JP5687685B2 - エッチャント組成物および方法 - Google Patents
エッチャント組成物および方法 Download PDFInfo
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- JP5687685B2 JP5687685B2 JP2012503735A JP2012503735A JP5687685B2 JP 5687685 B2 JP5687685 B2 JP 5687685B2 JP 2012503735 A JP2012503735 A JP 2012503735A JP 2012503735 A JP2012503735 A JP 2012503735A JP 5687685 B2 JP5687685 B2 JP 5687685B2
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- 238000000034 method Methods 0.000 title claims description 43
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- 239000002184 metal Substances 0.000 claims description 52
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- 238000005530 etching Methods 0.000 claims description 49
- 150000007524 organic acids Chemical class 0.000 claims description 35
- 150000003839 salts Chemical class 0.000 claims description 32
- -1 alkali metal salts Chemical class 0.000 claims description 26
- 239000012425 OXONE® Substances 0.000 claims description 24
- HJKYXKSLRZKNSI-UHFFFAOYSA-I pentapotassium;hydrogen sulfate;oxido sulfate;sulfuric acid Chemical compound [K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.OS(=O)(=O)O[O-].OS(=O)(=O)O[O-] HJKYXKSLRZKNSI-UHFFFAOYSA-I 0.000 claims description 24
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 23
- 239000001301 oxygen Substances 0.000 claims description 22
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- 239000007800 oxidant agent Substances 0.000 claims description 21
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- 238000012546 transfer Methods 0.000 description 4
- SDGNNLQZAPXALR-UHFFFAOYSA-N 3-sulfophthalic acid Chemical compound OC(=O)C1=CC=CC(S(O)(=O)=O)=C1C(O)=O SDGNNLQZAPXALR-UHFFFAOYSA-N 0.000 description 3
- 229910002651 NO3 Inorganic materials 0.000 description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 235000015165 citric acid Nutrition 0.000 description 3
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- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 3
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- 235000019800 disodium phosphate Nutrition 0.000 description 3
- 238000000157 electrochemical-induced impedance spectroscopy Methods 0.000 description 3
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- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 2
- RBNPOMFGQQGHHO-UHFFFAOYSA-N -2,3-Dihydroxypropanoic acid Natural products OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 description 2
- WXHLLJAMBQLULT-UHFFFAOYSA-N 2-[[6-[4-(2-hydroxyethyl)piperazin-1-yl]-2-methylpyrimidin-4-yl]amino]-n-(2-methyl-6-sulfanylphenyl)-1,3-thiazole-5-carboxamide;hydrate Chemical compound O.C=1C(N2CCN(CCO)CC2)=NC(C)=NC=1NC(S1)=NC=C1C(=O)NC1=C(C)C=CC=C1S WXHLLJAMBQLULT-UHFFFAOYSA-N 0.000 description 2
- ZMPRRFPMMJQXPP-UHFFFAOYSA-N 2-sulfobenzoic acid Chemical compound OC(=O)C1=CC=CC=C1S(O)(=O)=O ZMPRRFPMMJQXPP-UHFFFAOYSA-N 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
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- ODBLHEXUDAPZAU-ZAFYKAAXSA-N D-threo-isocitric acid Chemical compound OC(=O)[C@H](O)[C@@H](C(O)=O)CC(O)=O ODBLHEXUDAPZAU-ZAFYKAAXSA-N 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- ODBLHEXUDAPZAU-FONMRSAGSA-N Isocitric acid Natural products OC(=O)[C@@H](O)[C@H](C(O)=O)CC(O)=O ODBLHEXUDAPZAU-FONMRSAGSA-N 0.000 description 2
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- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
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- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- OKBMCNHOEMXPTM-UHFFFAOYSA-M potassium peroxymonosulfate Chemical compound [K+].OOS([O-])(=O)=O OKBMCNHOEMXPTM-UHFFFAOYSA-M 0.000 description 1
