JP5251518B2 - 粘着剤組成物及び粘着剤付き光学フィルム - Google Patents
粘着剤組成物及び粘着剤付き光学フィルム Download PDFInfo
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- JP5251518B2 JP5251518B2 JP2008555033A JP2008555033A JP5251518B2 JP 5251518 B2 JP5251518 B2 JP 5251518B2 JP 2008555033 A JP2008555033 A JP 2008555033A JP 2008555033 A JP2008555033 A JP 2008555033A JP 5251518 B2 JP5251518 B2 JP 5251518B2
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- 235000011121 sodium hydroxide Nutrition 0.000 description 1
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- 238000012916 structural analysis Methods 0.000 description 1
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- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
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- GYZQBXUDWTVJDF-UHFFFAOYSA-N tributoxy(methyl)silane Chemical compound CCCCO[Si](C)(OCCCC)OCCCC GYZQBXUDWTVJDF-UHFFFAOYSA-N 0.000 description 1
- UCSBCWBHZLSFGC-UHFFFAOYSA-N tributoxysilane Chemical compound CCCCO[SiH](OCCCC)OCCCC UCSBCWBHZLSFGC-UHFFFAOYSA-N 0.000 description 1
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 description 1
- UDUKMRHNZZLJRB-UHFFFAOYSA-N triethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OCC)(OCC)OCC)CCC2OC21 UDUKMRHNZZLJRB-UHFFFAOYSA-N 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- OZWKZRFXJPGDFM-UHFFFAOYSA-N tripropoxysilane Chemical compound CCCO[SiH](OCCC)OCCC OZWKZRFXJPGDFM-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/625—Polymers of alpha-beta ethylenically unsaturated carboxylic acids; hydrolyzed polymers of esters of these acids
- C08G18/6254—Polymers of alpha-beta ethylenically unsaturated carboxylic acids and of esters of these acids containing hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
