JP5303275B2 - デンプンを含む水安定性繊維及び物品並びにその製造方法 - Google Patents
デンプンを含む水安定性繊維及び物品並びにその製造方法 Download PDFInfo
- Publication number
- JP5303275B2 JP5303275B2 JP2008535644A JP2008535644A JP5303275B2 JP 5303275 B2 JP5303275 B2 JP 5303275B2 JP 2008535644 A JP2008535644 A JP 2008535644A JP 2008535644 A JP2008535644 A JP 2008535644A JP 5303275 B2 JP5303275 B2 JP 5303275B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- fiber
- starch
- fibers
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/22—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing macromolecular materials
- A61L15/28—Polysaccharides or their derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/04—Starch derivatives, e.g. crosslinked derivatives
- C08L3/08—Ethers
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/90—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/18—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4266—Natural fibres not provided for in group D04H1/425
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/435—Polyesters
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
- D04H1/43825—Composite fibres
- D04H1/43828—Composite fibres sheath-core
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/10—Organic non-cellulose fibres
- D21H13/28—Organic non-cellulose fibres from natural polymers
- D21H13/30—Non-cellulose polysaccharides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/10—Organic non-cellulose fibres
- D21H13/12—Organic non-cellulose fibres from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H13/14—Polyalkenes, e.g. polystyrene polyethylene
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
- D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
- D21H15/10—Composite fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/13—Silicon-containing compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/14—Carboxylic acids; Derivatives thereof
- D21H17/15—Polycarboxylic acids, e.g. maleic acid
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/38—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing crosslinkable groups
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/47—Condensation polymers of aldehydes or ketones
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/53—Polyethers; Polyesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/10—Packing paper
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
- Y10T428/2931—Fibers or filaments nonconcentric [e.g., side-by-side or eccentric, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/637—Including strand or fiber material which is a monofilament composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/637—Including strand or fiber material which is a monofilament composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
- Y10T442/638—Side-by-side multicomponent strand or fiber material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/637—Including strand or fiber material which is a monofilament composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
- Y10T442/641—Sheath-core multicomponent strand or fiber material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/637—Including strand or fiber material which is a monofilament composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
- Y10T442/642—Strand or fiber material is a blend of polymeric material and a filler material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/696—Including strand or fiber material which is stated to have specific attributes [e.g., heat or fire resistance, chemical or solvent resistance, high absorption for aqueous compositions, water solubility, heat shrinkability, etc.]
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Public Health (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Veterinary Medicine (AREA)
- Hematology (AREA)
- Manufacturing & Machinery (AREA)
- Toxicology (AREA)
- Epidemiology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Nonwoven Fabrics (AREA)
- Artificial Filaments (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Biological Depolymerization Polymers (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Laminated Bodies (AREA)
- Wrappers (AREA)
Description
デンプンは、天然に豊富であり、比較的安価であり得る。熱可塑性デンプンは、生分解性、堆肥化可能性、天然親水性、及び伝統的に石油系ポリマーと相性が悪い材料との相溶性を包含するがこれらに制限されない、従来の石油系ポリマーでは一般に観察されない望ましい特性を有することができる。
本明細書で使用するとき、「多価アルコール」とは、2つ以上のアルコール(すなわち、ヒドロキシル)官能基を有するアルコールを指す。理論に束縛されるものではないが、(上記のように)多価アルコールは、本発明のデンプン組成物において、デンプン可塑剤として作用する可能性があると考えられている。換言すれば、多価アルコールは、デンプンを流動させること及び加工すること、すなわち熱可塑性デンプンを作製することを可能にすると考えられる。
本発明において有用な酸は、カルボン酸、カルボン酸無水物、及びこれらの組み合わせから成る群から選択される少なくとも1つの官能基を有する。こうした酸としては、一酸、二酸、ポリ酸(少なくとも3つの酸性基を有する酸)、少なくとも1つの酸部分を含むポリマー、少なくとも1つの酸部分を含むコポリマー、これらの無水物、及びこれらの混合物が挙げられるが、これらに限定されない。
あらゆる好適なトリグリセリドは、トリアシルグリセロールとしても当該技術分野において既知であり、本発明において有用である。有用なトリグリセリドの非限定例としては、トリステアリン、トリオレイン、トリパルミチン、1,2−ジパルミトオレイン、1,3−ジパルミトオレイン、1−パルミト−3−ステアロ−2−オレイン、1−パルミト−2−ステアロ−3−オレイン、2−パルミト−1−ステアロ−3−オレイン、トリリノレイン、1,2−ジパルミトリノレイン、1−パルミト−ジリノレイン、1−ステアロ−ジリノレイン、1,2−ジアセトパルミチン、1,2−ジステアロ−オレイン、1,3−ジステアロ−オレイン、トリミリスチン、トリラウリン、及びこれらの組み合わせが挙げられる。
本発明に従う組成物は、繊維及び/又はプラスチック物品の加工及び/又は最終用途のために、所望により1以上の追加の構成成分を包含してよい。追加の構成成分は、あらゆる好適な量で存在してよい。ある実施形態では、追加の構成成分は、約0.01%〜約35%、又は約2%〜約20%の量で存在してよい。追加の構成成分の非限定例としては、追加のポリマー、加工助剤、及び同種のものが挙げられるが、これらに限定されない。
理論に束縛されるものではないが、本発明に従う熱可塑性ポリマー組成物は、前述のエステル交換反応及び/又はエステル縮合反応を通して、水安定性になる可能性がある。熱可塑性ポリマー組成物が、繊維及び/又は繊維を含む物品になるとき、反応は、繊維及び/又は物品の形成前、繊維及び/又は物品の形成中、繊維の及び/又は物品の形成(すなわち硬化)後、並びにこれらの組み合わせにおいて、誘発されてよい。ある実施形態では、反応(単数又は複数)は、熱の適用を通して引き起こされ、及び/又は完了される。本発明のある実施形態では、触媒が、エステル交換及び/又はエステル縮合反応を開始する及び/又は促進するために使用されてもよい。あらゆる好適な触媒が有用である。有用な触媒の非限定例としては、ルイス酸が挙げられる。ルイス酸の非限定例は、パラ−トルエンスルホン酸である。
(実施例1)
この実施例は、水安定性繊維の溶融混合及びワンショット紡糸を説明する。次の材料を、ハッケ・レオコード90メルトミキサー(Haake Rheocord 90 melt mixer)(サーモエレクトロン社(Thermo Electron Corporation)、(ニューハンプシャー州、ニューイントン(Newington)))にて混合する:
30gのエチレックス(Ethylex)(商標)2015ヒドロキシエチル化デンプン(テート&ライル(Tate& Lyle)、イリノイ州、ジケーター(Decatur))
12.5gのグリセロール(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
