JP5156167B2 - プロピレン−エチレンポリマー及び製造法 - Google Patents
プロピレン−エチレンポリマー及び製造法 Download PDFInfo
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- JP5156167B2 JP5156167B2 JP2002582103A JP2002582103A JP5156167B2 JP 5156167 B2 JP5156167 B2 JP 5156167B2 JP 2002582103 A JP2002582103 A JP 2002582103A JP 2002582103 A JP2002582103 A JP 2002582103A JP 5156167 B2 JP5156167 B2 JP 5156167B2
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- Prior art keywords
- propylene
- copolymer
- polymerization
- ethylene
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- -1 Propylene-ethylene Chemical group 0.000 title claims description 73
- 238000004519 manufacturing process Methods 0.000 title description 8
- 229920000573 polyethylene Polymers 0.000 title description 3
- 229920001577 copolymer Polymers 0.000 claims abstract description 119
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 98
- 238000006116 polymerization reaction Methods 0.000 claims description 86
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 68
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims description 65
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 59
- 239000005977 Ethylene Substances 0.000 claims description 59
- 238000000034 method Methods 0.000 claims description 38
- 150000001450 anions Chemical class 0.000 claims description 35
- 239000003054 catalyst Substances 0.000 claims description 33
- 238000002844 melting Methods 0.000 claims description 20
- 230000008018 melting Effects 0.000 claims description 20
- 229920001155 polypropylene Polymers 0.000 claims description 17
- 239000004743 Polypropylene Substances 0.000 claims description 15
- 125000003118 aryl group Chemical group 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 13
- 230000004927 fusion Effects 0.000 claims description 11
- 229910052757 nitrogen Inorganic materials 0.000 claims description 11
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims description 10
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 230000004913 activation Effects 0.000 claims description 5
- 150000003623 transition metal compounds Chemical class 0.000 claims description 5
- NMLGKEDSNASIHM-UHFFFAOYSA-N (2,3,4,5,6,7,8-heptafluoronaphthalen-1-yl)oxyboronic acid Chemical compound FC1=C(F)C(F)=C2C(OB(O)O)=C(F)C(F)=C(F)C2=C1F NMLGKEDSNASIHM-UHFFFAOYSA-N 0.000 claims description 4
- 239000002685 polymerization catalyst Substances 0.000 claims description 4
- 125000004122 cyclic group Chemical group 0.000 claims description 3
- 125000002524 organometallic group Chemical group 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 238000001994 activation Methods 0.000 claims 2
- 238000010924 continuous production Methods 0.000 claims 1
- 230000000707 stereoselective effect Effects 0.000 claims 1
- 150000001993 dienes Chemical class 0.000 abstract description 20
- 239000012968 metallocene catalyst Substances 0.000 abstract description 13
- 238000009827 uniform distribution Methods 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 description 88
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 63
- 239000000203 mixture Substances 0.000 description 51
- 239000000523 sample Substances 0.000 description 35
- 239000003446 ligand Substances 0.000 description 33
- 239000000178 monomer Substances 0.000 description 33
- 238000003780 insertion Methods 0.000 description 32
- 238000009826 distribution Methods 0.000 description 26
- 238000005481 NMR spectroscopy Methods 0.000 description 22
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 21
- 230000037431 insertion Effects 0.000 description 21
- 229910052799 carbon Inorganic materials 0.000 description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 19
- 239000012190 activator Substances 0.000 description 18
- 150000001768 cations Chemical class 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 16
- 229910052796 boron Inorganic materials 0.000 description 15
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 14
- 239000002904 solvent Substances 0.000 description 14
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 12
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 11
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 11
- 238000005194 fractionation Methods 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- 238000004458 analytical method Methods 0.000 description 10
- 238000005259 measurement Methods 0.000 description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 239000012954 diazonium Substances 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-O diazynium Chemical compound [NH+]#N IJGRMHOSHXDMSA-UHFFFAOYSA-O 0.000 description 8
- 238000000113 differential scanning calorimetry Methods 0.000 description 8
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002243 precursor Substances 0.000 description 8
- 230000009257 reactivity Effects 0.000 description 8
- 239000004711 α-olefin Substances 0.000 description 8
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- OJOSABWCUVCSTQ-UHFFFAOYSA-N cyclohepta-2,4,6-trienylium Chemical compound C1=CC=C[CH+]=C[CH]1 OJOSABWCUVCSTQ-UHFFFAOYSA-N 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 229920002521 macromolecule Polymers 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 229910052752 metalloid Inorganic materials 0.000 description 7
- 150000002738 metalloids Chemical class 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 125000000217 alkyl group Chemical group 0.000 description 6
- 125000004429 atom Chemical group 0.000 description 6
- JLTDJTHDQAWBAV-UHFFFAOYSA-O dimethyl(phenyl)azanium Chemical compound C[NH+](C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-O 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 239000002516 radical scavenger Substances 0.000 description 6
- 230000002441 reversible effect Effects 0.000 description 6
- OLFPYUPGPBITMH-UHFFFAOYSA-N tritylium Chemical compound C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1 OLFPYUPGPBITMH-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 5
- 239000012683 anionic precursor Substances 0.000 description 5
- 238000009835 boiling Methods 0.000 description 5
- 229920001971 elastomer Polymers 0.000 description 5
- 239000000806 elastomer Substances 0.000 description 5
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 5
- 150000004678 hydrides Chemical group 0.000 description 5
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 5
- 229920005629 polypropylene homopolymer Polymers 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- 229910052723 transition metal Inorganic materials 0.000 description 5
- IMFACGCPASFAPR-UHFFFAOYSA-O tributylazanium Chemical compound CCCC[NH+](CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-O 0.000 description 5
- 229910052795 boron group element Inorganic materials 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000005227 gel permeation chromatography Methods 0.000 description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- OJJVPGJEBAZOIF-UHFFFAOYSA-N (2,3,4,5-tetrafluorophenoxy)boronic acid Chemical compound OB(O)OC1=CC(F)=C(F)C(F)=C1F OJJVPGJEBAZOIF-UHFFFAOYSA-N 0.000 description 3
- FWUHUNUOUDQTFG-UHFFFAOYSA-N (3,4,5-trifluorophenoxy)boronic acid Chemical compound OB(O)OC1=CC(F)=C(F)C(F)=C1 FWUHUNUOUDQTFG-UHFFFAOYSA-N 0.000 description 3
- BNUHTPCULLFDEA-UHFFFAOYSA-N 1,2,2-trifluoroethenoxyboronic acid Chemical compound OB(O)OC(F)=C(F)F BNUHTPCULLFDEA-UHFFFAOYSA-N 0.000 description 3