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Description
即ち、従来から粘着剤分野で用いられているシラン化合物乃至オルガノポリシロキサンは、分子内にメトキシ基及び/又はエトキシ基を有するものが多かったが、この場合は、その加水分解性が十分にコントロールできず、保存安定性に問題があった。特にアクリル系粘着剤には、水分が含まれるため、シラン化合物を含む粘着剤を長期間、粘着剤としての性質を安定させることは困難であった。そこで、加水分解反応性の高いメトキシ基やエトキシ基と、加水分解反応性の低いプロポキシ基やブトキシ基等の炭素原子数3及び/又は4のアルコキシ基とを同一分子内に含有させることによって、シラン化合物の加水分解反応性を任意に変化させることができるオルガノポリシロキサンを見出した。従って、かかるオルガノポリシロキサンをアクリル樹脂及び架橋剤とともに配合した粘着剤組成物は、加水分解するアルコキシ基の量が長期にわたり一定に保たれるため、性能が安定している。
また、上記のオルガノポリシロキサンは、シランカップリング剤としての効果があり、ガラス及びアクリル樹脂との親和性が高いため、それを配分した粘着剤組成物から形成される粘着剤層が設けられた粘着剤付き光学フィルムは、その粘着剤層側でガラス基板に貼り合わせたときに、粘着剤層とガラス基板との間の浮きや剥れ等が抑制される。更にこのオルガノポリシロキサンは、シリコーン系剥離剤としての効果も発現するため、それを配合した粘着剤組成物から形成される粘着剤層が設けられた粘着剤付き光学フィルムは、ガラス基板に貼り付けたときのリワーク性にも優れるものとなることを知見し、本発明をなすに至った。
(1)(A)アクリル樹脂、
(B)架橋剤、及び
(C)下記平均組成式(I)
YaR1 bSi(OCH3)c(OC2H5)d(OR2)e(OH)fO(4-a-b-c-d-e-f)/2
…(I)
(式中、Yはメルカプト基、エポキシ基、(メタ)アクリロイロキシ基、アルケニル基、ハロアルキル基及びアミノ基から選ばれる少なくとも1種を有する有機基を表し;
R1は少なくとも1種の脂肪族不飽和結合を有さない炭素原子数1〜8の非置換の一価炭化水素基を表し;
R2は炭素原子数3及び/又は4のアルキル基あるいはメトキシプロピル基を表し;
a、b、c、d、e及びfは、0.01≦a≦1、0≦b<2、0<c≦2、0≦d≦2、0<e≦2、0≦f≦1であって、かつ0.1≦c+d+e≦2.5及び2≦a+b+c+d+e+f≦3を満たす数である。)
で表されるオルガノポリシロキサン
を含有することを特徴とする粘着剤組成物。
(2)アクリル樹脂(A)は、(メタ)アクリル酸アルキルエステルに由来する構造単位を主成分とし、極性官能基を有する(メタ)アクリル酸系化合物に由来する構造単位を含むアクリル樹脂を含有する(1)に記載の粘着剤組成物。
(3)極性官能基は、遊離カルボキシル基、水酸基、アミノ基及びエポキシ環から選ばれるものである(2)に記載の粘着剤組成物。
(4)架橋剤(B)は、イソシアネート系化合物を含む(1)〜(3)のいずれかに記載の粘着剤組成物。
(5)オルガノポリシロキサン(C)を表す前記平均組成式(I)において、Yがメルカプト基又はエポキシ基を有する有機基である(1)〜(4)のいずれかに記載の粘着剤組成物。
(6)オルガノポリシロキサン(C)を表す前記平均組成式(I)において、bが正数で、R1がメチル基であり、R2がプロピル基又はイソプロピル基である(1)〜(5)のいずれかに記載の粘着剤組成物。
(7)オルガノポリシロキサン(C)を表す前記平均組成式(I)において、dが正数である(1)〜(6)のいずれかに記載の粘着剤組成物。
(8)オルガノポリシロキサン(C)は、その平均重合度が3〜100である(1)〜(7)のいずれかに記載の粘着剤組成物。
(9)光学フィルムの少なくとも一方の面に、(1)〜(8)のいずれかに記載の粘着剤組成物から形成される粘着剤層が設けられていることを特徴とする粘着剤付き光学フィルム。
(10)光学フィルムは、偏光フィルム及び位相差フィルムから選ばれる(9)に記載の粘着剤付き光学フィルム。