7.5gの大豆油(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
0.0125gのp−トルエンスルホン酸(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
この例は、非水安定性デンプン繊維の溶融混合及びワンショット紡糸のための従来の方法を説明する。次の材料を、記載されたハッケ・レオコード90メルトミキサー(Haake Rheocord 90 melt mixer)にて混合する:
30gのエチレックス(Ethylex)(商標)2015デンプン(テート&ライル(Tate& Lyle)、イリノイ州、ジケーター(Decatur))
12.5gのグリセロール(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
この実施例は、様々な組成の水安定性デンプン繊維の溶融混合及びワンショット紡糸を説明する。次の材料を、実施例1に記載された様式で、記載されたハッケ・レオコード90メルトミキサー(Haake Rheocord 90 melt mixer)にて混合し、溶融ブレンドする。各組成物をおよそ50g製造する。
この実施例は、水安定性繊維の追加のブレンド及び紡糸を説明する。次の材料を使用する:
3500gのエチレックス(Ethylex)(商標)2015(テート&ライル(Tate& Lyle)、イリノイ州、ジケーター(Decatur))
1095gのグリセロール(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
438gの亜麻仁油(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
438gのステアリン酸(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
50gのステアリン酸マグネシウム(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
この実施例は、水安定性二構成成分繊維のブレンド及び紡糸を説明する。次の材料を使用して熱可塑性組成物を製造する:
3500gのエチレックス(Ethylex)(商標)2015(テート&ライル(Tate& Lyle)、イリノイ州、ジケーター(Decatur))
1095gのグリセロール(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
438gの大豆油(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
2gのp−トルエンスルホン酸(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
50gのステアリン酸マグネシウム(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
全体的な押出成形速度は9.1kg/hr(20lbs/hr)である。ペレット化の間、材料から水を抜き出すために、3つのベントポートのうちの2つに真空ラインを適用する。トルクは10%である。混合物を直径0.3〜0.8cmのストランドに押出成形し、コーンエアー・ペレタイザー(Conair pellitizer)を通して該ストランドを切り、ペレットを形成する。ペレットを66℃(150゜F)の通気空気乾燥機中で12時間乾燥する。ペレットを前述の二構成成分シース/コア4穴スピンパックを有するヒルズ(Hills)4穴押出成形機試験スタンドに供給する。二構成成分繊維のために、上記の熱可塑性組成物を押出成形機1に供給する。第2の押出成形機には、ナチュラワークスLLC(Natureworks LLC)から入手されたポリ乳酸(PLA)(グレード6251D)を次の条件で使用する:
PPとブレンドされた繊維
この実施例は、水安定性繊維の追加のブレンド及び紡糸を説明する。次の材料を使用する:
6000gのエチレックス(Ethylex)(商標)2065(テート&ライル(Tate& Lyle)、イリノイ州、ジケーター(Decatur))
2500gのグリセロール(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
500gのポリプロピレンプロファックス(Polypropylene Profax)(商標)PH835(バーゼル(Basell)、メリーランド州、エルクトン(Elkton))
500gのマレイン酸化ポリプロピレンG3003(イーストマンケミカルズ(Eastman Chemicals)、テネシー州、キングズポート(Kingsport))
500gの大豆油(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
2.5gのp−トルエンスルホン酸(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
50gのステアリン酸マグネシウム(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
この実施例は、水安定性二構成成分繊維のブレンド及び紡糸を説明する。次の材料を使用して熱可塑性組成物を製造する:
6000gのエチレックス(Ethylex)(商標)2065(テート&ライル(Tate& Lyle)、イリノイ州、ジケーター(Decatur))
2500gのグリセロール(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
500gのポリプロピレンプロファックス(Polypropylene Profax)(商標)PH835(バーゼル(Basell)、メリーランド州、エルクトン(Elkton))
500gのマレイン酸化ポリプロピレンG3003(イーストマンケミカルズ(Eastman Chemicals)、テネシー州、キングズポート(Kingsport))
750gの亜麻仁油(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
2.5gのp−トルエンスルホン酸(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))50gのステアリン酸マグネシウム(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
PPを有する二構成成分繊維
この実施例は、水安定性二構成成分繊維のブレンド及び紡糸を説明する。次の材料を使用して熱可塑性組成物を製造する:
6000gのエチレックス(Ethylex)(商標)2015(テート&ライル(Tate& Lyle)、イリノイ州、ジケーター(Decatur))
1900gのグリセロール(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
500gのポリプロピレンプロファックス(Polypropylene Profax)(商標)PH835(バーゼル(Basell)、メリーランド州、エルクトン(Elkton))
500gのマレイン酸化ポリプロピレンG3003(イーストマンケミカルズ(Eastman Chemicals)、テネシー州、キングズポート(Kingsport))
500gの亜麻仁油(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
2.5gのp−トルエンスルホン酸(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
50gのステアリン酸マグネシウム(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
バインダー繊維
この実施例は、水安定性バインダー繊維の追加のブレンド及び紡糸を説明する。次の材料を使用する:
6000gのエチレックス(Ethylex)(商標)2015(テート&ライル(Tate& Lyle)、イリノイ州、ジケーター(Decatur))
2500gのグリセロール(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
350gの大豆油(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
2gのp−トルエンスルホン酸(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
500gのマレイン酸化ポリプロピレン(イーストマンケミカルズ(Eastman Chemicals)、テネシー州、キングズポート(Kingsport))
50gのステアリン酸マグネシウム(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
この実施例は、水安定性二構成成分繊維のブレンド及び紡糸を説明する。次の材料を使用して熱可塑性組成物を製造する:
6000gのエチレックス(Ethylex)(商標)2015(テート&ライル(Tate& Lyle)、イリノイ州、ジケーター(Decatur))
1900gのグリセロール(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
500gのポリプロピレンプロファックス(Polypropylene Profax)(商標)PH835(バーゼル(Basell)、メリーランド州、エルクトン(Elkton))
500gのマレイン酸化ポリプロピレンG3003(イーストマンケミカルズ(Eastman Chemicals)、テネシー州、キングズポート(Kingsport))
500gのアジピン酸(ソルチアケミカルズ(Solutia Chemicals)、ミズーリ州、セントルイス(St.Louis))
500gの亜麻仁油(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
50gのステアリン酸マグネシウム(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
この実施例は、水安定性二構成成分繊維のブレンド及び紡糸を説明する。次の材料を使用して熱可塑性組成物を製造する:
6000gのエチレックス(Ethylex)(商標)2005(テート&ライル(Tate& Lyle)、イリノイ州、ジケーター(Decatur))
1900gのグリセロール(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
500gのポリプロピレンプロファックス(Polypropylene Profax)(商標)PH835(バーゼル(Basell)、メリーランド州、エルクトン(Elkton))
500gのマレイン酸化ポリプロピレンG3003(イーストマンケミカルズ(Eastman Chemicals)、テネシー州、キングズポート(Kingsport))
500gのアジピン酸(ソルチアケミカルズ(Solutia Chemicals)、ミズーリ州、セントルイス(St.Louis))
200gの大豆油(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
50gのステアリン酸マグネシウム(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
TPS繊維からのウェブ
コアシース比95/5のTPS/PPを有するTPS繊維を、実施例8のように調製する。およそ60g/m2のウェブを、ダイアモンド形状パターン(幅1mm、間隔2mm)を有する加熱したカレンダーを経由して、60℃で結合する。ウェブを115℃のオーブンで12時間乾燥する。ウェブの5cm×5cmの切片を、1000mLの水道水に入れ、3.1rad/s(30rpm)で24時間攪拌する。ウェブを水から取り出し、空気中で24時間乾燥した後、測定する。長さ及び幅の寸法の変化は、15%以下であり、ウェブは本質的に無傷である。ウェブは、水安定性を示すとされる。
非水安定性TPS繊維からのウェブ
次の材料を使用して熱可塑性組成物を製造する:
6000gのエチレックス(Ethylex)(商標)2015(テート&ライル(Tate& Lyle)、イリノイ州、ジケーター(Decatur))
2500gのグリセロール(アルドリッチケミカルズ(Aldrich Chemicals)、ミズーリ州、セントルイス(St.Louis))
Claims (18)
- 熱可塑性デンプン組成物を含む水安定性繊維であって、前記熱可塑性デンプン組成物は、
a.熱可塑性非構造化デンプンと、
b.エステル交換生成物と
の水安定化されたブレンドを含み、
前記熱可塑性非構造化デンプンおよび前記エステル交換生成物は、
(1)非構造化デンプンと、
(2)
i.アルコール官能基を有する多価アルコール、並びに
ii.エステル官能基を有するトリグリセリド
を含む反応体混合物と
を含む加熱デンプン混合物からインサイチューで形成され、
前記アルコール官能基:前記エステル官能基のモル比は1:1〜200:1であり、
前記加熱デンプン混合物は、存在する結合水の少なくとも一部を除去し、および前記多価アルコールと前記トリグリセリドとの間のエステル交換を前記熱可塑性デンプン組成物の水安定性を実現させる点まで進行させるのに、充分な温度および時間で加熱される
繊維。 - 前記トリグリセリドが、ココヤシ油、コーン胚芽油、オリーブ油、パーム種子油、綿実油、パーム油、菜種油、ヒマワリ油、鯨油、大豆油、ピーナッツ油、亜麻仁油、トール油、及びこれらの組み合わせから成る群から選択される油中に存在する、請求項1に記載の繊維。