- 125000004361 3,4,5-trifluorophenyl group Chemical group [H]C1=C(F)C(F)=C(F)C([H])=C1* 0.000 description 3
- 0 CC(C)(C1(C)NC1)N* Chemical compound CC(C)(C1(C)NC1)N* 0.000 description 3
- 150000004645 aluminates Chemical class 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 150000001491 aromatic compounds Chemical class 0.000 description 3
- 238000000429 assembly Methods 0.000 description 3
- 230000000712 assembly Effects 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229910052735 hafnium Inorganic materials 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 150000008040 ionic compounds Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 3
- OUHOZBRDLAZZLQ-UHFFFAOYSA-N (2,3,5,6-tetrafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=CC(F)=C1F OUHOZBRDLAZZLQ-UHFFFAOYSA-N 0.000 description 2
- HTGQCLJTWPSFNL-UHFFFAOYSA-N (2-methylphenoxy)boronic acid Chemical compound CC1=CC=CC=C1OB(O)O HTGQCLJTWPSFNL-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- 239000007848 Bronsted acid Substances 0.000 description 2
- OKTJSMMVPCPJKN-OUBTZVSYSA-N Carbon-13 Chemical compound [13C] OKTJSMMVPCPJKN-OUBTZVSYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- 239000002841 Lewis acid Substances 0.000 description 2
- 239000002879 Lewis base Substances 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 238000001460 carbon-13 nuclear magnetic resonance spectrum Methods 0.000 description 2
- 239000013256 coordination polymer Substances 0.000 description 2
- 125000005131 dialkylammonium group Chemical group 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
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- 229960004132 diethyl ether Drugs 0.000 description 2
- GGSUCNLOZRCGPQ-UHFFFAOYSA-O diethyl(phenyl)azanium Chemical compound CC[NH+](CC)C1=CC=CC=C1 GGSUCNLOZRCGPQ-UHFFFAOYSA-O 0.000 description 2
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
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- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 2
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 2
- 238000012685 gas phase polymerization Methods 0.000 description 2
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- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 2
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- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 2
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 2
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- ILFOXVJEPKJXFI-UHFFFAOYSA-N (2,3,4,5,6,7,8,9,10-nonafluoroanthracen-1-yl)oxy-(2,3,4,5,6-pentafluorophenoxy)borinic acid Chemical compound B(O)(OC1=C(C(=C(C2=C1C(=C3C(=C2F)C(=C(C(=C3F)F)F)F)F)F)F)F)OC4=C(C(=C(C(=C4F)F)F)F)F ILFOXVJEPKJXFI-UHFFFAOYSA-N 0.000 description 1
- DQVXWCCLFKMJTQ-UHFFFAOYSA-N (4-methylphenoxy)boronic acid Chemical compound CC1=CC=C(OB(O)O)C=C1 DQVXWCCLFKMJTQ-UHFFFAOYSA-N 0.000 description 1
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 1
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- YQNVPNRHJFZONU-UHFFFAOYSA-N CC(C)C(C)(C)N Chemical compound CC(C)C(C)(C)N YQNVPNRHJFZONU-UHFFFAOYSA-N 0.000 description 1
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- 241001441571 Hiodontidae Species 0.000 description 1
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- HCIMXTXCDVBLOA-UHFFFAOYSA-N [4-(trifluoromethyl)phenoxy]boronic acid Chemical compound OB(O)OC1=CC=C(C(F)(F)F)C=C1 HCIMXTXCDVBLOA-UHFFFAOYSA-N 0.000 description 1
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- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
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- BOXSCYUXSBYGRD-UHFFFAOYSA-N cyclopenta-1,3-diene;iron(3+) Chemical compound [Fe+3].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 BOXSCYUXSBYGRD-UHFFFAOYSA-N 0.000 description 1
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- XBPCUCUWBYBCDP-UHFFFAOYSA-O dicyclohexylazanium Chemical compound C1CCCCC1[NH2+]C1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-O 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- IDAPTOGYAAQMGT-UHFFFAOYSA-N diphenylmethylbenzene borate Chemical compound [O-]B([O-])[O-].C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1 IDAPTOGYAAQMGT-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/941—Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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| US09/834,256 | 2001-04-12 | ||
| US09/834,256 US6525157B2 (en) | 1997-08-12 | 2001-04-12 | Propylene ethylene polymers |
| US33665501P | 2001-12-05 | 2001-12-05 | |
| US60/336,655 | 2001-12-05 | ||
| US34218601P | 2001-12-19 | 2001-12-19 | |
| US60/342,186 | 2001-12-19 | ||
| PCT/US2002/010515 WO2002083754A1 (en) | 2001-04-12 | 2002-04-02 | Propylene ethylene polymers and production process |
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| AU4962399A (en) * | 1998-07-01 | 2000-01-24 | Exxon Chemical Patents Inc. | Elastic blends comprising crystalline polymer and crystallizable polymers of propylene |
| WO2004048424A1 (en) * | 2002-11-28 | 2004-06-10 | Basell Poliolefine Italia S.P.A. | Butene-1 copolymers and process for their preparation |
| WO2005049672A1 (en) | 2003-11-14 | 2005-06-02 | Exxonmobil Chemical Patents Inc. | Transparent and translucent crosslinked propylenebased elastomers, and their production and use |
| WO2006020309A1 (en) * | 2004-08-13 | 2006-02-23 | Exxonmobil Chemical Patents, Inc. | Polymeric compositions including their uses and methods of production |
| WO2006065300A1 (en) | 2004-12-16 | 2006-06-22 | Exxonmobil Chemical Patents Inc. | Polymeric compositions including their uses and methods of production |
| JP4782800B2 (ja) | 2004-12-17 | 2011-09-28 | エクソンモービル・ケミカル・パテンツ・インク | 均一ポリマー・ブレンドおよび該ブレンドからの製品 |
| WO2006083505A1 (en) | 2005-01-31 | 2006-08-10 | Exxonmobil Chemical Patents Inc. | Polymeric compositions including their uses and methods of production |
| WO2006083515A1 (en) * | 2005-01-31 | 2006-08-10 | Exxonmobil Chemical Patents Inc. | Polymer blends and pellets and methods of producing same |
| US8927108B2 (en) | 2006-01-10 | 2015-01-06 | Exxonmobil Chemical Patents Inc. | Films incorporating polymeric material combinations, articles made therefrom, and methods of making such films and articles |
| US8476326B2 (en) * | 2006-09-22 | 2013-07-02 | Dow Global Technologies Llc | Fibrillated polyolefin foam |
| JP5357169B2 (ja) * | 2007-10-22 | 2013-12-04 | ダウ グローバル テクノロジーズ エルエルシー | 物品を成形するためのポリマー組成物及び方法 |
| BRPI0819051A2 (pt) * | 2007-12-05 | 2015-05-05 | Dow Global Technologies Inc | Composição de resina, película e bolsa de retorta |
| US9938400B2 (en) | 2008-04-23 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Propylene copolymers in soft thermoplastic blends |
| JP5722456B2 (ja) * | 2010-11-09 | 2015-05-20 | エクソンモービル ケミカル パテンツ インコーポレイテッド | ２成分繊維およびそれらを作製する方法 |
| SG10201709919RA (en) | 2013-06-04 | 2017-12-28 | Exxonmobil Chemical Patents Inc | Polymer compositions and nonwoven compositions prepared therefrom |
| US11549201B2 (en) | 2013-06-18 | 2023-01-10 | Exxonmobil Chemicals Patents Inc. | Fibers and nonwoven materials prepared therefrom |
| JP6142085B2 (ja) | 2013-06-18 | 2017-06-07 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 繊維及びこれから調製された不織材料 |
| US9469753B2 (en) | 2013-07-22 | 2016-10-18 | Exxonmobil Chemical Patents Inc. | Propylene copolymers in elastomeric compositions |