(11)光学フィルムは、偏光子の少なくとも一方の面にアセチルセルロース系樹脂又は非晶性環状ポリオレフィン系樹脂からなる保護フィルムが貼着された偏光フィルムを含む(10)に記載の粘着剤付き光学フィルム。
本発明に用いられるアクリル樹脂は、具体的には(メタ)アクリル酸アルキルエステルに由来する構造単位を主成分とし、遊離カルボキシル基、水酸基、アミノ基、エポキシ環をはじめとする複素環基等の極性官能基を有するモノマー、好ましくは極性官能基を有する(メタ)アクリル酸系化合物に由来する構造単位を含むアクリル樹脂(A−1)であることが好ましい。ここで、(メタ)アクリル酸とは、アクリル酸又はメタクリル酸のいずれでもよいことを意味し、他に、(メタ)アクリレート等というときの「(メタ)」も同様の趣旨である。また、ここでのアルキル基は脂環式構造を有するアルキル基(シクロアルキル基)は含まない。
本発明の粘着剤組成物においては、以上のようなアクリル樹脂に、更に架橋剤を配合する。架橋剤は、極性官能基と架橋しうる官能基を分子内に少なくとも2個有する化合物であって、具体的には例えば、イソシアネート系化合物、エポキシ系化合物、金属キレート化合物、アジリジン系化合物等を挙げることができる。
本発明では更に、有機官能基及び炭素原子数が異なる複数種のアルコキシ基を一分子内に含有する下記平均組成式(I)で表されるオルガノポリシロキサンを配合する。
YaR1 bSi(OCH3)c(OC2H5)d(OR2)e(OH)fO(4-a-b-c-d-e-f)/2
…(I)
有機官能基及び炭素原子数が異なる複数種のアルコキシ基を一分子内に含有するオルガノポリシロキサンは、従来公知の各種処方によって製造することができ、一般的な手段としては、例えば、次のような方法を挙げることができる。
(2)有機官能基を含有するアルコキシシラン及びそれとは炭素原子数が異なるアルコキシ基を含有し、有機官能基を含有しないアルコキシシランを、部分共加水分解・重縮合する方法、
(3)同様の部分加水分解・重縮合操作によって得られた有機官能基とメトキシ基及び/又はエトキシ基とを含有するオルガノポリシロキサンに、炭素原子数3及び/又は4のアルコールとのエステル交換反応により、炭素原子数3及び/又は4のアルコキシ基を導入する方法等。
R1 pSi(OCH3)q(OC2H5)r(OR2)4-p-q-r …(III)
本発明においては、上記で説明したようなアクリル樹脂に、同じく上記で説明したような架橋剤及びオルガノポリシロキサンを配合して、粘着剤組成物とする。架橋剤は、粘着剤組成物を構成するアクリル樹脂100質量部(2種類以上用いる場合はその合計量)に対して、通常0.1〜10質量部程度、好ましくは0.1〜7質量部程度、更に好ましくは0.2〜3質量部程度の割合で配合される。アクリル樹脂100質量部に対する架橋剤の量が0.1質量部以上であると、粘着剤層の耐久性が向上する傾向にあることから好ましい。また、その量が10質量部以下であると、粘着剤付き光学フィルムを液晶表示装置に適用したときのいわゆる白抜けが目立たなくなることから好ましい。
本発明の粘着剤付き光学フィルムは、光学フィルムの少なくとも一方の面に、以上のような粘着剤組成物から形成される粘着剤層を設けたものである。ここで用いる光学フィルムとは、光学特性を有するフィルムであり、例えば、偏光フィルム、位相差フィルム等が挙げられる。
ゲルパーミエーションクロマトグラフィー(GPC)分析により、ポリスチレン標準サンプルから作成した検量線を基準として重量平均分子量を求め、更にそれから平均重合度を算出した。
アルカリクラッキング−ガスクロマトグラフィー(GC)分析法〔シリコーンハンドブック、792〜793頁(1990年,日刊工業新聞社発行)参照〕により、アルコキシ基含有量を測定し、前記平均組成式(I)における係数c、d及びeを決定した。
ケイ素核磁気共鳴スペクトル(29Si−NMR)分析及びプロトン核磁気共鳴スペクトル(1H−NMR)分析により行い、測定結果より前記平均組成式(I)における係数a、b及びfを決定した。