- 前記組成物が、多価アルコールと、カルボン酸、カルボン酸無水物、及びこれらの組み合わせから成る群から選択される少なくとも1つの官能基を有する酸とを含む反応体混合物から形成されるエステル縮合反応体生成物を更に含む、請求項1に記載の繊維。
- 前記酸が、一酸、二酸、ポリ酸、少なくとも1つの酸部分を含むポリマー、少なくとも1つの酸部分を含むコポリマー、これらの無水物、及びこれらの組み合わせから成る群から選択される、請求項3に記載の繊維。
- 前記酸が、アジピン酸、セバシン酸、ラウリン酸、ステアリン酸、ミリスチン酸、パルミチン酸、オレイン酸、リノール酸、セバシン酸、クエン酸、シュウ酸、マロン酸、コハク酸、グルタル酸、マレイン酸、フマル酸、フタル酸、イソフタル酸、テレフタル酸、アクリル酸、ポリアクリル酸、エチレン−アクリル酸共重合体、メタクリル酸、イタコン酸、メタクリル酸グリシジル、及びこれらの組み合わせから成る群から選択される、請求項4に記載の繊維。
- 前記酸が、無水マレイン酸、無水フタル酸、無水コハク酸、及びこれらの組み合わせから成る群から選択される、請求項4に記載の繊維。
- 前記多価アルコールが、グリセロール、グリコール、糖、糖アルコール、及びこれらの組み合わせから成る群から選択される、請求項1に記載の繊維。
- 前記組成物が、ポリヒドロキシアルカノエート、ポリビニルアルコール、ポリエチレン、ポリプロピレン、マレイン酸化ポリエチレン、マレイン酸化ポリプロピレン、ポリエチレンテレフタレート、ポリ乳酸、変性ポリプロピレン、ナイロン、カプロラクトン、及びこれらの組み合わせから成る群から選択される追加のポリマーを更に含む、請求項1に記載の繊維。
- 前記繊維が生分解性である、請求項1に記載の繊維。
- 前記熱可塑性組成物が、ポリビニルアルコール、エステル重縮合物、脂肪族/芳香族ポリエステル、及びこれらの組み合わせから成る群から選択される追加のポリマーを更に含む、請求項9に記載の繊維。
- 前記ポリマーが、ポリブチレンサクシネート、ポリブチレンサクシネート コ−アジパート、ブチレンジオール、アジピン酸、及びテレフタル酸のコポリエステル、及びこれらの組み合わせからなる群から選択される、請求項10に記載の繊維。
- 前記繊維が、単構成成分繊維、多構成成分繊維、多構成要素繊維、及びこれらの組み合わせから成る群から選択される、請求項1に記載の繊維。
- 前記繊維が、シース及びコアを有する多構成成分繊維であり、前記コアが前記熱可塑性デンプン組成物を含む、請求項12に記載の繊維。
- 前記シースが、ポリエチレンテレフタレート、ポリエチレン、ポリプロピレン、ポリヒドロキシアルカノエート、ポリ乳酸、ポリエステル、及びこれらの組み合わせからなる群から選択される、請求項13に記載の繊維。
- 前記繊維が海島型構成を有する多構成成分繊維であり、前記島が前記熱可塑性デンプン組成物を含む、請求項12に記載の繊維。
- 請求項1に記載の繊維を含む不織布。
- 請求項1に記載の繊維を含む個人衛生物品。
- 請求項1に記載の繊維を含む吸収性物品。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US72542405P | 2005-10-11 | 2005-10-11 | |
US60/725,424 | 2005-10-11 | ||
PCT/US2006/039707 WO2007044800A1 (en) | 2005-10-11 | 2006-10-11 | Water stable fibers and articles comprising starch, and methods of making the same |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2009511765A JP2009511765A (ja) | 2009-03-19 |
JP5303275B2 true JP5303275B2 (ja) | 2013-10-02 |
Family
ID=37642071
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2008535644A Expired - Fee Related JP5303275B2 (ja) | 2005-10-11 | 2006-10-11 | デンプンを含む水安定性繊維及び物品並びにその製造方法 |
JP2008535646A Expired - Fee Related JP5475287B2 (ja) | 2005-10-11 | 2006-10-11 | デンプンを含む水安定性繊維及び物品並びにその製造方法 |
JP2008535647A Expired - Fee Related JP5281893B2 (ja) | 2005-10-11 | 2006-10-11 | デンプンを含む水安定性組成物及び物品並びにその製造方法 |
JP2008535645A Expired - Fee Related JP5281892B2 (ja) | 2005-10-11 | 2006-10-11 | デンプンを含む水安定性組成物及び物品、並びにその製造方法 |
Family Applications After (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2008535646A Expired - Fee Related JP5475287B2 (ja) | 2005-10-11 | 2006-10-11 | デンプンを含む水安定性繊維及び物品並びにその製造方法 |
JP2008535647A Expired - Fee Related JP5281893B2 (ja) | 2005-10-11 | 2006-10-11 | デンプンを含む水安定性組成物及び物品並びにその製造方法 |
JP2008535645A Expired - Fee Related JP5281892B2 (ja) | 2005-10-11 | 2006-10-11 | デンプンを含む水安定性組成物及び物品、並びにその製造方法 |
Country Status (8)
Country | Link |
---|---|
US (6) | US20070082982A1 (ja) |
EP (4) | EP1934390B1 (ja) |
JP (4) | JP5303275B2 (ja) |
CN (4) | CN101283124B (ja) |
AT (4) | ATE449875T1 (ja) |
CA (4) | CA2625237C (ja) |
DE (4) | DE602006016972D1 (ja) |
WO (4) | WO2007044803A1 (ja) |
Families Citing this family (102)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070082982A1 (en) * | 2005-10-11 | 2007-04-12 | The Procter & Gamble Company | Water stable compositions and articles comprising starch and methods of making the same |
DE602005023671D1 (de) | 2005-12-15 | 2010-10-28 | Kimberly Clark Co | Biologisch abbaubare mehrkomponentenfasern |
EP2004396B1 (en) | 2006-04-07 | 2011-11-02 | Kimberly-Clark Worldwide, Inc. | Biodegradable nonwoven laminate |
KR101297865B1 (ko) * | 2006-07-14 | 2013-08-19 | 킴벌리-클라크 월드와이드, 인크. | 부직 웹에 사용하기 위한 생분해성 폴리락트산 |
DE602006018078D1 (de) | 2006-07-14 | 2010-12-16 | Kimberly Clark Co | Biologisch abbaubarer aliphatisch-aromatischer copolyester zur verwendung in vliesstoffen |
US8609808B2 (en) | 2006-07-14 | 2013-12-17 | Kimberly-Clark Worldwide, Inc. | Biodegradable aliphatic polyester for use in nonwoven webs |
CN102167890A (zh) * | 2006-07-28 | 2011-08-31 | 比澳格(香港)有限公司 | 适用于制备可生物降解的聚合物组合物的母料及其制备方法 |
US20080200890A1 (en) * | 2006-12-11 | 2008-08-21 | 3M Innovative Properties Company | Antimicrobial disposable absorbent articles |
US9555167B2 (en) * | 2006-12-11 | 2017-01-31 | 3M Innovative Properties Company | Biocompatible antimicrobial compositions |
KR100816497B1 (ko) | 2007-05-23 | 2008-03-31 | 에스엔비환경주식회사 | 생분해성 고분자 수지 조성물로 이루어진 성형재의제조방법 |
FR2920432A1 (fr) * | 2007-08-30 | 2009-03-06 | Conti Celine | Composition biodegradable pour la realisation d'un fil |
US20090068416A1 (en) * | 2007-09-12 | 2009-03-12 | Isao Noda | Process for Coating a Substrate with a Coating Precursor Forming a Coating as a Product of Ester Condensation and Products Coated with Such Coating Precursor |
DE102007050770A1 (de) * | 2007-10-22 | 2009-04-23 | Biotec Biologische Naturverpackungen Gmbh & Co. Kg | Polymeres Material und Verfahren zu dessen Herstellung |
KR101578233B1 (ko) * | 2007-11-13 | 2015-12-16 | 인비스타 테크놀러지스 에스.에이 알.엘. | 가소제를 포함하는 열-활성화 필름의 결합 |
FR2927084B1 (fr) * | 2008-02-01 | 2011-02-25 | Roquette Freres | Procede de preparation de compositions thermoplastiques a base d'amidon plastifie et compositions ainsi obtenues. |
FR2927088B1 (fr) * | 2008-02-01 | 2011-02-25 | Roquette Freres | Compositions thermoplastiques a base d'amidon plastifie et procede de preparation de telles compositions. |
WO2009137058A1 (en) | 2008-05-06 | 2009-11-12 | Metabolix, Inc. | Biodegradable polyester blends |
US8470222B2 (en) | 2008-06-06 | 2013-06-25 | Kimberly-Clark Worldwide, Inc. | Fibers formed from a blend of a modified aliphatic-aromatic copolyester and thermoplastic starch |
US8841386B2 (en) * | 2008-06-10 | 2014-09-23 | Kimberly-Clark Worldwide, Inc. | Fibers formed from aromatic polyester and polyether copolymer |
US8841363B2 (en) * | 2008-10-14 | 2014-09-23 | Basf Se | Copolymers having long-chain acrylates |
CA2652063C (en) * | 2009-01-30 | 2016-03-08 | 3M Innovative Properties Company | Tape comprising recycled paper |
