JP5162679B2 - ビトリファイド超砥粒加工工具および製造方法 - Google Patents
ビトリファイド超砥粒加工工具および製造方法 Download PDFInfo
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- JP5162679B2 JP5162679B2 JP2011005264A JP2011005264A JP5162679B2 JP 5162679 B2 JP5162679 B2 JP 5162679B2 JP 2011005264 A JP2011005264 A JP 2011005264A JP 2011005264 A JP2011005264 A JP 2011005264A JP 5162679 B2 JP5162679 B2 JP 5162679B2
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- abrasive wheel
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- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 238000003754 machining Methods 0.000 title description 2
- 239000011230 binding agent Substances 0.000 claims description 47
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 29
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims description 16
- 239000011521 glass Substances 0.000 claims description 16
- 239000011787 zinc oxide Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 12
- 239000000945 filler Substances 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 238000000465 moulding Methods 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 239000010432 diamond Substances 0.000 description 24
- 229910003460 diamond Inorganic materials 0.000 description 24
- 239000000463 material Substances 0.000 description 22
- 238000000227 grinding Methods 0.000 description 20
- 239000000203 mixture Substances 0.000 description 18
- 238000010304 firing Methods 0.000 description 14
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 239000000919 ceramic Substances 0.000 description 10
- 238000005520 cutting process Methods 0.000 description 9
- 238000012360 testing method Methods 0.000 description 8
- 229910052582 BN Inorganic materials 0.000 description 6
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 239000006061 abrasive grain Substances 0.000 description 5
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 239000003570 air Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 239000011800 void material Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 239000012080 ambient air Substances 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000000805 composite resin Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 2
- 229910001947 lithium oxide Inorganic materials 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910000480 nickel oxide Inorganic materials 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 2
- 229910001950 potassium oxide Inorganic materials 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
- 229910001948 sodium oxide Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 208000031872 Body Remains Diseases 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910018068 Li 2 O Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 238000005219 brazing Methods 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 238000013001 point bending Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D7/00—Bonded abrasive wheels, or wheels with inserted abrasive blocks, designed for acting otherwise than only by their periphery, e.g. by the front face; Bushings or mountings therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/02—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
- B24D3/04—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic
- B24D3/14—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic ceramic, i.e. vitrified bondings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
- C09K3/1409—Abrasive particles per se
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Polishing Bodies And Polishing Tools (AREA)
Description
組成物AおよびBを用いて比較テスト用のビトリファイドテストバーを作製した。組成物Aは、PCDおよびPCBN材料を研削するために用いられる市販のダイヤモンドホイール、特にダイヤモンドベースの切削工具のインサート、例えばPCD、CVDおよび他の物の中で用いられるフリット結合剤材料であった。組成物Aは、59〜72重量%のSiO2/Al2O3、20〜23重量%のB2O3、1〜2重量%のCaOおよび約5.0重量%のNa2Oを含有した。組成物Aは、ZnO、混合アルカリ金属酸化物、またはBaOを含有しなかった。組成物Bは、本発明のビトリファイド結合剤であり、重量パーセントで表1に示す。