酢酸/ヨウ化カリウム/ヨウ素酸カリウム添加−チオ硫酸ナトリウム溶液滴定法〔分析化学便覧、改訂二版、432〜433頁(1976年,丸善株式会社発行)参照〕に準拠して測定した。
JIS K 8803に準じた方法により25℃における粘度を測定した。
[重合例1]
冷却管、窒素導入管、温度計及び撹拌機を備えた反応器に、酢酸エチル81.8部、アクリル酸ブチル98.9部及びアクリル酸1.1部の混合溶液を仕込み、窒素ガスで装置内の空気を置換して酸素不含としながら、内温を55℃に上げた。その後、アゾビスイソブチロニトリル(重合開始剤)0.14部を酢酸エチル10部に溶かした溶液を全量添加した。開始剤添加1時間後に、モノマーを除くアクリル樹脂の濃度が35%になるよう、添加速度17.3部/hrで酢酸エチルを連続的に反応器に添加しながら、内温54〜56℃で12時間保温し、最後に酢酸エチルを添加して、アクリル樹脂の濃度が20%となるように調節した。得られたアクリル樹脂は、GPCによるポリスチレン換算の重量平均分子量Mwが1,670,000、Mw/Mnが4.4であった。これをアクリル樹脂A1とする。
モノマー組成を、アクリル酸ブチル98.8部、アクリル酸2−ヒドロキシエチル1.0部及びアクリル酸0.2部に変更した以外は、重合例1と同様にしてアクリル樹脂溶液を得た。得られたアクリル樹脂は、GPCによるポリスチレン換算の重量平均分子量Mwが1,470,000、Mw/Mnが4.2であった。これをアクリル樹脂A2とする。
[オルガノポリシロキサン合成例1]
撹拌装置、冷却コンデンサー、温度計及び滴下ロートを取り付けた容量1Lのフラスコに、テトラエトキシシラン62.5g(0.3モル)、テトラプロポキシシラン52.9g(0.2モル)、エタノール62.5g及びイソプロピルアルコール52.9gを仕込み、撹拌混合しながらオイルバス中で加熱して内温を50℃まで昇温した。フラスコ内を撹拌しながら、0.1N塩酸水溶液7.2g(水:0.4モル、塩化水素:7.2×10-4モル)とエタノール7.2gとの混合溶液を10分間かけて滴下し、更に昇温して還流下で2時間熟成して予備加水分解反応液C11を得た。
引き続き、常圧下で内温を80℃まで昇温しながらアルコール成分を留去し、更に30Torr(約4kPa)の減圧条件下に、内温を100℃まで昇温して残存アルコール成分と低沸点成分を留去した後、濾過を行って無色透明液状のオルガノポリシロキサンC1を得た(収量:127.5g、収率:92%)。
原料モル比:
HS(CH2)3Si(OCH3)3/CH3Si(OCH3)3/
Si(OC2H5)4/Si(OC3H7)4=0.2/0.3/0.3/0.2
触媒:HCl/KF/水=0.00162/0.00162/0.9
重量平均分子量:1,400
平均重合度:10.1
平均組成式:
[HS(CH2)3]0.2(CH3)0.3Si(OCH3)0.52(OC2H5)0.71
(OC3H7)0.49O0.89
メルカプト基当量:測定値696g/モル、理論値693g/モル
粘度:21.0mm2/s
撹拌装置、冷却コンデンサー、温度計及び滴下ロートを取り付けた容量1Lのフラスコに、テトラエトキシシラン41.7g(0.2モル)、テトラプロポキシシラン79.3g(0.3モル)、エタノール41.7g及びイソプロピルアルコール79.3gを仕込み、撹拌混合しながらオイルバス中で加熱して内温を50℃まで昇温した。フラスコ内を撹拌しながら、0.5N塩酸水溶液7.2g(水:0.4モル、塩化水素:3.6×10-3モル)とエタノール7.2gとの混合溶液を10分間かけて滴下し、更に昇温して還流下で2時間熟成して予備加水分解反応液C21を得た。
引き続き、常圧下で内温を80℃まで昇温しながらアルコール成分を留去し、更に30Torr(約4kPa)の減圧条件下に、内温を100℃まで昇温して残存アルコール成分と低沸点成分を留去した後、濾過を行って無色透明液状のオルガノポリシロキサンC2を得た(収量:136.7g、収率:94%)。
原料モル比:
HS(CH2)3Si(OC2H5)3/CH3Si(OCH3)3/