US20100286642A1 (en) * | 2009-05-11 | 2010-11-11 | Allen Jr William Maxwell | Water-stable, oil-modified, nonreactive alkyd resin construction adhesives, and use thereof |
US8026188B2 (en) | 2009-06-25 | 2011-09-27 | Techmer Pm, Llc | Hydrophobic additive for use with fabric, fiber, and film |
EP2270271B1 (en) * | 2009-06-25 | 2015-03-04 | Fibertex Personal Care A/S | High barrier nonwoven |
EP2301595B1 (en) * | 2009-09-23 | 2014-01-22 | Dentsply IH AB | Flushable catheter and method for producing such a catheter |
FR2957928B1 (fr) * | 2010-03-25 | 2013-07-05 | Roquette Freres | Compositions a base de matiere vegetale et procede de preparation de telles compositions |
EP2576876A1 (en) * | 2010-06-03 | 2013-04-10 | The Procter and Gamble Company | Fibers and nonwovens made from uncross-linked alkyd oligomers |
DE102010034371B4 (de) * | 2010-08-13 | 2020-12-24 | Autoliv Development Ab | Gassack |
US8445088B2 (en) * | 2010-09-29 | 2013-05-21 | H.J. Heinz Company | Green packaging |
CN103210033B (zh) * | 2010-11-23 | 2016-05-04 | 宝洁公司 | 热塑性淀粉组合物 |
US8889945B2 (en) * | 2010-12-08 | 2014-11-18 | Kimberly-Clark Worldwide, Inc. | Elastic film containing a renewable starch polymer |
KR20120111990A (ko) * | 2011-03-31 | 2012-10-11 | 유인식 | 식물 지방산이 함유된 합성섬유의 제조방법 |
DE102011015889A1 (de) * | 2011-04-01 | 2012-10-04 | Karl Thews | Absorptionsartikel |
CN103547624A (zh) * | 2011-05-20 | 2014-01-29 | 宝洁公司 | 聚合物-蜡组合物的模塑制品 |
CN103562289A (zh) * | 2011-05-20 | 2014-02-05 | 宝洁公司 | 聚合物-蜡组合物的膜 |
EP2710060A1 (en) * | 2011-05-20 | 2014-03-26 | The Procter and Gamble Company | Molded articles of polymer-oil compositions |
WO2012162134A1 (en) * | 2011-05-20 | 2012-11-29 | The Procter & Gamble Company | Films of polymer-oil compositions |
WO2012162083A1 (en) * | 2011-05-20 | 2012-11-29 | The Procter & Gamble Company | Fibers of polymer-oil compositions |
BR112013029832A2 (pt) * | 2011-05-20 | 2016-12-06 | Procter & Gamble | fibras de composições de amido, polímero e óleo |
JP2014517864A (ja) * | 2011-05-20 | 2014-07-24 | ザ プロクター アンド ギャンブル カンパニー | デンプン−ポリマー−油組成物、その製造及び使用方法 |
US20130012093A1 (en) * | 2011-05-20 | 2013-01-10 | Eric Bryan Bond | Fibers of polymer-wax compositions |
US20130089747A1 (en) * | 2011-05-20 | 2013-04-11 | William Maxwell Allen, Jr. | Fibers of Polymer-Wax Compositions |
BR112013028404A2 (pt) * | 2011-05-20 | 2017-03-01 | Procter & Gamble | filmes de composições de amido-polímero-cera-óleo |
US20130053480A1 (en) * | 2011-05-20 | 2013-02-28 | William Maxwell Allen | Polymer-oil compositions, methods of making and using the same |
CN103547628A (zh) * | 2011-05-20 | 2014-01-29 | 宝洁公司 | 淀粉-聚合物-蜡-油组合物的模塑制品 |
US8877862B2 (en) | 2011-07-15 | 2014-11-04 | Saudi Basic Industries Corporation | Method for color stabilization of poly(butylene-co-adipate terephthalate |
US8933162B2 (en) | 2011-07-15 | 2015-01-13 | Saudi Basic Industries Corporation | Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof |
US9334360B2 (en) | 2011-07-15 | 2016-05-10 | Sabic Global Technologies B.V. | Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof |
US8946345B2 (en) | 2011-08-30 | 2015-02-03 | Saudi Basic Industries Corporation | Method for the preparation of (polybutylene-co-adipate terephthalate) through the in situ phosphorus containing titanium based catalyst |
JP2013049760A (ja) * | 2011-08-30 | 2013-03-14 | Mitsubishi Chemicals Corp | 樹脂組成物の製造方法、並びに、成形体、フィルム及び袋の製造方法 |
US8901273B2 (en) | 2012-02-15 | 2014-12-02 | Saudi Basic Industries Corporation | Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof |
US8969506B2 (en) | 2012-02-15 | 2015-03-03 | Saudi Basic Industries Corporation | Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof |
US8889820B2 (en) | 2012-02-15 | 2014-11-18 | Saudi Basic Industries Corporation | Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof |
US9034983B2 (en) | 2012-03-01 | 2015-05-19 | Saudi Basic Industries Corporation | Poly(butylene-co-adipate terephthalate), method of manufacture and uses thereof |
US8895660B2 (en) | 2012-03-01 | 2014-11-25 | Saudi Basic Industries Corporation | Poly(butylene-co-adipate terephthalate), method of manufacture, and uses thereof |
US8901243B2 (en) | 2012-03-30 | 2014-12-02 | Saudi Basic Industries Corporation | Biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof |
US9475930B2 (en) | 2012-08-17 | 2016-10-25 | Metabolix, Inc. | Biobased rubber modifiers for polymer blends |
US9284662B2 (en) * | 2012-09-21 | 2016-03-15 | Board Of Regents Of The University Of Texas System | Soybean based fibers |
CN104955887A (zh) * | 2012-11-20 | 2015-09-30 | 宝洁公司 | 聚合物-皂组合物及其制备和使用方法 |
EP2922913A1 (en) * | 2012-11-20 | 2015-09-30 | The Procter & Gamble Company | Polymer-grease compositions and methods of making and using the same |
US20140142226A1 (en) * | 2012-11-20 | 2014-05-22 | The Procter & Gamble Company | Starch-Thermoplastic Polymer-Grease Compositions and Methods of Making and Using the Same |
US20140142225A1 (en) * | 2012-11-20 | 2014-05-22 | The Procter & Gamble Company | Starch-Thermoplastic Polymer-Soap Compositions and Methods of Making and Using the Same |
DE102012224379A1 (de) | 2012-12-27 | 2014-07-03 | Aesculap Ag | Faserprodukt und Verfahren zu seiner Herstellung |
US20140259483A1 (en) * | 2013-03-15 | 2014-09-18 | The Procter & Gamble Company | Wipes with improved properties |
US9205006B2 (en) * | 2013-03-15 | 2015-12-08 | The Procter & Gamble Company | Absorbent articles with nonwoven substrates having fibrils |
US20140272223A1 (en) * | 2013-03-15 | 2014-09-18 | The Procter & Gamble Company | Packages for articles of commerce |
US9504610B2 (en) | 2013-03-15 | 2016-11-29 | The Procter & Gamble Company | Methods for forming absorbent articles with nonwoven substrates |
WO2014194220A1 (en) | 2013-05-30 | 2014-12-04 | Metabolix, Inc. | Recyclate blends |
CN105793383B (zh) * | 2013-12-05 | 2017-10-27 | 英派尔科技开发有限公司 | 恒温材料、其制备方法和用途 |