表1に示したガラス質結合剤組成物Bを使用して研削ホイールタイプ6A2HAを以下の通り作製した。管状ミキサーを使用して、162gの原材料をふた付きのプラスチックコンテナの中で10分間混合し、結合剤混合物を形成した。混合物をダイヤモンド砥粒およびガラス/セラミック球のグレードSL150と混合した。ダイヤモンド砥粒は、S−Gセラミックス&プラスチック社(S-G Ceramics & Plastics, Inc.)から入手し、そして公称15/25のミクロンサイズであった。ガラス/セラミックス球はオーストラリアのエンバイロンスフェア社(Environsphere Co., Australia)から入手し、そして平均直径は60〜100μmであった。混合物を24メッシュスクリーン(米国標準サイズ)を通して篩いに掛け、如何なる塊も分けた。次に、混合物を成型リングに圧入し、そしてリングを空気中で、温度を最大800℃まで100℃/時間で上昇し、800℃で4時間リングを保持することによって、焼成した。焼成後、砥粒リング(またはリム)を冷却し、金型を剥がし、そしてコアに膠付けした。
その好ましい態様を参照して、本発明を詳細に示し、そして記載したが、添付の特許請求の範囲によって包含される本発明の範囲から離れずに、形式および細部の各種変更をその中で行なうことができることは、当業者に理解されるであろう。
Claims (7)
- a)金属コア、およびb)コアの周囲の砥粒リムを含んでなる砥粒ホイールであって、該リムは超砥粒成分、中空体を含むフィラー成分および850℃未満の温度で焼成されたガラス質結合剤成分を含み、該ガラス質結合剤の量が該リムの28容量%以下であり、かつ開放気孔率が少なくとも15容量%であり、該ガラス質結合剤は酸化亜鉛および少なくとも2種類のアルカリ金属酸化物を含み、該混合された酸化亜鉛の量が1〜6重量%であり、該混合されたアルカリ金属酸化物の量がガラス質結合剤成分の5〜15重量%であることを特徴とする砥粒ホイール。
- 金属コアがアルミニウムから形成されることを特徴とする請求項1に記載の砥粒ホイール。
- 中空体の少なくとも90重量%は粒径が20μm〜120μmの範囲内であることを特徴とする請求項1または2に記載の砥粒ホイール。
- 中空体が10〜30容量%の範囲の量で存在することを特徴とする請求項1〜3のいずれか一項に記載の砥粒ホイール。
- 混合されたアルカリ金属酸化物の量がガラス質結合剤成分の8〜12重量%であることを特徴とする請求項1〜4のいずれか一項に記載の砥粒ホイール。
- a)1〜6重量%の酸化亜鉛および5〜15重量%の少なくとも2種類のアルカリ金属酸化物を含むフリットガラス結合剤成分を選択すること、b)超砥粒成分、中空体を有するフィラー成分および該ガラス質結合剤成分を混合すること、およびc)少なくとも15容量%の開放気孔率を有する固定砥粒ホイールを形成するに十分な時間、混合された成分を600℃〜850℃の範囲の温度で焼成することの各工程を含んでなる固定砥粒ホイールの製造方法。
- a)少なくとも5容量%の量で存在する超砥粒成分、中空体を有しそして少なくとも10容量%の量で存在するフィラー成分、および1〜6重量%の酸化亜鉛および5〜15重量%の少なくとも2種類のアルカリ金属酸化物を含みそして28容量%以下の量で存在するガラス質結合剤成分を混合すること、b)該混合された成分を、中空体の10重量%よりも多くを押し潰すことを避けるに有効な圧力で成型すること、およびc)少なくとも15容量%の開放気孔率を有する固定砥粒ホイールを形成するに十分な時間、600℃〜850℃の範囲の温度で該混合された成分を焼成することの各工程を含んでなる固定砥粒ホイールの製造方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/934,261 | 2001-08-21 | ||
US09/934,261 US6609963B2 (en) | 2001-08-21 | 2001-08-21 | Vitrified superabrasive tool and method of manufacture |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006178612A Division JP4979997B2 (ja) | 2001-08-21 | 2006-06-28 | ビトリファイド超砥粒加工工具および製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2011067947A JP2011067947A (ja) | 2011-04-07 |
JP5162679B2 true JP5162679B2 (ja) | 2013-03-13 |
Family
ID=25465254
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2003522761A Expired - Fee Related JP4119366B2 (ja) | 2001-08-21 | 2002-07-24 | ビトリファイド超砥粒加工工具および製造方法 |
JP2006178612A Expired - Fee Related JP4979997B2 (ja) | 2001-08-21 | 2006-06-28 | ビトリファイド超砥粒加工工具および製造方法 |
JP2011005264A Expired - Fee Related JP5162679B2 (ja) | 2001-08-21 | 2011-01-13 | ビトリファイド超砥粒加工工具および製造方法 |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2003522761A Expired - Fee Related JP4119366B2 (ja) | 2001-08-21 | 2002-07-24 | ビトリファイド超砥粒加工工具および製造方法 |
JP2006178612A Expired - Fee Related JP4979997B2 (ja) | 2001-08-21 | 2006-06-28 | ビトリファイド超砥粒加工工具および製造方法 |
Country Status (20)
Country | Link |
---|---|
US (2) | US6609963B2 (ja) |
JP (3) | JP4119366B2 (ja) |
CN (1) | CN100467180C (ja) |
AT (1) | AT500868B1 (ja) |
AU (1) | AU2002319683A1 (ja) |
BR (1) | BR0211862B1 (ja) |
CA (2) | CA2454829C (ja) |
CH (1) | CH695851A5 (ja) |
DE (1) | DE10297124B4 (ja) |
DK (1) | DK200400373A (ja) |
ES (1) | ES2258395B2 (ja) |
FR (1) | FR2828886B1 (ja) |
GB (1) | GB2395200B (ja) |
HU (1) | HUP0401249A2 (ja) |
IT (1) | ITMI20021838A1 (ja) |
MX (1) | MXPA04001601A (ja) |
NL (1) | NL1021276C2 (ja) |
PL (1) | PL204369B1 (ja) |
SE (1) | SE527836C2 (ja) |
WO (1) | WO2003018261A2 (ja) |
Families Citing this family (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6609963B2 (en) * | 2001-08-21 | 2003-08-26 | Saint-Gobain Abrasives, Inc. | Vitrified superabrasive tool and method of manufacture |
DE10392985T5 (de) * | 2002-07-30 | 2005-09-08 | Unova Ip Corp., Woodland Hills | Segmentierte, super-abschleifende Schleifvorrichtung |
US20050047989A1 (en) * | 2003-08-25 | 2005-03-03 | Daniel Watson | Thermally treated polycrystalline diamond (PCD) and polycrystalline diamond compact (PDC) material |