Si(OC2H5)4/Si(OC3H7)4=0.2/0.3/0.2/0.3
触媒:HCl/KF/水=0.0081/0.0081/0.9
重量平均分子量:1,460
平均重合度:10.0
平均組成式:
[HS(CH2)3]0.2(CH3)0.3Si(OCH3)0.3(OC2H5)0.63
(OC3H7)0.78O0.895
メルカプト基当量:測定値741g/モル、理論値728g/モル
粘度:22.5mm2/s
撹拌装置、冷却コンデンサー、温度計及び滴下ロートを取り付けた容量1Lのフラスコに、3−メルカプトプロピルトリメトキシシラン39.3g(0.2モル)、メチルトリメトキシシラン40.9g(0.3モル)、テトラエトキシシラン104.2g(0.5モル)、メタノール80.2g及びエタノール104.2gを仕込み、内温20〜30℃でフラスコ内を撹拌しながら、0.1N塩酸水溶液16.2g(水:0.9モル、塩化水素:1.62×10-3モル)とメタノール16.2gとの混合溶液を30分間かけて滴下し、更に昇温して還流下で2時間熟成を行った。
原料モル比:
HS(CH2)3Si(OCH3)3/CH3Si(OCH3)3/Si(OC2H5)4
=0.2/0.3/0.5
触媒:HCl/KF/水=0.00162/0.00162/0.9
重量平均分子量:1,380
平均重合度:10.6
平均組成式:
[HS(CH2)3]0.2(CH3)0.3Si(OCH3)0.61(OC2H5)1.08O0.905
メルカプト基当量:測定値638g/モル、理論値651g/モル
粘度:20.5mm2/s
撹拌装置、冷却コンデンサー、温度計及び滴下ロートを取り付けた容量1Lのフラスコに、テトラプロポキシシラン132.2g(0.5モル)及びイソプロピルアルコール132.2gを仕込み、撹拌混合しながらオイルバス中で加熱して内温を50℃まで昇温した。フラスコ内を撹拌しながら、1N塩酸水溶液7.2g(水:0.4モル、塩化水素:7.2×10-3モル)とイソプロピルアルコール7.2gとの混合溶液を10分間かけて滴下し、更に昇温して還流下で2時間熟成して予備加水分解反応液C41を得た。
引き続き、常圧下で内温を80℃まで昇温しながらアルコール成分を留去し、更に30Torr(約4kPa)の減圧条件下に、内温を100℃まで昇温して残存アルコール成分と低沸点成分を留去した後、濾過を行って無色透明液状のオルガノポリシロキサンC4を得た(収量:140.8g、収率:90%)。
原料モル比:
HS(CH2)3Si(OC2H5)3/CH3Si(OC2H5)3/
CH3Si(OC3H7)3/Si(OC3H7)4=0.2/0.1/0.2/0.5
触媒:HCl/KF/水=0.0162/0.0162/0.9
重量平均分子量:1,620
平均重合度:10.3
平均組成式:
[HS(CH2)3]0.2(CH3)0.3Si(OC2H5)0.39(OC3H7)1.31O0.9
メルカプト基当量:測定値803g/モル、理論値785g/モル
粘度:33.6mm2/s
“コロネートL”:トリレンジイソシアネートのトリメチロールプロパンアダクト体の酢酸エチル溶液(固形分濃度75%)、日本ポリウレタン工業(株)製商品名
“TAZM”:トリメチロールプロパン トリ−β−アジリジニルプロピオネート(液体)、相互薬工(株)製商品名
“KBM−803”:3−メルカプトプロピルトリメトキシシラン(液体)、信越化学工業(株)製商品名
“KBM−303”:2−(3,4−エポキシシクロヘキシル)エチルトリメトキシシラン(液体)、信越化学工業(株)製商品名
(a)粘着剤の製造
重合例1で得たアクリル樹脂A1の酢酸エチル溶液又は重合例2で得たアクリル樹脂A2の酢酸エチル溶液をそれぞれ不揮発分で100部用い、そこに架橋剤として、“コロネートL”を、又は“コロネートL”と“TAZM”を、それぞれ表1に示す量、及び表1に示すオルガノポリシロキサン又はシラン化合物をそれぞれ表1に示す量混合し、粘着剤組成物を調製した。但し、表1中、架橋剤“コロネートL”の配合量(部)は、固形分の量である。