DE102014202578A1 (de) | 2014-02-12 | 2015-08-13 | Aesculap Ag | Medizinisches Produkt und Verfahren zu seiner Herstellung |
CN103924380B (zh) * | 2014-03-11 | 2017-06-27 | 绍兴文理学院 | 聚羟基丁酸戊酸共聚酯复合材料的制备方法 |
EP3122817B1 (en) | 2014-03-27 | 2020-07-29 | CJ CheilJedang Corporation | Highly filled polymer systems |
EP2924071B1 (en) * | 2014-03-28 | 2016-11-02 | URSA Insulation, S.A. | Improved curable formaldehyde-free resin dispersion with reduced viscosity and mineral wool products produced therewith |
US10844204B2 (en) | 2014-06-13 | 2020-11-24 | Continental Structural Plastics, Inc. | Thermoplastic formed with renewable content |
WO2016040618A2 (en) | 2014-09-10 | 2016-03-17 | The Procter & Gamble Company | Nonwoven web |
CN107106355B (zh) | 2014-11-06 | 2020-11-03 | 宝洁公司 | 卷曲纤维纺粘非织造网/层压体 |
US10400105B2 (en) | 2015-06-19 | 2019-09-03 | The Research Foundation For The State University Of New York | Extruded starch-lignin foams |
BE1023792B1 (nl) * | 2015-10-07 | 2017-07-27 | Syral Belgium Nv | Een hechtmiddelsamenstelling omvattende een zetmeelhydrolysaat voor het thermisch hechten |
CN106609399A (zh) * | 2015-10-21 | 2017-05-03 | 东丽纤维研究所(中国)有限公司 | 一种柔软纤维及其织物 |
CN109152678B (zh) | 2016-03-09 | 2021-04-30 | 宝洁公司 | 具有可活化材料的吸收制品 |
JP6860137B2 (ja) * | 2016-07-29 | 2021-04-14 | 日本製紙株式会社 | 繊維性成形品製造用の成形材料およびそれを用いた成形品 |
DK3325703T3 (da) | 2016-08-02 | 2019-10-28 | Fitesa Germany Gmbh | System og fremgangsmåde til fremstilling af ikke-vævede polymælkesyrestoffer |
US11441251B2 (en) | 2016-08-16 | 2022-09-13 | Fitesa Germany Gmbh | Nonwoven fabrics comprising polylactic acid having improved strength and toughness |
CN106120149A (zh) * | 2016-08-19 | 2016-11-16 | 马鞍山湖滨无纺布科技有限公司 | 一种防蚊的、可连续释放负氧离子的无纺布及其制备方法 |
CN106120163A (zh) * | 2016-08-19 | 2016-11-16 | 马鞍山湖滨无纺布科技有限公司 | 一种含艾叶油的、可连续释放负氧离子的无纺布及其制备方法 |
JP2018053192A (ja) * | 2016-09-30 | 2018-04-05 | 日本コーンスターチ株式会社 | エステル化澱粉及び澱粉系プラスチック組成物 |
US20190330770A1 (en) * | 2016-12-16 | 2019-10-31 | Kimberly-Clark Worldwide, Inc. | Wet-laid microfibers including polyolefin and thermoplastic starch |
JP6901856B2 (ja) * | 2016-12-28 | 2021-07-14 | 株式会社コバヤシ | 澱粉・樹脂複合成形加工材料の製造方法 |
JP6829598B2 (ja) * | 2016-12-28 | 2021-02-10 | 株式会社コバヤシ | 澱粉・樹脂複合成形加工材料 |
JP6850125B2 (ja) * | 2016-12-28 | 2021-03-31 | 株式会社コバヤシ | 澱粉複合中間粒体 |
JP6901855B2 (ja) * | 2016-12-28 | 2021-07-14 | 株式会社コバヤシ | 澱粉・樹脂複合中間粒体の製造方法 |
RU2633885C1 (ru) * | 2017-02-15 | 2017-10-19 | Александр Алексеевич Ермаков | Растительный пластилин |
EP3592316B1 (en) | 2017-03-09 | 2023-12-06 | The Procter & Gamble Company | Thermoplastic polymeric materials with heat activatable compositions |
CN110832124A (zh) * | 2018-01-02 | 2020-02-21 | 普莱玛有限公司 | 生物降解增强的合成纤维及其制备方法 |
CN108893799A (zh) * | 2018-06-20 | 2018-11-27 | 界首市旭派服饰有限公司 | 一种吸汗排湿的涤纶织物 |
JP2022524150A (ja) | 2019-03-15 | 2022-04-27 | グリーン ドット バイオプラスティクス インコーポレイテッド | 熱可塑性デンプンおよびその製造方法 |
CN110227036A (zh) * | 2019-05-21 | 2019-09-13 | 南京神奇科技开发有限公司 | 一种化妆品用原料及其制备方法 |
CN110295457B (zh) * | 2019-06-06 | 2021-08-06 | 肥城泰西无纺材料有限公司 | 一种含大豆纤维健康生态棉的制备方法 |
JP2021155655A (ja) * | 2020-03-30 | 2021-10-07 | セイコーエプソン株式会社 | 複合体、成形体および成形体の製造方法 |
BR102020017972A2 (pt) * | 2020-09-02 | 2022-03-15 | Unespar - Universidade Estadual Do Paraná | Polímero de amido hidrofóbico, processo para obtenção do mesmo, composição, processo para obtenção da composição, método de revestimento e uso do polímero de amido hidrofóbico |
US11523203B1 (en) * | 2021-03-11 | 2022-12-06 | Zeenat Ali | Starch based earphone covers |
DE102022116721A1 (de) | 2022-07-05 | 2024-01-11 | Paul Hartmann Ag | Absorbierender Inkontinenzartikel als wegwerfbares Einmalprodukt und Verfahren zur Herstellung des Inkontinenzartikels |
Family Cites Families (112)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US512617A (en) * | 1894-01-09 | Bale-tie machine | ||
US2850468A (en) * | 1955-04-08 | 1958-09-02 | Du Pont | Remoistenable adhesive comprising polyvinyl acetate, polyvinyl alcohol and a plasticizer and method of preparation |
US3320200A (en) * | 1965-03-01 | 1967-05-16 | Du Pont | Polyvinyl alcohol adhesives containing boric acid and hexamethylenetetramine or triethylenediamine as additive to impart quick tack |
US3417413A (en) | 1965-12-22 | 1968-12-24 | Du Pont | Pillow with fiber-on-end pile covering aiding prevention of facial acne aggravation |
US3767604A (en) * | 1969-07-15 | 1973-10-23 | Penick & Ford Ltd | Compatible mixtures of modified starch and polyvinyl alcohol |
US3848594A (en) | 1973-06-27 | 1974-11-19 | Procter & Gamble | Tape fastening system for disposable diaper |
US3860003B2 (en) * | 1973-11-21 | 1990-06-19 | Contractable side portions for disposable diaper | |
US3985937A (en) * | 1975-09-08 | 1976-10-12 | Georgia-Pacific Corporation | Paperboard laminating adhesive containing polyvinyl acetate/styrenebutadine polymers; paraffin wax; clay; and polyalkyleneglycol |
DE2708513C3 (de) | 1977-02-26 | 1981-01-08 | C.H. Boehringer Sohn, 6507 Ingelheim | Wasserunlösliche, physiologisch unbedenkliche Masse, Verfahren zu ihrer Herstellung und ihre Verwendung |
DE2964688D1 (en) * | 1978-03-23 | 1983-03-17 | Hoechst Ag | Polyvinyl alcohol pellets containing a plasticizer, and method for their preparation |
US4687478A (en) * | 1984-03-20 | 1987-08-18 | The Procter & Gamble Company | Shaped sanitary napkin with flaps |
US4589876A (en) | 1983-07-05 | 1986-05-20 | The Procter & Gamble Company | Sanitary napkin |
US4673438A (en) * | 1984-02-13 | 1987-06-16 | Warner-Lambert Company | Polymer composition for injection molding |
AU563019B2 (en) * | 1984-05-21 | 1987-06-25 | H.B. Fuller Licensing And Financing Inc. | Starch-based corrugating adhesive containing soluble polyvinyl alcohol |
US4615739A (en) * | 1985-02-28 | 1986-10-07 | Formby's Inc. | Oil-in-water-in-oil coating composition |
JPS6291502A (ja) | 1985-10-16 | 1987-04-27 | Sanmatsu Kogyo Kk | 低カロリ−多糖類の製造法 |
US4826719A (en) * | 1986-07-15 | 1989-05-02 | H. B. Fuller Company | Fast setting starch-based corrugating adhesive having fully hydrolyzed cold water insoluble polyvinyl alcohol component |