US8388774B1 (en) | 2003-06-24 | 2013-03-05 | Daniel Martin Watson | Multiwave thermal processes to improve metallurgical characteristics |
CN100376714C (zh) * | 2004-12-08 | 2008-03-26 | 上海江信超硬材料有限公司 | 一种金刚石表面涂覆玻璃涂覆三氧化二铝镀钛复合结构及制造方法 |
US7722691B2 (en) | 2005-09-30 | 2010-05-25 | Saint-Gobain Abrasives, Inc. | Abrasive tools having a permeable structure |
US7399330B2 (en) * | 2005-10-18 | 2008-07-15 | 3M Innovative Properties Company | Agglomerate abrasive grains and methods of making the same |
US20080190036A1 (en) * | 2007-02-14 | 2008-08-14 | Ramsey W Gene | Acoustic driven toughened foam glass abrasive devices and a method for producing the same |
EP2132003B1 (en) * | 2007-03-14 | 2014-03-05 | Saint-Gobain Abrasives, Inc. | Bonded abrasive article |
DE602008006756D1 (de) * | 2007-09-24 | 2011-06-16 | Saint Gobain Abrasifs Sa | Schleifprodukte mit aktiven füllern |
TW201024034A (en) | 2008-12-30 | 2010-07-01 | Saint Gobain Abrasives Inc | Bonded abrasive tool and method of forming |
DE102009006699A1 (de) * | 2009-01-29 | 2010-08-05 | Rhodius Schleifwerkzeuge Gmbh & Co. Kg | Schleifmittel mit pflanzlichen Samenkapseln als Füllstoff |
WO2010135058A2 (en) * | 2009-05-19 | 2010-11-25 | Saint-Gobain Abrasives, Inc. | Method and apparatus for roll grinding |
EP2485869B1 (en) | 2009-10-08 | 2019-06-26 | Saint-Gobain Abrasives, Inc. | Bonded abrasive article and method of forming |
KR101528151B1 (ko) * | 2009-12-02 | 2015-06-12 | 생-고뱅 어브레이시브즈, 인코포레이티드 | 결합된 연마 물품 및 생성 방법 |
JP5538558B2 (ja) * | 2009-12-02 | 2014-07-02 | サンーゴバン アブレイシブズ,インコーポレイティド | ボンド研磨物品およびその形成方法 |
CN102001053B (zh) * | 2010-10-27 | 2012-07-18 | 南京航空航天大学 | 陶瓷空心球复合结合剂立方氮化硼砂轮工作层及其制造方法 |
JP5419173B2 (ja) * | 2011-03-28 | 2014-02-19 | 株式会社アライドマテリアル | 超砥粒ホイールおよびそれを用いた研削加工法 |
US20140057534A1 (en) * | 2011-04-18 | 2014-02-27 | 3M Innovative Properties Company | Resin bonded grinding wheel |
US20140287658A1 (en) * | 2011-09-07 | 2014-09-25 | 3M Innovative Properties Company | Bonded abrasive article |
BR112014011452A2 (pt) | 2011-11-23 | 2017-05-02 | Saint Gobain Abrasifs Sa | artigo abrasivo para operações de moagem de taxa de remoção de material ultra elevada |
EP2798031B1 (en) * | 2011-12-30 | 2019-02-20 | Saint-Gobain Abrasives, Inc. | Abrasive articles and method of forming same |
US9266220B2 (en) | 2011-12-30 | 2016-02-23 | Saint-Gobain Abrasives, Inc. | Abrasive articles and method of forming same |
AR091550A1 (es) | 2012-06-29 | 2015-02-11 | Saint Gobain Abrasives Inc | Producto abrasivo aglomerado y metodo de formacion |
DE102012017969B4 (de) * | 2012-09-12 | 2017-06-29 | Center For Abrasives And Refractories Research & Development C.A.R.R.D. Gmbh | Agglomerat-Schleifkorn mit eingelagerten Mikrohohlkugeln |
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- 2002-07-24 CA CA2683100A patent/CA2683100C/en not_active Expired - Fee Related
- 2002-07-24 MX MXPA04001601A patent/MXPA04001601A/es active IP Right Grant
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- 2002-07-24 WO PCT/US2002/023536 patent/WO2003018261A2/en active IP Right Grant
- 2002-07-24 CN CNB028163648A patent/CN100467180C/zh not_active Expired - Lifetime
- 2002-07-24 JP JP2003522761A patent/JP4119366B2/ja not_active Expired - Fee Related
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- 2002-07-24 GB GB0405109A patent/GB2395200B/en not_active Expired - Fee Related
- 2002-07-24 AU AU2002319683A patent/AU2002319683A1/en not_active Abandoned
- 2002-07-24 HU HU0401249A patent/HUP0401249A2/hu unknown
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- 2002-08-19 FR FR0210420A patent/FR2828886B1/fr not_active Expired - Fee Related
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- 2004-03-05 DK DK200400373A patent/DK200400373A/da not_active Application Discontinuation
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