上記の各粘着剤組成物を、離型処理されたポリエチレンテレフタレートフィルム(“PET 3811”、リンテック(株)製商品名;セパレーターと呼ぶ)の離型処理面に、アプリケーターを用いて乾燥後の厚さが15μmとなるように塗布し、90℃で1分間乾燥させ、シート状の粘着剤を得た。次いで、ヨウ素が吸着配向したポリビニルアルコール偏光子の両面をトリアセチルセルロースからなる保護フィルムで挟んだ3層構造の偏光フィルムの片面に、上記で得たシート状粘着剤のセパレーターと反対側の面(粘着剤面)をラミネーターにより貼り合わせたのち、温度23℃、相対湿度65%の条件で7日間熟成させ、粘着剤付き偏光フィルムを得た。また、それらの粘着剤付き偏光フィルムをアルミニウム箔付きパックで密閉し、温度60℃で更に6日間熟成させ、熱による経時変化を促進させた。
上記(b)で作製した粘着剤付き偏光フィルム(23℃×65%RH×7日間熟成したもの、及びその後更に60℃×6日間熟成したもの)を、液晶セル用ガラス基板(“1737”、コーニング社製商品名)の両面にクロスニコルとなるよう、それぞれ粘着剤層側で貼着し、光学積層体を作製した。
上記(c)で得られた光学積層体について、温度80℃の乾燥条件下で300時間保管する耐熱試験を行い、また温度60℃、相対湿度90%で300時間保管する耐湿熱試験を行い、それぞれ試験後の光学積層体を目視で観察し、以下の4段階で評価した。結果を表2にまとめた。
〈耐熱性及び耐湿熱性の評価基準〉
◎:浮き、剥れ、発泡等の外観変化が全くみられない。
○:浮き、剥れ、発泡等の外観変化がほとんどみられない。
△:浮き、剥れ、発泡等の外観変化がやや目立つ。
×:浮き、剥れ、発泡等の外観変化が顕著に認められる。
リワーク性の評価は次のように行った。まず、(b)で作製した粘着剤付き偏光フィルム(23℃×65%RH×7日間熟成したもの、及びその後更に60℃×6日間熟成したもの)をそれぞれ25mm×150mmの大きさの試験片に裁断した。次に、この試験片をその粘着剤層側で、貼付装置(“ラミパッカー”、フジプラ(株)製商品名)を用いて液晶セル用ガラス基板に貼り付け、50℃、5kgf/cm2(490.3kPa)で20分間オートクレーブ処理を行った。次に、温度23℃、相対湿度50%の雰囲気中にて24時間保管したサンプルと、50℃のオーブン中にて48時間保管したサンプルとの2種類を作製し、温度23℃、相対湿度50%の雰囲気中にて、この貼着試験片から偏光フィルムを300mm/分の速度で180°方向に剥離し、それぞれのガラス基板表面の状態を観察して、以下の基準で評価した。結果を、併せて表2に示した。
〈リワーク性評価基準〉
◎:ガラス板表面に曇り等が全く認められない。
○:ガラス板表面に曇り等がほとんど認められない。
△:ガラス板表面に曇り等が認められる。
×:ガラス板表面に粘着剤の残りが認められる。
Claims (11)
- (A)アクリル樹脂、
(B)架橋剤、及び
(C)下記平均組成式(I)
YaR1 bSi(OCH3)c(OC2H5)d(OR2)e(OH)fO(4-a-b-c-d-e-f)/2
…(I)
(式中、Yはメルカプト基、エポキシ基、(メタ)アクリロイロキシ基、アルケニル基、ハロアルキル基及びアミノ基から選ばれる少なくとも1種を有する有機基を表し;
R1は少なくとも1種の脂肪族不飽和結合を有さない炭素原子数1〜8の非置換の一価炭化水素基を表し;
R2は炭素原子数3及び/又は4のアルキル基あるいはメトキシプロピル基を表し;
a、b、c、d、e及びfは、0.01≦a≦1、0≦b<2、0<c≦2、0≦d≦2、0<e≦2、0≦f≦1であって、かつ0.1≦c+d+e≦2.5及び2≦a+b+c+d+e+f≦3を満たす数である。)
で表されるオルガノポリシロキサン
を含有することを特徴とする粘着剤組成物。 - アクリル樹脂(A)は、(メタ)アクリル酸アルキルエステルに由来する構造単位を主成分とし、極性官能基を有する(メタ)アクリル酸系化合物に由来する構造単位を含むアクリル樹脂を含有する請求項1に記載の粘着剤組成物。