GB2205323B (en) * | 1987-03-09 | 1991-01-30 | Warner Lambert Co | Destructurized starch and process for making same |
GB2214918B (en) * | 1988-02-03 | 1992-10-07 | Warner Lambert Co | Polymeric materials made from starch and at least one synthetic thermoplastic polymeric material |
US5095054A (en) * | 1988-02-03 | 1992-03-10 | Warner-Lambert Company | Polymer compositions containing destructurized starch |
DE3939721C2 (de) * | 1988-12-05 | 2002-08-01 | Nippon Synthetic Chem Ind | Polyvinylalkohol-Stärke-Film |
US5093393A (en) * | 1989-02-13 | 1992-03-03 | H. B. Fuller Company | Starch-based corrugating adhesive having a polyvinyl alcohol component |
IL93620A0 (en) * | 1989-03-09 | 1990-12-23 | Butterfly Srl | Biodegradable articles based on starch and process for producing them |
IT1234783B (it) * | 1989-05-30 | 1992-05-27 | Butterfly Srl | Procedimento per la produzione di composizioni a base di amido destrutturato e composizioni cosi ottenute |
IT1232910B (it) * | 1989-08-07 | 1992-03-05 | Butterfly Srl | Composizioni polimeriche per la produzione di articoli di materiale plastico biodegradabile e procedimenti per la loro preparazione |
US5409973A (en) * | 1989-08-07 | 1995-04-25 | Butterfly S.R.L. | Polymer composition including destructured starch and an ethylene copolymer |
US5219646A (en) | 1990-05-11 | 1993-06-15 | E. I. Du Pont De Nemours And Company | Polyester blends and their use in compostable products such as disposable diapers |
IT1240503B (it) * | 1990-07-25 | 1993-12-17 | Butterfly Srl | Miscela polimerica amidacea particolarmente per la produzione di film e simili e procedimento per la sua produzione. |
CA2072116C (en) * | 1990-08-30 | 2003-09-23 | Ewart Thomas Cole | Shaped articles as obtained from a thermoplastic starch melt |
US5292782A (en) | 1991-02-20 | 1994-03-08 | Novamont S.P.A. | Biodegradable polymeric compositions based on starch and thermoplastic polymers |
DE4114185C1 (ja) * | 1991-04-30 | 1993-02-04 | Battelle-Institut E.V., 6000 Frankfurt, De | |
IT1256693B (it) | 1992-03-10 | 1995-12-12 | Novamont Spa | Composizione polimerica amidacea filmabile, ed articoli sagomati, particolarmente film e foglie ottenibili da tale composizione, aventi elevato effetto barriera e procedimento relativo. |
US5412005A (en) * | 1991-05-03 | 1995-05-02 | Novamont S.P.A. | Biodegradable polymeric compositions based on starch and thermoplastic polymers |
EP0525245A1 (en) * | 1991-08-01 | 1993-02-03 | NOVAMONT S.p.A. | Disposable absorbent articles |
GB9123997D0 (en) * | 1991-11-12 | 1992-01-02 | Ici Plc | Structure having controlled water resistance |
WO1993015140A1 (en) * | 1992-01-30 | 1993-08-05 | Ppg Industries, Inc. | Starch oil sizing composition and glass fibers treated therewith |
DE4209095A1 (de) * | 1992-03-20 | 1993-09-23 | Henkel Kgaa | Thermoplastisch verarbeitbare werkstoffe auf staerkebasis, daraus gewonnene formteile und verfahren zu ihrer herstellung |
WO1993020141A1 (en) | 1992-03-31 | 1993-10-14 | Parke-Davis & Company | Biodegradable starch derivative compositions |
WO1993020140A1 (en) | 1992-03-31 | 1993-10-14 | Parke-Davis & Company | Biodegradable polymer compositions |
JP2589908B2 (ja) * | 1992-05-13 | 1997-03-12 | 昭和高分子株式会社 | ポリエステル製不織布 |
US6277899B1 (en) * | 1992-08-03 | 2001-08-21 | Novamont S.P.A. | Biodegradable polymeric composition |
US5783126A (en) * | 1992-08-11 | 1998-07-21 | E. Khashoggi Industries | Method for manufacturing articles having inorganically filled, starch-bound cellular matrix |
US5393804A (en) * | 1992-11-24 | 1995-02-28 | Parke, Davis & Company | Biodegradable compositions comprising starch and alkenol polymers |
US5716675A (en) * | 1992-11-25 | 1998-02-10 | E. Khashoggi Industries | Methods for treating the surface of starch-based articles with glycerin |
US5399728A (en) * | 1993-04-05 | 1995-03-21 | Arco Chemical Technology, L.P. | Process for the preparation of highly esterified alkoxylated polyol compositions |
ES2107021T3 (es) * | 1993-05-03 | 1997-11-16 | Stockhausen Chem Fab Gmbh | Composiciones polimericas, fabricacion de las composiciones polimericas, en especial de materiales de absorcion y su utilizacion. |
US5462983A (en) * | 1993-07-27 | 1995-10-31 | Evercorn, Inc. | Biodegradable moldable products and films comprising blends of starch esters and polyesters |
ID23491A (id) | 1994-01-28 | 1995-09-07 | Procter & Gamble | Kopolimer-kopolimer yang dapat dibiodegradasi dan baha-bahan plastik yang terdiri dari kopolimer-kopolimer yang dapat dibiodegradasi |
US6472042B1 (en) * | 1994-02-10 | 2002-10-29 | Dow Global Technologies Inc. | Highly filled thermoplastic compositions |
US5500465A (en) * | 1994-03-10 | 1996-03-19 | Board Of Trustees Operating Michigan State University | Biodegradable multi-component polymeric materials based on unmodified starch-like polysaccharides |
IT1274603B (it) | 1994-08-08 | 1997-07-18 | Novamont Spa | Materiali espansi plastici biodegradabili |
IT1272871B (it) * | 1995-01-10 | 1997-07-01 | Novamont Spa | Composizioni termoplastiche compredenti amido ed altre componenti di origine naturale |
WO1996031561A1 (de) | 1995-04-07 | 1996-10-10 | Biotec Biologische Naturverpackungen Gmbh | Biologisch abbaubare polymermischung |
US20010048176A1 (en) | 1995-04-14 | 2001-12-06 | Hans G. Franke | Resilient biodegradable packaging materials |
JP2740824B2 (ja) * | 1995-08-31 | 1998-04-15 | 工業技術院長 | エステル化澱粉を含む高分子組成物 |
US5756194A (en) * | 1996-01-25 | 1998-05-26 | The United States Of America, As Represented By The Secretary Of Agriculture | Enhanced water resistance of starch-based materials |
JPH09255880A (ja) | 1996-03-22 | 1997-09-30 | Takahashi Seisakusho:Kk | 生分解性プラスチック組成物 |
DE19624641A1 (de) * | 1996-06-20 | 1998-01-08 | Biotec Biolog Naturverpack | Biologisch abbaubarer Werkstoff, bestehend im wesentlichen aus oder auf Basis thermoplastischer Stärke |