| EP3052316B1 (en) | 2013-09-30 | 2020-11-25 | ExxonMobil Chemical Patents Inc. | Polymer compositions and articles made therefrom |
| KR101579616B1 (ko) * | 2014-06-10 | 2015-12-22 | 주식회사 엘지화학 | 프로필렌계 엘라스토머 |
| KR101580591B1 (ko) * | 2014-06-10 | 2015-12-28 | 주식회사 엘지화학 | 프로필렌계 엘라스토머 |
| WO2015190831A1 (ko) * | 2014-06-10 | 2015-12-17 | 주식회사 엘지화학 | 프로필렌계 엘라스토머 |
| US10106676B2 (en) | 2014-06-10 | 2018-10-23 | Exxonmobil Chemical Patents Inc. | Propylene-based polymers having improved stability and methods for producing the same |
| US20170181498A1 (en) | 2014-07-25 | 2017-06-29 | Exxonmobil Chemical Patents Inc. | Footwear Compositions Comprising Propylene-Based Elastomers |
| SG11201701351TA (en) * | 2014-08-21 | 2017-03-30 | Dow Global Technologies Llc | Hot melt adhesive composition including a crystalline block composite |
| KR101925434B1 (ko) | 2014-09-05 | 2018-12-05 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 중합체 조성물 및 이로부터 제조된 부직포 재료 |
| WO2016137556A1 (en) | 2015-02-26 | 2016-09-01 | Exxonmobil Chemical Patents Inc. | Process for forming thermoplastic vulcanizates and thermoplastic vulcanizates made therefrom |
| WO2016137559A1 (en) | 2015-02-26 | 2016-09-01 | Exxonmobil Chemical Patents Inc. | Compositions comprising propylene-based elastomers and polyalphaolefins |
| WO2016154770A1 (en) | 2015-03-27 | 2016-10-06 | Exxonmobil Chemical Patents Inc. | Propylene-based polymer compositions for grip applications |
| CN107709447B (zh) | 2015-05-22 | 2020-09-08 | 埃克森美孚化学专利公司 | 包含基于丙烯的弹性体的热塑性硫化橡胶材料及其制造方法 |
| US10323140B2 (en) | 2015-05-29 | 2019-06-18 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates comprising broad molecular weight distribution polypropylene |
| US11118041B2 (en) | 2015-06-19 | 2021-09-14 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer compositions comprising ultrahigh molecular weight polyethylene and methods for making the same |
| US9926443B2 (en) | 2015-11-09 | 2018-03-27 | Exxonmobil Chemical Patents Inc. | Propylene-based elastomers for roofing compositions and methods for preparing the same |
| CA3003698C (en) | 2015-11-09 | 2020-05-05 | Exxonmobil Chemical Patents Inc. | Propylene-based elastomers for roofing compositions and methods for preparing the same |
| WO2018034760A1 (en) | 2016-08-15 | 2018-02-22 | Exxonmobil Chemical Patents Inc. | Propylene-alpha olefin copolymers and methods for making the same |
| WO2018034759A1 (en) | 2016-08-15 | 2018-02-22 | Exxonmobil Chemical Patents Inc. | Propylene-olefin copolymers and methods for making the same |
| WO2018057124A1 (en) | 2016-09-23 | 2018-03-29 | Exxonmobil Chemical Patents Inc. | Shrinkable thermoplastic vulcanizate and method and article |
| US11370850B2 (en) * | 2018-05-12 | 2022-06-28 | Pretium Innovation, Llc | Polymerization compositions and methods for making and using same |
| CN113039312B (zh) | 2018-11-16 | 2023-10-10 | 埃克森美孚化学专利公司 | 用于纤维和非织造材料的聚α-烯烃改性的聚合物共混物 |
| WO2021195070A1 (en) | 2020-03-26 | 2021-09-30 | Exxonmobil Chemical Patents Inc. | Processes for making 3-d objects from blends of polypropylene and semi-amorphous polymers |
| WO2021231362A1 (en) | 2020-05-12 | 2021-11-18 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer compositions for use in pharmaceutical articles |
| US20240011198A1 (en) | 2020-11-19 | 2024-01-11 | Exxonmobil Chemical Patents Inc. | Nonwoven Fabrics with Improved Haptics and Mechanical Properties |
| EP4658719A1 (en) | 2023-02-02 | 2025-12-10 | ExxonMobil Technology and Engineering Company | Compositions and methods relating to impact copolymer compatibilizers |
| KR20250155049A (ko) | 2023-03-03 | 2025-10-29 | 엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니 | 발포 프로필렌 기반 엘라스토머 조성물, 이의 제조 방법 및 이로부터 제조된 제품 |
| CN120813645A (zh) | 2023-03-06 | 2025-10-17 | 埃克森美孚技术与工程公司 | 用于地下防水应用的基于丙烯的弹性体组合物 |
| CN119735728A (zh) * | 2025-01-07 | 2025-04-01 | 浙江大学 | 一种高熔点丙乙烯烃聚合物弹性体及其制备方法 |
Family Cites Families (313)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE534424A (OSRAM) | 1953-12-24 | |||
| US4076698A (en) | 1956-03-01 | 1978-02-28 | E. I. Du Pont De Nemours And Company | Hydrocarbon interpolymer compositions |
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| US3485706A (en) | 1968-01-18 | 1969-12-23 | Du Pont | Textile-like patterned nonwoven fabrics and their production |
| US3520861A (en) | 1968-12-26 | 1970-07-21 | Dow Chemical Co | Copolymers of ethylene |
| NL7001827A (OSRAM) | 1970-02-10 | 1971-08-12 | ||
| US3758656A (en) | 1970-03-25 | 1973-09-11 | Du Pont | Ainst excessive cold flow during shipment or storage process for preparing an elastomer which is structurally supported ag |
| US3812077A (en) | 1971-12-27 | 1974-05-21 | Gen Electric | Fiber reinforced composite materials |
| US3989867A (en) | 1973-02-16 | 1976-11-02 | The Procter & Gamble Company | Absorptive devices having porous backsheet |
| US3888949A (en) | 1973-06-21 | 1975-06-10 | Du Pont | Blends of propylene-alpha-olefin copolymers and polypropylene |
| US3882197A (en) | 1973-06-21 | 1975-05-06 | Du Pont | Alpha-olefin copolymer blends |
| US3881489A (en) | 1973-08-20 | 1975-05-06 | Procter & Gamble | Breathable, liquid inpervious backsheet for absorptive devices |
| DE2417093B2 (de) | 1974-04-08 | 1979-09-27 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von Polypropylen-Formmassen |
| DE2726963C3 (de) | 1977-06-15 | 1980-04-30 | Hermann Berstorff Maschinenbau Gmbh, 3000 Hannover | Vorrichtung zum Abziehen eines Zylinderteiles von einem Schneckenextruder |
| US4211852A (en) | 1977-09-26 | 1980-07-08 | Mitsui Petrochemical Industries Ltd. | Thermoplastic olefin resin composition and laminated film or sheet thereof |
| US4425393A (en) | 1979-04-26 | 1984-01-10 | Brunswick Corporation | Low modulus, small diameter fibers and products made therefrom |
| US4330646A (en) | 1979-08-13 | 1982-05-18 | Asahi Kasei Kogyo Kabushiki Kaisha | Polymerization of an α-olefin |
| DE3165167D1 (en) | 1980-04-03 | 1984-09-06 | Ici Plc | Method and apparatus for the treatment of wastewater |
| US4322027A (en) | 1980-10-02 | 1982-03-30 | Crown Zellerbach Corporation | Filament draw nozzle |
| US4381781A (en) | 1981-01-05 | 1983-05-03 | Kimberly-Clark Corporation | Flexible waist diaper |
| US4411821A (en) | 1981-02-23 | 1983-10-25 | E. I. Du Pont De Nemours And Company | 1-Olefin polymerization catalyst |
| US4413110A (en) | 1981-04-30 | 1983-11-01 | Allied Corporation | High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore |
| US4491652A (en) | 1981-05-13 | 1985-01-01 | Uniroyal, Inc. | Sequentially prepared thermoplastic elastomer and method of preparing same |
| DE3127133A1 (de) | 1981-07-09 | 1983-01-27 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von polyolefinen und deren copolymerisaten |
| US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
| US4588790A (en) | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
| US4430563A (en) | 1982-04-30 | 1984-02-07 | Minnesota Mining And Manufacturing Company | Data processing form |
| DE3240383A1 (de) | 1982-11-02 | 1984-05-03 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von oligomeren aluminoxanen |
| US5085654A (en) | 1982-11-15 | 1992-02-04 | The Procter & Gamble Company | Disposable garment with breathable leg cuffs |
| DE3461811D1 (en) | 1983-01-25 | 1987-02-05 | Mitsui Petrochemical Ind | Film-forming propylene copolymer, film thereof and process for production of the film |