- 極性官能基は、遊離カルボキシル基、水酸基、アミノ基及びエポキシ環から選ばれるものである請求項2に記載の粘着剤組成物。
- 架橋剤(B)は、イソシアネート系化合物を含む請求項1〜3のいずれかに記載の粘着剤組成物。
- オルガノポリシロキサン(C)を表す前記平均組成式(I)において、Yがメルカプト基又はエポキシ基を有する有機基である請求項1〜4のいずれかに記載の粘着剤組成物。
- オルガノポリシロキサン(C)を表す前記平均組成式(I)において、bが正数で、R1がメチル基であり、R2がプロピル基又はイソプロピル基である請求項1〜5のいずれかに記載の粘着剤組成物。
- オルガノポリシロキサン(C)を表す前記平均組成式(I)において、dが正数である請求項1〜6のいずれかに記載の粘着剤組成物。
- オルガノポリシロキサン(C)は、その平均重合度が3〜100である請求項1〜7のいずれかに記載の粘着剤組成物。
- 光学フィルムの少なくとも一方の面に、請求項1〜8のいずれかに記載の粘着剤組成物から形成される粘着剤層が設けられていることを特徴とする粘着剤付き光学フィルム。
- 光学フィルムは、偏光フィルム及び位相差フィルムから選ばれる請求項9に記載の粘着剤付き光学フィルム。
- 光学フィルムは、偏光子の少なくとも一方の面にアセチルセルロース系樹脂又は非晶性環状ポリオレフィン系樹脂からなる保護フィルムが貼着された偏光フィルムを含む請求項10に記載の粘着剤付き光学フィルム。
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JP5349019B2 (ja) * | 2007-12-27 | 2013-11-20 | 日本合成化学工業株式会社 | 光学部材用粘着剤組成物、光学部材用粘着剤及び粘着剤層付き光学部材 |
US9243168B2 (en) * | 2009-12-14 | 2016-01-26 | Cheil Industries, Inc. | Adhesive composition and optical member using the same |
JP5889035B2 (ja) | 2012-02-22 | 2016-03-22 | リンテック株式会社 | 粘着シート |
JP5951323B2 (ja) * | 2012-04-04 | 2016-07-13 | 日東電工株式会社 | 光学フィルム用粘着剤組成物、光学フィルム用粘着剤層、粘着剤層付光学フィルムおよび画像表示装置 |
JP5765303B2 (ja) * | 2012-08-20 | 2015-08-19 | 信越化学工業株式会社 | 光学用感圧接着剤組成物 |
JP5988889B2 (ja) * | 2013-02-15 | 2016-09-07 | リンテック株式会社 | 粘着性組成物、粘着剤および粘着シート |
JP2016014827A (ja) * | 2014-07-03 | 2016-01-28 | チェイル インダストリーズ インコーポレイテッド | 光学フィルム(film)用粘着剤、光学フィルム、及び表示装置 |
US9725552B2 (en) | 2014-10-14 | 2017-08-08 | Industrial Technology Research Institute | HMF-based phenol formaldehyde resin |
JP6721341B2 (ja) * | 2016-01-13 | 2020-07-15 | 住友化学株式会社 | 粘着剤組成物 |
KR102358556B1 (ko) * | 2016-08-17 | 2022-02-04 | 미쯔비시 케미컬 주식회사 | 아크릴계 점착제 조성물, 및 이를 사용하여 이루어진 점착제, 편광판용 점착제, 및 화상 표시장치 |
JP6502999B2 (ja) * | 2017-04-17 | 2019-04-17 | リンテック株式会社 | 粘着性組成物、粘着剤および粘着シート |
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