US5776619A (en) * | 1996-07-31 | 1998-07-07 | Fort James Corporation | Plate stock |
JP4241930B2 (ja) * | 1996-08-09 | 2009-03-18 | ビオ−テック ビオロギッシェ ナトゥーアフェアパックンゲン ゲゼルシャフト ミット ベシュレンクテル ハフツング ウント コンパニー コマンディートゲゼルシャフト | 熱可塑的に加工可能な澱粉又は澱粉誘導体―ポリマー混合物 |
ATE287928T1 (de) * | 1996-11-05 | 2005-02-15 | Novamont Spa | Biologisch abbaubare polymerzusammensetzungen, die stärke und ein thermoplastisches polymer enthalten |
US6368990B1 (en) | 1997-08-04 | 2002-04-09 | Bba Nonwovens Sweden Ab | Fabrics formed of hollow filaments and fibers and methods of making the same |
IT1303553B1 (it) * | 1998-09-01 | 2000-11-14 | Novamont Spa | Composizioni biodegradabili comprendenti amido ed esteri di cellulosa. |
JP2002527333A (ja) * | 1998-10-13 | 2002-08-27 | ピーピージー インダストリーズ オハイオ, インコーポレイテッド | 含浸ガラス繊維ストランドおよびこれを含む製品 |
IT1307022B1 (it) * | 1999-03-15 | 2001-10-23 | Novamont Spa | Processo semplificato per l'ottenimento di poliesteri alifaticibiodegradabili. |
US6632862B2 (en) * | 1999-04-12 | 2003-10-14 | The United States Of America As Represented By The Secretary Of Agriculture | Biodegradable polymer compositions, methods for making same, and articles therefrom |
FR2792546B1 (fr) * | 1999-04-26 | 2003-01-03 | Rhodia Chimie Sa | Composition solide comprenant au moins un tensioactif a bas point de fusion |
DE19958472A1 (de) * | 1999-12-04 | 2001-06-07 | Henkel Kgaa | Teilchenförmiges Kompositmaterial zur gesteuerten Freisetzung eines Wirkstoffs |
US6605657B1 (en) * | 1999-12-27 | 2003-08-12 | Polyvalor Societe En Commandite | Polymer compositions containing thermoplastic starch |
US6231970B1 (en) * | 2000-01-11 | 2001-05-15 | E. Khashoggi Industries, Llc | Thermoplastic starch compositions incorporating a particulate filler component |
US6797753B2 (en) * | 2000-06-20 | 2004-09-28 | Battelle Memorial Institute | Plasticizers derived from vegetable oils |
EP1176255A1 (en) * | 2000-07-24 | 2002-01-30 | The Dow Chemical Company | Use of starch dispersions as binder in coating compositions and process for preparing the starch dispersions |
EP1321289B1 (en) * | 2000-09-13 | 2006-07-12 | Nissei Kabushiki Kaisha | Biodegradable molded articles, process for producing the same and compositions for foam molding |
US6365642B1 (en) * | 2000-10-10 | 2002-04-02 | The Procter & Gamble Company | Rapid preparation of foam materials from high internal phase emulsions |
US7402618B2 (en) * | 2000-11-23 | 2008-07-22 | Hao Xu | Biodegradable composition for the preparation of tableware, drink container, mulching film and package and method for preparing the same |
US7241832B2 (en) * | 2002-03-01 | 2007-07-10 | bio-tec Biologische Naturverpackungen GmbH & Co., KG | Biodegradable polymer blends for use in making films, sheets and other articles of manufacture |
US6946506B2 (en) * | 2001-05-10 | 2005-09-20 | The Procter & Gamble Company | Fibers comprising starch and biodegradable polymers |
US6783854B2 (en) * | 2001-05-10 | 2004-08-31 | The Procter & Gamble Company | Bicomponent fibers comprising a thermoplastic polymer surrounding a starch rich core |
US20030077444A1 (en) * | 2001-05-10 | 2003-04-24 | The Procter & Gamble Company | Multicomponent fibers comprising starch and polymers |
US6743506B2 (en) * | 2001-05-10 | 2004-06-01 | The Procter & Gamble Company | High elongation splittable multicomponent fibers comprising starch and polymers |
US7077994B2 (en) * | 2001-10-19 | 2006-07-18 | The Procter & Gamble Company | Polyhydroxyalkanoate copolymer/starch compositions for laminates and films |
AT5783U1 (de) * | 2001-11-06 | 2002-11-25 | Avl List Gmbh | Verfahren zur durchführung einer internen abgasrückführung in den brennraum einer brennkraftmaschine |
JP3688627B2 (ja) | 2001-11-07 | 2005-08-31 | 株式会社ナード研究所 | 耐水性澱粉組成物およびその発泡体 |
US6699363B2 (en) * | 2001-11-13 | 2004-03-02 | E. I. Du Pont De Nemours And Company | Modified starch and process therefor |
KR20040078106A (ko) * | 2001-11-28 | 2004-09-08 | 제임스 하디 리서치 피티와이 리미티드 | 접착성-주연부를 갖는 건축용 패널 및 그 제조방법 |
US6787489B2 (en) * | 2001-12-12 | 2004-09-07 | Multisorb Technologies, Inc. | Absorbent mixture and product |
KR20030061675A (ko) * | 2002-01-11 | 2003-07-22 | 뉴 아이스 리미티드 | 생분해성 또는 부패성 컨테이너 |
DE10202390A1 (de) * | 2002-01-23 | 2003-09-25 | Henkel Kgaa | Kombination von Cellulasen und spezieller Cellulose in Waschmitteln |
US6723160B2 (en) * | 2002-02-01 | 2004-04-20 | The Procter & Gamble Company | Non-thermoplastic starch fibers and starch composition for making same |
FI113875B (fi) | 2002-02-15 | 2004-06-30 | Valtion Teknillinen | Uudet tärkkelysjohdannaiset ja menetelmä niiden valmistamiseksi |
JP3421769B1 (ja) * | 2002-04-02 | 2003-06-30 | 大八化学工業株式会社 | エステル化合物、生分解性脂肪族系ポリエステル樹脂用可塑剤及び生分解性樹脂組成物 |
EP1354512A1 (en) * | 2002-04-19 | 2003-10-22 | Coöperatieve Verkoop- en Productievereniging van Aardappelmeel en Derivaten 'AVEBE' B.A. | Pet's chew |
ITMI20020864A1 (it) * | 2002-04-22 | 2003-10-22 | Novamont Spa | Copolimeri a blocchi amorfo-cristallini |
ATE387191T1 (de) | 2002-04-25 | 2008-03-15 | Banner Pharmacaps Inc | Kaubare weichkapsel |
US20030207038A1 (en) * | 2002-05-03 | 2003-11-06 | Inkwan Han | Coatings for food service articles |
US7998712B2 (en) * | 2002-09-13 | 2011-08-16 | Suntory Holdings Limited | Process for production of transesterified oils/fats or triglycerides |
FI113874B (fi) * | 2002-09-27 | 2004-06-30 | Valtion Teknillinen | Polymeeriliuokset ja -dispersiot ja menetelmä niiden valmistamiseksi |
US6830810B2 (en) * | 2002-11-14 | 2004-12-14 | The Procter & Gamble Company | Compositions and processes for reducing water solubility of a starch component in a multicomponent fiber |
US20050205574A1 (en) * | 2002-11-15 | 2005-09-22 | Alexander Lambotte | Water-soluble portion packaging with a filling |
FR2848560B1 (fr) * | 2002-12-12 | 2006-12-08 | Oreal | Polymere acrylique, dispersion dudit polymere stable dans un milieu organique non aqueux silicone et composition comprenant ladite dispersion. |
