymers (AREA)
  • Pyridine Compounds (AREA)
JP2012519754A 2009-07-10 2010-07-09 ヒドロシリル化触媒 Expired - Fee Related JP5969387B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US22460909P 2009-07-10 2009-07-10
US61/224,609 2009-07-10
US12/832,533 US8415443B2 (en) 2009-07-10 2010-07-08 Hydrosilylation catalysts
US12/832,533 2010-07-08
PCT/US2010/041499 WO2011006049A1 (en) 2009-07-10 2010-07-09 Hydrosilylation catalysts

Publications (3)

Publication Number Publication Date
JP2012532885A JP2012532885A (ja) 2012-12-20
JP2012532885A5 JP2012532885A5 (cg-RX-API-DMAC7.html) 2016-06-02
JP5969387B2 true JP5969387B2 (ja) 2016-08-17

Family

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JP2012519754A Expired - Fee Related JP5969387B2 (ja) 2009-07-10 2010-07-09 ヒドロシリル化触媒

Country Status (8)

Country Link
US (1) US8415443B2 (cg-RX-API-DMAC7.html)
EP (1) EP2451818A1 (cg-RX-API-DMAC7.html)
JP (1) JP5969387B2 (cg-RX-API-DMAC7.html)
KR (1) KR101450080B1 (cg-RX-API-DMAC7.html)
CN (1) CN102471354B (cg-RX-API-DMAC7.html)
BR (1) BR112012000167A2 (cg-RX-API-DMAC7.html)
TW (1) TWI511785B (cg-RX-API-DMAC7.html)
WO (1) WO2011006049A1 (cg-RX-API-DMAC7.html)

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CN103339135B (zh) 2010-11-24 2016-09-14 莫门蒂夫性能材料股份有限公司 用作氢化硅烷化催化剂的金属络合物的原位活化
CN103347889A (zh) 2010-11-24 2013-10-09 莫门蒂夫性能材料股份有限公司 氢化硅烷化催化剂
KR101896423B1 (ko) * 2010-11-24 2018-10-04 모멘티브 퍼포먼스 머티리얼즈 인크. 폴리불포화 화합물의 금속-촉매 모노-하이드로실릴화
WO2013043846A1 (en) * 2011-09-20 2013-03-28 Dow Corning Corporation Metal containing hydrosilylation catalysts and compositions containing the catalysts
US9139699B2 (en) 2012-10-04 2015-09-22 Dow Corning Corporation Metal containing condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
US9782763B2 (en) 2011-12-14 2017-10-10 Momentive Performance Materials Inc. Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity
US9458185B2 (en) 2012-02-10 2016-10-04 The Regents Of The University Of California First row metal-based catalysts for hydosilylation
BR102013016146A2 (pt) * 2012-08-16 2016-09-13 Momentive Performance Mat Inc processo para produzir um produto sililado, por desidrogenação, composição, composto e processo para produzir um material reticulado
JP6125222B2 (ja) * 2012-08-16 2017-05-10 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド コバルト触媒を用いる脱水素シリル化および架橋
US9371340B2 (en) 2012-08-16 2016-06-21 Momentive Performance Materials Inc. Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts
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WO2014201082A1 (en) 2013-06-12 2014-12-18 Arizona Board Of Regents On Behalf Of Arizona State University First-row transition metal hydrogenation and hydrosilylation catalysts
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JP6308547B2 (ja) * 2014-02-20 2018-04-11 公立大学法人大阪市立大学 有機ケイ素化合物の製造方法
WO2015171881A1 (en) * 2014-05-08 2015-11-12 Momentive Performance Materials Inc. Dialkyl cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
JP6515930B2 (ja) 2014-08-12 2019-05-22 国立大学法人九州大学 ヒドロシリル化反応触媒
EP3195932B1 (en) 2014-08-12 2024-08-21 Kyushu University, National University Corporation Hydrosilylation reaction catalyst
JP6761997B2 (ja) 2014-08-19 2020-09-30 国立大学法人九州大学 ヒドロシリル化鉄触媒
JP6373125B2 (ja) * 2014-08-22 2018-08-15 国立大学法人山形大学 トランジスタ型重金属イオンセンサ
WO2016109534A1 (en) * 2014-12-30 2016-07-07 Momentive Performance Materials Inc. Siloxane coordination polymers
US20180200703A1 (en) 2015-07-14 2018-07-19 Kyushu University, National University Corporation Hydrosilylation reaction catalyst
CN108026126B (zh) 2015-07-24 2021-04-20 莫门蒂夫性能材料股份有限公司 使用吡啶二亚胺羧酸钴催化剂的脱氢硅烷化、氢化硅烷化和交联
JP6536262B2 (ja) * 2015-07-31 2019-07-03 株式会社豊田中央研究所 固体触媒
US11091573B2 (en) 2015-11-25 2021-08-17 General Cable Technologies Corporation Hydrosilylation crosslinking of polyolefin cable components
JP6620823B2 (ja) 2016-01-22 2019-12-18 信越化学工業株式会社 新規イソシアニド化合物及びヒドロシリル化反応触媒
JP6933835B2 (ja) * 2017-01-25 2021-09-08 公立大学法人大阪 鉄錯体触媒を用いたカルボニル化合物のヒドロシリル化反応によるアルコキシシランの製造方法
WO2018159595A1 (ja) 2017-02-28 2018-09-07 国立大学法人九州大学 ヒドロシリル化反応、水素化反応およびヒドロシラン還元反応用触媒
WO2019018357A1 (en) * 2017-07-17 2019-01-24 Dow Silicones Corporation CATALYST AND ASSOCIATED METHODS INVOLVING HYDROSILYLATION AND DEHYDROGENANT SILYLATION
JP2019064950A (ja) 2017-09-29 2019-04-25 国立大学法人九州大学 コバルト錯体、その製造方法およびヒドロシリル化反応用触媒
US11273432B2 (en) 2018-05-31 2022-03-15 Arizona Board Of Regents On Behalf Of Arizona State University Beta-diketiminate manganese catalysts for hydrosilylation, hydroboration, and dehydrogenative pnictogen-silicon and pnictogen-boron bond formation
JP2022500530A (ja) 2018-09-13 2022-01-04 モメンティブ パフォーマンス マテリアルズ ゲーエムベーハーMomentive Performance Materials GmbH 官能性ポリシロキサン
JP6806299B2 (ja) * 2019-02-15 2021-01-06 国立大学法人九州大学 ヒドロシリル化鉄触媒の調製方法
JP7351460B2 (ja) * 2019-06-19 2023-09-27 公立大学法人大阪 イミノビピリジンコバルト錯体、及びイミノビピリジンコバルト錯体を利用したヒドロシリル化反応による有機ケイ素化合物の製造方法
CN110465330B (zh) * 2019-08-09 2022-06-10 杭州师范大学 一种利用钴催化剂的硅氢加成反应的方法
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US20110009565A1 (en) 2011-01-13
CN102471354B (zh) 2015-09-30
KR20120023148A (ko) 2012-03-12
TWI511785B (zh) 2015-12-11
US8415443B2 (en) 2013-04-09
TW201111041A (en) 2011-04-01
JP2012532885A (ja) 2012-12-20
CN102471354A (zh) 2012-05-23
WO2011006049A1 (en) 2011-01-13
EP2451818A1 (en) 2012-05-16
KR101450080B1 (ko) 2014-10-13
BR112012000167A2 (pt) 2017-08-22

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