JP4912870B2 - アルキルベンゼンヒドロペルオキシドの製造方法 - Google Patents

アルキルベンゼンヒドロペルオキシドの製造方法 Download PDF

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Publication number
JP4912870B2
JP4912870B2 JP2006503496A JP2006503496A JP4912870B2 JP 4912870 B2 JP4912870 B2 JP 4912870B2 JP 2006503496 A JP2006503496 A JP 2006503496A JP 2006503496 A JP2006503496 A JP 2006503496A JP 4912870 B2 JP4912870 B2 JP 4912870B2
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Prior art keywords
oxidation
alkali metal
hydroperoxide
metal base
amount
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Japanese (ja)
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JP2006517968A5 (enExample
JP2006517968A (ja
Inventor
ブラツク，ジエシー・レイモンド
ヤン，ジエミン
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シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/08—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring monocyclic with no unsaturation outside the aromatic ring
    • C07C39/04—Phenol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
    • C07C409/08—Compounds containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
    • C07C409/08—Compounds containing six-membered aromatic rings
    • C07C409/10—Cumene hydroperoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2006503496A 2003-02-14 2004-02-11 アルキルベンゼンヒドロペルオキシドの製造方法 Expired - Fee Related JP4912870B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US44752603P 2003-02-14 2003-02-14
US60/447,526 2003-02-14
US10/761,641 US7141703B2 (en) 2003-02-14 2004-01-21 Process for producing phenol and ketone using neutralizing base
US10/761,641 2004-01-21
PCT/US2004/004010 WO2004074241A1 (en) 2003-02-14 2004-02-11 Process for producing alkylbenzene hydroperoxides

Publications (3)

Publication Number Publication Date
JP2006517968A JP2006517968A (ja) 2006-08-03
JP2006517968A5 JP2006517968A5 (enExample) 2011-04-14
JP4912870B2 true JP4912870B2 (ja) 2012-04-11

Family

ID=32853507

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2006503496A Expired - Fee Related JP4912870B2 (ja) 2003-02-14 2004-02-11 アルキルベンゼンヒドロペルオキシドの製造方法

Country Status (8)

Country Link
US (1) US7141703B2 (enExample)
EP (1) EP1594838A1 (enExample)
JP (1) JP4912870B2 (enExample)
KR (1) KR20050097550A (enExample)
BR (1) BRPI0407404A (enExample)
MY (1) MY139447A (enExample)
TW (1) TW200508188A (enExample)
WO (1) WO2004074241A1 (enExample)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007106747A (ja) * 2005-09-15 2007-04-26 Sumitomo Chemical Co Ltd アルキルベンゼンハイドロパーオキサイドの製造方法
US7326815B2 (en) * 2005-12-27 2008-02-05 Exxonmobil Chemical Patents Inc. Selective oxidation of alkylbenzenes
US7446232B2 (en) * 2006-08-03 2008-11-04 Exxonmobil Chemical Patents Inc. Process for oxidizing alkylaromatic compounds
US8581016B2 (en) * 2006-11-21 2013-11-12 Mitsui Chemicals, Inc. Process for producing alkylated aromatic compound and process for producing phenol
TW200846312A (en) * 2007-02-22 2008-12-01 Exxonmobil Chem Patents Inc Oxidation of sec-butylbenzene and production of phenol and methyl ethyl ketone
ATE509898T1 (de) 2007-02-23 2011-06-15 Mitsui Chemicals Inc Verfahren zur herstellung einer alkylierten aromatischen verbindung
CN101687784B (zh) * 2007-08-22 2014-11-12 埃克森美孚化学专利公司 烃的氧化
US8658836B2 (en) * 2007-10-31 2014-02-25 Exxonmobil Chemical Patents Inc. Oxidation of hydrocarbons
WO2011031374A2 (en) 2009-08-28 2011-03-17 Exxonmobil Chemical Patents Inc. Oxidation of hydrocarbons
JP2011500816A (ja) * 2007-10-31 2011-01-06 エクソンモービル・ケミカル・パテンツ・インク 炭化水素の酸化
KR101242254B1 (ko) 2008-06-10 2013-03-11 미쓰이 가가쿠 가부시키가이샤 알킬화 방향족 화합물의 제조방법 및 페놀의 제조방법
JP2011525195A (ja) * 2008-08-26 2011-09-15 エクソンモービル・ケミカル・パテンツ・インク アルキルベンゼンヒドロペルオキシドの製造方法
WO2010042273A1 (en) * 2008-10-10 2010-04-15 Exxonmobil Chemical Patents Inc. Oxidation of hydrocarbons
KR101320163B1 (ko) * 2008-10-23 2013-10-23 미쓰이 가가쿠 가부시키가이샤 알킬화 방향족 화합물의 제조 방법, 쿠멘의 제조 방법 및 페놀의 제조 방법
CN102227405A (zh) 2008-12-15 2011-10-26 埃克森美孚化学专利公司 烷基芳族化合物的氧化
JP5345203B2 (ja) 2009-03-19 2013-11-20 三井化学株式会社 アルキル化芳香族化合物の製造方法およびフェノールの製造方法

Family Cites Families (25)

* Cited by examiner, † Cited by third party
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US2632773A (en) * 1947-04-01 1953-03-24 Hercules Powder Co Ltd Manufacture of peroxidic compounds
US3187055A (en) * 1948-03-19 1965-06-01 Hercules Powder Co Ltd Manufacture of peroxidic compounds
US2632026A (en) * 1950-02-18 1953-03-17 Hercules Powder Co Ltd Oxidation of aromatic hydrocarbons
US2757209A (en) * 1951-04-26 1956-07-31 Allied Chem & Dye Corp Recovery of phenol and alphamethylstyrene from cumene oxidation reaction mixtures
NL136649C (enExample) * 1966-11-03
US3907901A (en) * 1969-07-14 1975-09-23 Allied Chem Continuous process for preparing cumene hydroperoxide
US4016213A (en) * 1971-05-03 1977-04-05 Allied Chemical Corporation Recovery of phenol, acetone and dimethyl phenyl carbinol from cumene oxidation product
DE2300903A1 (de) 1972-01-10 1973-08-02 Union Carbide Corp Verfahren zur herstellung von butylbenzolhydroperoxid und dessen verwendung zur herstellung von phenol, acetophenon und methylaethylketon
US4358618A (en) * 1981-06-22 1982-11-09 Allied Corporation Decomposition of cumene oxidation product
US4431849A (en) * 1981-10-21 1984-02-14 The Goodyear Tire & Rubber Company Process for preparing a methyl phenol
JPH0635407B2 (ja) * 1985-02-21 1994-05-11 三井石油化学工業株式会社 ２，６−ジイソプロピルナフタレンの酸化方法
JP2686490B2 (ja) * 1988-09-05 1997-12-08 三菱化学株式会社 クメンヒドロペルオキシドの精製方法
US4950794A (en) 1989-05-24 1990-08-21 Arco Chemical Technology, Inc. Ethylbenzene oxidation
JP3061394B2 (ja) 1990-04-02 2000-07-10 三井化学株式会社 クメンハイドロパーオキサイドの製造方法
TW226011B (enExample) * 1991-12-26 1994-07-01 Sumitomo Chemical Co
TW237445B (enExample) * 1992-07-07 1995-01-01 Sumitomo Chemical Co
US5254751A (en) * 1992-09-14 1993-10-19 General Electric Company Method for the decomposition of cumene hydroperoxide by acidic catalyst to phenol and acetone
RU2108318C1 (ru) * 1994-03-01 1998-04-10 Закошанский Владимир Михайлович СПОСОБ ПОЛУЧЕНИЯ ФЕНОЛА, АЦЕТОНА И α МЕТИЛСТИРОЛА
US5767322A (en) * 1996-06-27 1998-06-16 General Electric Company Cumene oxidation process
JP3391644B2 (ja) * 1996-12-19 2003-03-31 住友化学工業株式会社 ハイドロパーオキシドの抽出方法
US6077977A (en) * 1998-06-01 2000-06-20 General Electric Company Method for preparing hydroperoxides by oxygenation
CN1227202C (zh) 1998-09-04 2005-11-16 伊拉国际有限责任公司 苯酚和丙酮生产的高选择性方法
ES2247191T3 (es) * 2000-12-27 2006-03-01 Shell Internationale Research Maatschappij B.V. Procedimiento para preparar hidroperoxidos organicos con una cantidad reducida de contaminantes.
US6465695B1 (en) * 2001-07-27 2002-10-15 General Electric Company Method and system for manufacturing cumene hydroperoxide
US6486365B1 (en) * 2002-04-04 2002-11-26 General Electric Company Production and purification of phenol: hydroxyacetone removal by hydrotalcite

Also Published As

Publication number Publication date
BRPI0407404A (pt) 2006-02-21
WO2004074241A1 (en) 2004-09-02
US20040162448A1 (en) 2004-08-19
TW200508188A (en) 2005-03-01
US7141703B2 (en) 2006-11-28
KR20050097550A (ko) 2005-10-07
JP2006517968A (ja) 2006-08-03
EP1594838A1 (en) 2005-11-16
MY139447A (en) 2009-10-30

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