- ZVJHJDDKYZXRJI-UHFFFAOYSA-N pyrroline Natural products C1CC=NC1 ZVJHJDDKYZXRJI-UHFFFAOYSA-N 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- HGKLFYLYWZXWPO-UHFFFAOYSA-N sulfo benzoate Chemical compound OS(=O)(=O)OC(=O)C1=CC=CC=C1 HGKLFYLYWZXWPO-UHFFFAOYSA-N 0.000 description 1
- WAGFXJQAIZNSEQ-UHFFFAOYSA-M tetraphenylphosphonium chloride Chemical compound [Cl-].C1=CC=CC=C1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 WAGFXJQAIZNSEQ-UHFFFAOYSA-M 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000004148 unit process Methods 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 235000012431 wafers Nutrition 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K13/00—Etching, surface-brightening or pickling compositions
- C09K13/04—Etching, surface-brightening or pickling compositions containing an inorganic acid
- C09K13/06—Etching, surface-brightening or pickling compositions containing an inorganic acid with organic material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F1/00—Etching metallic material by chemical means
- C23F1/02—Local etching
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F1/00—Etching metallic material by chemical means
- C23F1/10—Etching compositions
- C23F1/14—Aqueous compositions
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
- H01L21/321—After treatment
- H01L21/3213—Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer
- H01L21/32133—Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer by chemical means only
- H01L21/32134—Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer by chemical means only by liquid etching only
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/02—Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding
- H05K3/06—Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding the conductive material being removed chemically or electrolytically, e.g. by photo-etch process
- H05K3/067—Etchants
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/38—Improvement of the adhesion between the insulating substrate and the metal
- H05K3/388—Improvement of the adhesion between the insulating substrate and the metal by the use of a metallic or inorganic thin film adhesion layer
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Power Engineering (AREA)
- ing And Chemical Polishing (AREA)
- Weting (AREA)
- Manufacturing Of Printed Circuit Boards (AREA)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16626709P | 2009-04-03 | 2009-04-03 | |
| US16627309P | 2009-04-03 | 2009-04-03 | |
| US61/166,267 | 2009-04-03 | ||
| US61/166,273 | 2009-04-03 | ||
| US12/721,903 US20100252530A1 (en) | 2009-04-03 | 2010-03-11 | Etchant composition and method |
| US12/721,903 | 2010-03-11 | ||
| PCT/US2010/029741 WO2010115075A1 (en) | 2009-04-03 | 2010-04-02 | Etchant composition and method |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012522895A JP2012522895A (ja) | 2012-09-27 |
| JP2012522895A5 JP2012522895A5 (enExample) | 2013-05-02 |
| JP5687685B2 true JP5687685B2 (ja) | 2015-03-18 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012503735A Active JP5687685B2 (ja) | 2009-04-03 | 2010-04-02 | エッチャント組成物および方法 |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP5687685B2 (enExample) |
| CN (1) | CN102395708B (enExample) |
| TW (1) | TWI480360B (enExample) |
| WO (1) | WO2010115075A1 (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9644274B2 (en) | 2011-07-04 | 2017-05-09 | Mitsubishi Gas Chemical Company, Inc. | Etching solution for copper or a compound comprised mainly of copper |
| CN103764874B (zh) * | 2011-08-31 | 2016-07-27 | 东友精细化工有限公司 | 用于包括铜和钛的金属层的蚀刻液组合物 |
| JP5799791B2 (ja) * | 2011-12-16 | 2015-10-28 | 三菱瓦斯化学株式会社 | 銅及びモリブデンを含む多層膜用エッチング液 |
| JP6135999B2 (ja) * | 2012-04-10 | 2017-05-31 | 三菱瓦斯化学株式会社 | 銅およびモリブデンを含む多層膜のエッチングに使用される液体組成物、およびそれを用いたエッチング方法 |
| KR101394133B1 (ko) * | 2012-08-22 | 2014-05-15 | 주식회사 이엔에프테크놀로지 | 몰리브덴 합금막 및 인듐 산화막 식각액 조성물 |
| CN102923963A (zh) * | 2012-11-15 | 2013-02-13 | 杭州格林达化学有限公司 | 一种玻璃减薄刻蚀液补充液 |
| CN103924242B (zh) * | 2013-01-14 | 2016-05-11 | 易安爱富科技有限公司 | 铜/钼膜或铜/钼合金膜的蚀刻液组合物 |
| CN104955985B (zh) * | 2013-04-15 | 2018-07-20 | Mec股份有限公司 | 蚀刻液、补给液及铜配线的形成方法 |
| JP6207248B2 (ja) * | 2013-06-17 | 2017-10-04 | 株式会社Adeka | エッチング液組成物及びエッチング方法 |
| CN104233302B (zh) * | 2014-09-15 | 2016-09-14 | 南通万德科技有限公司 | 一种蚀刻液及其应用 |
| JP6807864B2 (ja) * | 2015-11-27 | 2021-01-06 | 三井金属鉱業株式会社 | 配線パターン付樹脂積層体の製造方法 |
| CN108930037B (zh) * | 2017-05-22 | 2021-02-26 | 东友精细化工有限公司 | 金属膜蚀刻液组合物及利用其的导电图案形成方法 |
| JP6736088B2 (ja) * | 2017-05-22 | 2020-08-05 | メック株式会社 | エッチング液、補給液および銅配線の形成方法 |
| KR102433304B1 (ko) * | 2017-08-11 | 2022-08-16 | 동우 화인켐 주식회사 | 금속막 식각액 조성물 및 이를 이용한 도전 패턴 형성 방법 |
| KR102457165B1 (ko) * | 2017-08-11 | 2022-10-19 | 동우 화인켐 주식회사 | 은 함유막 식각액 조성물 및 이를 이용한 도전 패턴 형성 방법 |
| KR102457174B1 (ko) * | 2017-08-28 | 2022-10-19 | 동우 화인켐 주식회사 | 은 함유막 식각액 조성물 및 이를 이용한 도전 패턴 형성 방법 |
| KR102586421B1 (ko) * | 2017-08-28 | 2023-10-10 | 동우 화인켐 주식회사 | 금속막 식각액 조성물 및 이를 이용한 도전 패턴 형성 방법 |
| CN108004598A (zh) * | 2017-12-01 | 2018-05-08 | 绍兴拓邦电子科技有限公司 | 一种晶体硅边缘刻蚀添加剂及其使用方法 |
| EP3761766A1 (en) * | 2019-07-03 | 2021-01-06 | AT & S Austria Technologie & Systemtechnik Aktiengesellschaft | Anisotropic etching using additives |
| CN110938822A (zh) * | 2019-11-14 | 2020-03-31 | 浙江工业大学 | 一种钼/铜复合金属层的蚀刻液、蚀刻方法与应用 |
| KR20250160428A (ko) * | 2023-03-14 | 2025-11-13 | 미쯔비시 케미컬 주식회사 | 에칭 조성물, 에칭 조성물의 제조 방법, 에칭 방법, 반도체 디바이스의 제조 방법 및 게이트 올 어라운드형 트랜지스터의 제조 방법 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6117783A (en) * | 1996-07-25 | 2000-09-12 | Ekc Technology, Inc. | Chemical mechanical polishing composition and process |
| US5855805A (en) * | 1996-08-08 | 1999-01-05 | Fmc Corporation | Microetching and cleaning of printed wiring boards |
| JP3974305B2 (ja) * | 1999-06-18 | 2007-09-12 | エルジー フィリップス エルシーディー カンパニー リミテッド | エッチング剤及びこれを用いた電子機器用基板の製造方法と電子機器 |
| KR100396695B1 (ko) * | 2000-11-01 | 2003-09-02 | 엘지.필립스 엘시디 주식회사 | 에천트 및 이를 이용한 전자기기용 기판의 제조방법 |
| KR100456373B1 (ko) * | 2001-12-31 | 2004-11-09 | 엘지.필립스 엘시디 주식회사 | 구리 또는 구리/티타늄 식각액 |
| US6818142B2 (en) * | 2003-03-31 | 2004-11-16 | E. I. Du Pont De Nemours And Company | Potassium hydrogen peroxymonosulfate solutions |
| JP2005029853A (ja) * | 2003-07-08 | 2005-02-03 | Mitsubishi Gas Chem Co Inc | 銅および銅合金のエッチング液 |
| US20050045852A1 (en) * | 2003-08-29 | 2005-03-03 | Ameen Joseph G. | Particle-free polishing fluid for nickel-based coating planarization |
| US7090820B2 (en) * | 2003-09-23 | 2006-08-15 | Truox, Inc. | Potassium monopersulfate triple salt with increased active oxygen content and substantially no K2S2O8 |
| US7442323B2 (en) | 2006-06-02 | 2008-10-28 | E. I. Du Pont De Nemours And Company | Potassium monopersulfate solutions |
| CN101245462A (zh) * | 2007-02-13 | 2008-08-20 | 峻科技有限公司 | 蚀刻液组合物与蚀刻方法 |
| US20080224092A1 (en) * | 2007-03-15 | 2008-09-18 | Samsung Electronics Co., Ltd. | Etchant for metal |
| WO2008121952A1 (en) * | 2007-03-31 | 2008-10-09 | Advanced Technology Materials, Inc. | Methods for stripping material for wafer reclamation |
-
2010
- 2010-03-23 TW TW099108561A patent/TWI480360B/zh active
- 2010-04-02 WO PCT/US2010/029741 patent/WO2010115075A1/en not_active Ceased
- 2010-04-02 JP JP2012503735A patent/JP5687685B2/ja active Active
- 2010-04-02 CN CN201080016265.0A patent/CN102395708B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2012522895A (ja) | 2012-09-27 |
| TW201105780A (en) | 2011-02-16 |
| TWI480360B (zh) | 2015-04-11 |
| CN102395708B (zh) | 2016-10-26 |
| CN102395708A (zh) | 2012-03-28 |
| WO2010115075A1 (en) | 2010-10-07 |
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