| US4461872A (en) | 1983-02-22 | 1984-07-24 | E. I. Du Pont De Nemours And Company | Blends of a propylene/α-olefin copolymer with isotactic prolypropylene |
| EP0128046B1 (en) | 1983-06-06 | 1987-10-21 | Exxon Research And Engineering Company | Process and catalyst for producing reactor blend polyolefins |
| US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
| US4599392A (en) | 1983-06-13 | 1986-07-08 | The Dow Chemical Company | Interpolymers of ethylene and unsaturated carboxylic acids |
| US4540753A (en) | 1983-06-15 | 1985-09-10 | Exxon Research & Engineering Co. | Narrow MWD alpha-olefin copolymers |
| US4758656A (en) | 1983-12-26 | 1988-07-19 | Kyowa Hakko Kogyo Co., Ltd. | Novel human interferon-gamma polypeptide derivative |
| US4578414A (en) | 1984-02-17 | 1986-03-25 | The Dow Chemical Company | Wettable olefin polymer fibers |
| US4909975A (en) | 1984-02-17 | 1990-03-20 | The Dow Chemical Company | Fine denier fibers of olefin polymers |
| US4830907A (en) | 1984-11-16 | 1989-05-16 | The Dow Chemical Company | Fine denier fibers of olefin polymers |
| DE3582003D1 (de) | 1984-10-15 | 1991-04-11 | Exxon Research Engineering Co | Herstellung von glycolmonoestern. |
| US4612300A (en) | 1985-06-06 | 1986-09-16 | The Dow Chemical Company | Novel catalyst for producing relatively narrow molecular weight distribution olefin polymers |
| US4808561A (en) | 1985-06-21 | 1989-02-28 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| US4897455A (en) | 1985-06-21 | 1990-01-30 | Exxon Chemical Patents Inc. | Polymerization process |
| US4663220A (en) | 1985-07-30 | 1987-05-05 | Kimberly-Clark Corporation | Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers |
| US4668566A (en) | 1985-10-07 | 1987-05-26 | Kimberly-Clark Corporation | Multilayer nonwoven fabric made with poly-propylene and polyethylene |
| JPH06104701B2 (ja) * | 1985-11-20 | 1994-12-21 | 三井石油化学工業株式会社 | プロピレン系ランダム共重合体およびそれからなる熱可塑性樹脂用耐衝撃性改善剤 |
| AU602873B2 (en) | 1985-11-29 | 1990-11-01 | American National Can Company | Films using blends of polypropylene and polyisobutylene |
| US4752597A (en) | 1985-12-12 | 1988-06-21 | Exxon Chemical Patents Inc. | New polymerization catalyst |
| US4644045A (en) | 1986-03-14 | 1987-02-17 | Crown Zellerbach Corporation | Method of making spunbonded webs from linear low density polyethylene |
| US5068141A (en) | 1986-05-31 | 1991-11-26 | Unitika Ltd. | Polyolefin-type nonwoven fabric and method of producing the same |
| US4859757A (en) | 1986-06-30 | 1989-08-22 | Rexene Products Company | Novel propylene polymers |
| PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
| US5408017A (en) | 1987-01-30 | 1995-04-18 | Exxon Chemical Patents Inc. | High temperature polymerization process using ionic catalysts to produce polyolefins |
| US5384299A (en) | 1987-01-30 | 1995-01-24 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| IL85097A (en) | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
| US5153157A (en) | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| US4826774A (en) | 1987-01-30 | 1989-05-02 | Minnesota Mining And Manufacturing Company | Vapocheromic double-complex salts |
| US5391629A (en) | 1987-01-30 | 1995-02-21 | Exxon Chemical Patents Inc. | Block copolymers from ionic catalysts |
| US5198401A (en) | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| US4874880A (en) | 1987-03-10 | 1989-10-17 | Chisso Corporation | Bis(di-, tri- or tetra-substituted-cyclopentadienyl)-zirconium dihalides |
| US4988781A (en) | 1989-02-27 | 1991-01-29 | The Dow Chemical Company | Process for producing homogeneous modified copolymers of ethylene/alpha-olefin carboxylic acids or esters |
| US5093415A (en) | 1987-05-19 | 1992-03-03 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing stereoregular polymers having a narrow molecular weight distribution |
| DE3726067A1 (de) | 1987-08-06 | 1989-02-16 | Hoechst Ag | Verfahren zur herstellung von 1-olefinpolymeren |
| US5015749A (en) | 1987-08-31 | 1991-05-14 | The Dow Chemical Company | Preparation of polyhydrocarbyl-aluminoxanes |
| US5112686A (en) | 1987-10-27 | 1992-05-12 | The Dow Chemical Company | Linear ethylene polymer staple fibers |
| US4842922A (en) | 1987-10-27 | 1989-06-27 | The Dow Chemical Company | Polyethylene fibers and spunbonded fabric or web |
| IT1221653B (it) | 1987-11-27 | 1990-07-12 | Ausimonti Spa | Copolimeri cristallini del propilene |
| US4940464A (en) | 1987-12-16 | 1990-07-10 | Kimberly-Clark Corporation | Disposable incontinence garment or training pant |
| US4937217A (en) | 1987-12-17 | 1990-06-26 | Exxon Chemical Patents Inc. | Method for utilizing triethylaluminum to prepare an alumoxane support for an active metallocene catalyst |
| US4912075A (en) | 1987-12-17 | 1990-03-27 | Exxon Chemical Patents Inc. | Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization |
| US4937301A (en) | 1987-12-17 | 1990-06-26 | Exxon Chemical Patents Inc. | Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization |
| US4879170A (en) | 1988-03-18 | 1989-11-07 | Kimberly-Clark Corporation | Nonwoven fibrous hydraulically entangled elastic coform material and method of formation thereof |
| US4939016A (en) | 1988-03-18 | 1990-07-03 | Kimberly-Clark Corporation | Hydraulically entangled nonwoven elastomeric web and method of forming the same |
| US5017714A (en) | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
| US5120867A (en) | 1988-03-21 | 1992-06-09 | Welborn Jr Howard C | Silicon-bridged transition metal compounds |
| US5008228A (en) | 1988-03-29 | 1991-04-16 | Exxon Chemical Patents Inc. | Method for preparing a silica gel supported metallocene-alumoxane catalyst |
| US5086025A (en) | 1988-03-29 | 1992-02-04 | Exxon Chemical Patents Inc. | Method for preparing a silica gel supported metallocene-alumoxane catalyst |
| US5147949A (en) | 1988-03-29 | 1992-09-15 | Exxon Chemical Patents Inc. | Polymerization process using a silica gel supported metallocene-alumoxane catalyst |
| US4871705A (en) | 1988-06-16 | 1989-10-03 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst |
| US5229478A (en) | 1988-06-16 | 1993-07-20 | Exxon Chemical Patents Inc. | Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system |
| FR2634212B1 (fr) | 1988-07-15 | 1991-04-19 | Bp Chimie Sa | Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise |
| US5700896A (en) | 1988-07-30 | 1997-12-23 | Hoechst Aktiengesellschaft | Polymer having long isotactic sequences and randomly-distributed ethylene content obtained by polymerizing propylene in presence of specific catalysts |
| DE68928938T2 (de) | 1988-08-08 | 1999-09-30 | Biopak Technology Ltd., Golden | Verfahren zur Weichmachung von Lactidpolymerisaten |
| JP2762492B2 (ja) | 1988-11-16 | 1998-06-04 | 住友化学工業株式会社 | ポリプロピレン延伸フィルム |
| US5041584A (en) | 1988-12-02 | 1991-08-20 | Texas Alkyls, Inc. | Modified methylaluminoxane |
| US4960878A (en) | 1988-12-02 | 1990-10-02 | Texas Alkyls, Inc. | Synthesis of methylaluminoxanes |
| KR900009719A (ko) | 1988-12-16 | 1990-07-05 | 엠. 데이비드 레오나이드 | 신규 에틸렌-프로필렌 공중합체 |
| DE68928696T2 (de) | 1988-12-26 | 1998-12-03 | Mitsui Chemicals, Inc., Tokio/Tokyo | Olefin-kopolymer und verfahren zur herstellung |
| US5218071A (en) | 1988-12-26 | 1993-06-08 | Mitsui Petrochemical Industries, Ltd. | Ethylene random copolymers |
| DE3904468A1 (de) | 1989-02-15 | 1990-08-16 | Hoechst Ag | Polypropylenwachs und verfahren zu seiner herstellung |
| AU661456B2 (en) | 1989-02-27 | 1995-07-27 | Dow Chemical Company, The | Process for producing homogeneous modified copolymers of ethylene/alpha-olefin carboxylic acids or esters |
| US5037416A (en) | 1989-03-09 | 1991-08-06 | The Procter & Gamble Company | Disposable absorbent article having elastically extensible topsheet |
| JP2682130B2 (ja) | 1989-04-25 | 1997-11-26 | 三井石油化学工業株式会社 | 柔軟な長繊維不織布 |
| NZ235032A (en) | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| US5057475A (en) | 1989-09-13 | 1991-10-15 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization |
| US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| US5763549A (en) | 1989-10-10 | 1998-06-09 | Fina Technology, Inc. | Cationic metallocene catalysts based on organoaluminum anions |
| EP0427697B1 (en) | 1989-10-10 | 1996-05-08 | Fina Technology, Inc. | Metallocene catalysts with Lewis acids and aluminum alkyls |
| US5387568A (en) | 1989-10-30 | 1995-02-07 | Fina Technology, Inc. | Preparation of metallocene catalysts for polymerization of olefins |
| DE69018376T3 (de) | 1989-10-30 | 2002-05-16 | Fina Technology, Inc. | Herstellung von Metallocenkatalysatoren für Olefinpolymerisation. |
| US6001933A (en) | 1989-11-28 | 1999-12-14 | Idemitsupetrochemical Co., Ltd. | Flexible polypropylene resins, propylene based elastomer compositions and process for production of olefin polymers |
| US6156846A (en) | 1989-11-28 | 2000-12-05 | Idemitsu Petrochemical Co., Ltd. | Flexible polypropylene resins, propylene bases elastomer compositions and process for production of olefin polymers |
| DE3942363A1 (de) | 1989-12-21 | 1991-06-27 | Hoechst Ag | Verfahren zur herstellung einer polypropylen-formmasse |
| US5280074A (en) | 1989-12-21 | 1994-01-18 | Hoechst Ag | Process for the preparation of a polypropylene molding composition |
| FR2656314B1 (fr) | 1989-12-22 | 1992-04-17 | Bp Chemicals Snc | Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines. |
| US5032562A (en) | 1989-12-27 | 1991-07-16 | Mobil Oil Corporation | Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution |
| DE4005947A1 (de) | 1990-02-26 | 1991-08-29 | Basf Ag | Loesliche katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen |
| US5044438A (en) | 1990-03-16 | 1991-09-03 | Young Joe A | Wellhead bowl protector and retrieving tool |
| US5618895A (en) | 1990-04-06 | 1997-04-08 | Basf Aktiengesellschaft | Process for preparing copolymers of propylene with other 1-alkenes |
| PL166690B1 (pl) | 1990-06-04 | 1995-06-30 | Exxon Chemical Patents Inc | Sposób wytwarzania polimerów olefin PL |
| US5041585A (en) | 1990-06-08 | 1991-08-20 | Texas Alkyls, Inc. | Preparation of aluminoxanes |
| US5041583A (en) | 1990-06-28 | 1991-08-20 | Ethyl Corporation | Preparation of aluminoxanes |
| US5272236A (en) | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| JP2545006B2 (ja) | 1990-07-03 | 1996-10-16 | ザ ダウ ケミカル カンパニー | 付加重合触媒 |
| DE4030379A1 (de) | 1990-09-26 | 1992-04-02 | Basf Ag | Polymerwachse des propylens mit hoher haerte und kristallinitaet |
| IL99741A0 (en) | 1990-11-01 | 1992-08-18 | Himont Inc | Propylene polymer films and laminates |
| US5243001A (en) | 1990-11-12 | 1993-09-07 | Hoechst Aktiengesellschaft | Process for the preparation of a high molecular weight olefin polymer |
| US5134209A (en) | 1990-12-26 | 1992-07-28 | Shell Oil Company | Process of producing ethylene-propylene rubbery copolymer |
| US5189192A (en) | 1991-01-16 | 1993-02-23 | The Dow Chemical Company | Process for preparing addition polymerization catalysts via metal center oxidation |
| US5204037A (en) | 1991-01-25 | 1993-04-20 | Idemitsu Petrochemical Co., Ltd. | Process for production of polypropylene sheets or films |
| EP0499216B1 (en) | 1991-02-15 | 1998-01-07 | MITSUI TOATSU CHEMICALS, Inc. | Transparent impact-resistant molded articles |
| MX9200724A (es) | 1991-02-22 | 1993-05-01 | Exxon Chemical Patents Inc | Mezcla termosellable de polietileno o plastomero de muy baja densidad con polimeros a base de polipropileno y pelicula termosellable asi como articulos hechos con aquellas. |
| JP3275211B2 (ja) | 1991-05-20 | 2002-04-15 | ザ ダウ ケミカル カンパニー | 付加重合触媒の製造方法 |
| CA2067451A1 (en) | 1991-05-24 | 1993-10-29 | Gregory B. Kharas | Polylactide blends |
| DE4120009A1 (de) | 1991-06-18 | 1992-12-24 | Basf Ag | Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen |
| US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
| US5710224A (en) | 1991-07-23 | 1998-01-20 | Phillips Petroleum Company | Method for producing polymer of ethylene |
| TW300901B (OSRAM) | 1991-08-26 | 1997-03-21 | Hoechst Ag | |
| US5525695A (en) | 1991-10-15 | 1996-06-11 | The Dow Chemical Company | Elastic linear interpolymers |
| US6448355B1 (en) | 1991-10-15 | 2002-09-10 | The Dow Chemical Company | Elastic fibers, fabrics and articles fabricated therefrom |
| US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
| ATE286918T1 (de) | 1991-10-15 | 2005-01-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung eines olefinpolymers unter verwendung von metallocenen mit speziell substituierten indenylliganden |
| EP0538749B1 (en) | 1991-10-21 | 1995-01-11 | Mitsubishi Petrochemical Co., Ltd. | Propylene copolymer composition |
| BE1006840A5 (fr) | 1992-05-04 | 1995-01-03 | Solvay | Systeme catalytique pour la polymerisation d'olefines; procede pour cette polymerisation et polymeres ainsi obtenus. |
| DE69224600T2 (de) | 1991-11-12 | 1998-08-27 | Nippon Oil Co Ltd | Katalysatorbestandteile für Olefinpolymerisation |
| CA2124187C (en) | 1991-11-25 | 2001-08-07 | Howard William Turner | Polyonic transition metal catalyst composition |
| CA2083664A1 (en) | 1991-12-20 | 1993-06-21 | Arnold Lustiger | Semicrystalline polymer blend compositions with enhanced interspherulitic and interlamellar strength |
| US6153703A (en) | 1991-12-20 | 2000-11-28 | Exxon Research And Engineering Company | Semicrystalline polymer blend compositions with enhanced interspherulitic and interlamellar strength |
| US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
| US5436304A (en) | 1992-03-19 | 1995-07-25 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| US5374696A (en) | 1992-03-26 | 1994-12-20 | The Dow Chemical Company | Addition polymerization process using stabilized reduced metal catalysts |
| US5296433A (en) | 1992-04-14 | 1994-03-22 | Minnesota Mining And Manufacturing Company | Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom |
| EP0641362B1 (en) | 1992-04-20 | 1998-11-11 | Exxon Chemical Patents Inc. | Ethylene/branched olefin copolymers |
| US5350723A (en) | 1992-05-15 | 1994-09-27 | The Dow Chemical Company | Process for preparation of monocyclopentadienyl metal complex compounds and method of use |
| JP3058690B2 (ja) | 1992-06-15 | 2000-07-04 | エクソン・ケミカル・パテンツ・インク | ポリオレフィンを製造するためのイオン性触媒を使用する高温重合プロセス |
| US5238892A (en) | 1992-06-15 | 1993-08-24 | Exxon Chemical Patents Inc. | Supported catalyst for 1-olefin(s) (co)polymerization |
| WO1994000500A1 (en) | 1992-06-26 | 1994-01-06 | Exxon Chemical Patents Inc. | Solution phase polymerization process utilizing metallocene catalyst with production of olefin polymers |
| DE69332811T2 (de) | 1992-07-01 | 2004-01-29 | Exxonmobil Chem Patents Inc | Auf Übergangsmetallen der Gruppen 5 und 6 basierende Katalysator-Vorläufer |
| EP0582194B1 (de) | 1992-08-03 | 1998-05-06 | TARGOR GmbH | Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden |
| JPH07509752A (ja) | 1992-08-05 | 1995-10-26 | エクソン・ケミカル・パテンツ・インク | オレフィン重合用の担持されたイオン遷移金属触媒 |
| JPH0657057A (ja) | 1992-08-11 | 1994-03-01 | Sumitomo Chem Co Ltd | ポリプロピレン組成物及びそのフィルム |
| US5382400A (en) | 1992-08-21 | 1995-01-17 | Kimberly-Clark Corporation | Nonwoven multicomponent polymeric fabric and method for making same |
| US5336552A (en) | 1992-08-26 | 1994-08-09 | Kimberly-Clark Corporation | Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and ethylene alkyl acrylate copolymer |
| US5681913A (en) * | 1992-09-08 | 1997-10-28 | Rexene Corporation | High tensile strength amorphous 1-butene/propylene and ethylene/propylene copolymers |
| US5317036A (en) | 1992-10-16 | 1994-05-31 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization reactions utilizing soluble unsupported catalysts |
| US5322728A (en) | 1992-11-24 | 1994-06-21 | Exxon Chemical Patents, Inc. | Fibers of polyolefin polymers |
| US5608019A (en) | 1992-12-28 | 1997-03-04 | Mobil Oil Corporation | Temperature control of MW in olefin polymerization using supported metallocene catalyst |
| US5332706A (en) | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
| IT1256260B (it) | 1992-12-30 | 1995-11-29 | Montecatini Tecnologie Srl | Polipropilene atattico |
| DE69431077T2 (de) | 1993-01-11 | 2003-01-23 | Mitsui Chemicals, Inc. | Zusammensetzung von Propylen-Polymeren |
| US6448341B1 (en) | 1993-01-29 | 2002-09-10 | The Dow Chemical Company | Ethylene interpolymer blend compositions |
| ES2149262T3 (es) | 1993-01-29 | 2000-11-01 | Dow Chemical Co | Interpolimerizaciones de etileno. |
| EP0617063B1 (de) | 1993-03-18 | 1999-09-08 | BASF Aktiengesellschaft | Mit radikalisch zerfallenden Initiatoren gepfropfte Propylencopolymerisate |
| DE4308591A1 (de) | 1993-03-18 | 1994-09-22 | Basf Ag | Gepfropfte Propylencopolymerisate |
| US5462999A (en) | 1993-04-26 | 1995-10-31 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| AU682821B2 (en) | 1993-04-26 | 1997-10-23 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| US5883188A (en) | 1993-04-28 | 1999-03-16 | The Dow Chemical Company | Paintable olefinic interpolymer compositions |
| FR2705252B1 (fr) | 1993-05-19 | 1995-07-21 | Bp Chemicals Snc | Procédé d'introduction d'un solide dans un réacteur et appareillage. |
| ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
| DE4317655A1 (de) | 1993-05-27 | 1994-12-01 | Basf Ag | Mehrphasige Blockcopolymerisate des Propylens |
| EP1070729B1 (en) | 1993-06-07 | 2011-09-28 | Mitsui Chemicals, Inc. | Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said component, process for olefin polymerization using said catalyst, propylene homopolymer, propylene copolymer and propylene elastomer |
| EP1209165B1 (en) * | 1993-06-07 | 2006-04-19 | Mitsui Chemicals, Inc. | Propylene elastomer |
| ATE147748T1 (de) | 1993-06-24 | 1997-02-15 | Dow Chemical Co | Titan-und zirkoniumkomplexe und diese enthaltende polymerisationskatalysatoren |
| US5455305A (en) | 1993-07-12 | 1995-10-03 | Montell North America Inc. | Propylene polymer yarn and articles made therefrom |
| US6005049A (en) | 1993-07-19 | 1999-12-21 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the production of polypropylene |
| US6284857B1 (en) | 1993-07-22 | 2001-09-04 | Mitsui Chemical, Inc. | Propylene polymer, propylene block copolymer, process for preparing said polymer and said block copolymer, and propylene polymer composition |
| TW272986B (OSRAM) | 1993-07-28 | 1996-03-21 | Mitsui Petroleum Chemicals Ind | |
| US5472775A (en) | 1993-08-17 | 1995-12-05 | The Dow Chemical Company | Elastic materials and articles therefrom |
| IT1271406B (it) | 1993-09-13 | 1997-05-28 | Spherilene Srl | Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti |
| US5576259A (en) | 1993-10-14 | 1996-11-19 | Tosoh Corporation | Process for producing α-olefin polymer |
| DE69417983T2 (de) | 1993-10-20 | 1999-09-16 | Sumitomo Chemical Co., Ltd. | Zusammensetzung aus statistischem Propylencopolymer |
| WO1995013305A1 (en) | 1993-11-08 | 1995-05-18 | Mobil Oil Corporation | Process for the polymerization or copolymerization of ethylene |
| DE69412576T3 (de) | 1993-12-21 | 2002-05-29 | Univation Technologies,Llc | Herstellung von Polyolefinen mit lankettiger Verzweigung nach einem Gasphaseverfahren |
| US5504223A (en) | 1994-01-25 | 1996-04-02 | The Dow Chemical Company | Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides |
| US5594080A (en) | 1994-03-24 | 1997-01-14 | Leland Stanford, Jr. University | Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor |
| DE69534436T2 (de) | 1994-04-07 | 2006-02-23 | Innovene Europe Limited, Sunbury On Thames | Copolymere |
| DE4416876A1 (de) | 1994-05-13 | 1995-11-16 | Basf Ag | Verfahren zur Herstellung von verbrückten Halbsandwichkomplexen |
| FR2719847B1 (fr) | 1994-05-16 | 1996-08-09 | Bp Chemicals Snc | Procédé de polymérisation d'oléfine en phase gazeuse. |
| IT1270256B (it) | 1994-06-20 | 1997-04-29 | Himont Inc | Composizioni poliolefiniche per fogli e film saldabili con radiofrequenze |
| ES2164157T3 (es) | 1994-06-24 | 2002-02-16 | Exxonmobil Chem Patents Inc | Compuestos monociclopentadienilo-metal para catalizadores de produccion de copolimeros etileno-alfa-olefinas. |
| EP0696616A3 (en) | 1994-07-11 | 1999-01-13 | Tonen Chemical Corporation | Polypropylene resin composition |
| US5461123A (en) | 1994-07-14 | 1995-10-24 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase fluidized bed polyolefin polymerization process using sound waves |
| DE4431644A1 (de) | 1994-08-01 | 1996-03-07 | Danubia Petrochem Deutschland | Katalysatorsystem und Verfahren zur Polymerisation von Olefinen |
| US5616664A (en) | 1994-08-02 | 1997-04-01 | The Dow Chemical Company | Polymerization process with biscyclopentadienyl diene complex containing catalysts |
| US5453471B1 (en) | 1994-08-02 | 1999-02-09 | Carbide Chemicals & Plastics T | Gas phase polymerization process |
| US5548042A (en) | 1994-08-19 | 1996-08-20 | Union Carbide Chemical & Plastics Technology Corporation | Process for the production of polypropylene |
| US5763534A (en) | 1994-08-25 | 1998-06-09 | Solvay Engineered Polymers | Thermoplastic polypropylene blends with mixtures of ethylene/butene and ethylene/octene copolymer elastomers |
| US5625087A (en) | 1994-09-12 | 1997-04-29 | The Dow Chemical Company | Silylium cationic polymerization activators for metallocene complexes |
| US5529965A (en) | 1994-10-28 | 1996-06-25 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
| CA2164461C (en) | 1994-12-06 | 2000-08-08 | Tatsuya Tanizaki | Polypropylene composition and uses thereof |
| JP3824325B2 (ja) | 1994-12-20 | 2006-09-20 | モンテル テクノロジー カンパニー ビーブイ | 反応体ブレンドのポリプロピレン、その製造法及びメタロセンリガンドの製造法 |
| JP3497029B2 (ja) | 1994-12-28 | 2004-02-16 | 三井化学株式会社 | 気相重合装置用ガス分散板 |
| US5645542A (en) | 1994-12-29 | 1997-07-08 | Kimberly-Clark Worldwide, Inc. | Elastomeric absorbent structure |
| AU729324B2 (en) | 1995-01-24 | 2001-02-01 | E.I. Du Pont De Nemours And Company | Alpha-olefins and olefin polymers and processes therefor |
| US5539056A (en) | 1995-01-31 | 1996-07-23 | Exxon Chemical Patents Inc. | Thermoplastic elastomers |
| US5516848A (en) | 1995-01-31 | 1996-05-14 | Exxon Chemical Patents Inc. | Process to produce thermoplastic elastomers |
| DE69602331T2 (de) | 1995-02-07 | 1999-10-14 | Mitsui Chemicals | Verfahren zur herstellung von polyolefin |
| FR2730999B1 (fr) | 1995-02-24 | 1997-04-18 | Bp Chemicals Snc | Appareillage et procede de polymerisation d'olefine en phase gazeuse |
| FR2731000B1 (fr) | 1995-02-24 | 1997-04-18 | Bp Chemicals Snc | Procede de polymerisation d'olefine en phase gazeuse |
| IT1275857B1 (it) | 1995-03-03 | 1997-10-24 | Spherilene Srl | Copolimeri atattici del propilene con l'etilene |
| US5616661A (en) | 1995-03-31 | 1997-04-01 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling particle growth during production of sticky polymers |
| US5637660A (en) | 1995-04-17 | 1997-06-10 | Lyondell Petrochemical Company | Polymerization of α-olefins with transition metal catalysts based on bidentate ligands containing pyridine or quinoline moiety |
| TW420692B (en) | 1995-06-26 | 2001-02-01 | Japan Polyolefins Co Ltd | Propylene block copolymer, process for preparation thereof and propylene resin composition comprising same |
| US5731253A (en) | 1995-07-27 | 1998-03-24 | Albemarle Corporation | Hydrocarbylsilloxy - aluminoxane compositions |
| US5869575A (en) | 1995-08-02 | 1999-02-09 | The Dow Chemical Company | Ethylene interpolymerizations |
| US5962714A (en) | 1995-10-02 | 1999-10-05 | Mccullough; Laughlin Gerard | Monocyclopentadienyl transition metal catalyst and olefin polymerization process |
| AT405286B (de) | 1995-10-16 | 1999-06-25 | Danubia Petrochem Polymere | Polypropylene mit reduzierter weissbruchneigung |
| US5728855A (en) | 1995-10-19 | 1998-03-17 | Akzo Nobel Nv | Modified polyalkylaluminoxane composition formed using reagent containing carbon-oxygen double bond |
| US5767208A (en) | 1995-10-20 | 1998-06-16 | Exxon Chemical Patents Inc. | High temperature olefin polymerization process |
| CN1158309C (zh) | 1995-12-18 | 2004-07-21 | 尤利维森技术公司 | 利用无载体催化剂的流化床反应系统的改进 |
| EP1063244A3 (en) | 1995-12-19 | 2003-11-26 | ExxonMobil Chemical Patents Inc. | High temperature olefin polymerization process |
| WO1997022639A1 (en) | 1995-12-19 | 1997-06-26 | Exxon Chemical Patents Inc. | High temperature solution polymerization process |
| US6074977A (en) | 1996-01-26 | 2000-06-13 | The Dow Chemical Company | Olefin addition polymerization catalyst composition |
| US6087446A (en) | 1996-03-20 | 2000-07-11 | Hercules Incorporated | Masterbatch formulations for polyolefin applications |
| CN1120849C (zh) | 1996-03-27 | 2003-09-10 | 陶氏环球技术公司 | 高度可溶性烯烃聚合反应催化活化剂 |
| CN1214698A (zh) | 1996-03-27 | 1999-04-21 | 陶氏化学公司 | 采用分散的催化剂活化剂进行的溶液聚合方法 |
| US5977251A (en) | 1996-04-01 | 1999-11-02 | The Dow Chemical Company | Non-adiabatic olefin solution polymerization |
| TW370537B (en) | 1996-05-03 | 1999-09-21 | Dsm Nv | Process for the preparation of an ethylene/α-olefin copolymer |
| US6403708B2 (en) | 1996-05-27 | 2002-06-11 | Mitsui Chemicals Inc | Crystalline polypropylenes, process for preparing thereof, polypropylene compositions, and thermoformed products |
| US5912302A (en) | 1996-06-11 | 1999-06-15 | Gadkari; Avinash Chandrakant | Elastomeric compositions and a process to produce elastomeric compositions |
| US5929147A (en) | 1996-06-18 | 1999-07-27 | Montell North America Inc. | Embrittlement-resistant polyolefin composition and flexible articles therefrom |
| WO1998003520A1 (en) | 1996-07-22 | 1998-01-29 | The Dow Chemical Company | Metal complexes containing bridged, non-aromatic, anionic, dienyl groups and addition polymerization catalysts therefrom |
| EP0854155A4 (en) | 1996-07-31 | 2002-01-02 | Japan Polyolefins Co Ltd | HIGH CRYSTALLINE POLYPROPYLENE |
| WO1998006727A1 (en) | 1996-08-08 | 1998-02-19 | The Dow Chemical Company | 3-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process |
| US6576306B2 (en) | 1996-09-04 | 2003-06-10 | Exxonmobil Chemical Patents Inc. | Propylene polymers for films |
| US6015868A (en) | 1996-10-03 | 2000-01-18 | The Dow Chemical Company | Substituted indenyl containing metal complexes and olefin polymerization process |
| US5910224A (en) | 1996-10-11 | 1999-06-08 | Kimberly-Clark Worldwide, Inc. | Method for forming an elastic necked-bonded material |
| CA2222076C (en) | 1996-11-26 | 2007-08-07 | Mitsui Chemicals, Incorporated | Polypropylene resin compositions |
| TW442528B (en) | 1996-12-02 | 2001-06-23 | Chisso Corp | Polypropylene composition |
| EP0846696B1 (en) | 1996-12-09 | 2003-06-18 | Mitsubishi Chemical Corporation | Catalyst for polymerization of alpha-olefins |
| US6245856B1 (en) | 1996-12-17 | 2001-06-12 | Exxon Chemical Patents, Inc. | Thermoplastic olefin compositions |
| US5965756A (en) | 1996-12-19 | 1999-10-12 | The Dow Chemical Company | Fused ring substituted indenyl metal complexes and polymerization process |
| US5703197A (en) | 1997-02-13 | 1997-12-30 | Molecular Optoelectronics Corporation | Indane polycarbonates |
| US5994482A (en) | 1997-03-04 | 1999-11-30 | Exxon Chemical Patents, Inc. | Polypropylene copolymer alloys and process for making |
| DE19757563A1 (de) * | 1997-03-07 | 1999-07-08 | Targor Gmbh | Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| CA2200373C (en) | 1997-03-19 | 2005-11-15 | Rupert Edward Von Haken Spence | Heteroligand |
| US5922822A (en) | 1997-04-09 | 1999-07-13 | Eastman Kodak Company | (2-(sulfonamidomethylene)-2-cyanoacetamido)phenyl acrylate polymers |
| CA2204803C (en) | 1997-05-08 | 2005-11-15 | Nova Chemicals Ltd. | Process to prepare bridged phosphole-cyclopentadienyl compounds |
| TW400341B (en) | 1997-05-22 | 2000-08-01 | Chisso Corp | Propyene polymer blends, processes of producing the same, and polypropylene resin compositions |
| CN1116315C (zh) | 1997-05-30 | 2003-07-30 | 株式会社宏大化纤 | 聚丙烯树脂组合物及注射成型制品 |
| US6342564B1 (en) | 1997-06-24 | 2002-01-29 | Borealis Technology Oy | Heterophasic propylene copolymer and process for its preparation |
| FI104824B (fi) | 1997-06-24 | 2000-04-14 | Borealis As | Menetelmä propeenin terpolymeerien aikaansaamiseksi |
| US6103657A (en) | 1997-07-02 | 2000-08-15 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
| US6268447B1 (en) | 1998-12-18 | 2001-07-31 | Univation Technologies, L.L.C. | Olefin polymerization catalyst |
| CA2210131C (en) | 1997-07-09 | 2005-08-02 | Douglas W. Stephan | Supported phosphinimine-cp catalysts |
| DE19729833A1 (de) | 1997-07-11 | 1999-01-14 | Clariant Gmbh | Polypropylenwachs |
| WO1999006412A1 (en) * | 1997-08-01 | 1999-02-11 | The Dow Chemical Company | Perfluoronaphthyl substituted boron containing catalyst activator |
| JP3852283B2 (ja) | 1997-08-12 | 2006-11-29 | チッソ株式会社 | オレフィン（共）重合体ならびにその応用 |
| US6635715B1 (en) * | 1997-08-12 | 2003-10-21 | Sudhin Datta | Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers |
| US7026404B2 (en) | 1997-08-12 | 2006-04-11 | Exxonmobil Chemical Patents Inc. | Articles made from blends made from propylene ethylene polymers |
| US6525157B2 (en) | 1997-08-12 | 2003-02-25 | Exxonmobile Chemical Patents Inc. | Propylene ethylene polymers |
| US6921794B2 (en) | 1997-08-12 | 2005-07-26 | Exxonmobil Chemical Patents Inc. | Blends made from propylene ethylene polymers |
| US7232871B2 (en) | 1997-08-12 | 2007-06-19 | Exxonmobil Chemical Patents Inc. | Propylene ethylene polymers and production process |
| TW482770B (en) | 1997-08-15 | 2002-04-11 | Chisso Corp | Propylene/ethylene random copolymer, molding material, and molded article |
| US6153702A (en) | 1997-09-12 | 2000-11-28 | Eastman Chemical Company | Polymers, and novel compositions and films therefrom |
| CA2215444C (en) | 1997-09-15 | 2005-08-02 | Stephen John Brown | Catalyst having a ketimide ligand |
| US6150297A (en) | 1997-09-15 | 2000-11-21 | The Dow Chemical Company | Cyclopentaphenanthrenyl metal complexes and polymerization process |
| KR20010023881A (ko) | 1997-09-18 | 2001-03-26 | 고또오 슈운기찌 | 폴리프로필렌 조성물 |
| US6323389B1 (en) | 1997-10-03 | 2001-11-27 | Kimberly-Clark Worldwide, Inc. | High performance elastic composite materials made from high molecular weight thermoplastic triblock elastomers |
| WO1999020663A2 (en) * | 1997-10-17 | 1999-04-29 | Exxon Chemical Patents Inc. | High impact, flexural moduli polymeric materials formed using sequential donors |
| US6197886B1 (en) | 1997-10-24 | 2001-03-06 | Union Carbide Chemicals & Plastics Technology Corporation | Compositions containing impact copolymers made from a blend of a homopolymer phase and a rubber phase having a high ethylene content |
| US6117962A (en) | 1997-12-10 | 2000-09-12 | Exxon Chemical Patents Inc. | Vinyl-containing stereospecific polypropylene macromers |
| US6518378B2 (en) | 1998-01-09 | 2003-02-11 | The Board Of Trustees Of The Leland Stanford Junior University | High-melting polyolefin copolymer elastomers, catalysts and methods of synthesis |
| AU2111599A (en) | 1998-01-09 | 1999-07-26 | Board Of Trustees Of The Leland Stanford Junior University | High-melting polyolefin copolymer elastomers, catalysts and methods of synthesis |
| JP4418107B2 (ja) | 1998-03-04 | 2010-02-17 | エクソンモービル・ケミカル・パテンツ・インク | 生成物及びポリオレフィンポリマー分散体を製造するための方法 |
| JP2002505353A (ja) * | 1998-03-04 | 2002-02-19 | エクソンモービル・ケミカル・パテンツ・インク | 高温オレフィン重合法 |
| US6034240A (en) | 1998-03-09 | 2000-03-07 | Symyx Technologies, Inc. | Substituted aminomethylphosphines, coordination complexes of aminomethylphosphines and their synthesis |
| US6190768B1 (en) | 1998-03-11 | 2001-02-20 | The Dow Chemical Company | Fibers made from α-olefin/vinyl or vinylidene aromatic and/or hindered cycloaliphatic or aliphatic vinyl or vinylidene interpolymers |
| DE19812229A1 (de) | 1998-03-20 | 1999-09-23 | Basf Ag | Polymere des Propens |
| US6211300B1 (en) | 1998-04-10 | 2001-04-03 | Chisso Corporation | Propylene-ethylene block copolymer compositions and processes for production thereof |
| AR016248A1 (es) | 1998-05-01 | 2001-06-20 | Dow Global Technologies Inc | Metodo para fabricar capas o laminas fibrosas por soplado en fusion, las laminas o capas de material asi obtenidas |
| AU4962399A (en) | 1998-07-01 | 2000-01-24 | Exxon Chemical Patents Inc. | Elastic blends comprising crystalline polymer and crystallizable polymers of propylene |
| EP1091984A1 (en) * | 1998-07-02 | 2001-04-18 | Exxon Chemical Patents Inc. | Propylene olefin copolymers |
| JP2002519484A (ja) | 1998-07-02 | 2002-07-02 | モンテル テクノロジー カンパニー ビーブイ | 実質的非晶質α−オレフィンポリマーの製造法とそれを含有する組成物および橋状リガンドの製造法 |
| US6225243B1 (en) | 1998-08-03 | 2001-05-01 | Bba Nonwovens Simpsonville, Inc. | Elastic nonwoven fabric prepared from bi-component filaments |
| US6037417A (en) | 1998-08-18 | 2000-03-14 | Montell Technology Company Bv | Polypropylene composition useful for making solid state oriented film |
| US6268063B1 (en) | 1998-08-25 | 2001-07-31 | Tokuyama Corporation | Propylene resin composition, process for the preparation thereof, and use thereof |
| DE19949235A1 (de) | 1998-10-16 | 2000-05-11 | Chisso Corp | Propylen/Ethylen/alpha-Olefin-Terpolymere und Verfahren zu ihrer Herstellung |
| DE69922536T2 (de) * | 1998-10-23 | 2005-12-15 | Exxonmobil Chemical Patents Inc., Baytown | Verbrückte hafnocenen für die copolymerisation von olefinen |
| US6300433B1 (en) | 1998-10-23 | 2001-10-09 | Exxonmobil Chemical Patents Inc. | Olefin copolymerization process with bridged hafnocenes |
| US6303719B1 (en) | 1998-12-18 | 2001-10-16 | Univation Technologies | Olefin polymerization catalyst system |
| KR100565151B1 (ko) | 1999-02-04 | 2006-03-30 | 미쓰이 가가쿠 가부시키가이샤 | 폴리프로필렌 블록 공중합체 수지 및 제조 방법 |
| JP3832129B2 (ja) | 1999-02-05 | 2006-10-11 | 株式会社プライムポリマー | ポリプロピレン樹脂組成物および射出成形品 |
| SE9901053L (sv) | 1999-03-23 | 2000-02-28 | Lind Finance & Dev Ab | Anordning vid verktygsspindel |
| JP2000281844A (ja) | 1999-03-31 | 2000-10-10 | Mitsui Chemicals Inc | オレフィン系樹脂組成物およびその成形体 |
| JP2000313777A (ja) | 1999-04-28 | 2000-11-14 | Idemitsu Petrochem Co Ltd | プロピレン系共重合体及び該共重合体を成形してなる成形体 |
| EP1505181B1 (en) | 1999-05-13 | 2008-10-29 | ExxonMobil Chemical Patents Inc. | Elastic fibers and articles made therefrom, including crystalline and crystallizable polymers of propylene |
| US6500563B1 (en) | 1999-05-13 | 2002-12-31 | Exxonmobil Chemical Patents Inc. | Elastic films including crystalline polymer and crystallizable polymers of propylene |
| US6340730B1 (en) | 1999-12-06 | 2002-01-22 | Univation Technologies, Llc | Multiple catalyst system |
| MXPA02005766A (es) | 1999-12-10 | 2004-08-12 | Dow Global Technologies Inc | Complejos sustituidos con metal del grupo 4, catalizadores y proceso de polimerizacion de olefinas. |
| US20020165329A1 (en) | 1999-12-10 | 2002-11-07 | Jerzy Klosin | Alkylphenyl-substituted group 4 metal complexes, catalysts and olefin polymerization process |
| US6825295B2 (en) | 1999-12-10 | 2004-11-30 | Dow Global Technologies Inc. | Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process |
| WO2001046277A2 (en) | 1999-12-22 | 2001-06-28 | Exxonmobil Chemical Patents, Inc. | Polypropylene-based adhesive compositions |
| US6492465B1 (en) | 2000-02-08 | 2002-12-10 | Exxonmobil Chemical Patents, Inc. | Propylene impact copolymers |
| US20020049288A1 (en) | 2000-04-04 | 2002-04-25 | Christopher Goh | Ether-amine based polymerization catalysts, compositions and processes using same |
| US6372847B1 (en) | 2000-05-10 | 2002-04-16 | Exxon Mobil Chemical Patents, Inc. | Polyolefin compositions having improved low temperature toughness |
| ATE431353T1 (de) | 2000-06-30 | 2009-05-15 | Dow Global Technologies Inc | Polyzyklische, kondensierte ringverbindungen, metallkomplexe und polymerisationsprozess |
| US6806327B2 (en) | 2000-06-30 | 2004-10-19 | Dow Global Technologies Inc. | Substituted polycyclic, fused ring compounds, metal complexes and polymerization process |
| US6673869B2 (en) | 2000-07-27 | 2004-01-06 | Basell Poliolefine Italia S.P.A. | Transparent elastomeric thermoplastic polyolefin compositions |
| US6750345B2 (en) | 2000-11-07 | 2004-06-15 | Symyx Technologies, Inc. | Substituted pyridyl amine catalysts, complexes and compositions |
-
2002
- 2002-04-02 JP JP2002582103A patent/JP5156167B2/ja not_active Expired - Lifetime
- 2002-04-02 EP EP02721670A patent/EP1390417B1/en not_active Expired - Lifetime
- 2002-04-02 WO PCT/US2002/010515 patent/WO2002083754A1/en not_active Ceased
- 2002-04-02 AT AT02721670T patent/ATE485319T1/de not_active IP Right Cessation
- 2002-04-02 DE DE60238049T patent/DE60238049D1/de not_active Expired - Lifetime
-
2007
- 2007-04-19 US US11/788,258 patent/US8026323B2/en not_active Expired - Lifetime
-
2011
- 2011-08-26 US US13/219,090 patent/US8501892B2/en not_active Expired - Fee Related
-
2012
- 2012-10-29 JP JP2012237938A patent/JP2013049863A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| WO2002083754A1 (en) | 2002-10-24 |
| EP1390417B1 (en) | 2010-10-20 |
| US8026323B2 (en) | 2011-09-27 |
| US8501892B2 (en) | 2013-08-06 |
| JP2004528447A (ja) | 2004-09-16 |
| ATE485319T1 (de) | 2010-11-15 |
| US20070244276A1 (en) | 2007-10-18 |
| US20110313117A1 (en) | 2011-12-22 |
| DE60238049D1 (de) | 2010-12-02 |
| EP1390417A1 (en) | 2004-02-25 |
| JP2013049863A (ja) | 2013-03-14 |
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