US7071248B2 (en) * | 2003-01-21 | 2006-07-04 | Ashland Licensing And Intellectual Property, Llc | Adhesive additives and adhesive compositions containing an adhesive additive |
KR100574547B1 (ko) * | 2003-03-21 | 2006-04-27 | 율촌화학 주식회사 | 내수성이 개선된 생분해성 조성물 및 그 제조방법 |
DE10313939A1 (de) * | 2003-03-27 | 2004-10-14 | Wacker Polymer Systems Gmbh & Co. Kg | Verwendung von Polymerisaten zur Stärkemodifizierung |
US7041239B2 (en) * | 2003-04-03 | 2006-05-09 | Valence Technology, Inc. | Electrodes comprising mixed active particles |
US7098292B2 (en) * | 2003-05-08 | 2006-08-29 | The Procter & Gamble Company | Molded or extruded articles comprising polyhydroxyalkanoate copolymer and an environmentally degradable thermoplastic polymer |
JP2005041129A (ja) | 2003-07-23 | 2005-02-17 | Murakami Corporation Co | 澱粉系組成物を用いた食品容器の製造方法および澱粉系組成物を用いた食品容器 |
EP1523892A1 (en) * | 2003-10-17 | 2005-04-20 | Paragon Products B.V. i.o. | Pet's chew |
WO2005075725A1 (en) * | 2004-01-30 | 2005-08-18 | The Procter & Gamble Company | Shaped fiber fabrics |
HN2004000023A (es) * | 2004-03-22 | 2007-11-23 | Mars Inc | Mascadura para animales |
CN101203555A (zh) * | 2005-05-06 | 2008-06-18 | 太尔公司 | 基于聚乙烯醇且不含甲醛的可固化含水组合物 |
JP2006335874A (ja) * | 2005-06-02 | 2006-12-14 | Kao Corp | 生分解性樹脂用可塑剤 |
US20070082982A1 (en) * | 2005-10-11 | 2007-04-12 | The Procter & Gamble Company | Water stable compositions and articles comprising starch and methods of making the same |
-
2006
- 2006-10-10 US US11/545,263 patent/US20070082982A1/en not_active Abandoned
- 2006-10-10 US US11/545,262 patent/US8435354B2/en not_active Expired - Fee Related
- 2006-10-10 US US11/545,264 patent/US20070079945A1/en not_active Abandoned
- 2006-10-10 US US11/545,265 patent/US20070082573A1/en not_active Abandoned
- 2006-10-11 JP JP2008535644A patent/JP5303275B2/ja not_active Expired - Fee Related
- 2006-10-11 WO PCT/US2006/039710 patent/WO2007044803A1/en active Application Filing
- 2006-10-11 CN CN2006800373833A patent/CN101283124B/zh not_active Expired - Fee Related
- 2006-10-11 CA CA 2625237 patent/CA2625237C/en not_active Expired - Fee Related
- 2006-10-11 DE DE200660016972 patent/DE602006016972D1/de active Active
- 2006-10-11 AT AT06816702T patent/ATE449875T1/de not_active IP Right Cessation
- 2006-10-11 CA CA 2625248 patent/CA2625248C/en not_active Expired - Fee Related
- 2006-10-11 AT AT06816703T patent/ATE505570T1/de not_active IP Right Cessation
- 2006-10-11 DE DE200660007724 patent/DE602006007724D1/de active Active
- 2006-10-11 CN CN2006800377637A patent/CN101283034B/zh not_active Expired - Fee Related
- 2006-10-11 CA CA 2625209 patent/CA2625209C/en not_active Expired - Fee Related
- 2006-10-11 DE DE200660010724 patent/DE602006010724D1/de active Active
- 2006-10-11 EP EP20060816703 patent/EP1934390B1/en not_active Not-in-force
- 2006-10-11 CN CNA2006800377444A patent/CN101283033A/zh active Pending
- 2006-10-11 WO PCT/US2006/039709 patent/WO2007044802A1/en active Application Filing
- 2006-10-11 JP JP2008535646A patent/JP5475287B2/ja not_active Expired - Fee Related
- 2006-10-11 AT AT06825757T patent/ATE481450T1/de not_active IP Right Cessation
- 2006-10-11 WO PCT/US2006/039708 patent/WO2007044801A1/en active Application Filing
- 2006-10-11 EP EP20060816704 patent/EP1934280B1/en not_active Not-in-force
- 2006-10-11 AT AT06816704T patent/ATE435886T1/de not_active IP Right Cessation
- 2006-10-11 EP EP20060816702 patent/EP1934389B1/en not_active Not-in-force
- 2006-10-11 DE DE200660021330 patent/DE602006021330D1/de active Active
- 2006-10-11 CN CNA2006800371503A patent/CN101283123A/zh active Pending
- 2006-10-11 JP JP2008535647A patent/JP5281893B2/ja not_active Expired - Fee Related
- 2006-10-11 WO PCT/US2006/039707 patent/WO2007044800A1/en active Application Filing
- 2006-10-11 EP EP20060825757 patent/EP1937768B1/en not_active Not-in-force
- 2006-10-11 JP JP2008535645A patent/JP5281892B2/ja not_active Expired - Fee Related
- 2006-10-11 CA CA 2625240 patent/CA2625240C/en not_active Expired - Fee Related
-
2012
- 2012-05-07 US US13/466,052 patent/US20120216709A1/en not_active Abandoned
- 2012-07-18 US US13/552,362 patent/US8530557B2/en not_active Expired - Fee Related
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5303275B2 (ja) | デンプンを含む水安定性繊維及び物品並びにその製造方法 | |
US9925706B2 (en) | Process of producing a melt-spinnable fiber using thermoplastic polymer and destructured starch | |
JP4118879B2 (ja) | 多構成成分繊維中のデンプン構成成分の水溶解度を減少するための組成物及び方法 | |
JP4119756B2 (ja) | デンプン及び生分解性ポリマーを含む繊維 | |
JP4119260B2 (ja) | デンプン及び生分解性ポリマーを含む多成分繊維 | |
JP4181549B2 (ja) | 溶解可能なデンプン構成成分を含む多構成成分繊維、そのための方法、及びそれからの繊維 | |
JP4098304B2 (ja) | デンプンを多く含むコアを取り囲む熱可塑性ポリマーを含む二成分繊維 | |
JP4100516B2 (ja) | デンプン及びポリマーを含む高伸長多成分繊維 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20110325 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110329 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20110629 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20110706 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20110729 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20110805 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20110829 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20110905 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110929 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20120518 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20120820 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20120827 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20120914 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20120924 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20121018 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20121025 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20121116 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20130524 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20130624 |
|
R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |